CN116234794A - 含氟聚合物的水性聚合反应中的低反应性烃分散剂 - Google Patents

含氟聚合物的水性聚合反应中的低反应性烃分散剂 Download PDF

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Publication number
CN116234794A
CN116234794A CN202180067243.5A CN202180067243A CN116234794A CN 116234794 A CN116234794 A CN 116234794A CN 202180067243 A CN202180067243 A CN 202180067243A CN 116234794 A CN116234794 A CN 116234794A
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hydrogen
butyl
ammonium
tert
groups
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English (en)
Chinese (zh)
Inventor
曾凡令
M·迪默
V·佛朗哥
S·福瑞克
S·J·盖蒂
D·D·哈斯尼斯
刘晓琳
A·A·马尔乔内
A·马茨内夫
B·W·梅斯莫尔
P·A·莫肯
C·帕里什
A·P·史密斯
E·P·凯里
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Chemours Co FC LLC
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Chemours Co FC LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C08F2/20—Suspension polymerisation with the aid of macromolecular dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F114/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F114/18—Monomers containing fluorine
    • C08F114/26—Tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/29—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings
    • C07C309/30—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings of six-membered aromatic rings substituted by alkyl groups
    • C07C309/31—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings of six-membered aromatic rings substituted by alkyl groups by alkyl groups containing at least three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/14—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/16—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C317/22—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/22—Vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/26—Tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/28—Hexafluoropropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/22—Vinylidene fluoride

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymerisation Methods In General (AREA)
CN202180067243.5A 2020-10-01 2021-09-30 含氟聚合物的水性聚合反应中的低反应性烃分散剂 Pending CN116234794A (zh)

Applications Claiming Priority (3)

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US202063086331P 2020-10-01 2020-10-01
US63/086331 2020-10-01
PCT/US2021/052961 WO2022072693A1 (en) 2020-10-01 2021-09-30 Low reactivity hydrocarbon dispersing agents in the aqueous polymerization of fluoropolymers

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CN116234794A true CN116234794A (zh) 2023-06-06

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US (1) US20240002553A1 (https=)
EP (1) EP4222141B1 (https=)
JP (1) JP2023543807A (https=)
CN (1) CN116234794A (https=)
ES (1) ES3039143T3 (https=)
WO (1) WO2022072693A1 (https=)

Families Citing this family (6)

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Publication number Priority date Publication date Assignee Title
MX2022004325A (es) * 2019-10-11 2022-09-19 Gujarat Fluorochemicals Ltd Proceso para preparar fluoropolímeros y fluoroelastómeros en presencia de un hidrocarburo de tipo sulfonato no fluorado que contiene tensioactivo.
CN115197105A (zh) * 2022-08-02 2022-10-18 江西瑞威尔生物科技有限公司 一种制备磺酰胺类化合物的合成工艺
CN121058094A (zh) 2023-02-07 2025-12-02 世索科特殊聚合物意大利有限公司 用于二次电池的粘合剂组合物
WO2025187824A1 (ja) * 2024-03-07 2025-09-12 ダイキン工業株式会社 フルオロポリマー水性分散液の製造方法
WO2025262979A1 (ja) * 2024-06-19 2025-12-26 Ａｇｃ株式会社 分散液の製造方法及び水性分散液の製造方法
CN118562034B (zh) * 2024-08-05 2024-10-18 黄山熠能科技有限公司 一种氟乙烯聚合方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040171726A1 (en) * 2003-02-03 2004-09-02 Joseph D'haenens Luk Germain Pierre Stabilized aqueous dispersion of fluoropolymer
US20080039599A1 (en) * 2006-08-11 2008-02-14 Libin Du Process of fluoromonomer polymerization
CN101903421A (zh) * 2007-11-09 2010-12-01 杜邦特性弹性体有限责任公司 制备含氟聚合物的方法
CN104844737A (zh) * 2008-01-22 2015-08-19 纳幕尔杜邦公司 制备含氟聚合物的方法
CN106054530A (zh) * 2015-04-13 2016-10-26 信越化学工业株式会社 使用新型鎓盐的化学增幅型负型抗蚀剂组合物和抗蚀剂图案形成方法
CN106188353A (zh) * 2010-11-09 2016-12-07 纳幕尔杜邦公司 使用烃表面活性剂的含氟单体的含水聚合
CN109337458A (zh) * 2018-09-13 2019-02-15 佛山科学技术学院 一种防水隔热保温涂料及其制备方法

