CN116134179A - 锂金属阳极和电池 - Google Patents

锂金属阳极和电池 Download PDF

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Publication number
CN116134179A
CN116134179A CN202180051530.7A CN202180051530A CN116134179A CN 116134179 A CN116134179 A CN 116134179A CN 202180051530 A CN202180051530 A CN 202180051530A CN 116134179 A CN116134179 A CN 116134179A
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China
Prior art keywords
lithium
lithium metal
conductive substrate
layer
ion selective
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Pending
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CN202180051530.7A
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English (en)
Chinese (zh)
Inventor
艾米莉·博多恩
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Pure Lithium Co
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Pure Lithium Co
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Publication of CN116134179A publication Critical patent/CN116134179A/zh
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/66—Electroplating: Baths therefor from melts
    • C25D3/665—Electroplating: Baths therefor from melts from ionic liquids
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/02—Electrolytic production, recovery or refining of metals by electrolysis of solutions of light metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/02—Electrolytic production, recovery or refining of metals by electrolysis of melts of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/04—Diaphragms; Spacing elements
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/06—Operating or servicing
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/54—Electroplating: Baths therefor from solutions of metals not provided for in groups C25D3/04 - C25D3/50
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562—Solid materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H01M4/045—Electrochemical coating; Electrochemical impregnation
    • H01M4/0452—Electrochemical coating; Electrochemical impregnation from solutions
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H01M4/382—Lithium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/663—Selection of materials containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/665—Composites
    • H01M4/667—Composites in the form of layers, e.g. coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/46—Separators, membranes or diaphragms characterised by their combination with electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
    • H01M50/497—Ionic conductivity
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Cell Separators (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
  • Primary Cells (AREA)
CN202180051530.7A 2020-08-28 2021-07-22 锂金属阳极和电池 Pending CN116134179A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US17/006,048 2020-08-28
US17/006,048 US11588146B2 (en) 2020-08-28 2020-08-28 Lithium metal anode and battery
PCT/US2021/042694 WO2022046327A1 (en) 2020-08-28 2021-07-22 Lithium metal anode and battery

Publications (1)

Publication Number Publication Date
CN116134179A true CN116134179A (zh) 2023-05-16

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN202180051530.7A Pending CN116134179A (zh) 2020-08-28 2021-07-22 锂金属阳极和电池

Country Status (9)

Country Link
US (2) US11588146B2 (cg-RX-API-DMAC7.html)
EP (1) EP4204610A1 (cg-RX-API-DMAC7.html)
JP (1) JP7894858B2 (cg-RX-API-DMAC7.html)
KR (1) KR20230058082A (cg-RX-API-DMAC7.html)
CN (1) CN116134179A (cg-RX-API-DMAC7.html)
AU (3) AU2021333283B2 (cg-RX-API-DMAC7.html)
CA (1) CA3188848A1 (cg-RX-API-DMAC7.html)
IL (2) IL326125A (cg-RX-API-DMAC7.html)
WO (1) WO2022046327A1 (cg-RX-API-DMAC7.html)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12100828B2 (en) 2021-01-29 2024-09-24 Pure Lithium Corporation Microscopically smooth substrates for lithium metal deposition
US12368155B2 (en) 2020-08-28 2025-07-22 Pure Lithium Corporation Lithium metal anode and battery
US12431480B2 (en) 2020-08-28 2025-09-30 Pure Lithium Corporation Methods for forming an energy storage device
US12027691B2 (en) 2020-08-28 2024-07-02 Pure Lithium Corporation Vertically integrated pure lithium metal production and lithium battery production
CA3218652A1 (en) * 2021-05-12 2022-11-17 Donald R. Sadoway Rechargeable battery and electrolysis method of making the same
TWI814308B (zh) 2022-03-28 2023-09-01 國立臺灣科技大學 增加電池電容量的連續製程設備
WO2024167863A1 (en) * 2023-02-06 2024-08-15 Pure Lithium Corporation Electrochemical welding of current collector to separator in electrochemical device
US12241171B2 (en) 2023-03-16 2025-03-04 Lyten, Inc. Membrane-based critical minerals purification system
US12012664B1 (en) 2023-03-16 2024-06-18 Lyten, Inc. Membrane-based alkali metal extraction system
US12148902B2 (en) 2023-03-16 2024-11-19 Lyten, Inc. Energy reclamation and carbon-neutral system for critical mineral extraction
WO2024211580A2 (en) * 2023-04-05 2024-10-10 Pure Lithium Corporation Liquid-liquid extraction system for electroactive metal electrodeposition from brine
EP4785397A2 (en) * 2023-08-25 2026-08-05 Pure Lithium Corporation Lithium metal battery
WO2025049328A1 (en) * 2023-08-25 2025-03-06 Pure Lithium Corporation Systems and methods for lithium electrodeposition from brine

