CN116023636B - 一种半芳香族聚酯及其制备方法和应用 - Google Patents

一种半芳香族聚酯及其制备方法和应用 Download PDF

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Publication number
CN116023636B
CN116023636B CN202111249166.3A CN202111249166A CN116023636B CN 116023636 B CN116023636 B CN 116023636B CN 202111249166 A CN202111249166 A CN 202111249166A CN 116023636 B CN116023636 B CN 116023636B
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acid
reaction
temperature
polyester
component
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Chinese (zh)
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CN116023636A (zh
Inventor
张传辉
陈平绪
叶南飚
欧阳春平
麦开锦
董学腾
曾祥斌
卢昌利
蔡彤旻
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Zhuhai Wango Chemical Co ltd
Kingfa Science and Technology Co Ltd
Jiangsu Kingfa New Material Co Ltd
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Zhuhai Wango Chemical Co ltd
Kingfa Science and Technology Co Ltd
Jiangsu Kingfa New Material Co Ltd
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Application filed by Zhuhai Wango Chemical Co ltd, Kingfa Science and Technology Co Ltd, Jiangsu Kingfa New Material Co Ltd filed Critical Zhuhai Wango Chemical Co ltd
Priority to CN202111249166.3A priority Critical patent/CN116023636B/zh
Priority to EP22885675.3A priority patent/EP4421106A4/en
Priority to US18/704,468 priority patent/US20240425639A1/en
Priority to JP2024526880A priority patent/JP2024539401A/ja
Priority to PCT/CN2022/124852 priority patent/WO2023071796A1/zh
Priority to KR1020247017308A priority patent/KR20240090920A/ko
Publication of CN116023636A publication Critical patent/CN116023636A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4219—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from aromatic dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4216—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from mixtures or combinations of aromatic dicarboxylic acids and aliphatic dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids
    • C—CHEMISTRY; METALLURGY
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    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
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    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
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    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • C—CHEMISTRY; METALLURGY
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
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    • C—CHEMISTRY; METALLURGY
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    • C08G2230/00—Compositions for preparing biodegradable polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
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    • C—CHEMISTRY; METALLURGY
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    • C08L2203/00—Applications
    • C08L2203/12—Applications used for fibers
    • C—CHEMISTRY; METALLURGY
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    • C08L2205/00—Polymer mixtures characterised by other features
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  • Chemical & Material Sciences (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN202111249166.3A 2021-10-26 2021-10-26 一种半芳香族聚酯及其制备方法和应用 Active CN116023636B (zh)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CN202111249166.3A CN116023636B (zh) 2021-10-26 2021-10-26 一种半芳香族聚酯及其制备方法和应用
EP22885675.3A EP4421106A4 (en) 2021-10-26 2022-10-12 SEMI-AROMATIC POLYESTER AND PRODUCTION METHOD AND USE THEREOF
US18/704,468 US20240425639A1 (en) 2021-10-26 2022-10-12 Semi-aromatic polyester, and preparation method therefor and use thereof
JP2024526880A JP2024539401A (ja) 2021-10-26 2022-10-12 半芳香族ポリエステルおよびその調製方法と応用
PCT/CN2022/124852 WO2023071796A1 (zh) 2021-10-26 2022-10-12 一种半芳香族聚酯及其制备方法和应用
KR1020247017308A KR20240090920A (ko) 2021-10-26 2022-10-12 반방향족 폴리에스테르 및 이의 제조 방법과 응용

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CN116023636B true CN116023636B (zh) 2025-03-25

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EP (1) EP4421106A4 (https=)
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Publication number Priority date Publication date Assignee Title
CN113683763B (zh) * 2021-10-26 2022-09-13 江苏金发科技新材料有限公司 一种半芳香族聚酯及其制备方法和应用
CN115873222B (zh) * 2022-12-08 2024-05-14 金发科技股份有限公司 一种可生物降解聚酯组合物及其制备方法和应用
CN118206726A (zh) * 2024-04-25 2024-06-18 金发科技股份有限公司 一种脂肪族-芳香族共聚酯及其制备方法和应用

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CN112280026A (zh) * 2020-12-31 2021-01-29 江苏金发科技新材料有限公司 一种半芳香族聚酯及其制备方法和应用

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KR101992391B1 (ko) * 2012-09-04 2019-09-30 (주)새한폴리머 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법
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CN103881072B (zh) * 2012-12-22 2016-05-11 北京化工大学 可生物降解脂肪族—芳香族嵌段混合聚酯的制备方法
CN103709679B (zh) * 2013-11-29 2016-02-10 金发科技股份有限公司 一种改性脂肪族-芳香族共聚酯及其制备方法和应用
CN113683763B (zh) * 2021-10-26 2022-09-13 江苏金发科技新材料有限公司 一种半芳香族聚酯及其制备方法和应用

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CN112280026A (zh) * 2020-12-31 2021-01-29 江苏金发科技新材料有限公司 一种半芳香族聚酯及其制备方法和应用

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CN116023636A (zh) 2023-04-28
KR20240090920A (ko) 2024-06-21
WO2023071796A1 (zh) 2023-05-04
EP4421106A4 (en) 2025-03-12
US20240425639A1 (en) 2024-12-26
JP2024539401A (ja) 2024-10-28
EP4421106A1 (en) 2024-08-28

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