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US703185A (en) 1902-01-20 1902-06-24 Alexander Clark Roadway for motor-vehicles.
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US4036802A (en) 1975-09-24 1977-07-19 E. I. Du Pont De Nemours And Company Tetrafluoroethylene copolymer fine powder resin
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4552631A (en) 1983-03-10 1985-11-12 E. I. Du Pont De Nemours And Company Reinforced membrane, electrochemical cell and electrolysis process
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US5637748A (en) 1995-03-01 1997-06-10 E. I. Du Pont De Nemours And Company Process for synthesizing fluorinated nitrile compounds
US5969067A (en) 1996-09-13 1999-10-19 E.I. Dupont De Nemours And Company Phosphorus-containing fluoromonomers and polymers thereof
US5866711A (en) 1996-09-13 1999-02-02 E. I. Du Pont De Nemours And Company Fluorocyanate and fluorocarbamate monomers and polymers thereof
CN1233267A (zh) 1996-10-15 1999-10-27 纳幕尔杜邦公司 含有高度氟化的离子交换聚合物颗粒的组合物
US6310141B1 (en) * 2000-06-27 2001-10-30 Dyneon Llc Fluoropolymer-containing compositions
US6512063B2 (en) 2000-10-04 2003-01-28 Dupont Dow Elastomers L.L.C. Process for producing fluoroelastomers
JP2002308914A (ja) * 2001-04-17 2002-10-23 Daikin Ind Ltd 含フッ素重合体ラテックスの製造方法
US7122610B2 (en) 2004-04-27 2006-10-17 Arkema Inc. Method of producing thermoplastic fluoropolymers using alkyl sulfonate surfactants
CA2584744C (en) * 2004-10-25 2013-09-24 The Lubrizol Corporation Star polymers and compositions thereof
US8080621B2 (en) 2005-06-10 2011-12-20 Arkema Inc. Aqueous process for making fluoropolymers
US20060281845A1 (en) 2005-06-10 2006-12-14 Ramin Amin-Sanayei Aqueous process for making fluoropolymers
US8338518B2 (en) 2005-06-10 2012-12-25 Arkema Inc. Aqueous process for making a stable fluoropolymer dispersion
EP1948706B1 (en) 2005-11-18 2012-09-19 E.I. Du Pont De Nemours And Company Core/shell polymer
JP5439186B2 (ja) 2006-11-09 2014-03-12 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フルオロポリエーテル酸または塩および炭化水素系界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合
US7521513B2 (en) 2006-11-29 2009-04-21 Dupont Performance Elastomers Llc Semi-batch process for producing fluoroelastomers
US20090281241A1 (en) 2008-05-09 2009-11-12 E. I. Du Pont De Nemours And Company Aqueous Polymerization of Fluorinated Monomer Using a Mixture of Fluoropolyether Acids or Salts
US8153738B2 (en) 2008-12-23 2012-04-10 E I Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
WO2012064858A1 (en) 2010-11-09 2012-05-18 E. I. Du Pont De Nemours And Company Reducing the telogenic behavior of hydrocarbon-containing surfactants in aqueous dispersion fluoromonomer polymerization
EP3533811B1 (en) 2010-11-09 2021-08-11 The Chemours Company FC, LLC Nucleation in aqueous polymerization of fluoromonomer
JP6222098B2 (ja) * 2012-10-19 2017-11-01 旭硝子株式会社 蓄電デバイス用バインダー組成物の製造方法
JP6622209B2 (ja) 2013-11-26 2019-12-18 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー フルオロモノマーの水性重合において核を形成するためのポリアルキレンオキシドの使用
MX2022004325A (es) * 2019-10-11 2022-09-19 Gujarat Fluorochemicals Ltd Proceso para preparar fluoropolímeros y fluoroelastómeros en presencia de un hidrocarburo de tipo sulfonato no fluorado que contiene tensioactivo.

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040171726A1 (en) * 2003-02-03 2004-09-02 Joseph D'haenens Luk Germain Pierre Stabilized aqueous dispersion of fluoropolymer
US20080039599A1 (en) * 2006-08-11 2008-02-14 Libin Du Process of fluoromonomer polymerization
CN101903421A (zh) * 2007-11-09 2010-12-01 杜邦特性弹性体有限责任公司 制备含氟聚合物的方法
CN104844737A (zh) * 2008-01-22 2015-08-19 纳幕尔杜邦公司 制备含氟聚合物的方法
CN106188353A (zh) * 2010-11-09 2016-12-07 纳幕尔杜邦公司 使用烃表面活性剂的含氟单体的含水聚合
CN106054530A (zh) * 2015-04-13 2016-10-26 信越化学工业株式会社 使用新型鎓盐的化学增幅型负型抗蚀剂组合物和抗蚀剂图案形成方法
CN109337458A (zh) * 2018-09-13 2019-02-15 佛山科学技术学院 一种防水隔热保温涂料及其制备方法

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WO2022072693A1 (en) 2022-04-07
EP4222141B1 (en) 2025-08-06
ES3039143T3 (en) 2025-10-17
JP2023543807A (ja) 2023-10-18
EP4222141A1 (en) 2023-08-09
US20240002553A1 (en) 2024-01-04

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