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105556733A (zh) * 2013-08-12 2016-05-04 住友电气工业株式会社 锂离子二次电池、充放电系统和充电方法
CN107636204A (zh) * 2015-05-30 2018-01-26 清洁锂公司 高纯度锂和相关产品及方法
CN107864687A (zh) * 2015-06-18 2018-03-30 南加利福尼亚大学 混合锂离子的传导膜改善锂硫电池和其他储能装置的性能
US20180198170A1 (en) * 2015-10-15 2018-07-12 Ngk Insulators, Ltd. All-solid-state lithium battery

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4009052A (en) 1975-02-24 1977-02-22 Exxon Research And Engineering Company Chalcogenide battery
JPS59228360A (ja) * 1983-06-08 1984-12-21 Matsushita Electric Ind Co Ltd 有機電解質電池
US4781756A (en) 1987-07-02 1988-11-01 Lithium Corporation Of America Removal of lithium nitride from lithium metal
JPH02239574A (ja) * 1989-03-13 1990-09-21 Sanyo Electric Co Ltd 非水電解液二次電池
JPH06290773A (ja) * 1993-03-30 1994-10-18 Nippondenso Co Ltd リチウム二次電池
JP4329357B2 (ja) * 2003-02-24 2009-09-09 住友電気工業株式会社 リチウム二次電池負極部材、及びその製造方法
US20150014184A1 (en) 2013-07-10 2015-01-15 Lawence Ralph Swonger Producing lithium
WO2016187448A1 (en) * 2015-05-21 2016-11-24 The University Of North Carolina At Chapel Hill Hybrid solid single-ion-conducting electrolytes for alkali batteries
EP3384542A4 (en) * 2015-12-03 2019-07-10 alpha-En Corporation METHOD FOR PRODUCING A LITHIUM LAYER
CN109312030A (zh) 2016-06-17 2019-02-05 康奈尔大学 交联聚合材料
KR102699849B1 (ko) * 2017-03-29 2024-08-29 유니버시티 오브 매릴랜드, 칼리지 파크 고체 상태 하이브리드 전해질, 이의 제조 방법 및 이의 용도
US20190048483A1 (en) 2017-08-08 2019-02-14 Alpha-En Corporation Producing lithium directly from lithium feed sources
KR102268176B1 (ko) * 2017-08-28 2021-06-22 주식회사 엘지에너지솔루션 리튬 이차전지
WO2019144109A2 (en) 2018-01-22 2019-07-25 Alpha-En Corporation System and process for producing lithium
WO2020005657A1 (en) * 2018-06-29 2020-01-02 Applied Materials, Inc. Liquid lithium supply and regulation
US11111590B2 (en) 2018-09-18 2021-09-07 Uchicago Argonne, Llc Lithium metal synthesis
US11201324B2 (en) 2018-09-18 2021-12-14 Uchicago Argonne, Llc Production of lithium via electrodeposition
US12214319B2 (en) * 2018-09-18 2025-02-04 Uchicago Argonne, Llc Lithium ion conducting membranes
KR102745343B1 (ko) * 2018-10-30 2024-12-23 삼성전자주식회사 전고체 이차전지, 및 전고체 이차전지의 제조 방법
JP7686911B2 (ja) * 2019-01-29 2025-06-03 パイオトレック株式会社 導電ポリマー無機固体電解質二次電池の製造法
US20210381115A1 (en) * 2020-06-05 2021-12-09 Uchicago Argonne, Llc Production of lithium via electrodeposition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105556733A (zh) * 2013-08-12 2016-05-04 住友电气工业株式会社 锂离子二次电池、充放电系统和充电方法
CN107636204A (zh) * 2015-05-30 2018-01-26 清洁锂公司 高纯度锂和相关产品及方法
CN107864687A (zh) * 2015-06-18 2018-03-30 南加利福尼亚大学 混合锂离子的传导膜改善锂硫电池和其他储能装置的性能
US20180198170A1 (en) * 2015-10-15 2018-07-12 Ngk Insulators, Ltd. All-solid-state lithium battery

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US20220069282A1 (en) 2022-03-03
US11588146B2 (en) 2023-02-21
AU2021333283A1 (en) 2023-03-16
JP7894858B2 (ja) 2026-07-24
IL300513B2 (en) 2026-07-01
JP2023539844A (ja) 2023-09-20
KR20230058082A (ko) 2023-05-02
IL300513A (en) 2023-04-01
AU2021333283B2 (en) 2025-09-18
WO2022046327A1 (en) 2022-03-03
CA3188848A1 (en) 2022-03-03
IL326125A (en) 2026-03-01
AU2026203708A1 (en) 2026-05-28
US20230207779A1 (en) 2023-06-29
AU2025271196A1 (en) 2025-12-18
AU2025271196B2 (en) 2026-04-02
EP4204610A1 (en) 2023-07-05
IL300513B1 (en) 2026-03-01

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