CN115975459B - Stain-resistant sand-falling-preventing stone-like paint containing traditional Chinese medicine components and preparation method thereof - Google Patents
Stain-resistant sand-falling-preventing stone-like paint containing traditional Chinese medicine components and preparation method thereof Download PDFInfo
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- CN115975459B CN115975459B CN202211719192.2A CN202211719192A CN115975459B CN 115975459 B CN115975459 B CN 115975459B CN 202211719192 A CN202211719192 A CN 202211719192A CN 115975459 B CN115975459 B CN 115975459B
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- 239000003973 paint Substances 0.000 title claims abstract description 89
- 239000003814 drug Substances 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000004576 sand Substances 0.000 claims abstract description 65
- 241000723346 Cinnamomum camphora Species 0.000 claims abstract description 64
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000007788 liquid Substances 0.000 claims abstract description 40
- 229920006217 cellulose acetate butyrate Polymers 0.000 claims abstract description 30
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- 239000002994 raw material Substances 0.000 claims abstract description 17
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- 238000000034 method Methods 0.000 claims abstract description 7
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 12
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- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 2
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- 239000004480 active ingredient Substances 0.000 description 6
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 6
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 6
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
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- 239000013530 defoamer Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 3
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 3
- 239000005770 Eugenol Substances 0.000 description 3
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 description 3
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 3
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- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 3
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229930006739 camphene Natural products 0.000 description 3
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 description 3
- 229930008380 camphor Natural products 0.000 description 3
- 229960000846 camphor Drugs 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 3
- 229960002217 eugenol Drugs 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
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- 239000011550 stock solution Substances 0.000 description 3
- 229940116411 terpineol Drugs 0.000 description 3
- 238000003809 water extraction Methods 0.000 description 3
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 2
- HPUZPAIWNCLQGV-UHFFFAOYSA-N 1-(2-butoxyethoxy)propan-1-ol Chemical compound CCCCOCCOC(O)CC HPUZPAIWNCLQGV-UHFFFAOYSA-N 0.000 description 2
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 244000248349 Citrus limon Species 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
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- 238000002474 experimental method Methods 0.000 description 2
- 229940051250 hexylene glycol Drugs 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
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- 239000003921 oil Substances 0.000 description 2
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- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 1
- 229920000875 Dissolving pulp Polymers 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- UGZICOVULPINFH-UHFFFAOYSA-N acetic acid;butanoic acid Chemical compound CC(O)=O.CCCC(O)=O UGZICOVULPINFH-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 229940025250 camphora Drugs 0.000 description 1
- 239000010238 camphora Substances 0.000 description 1
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- 239000000498 cooling water Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
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- 238000011010 flushing procedure Methods 0.000 description 1
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- 239000010438 granite Substances 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention provides an anti-pollution anti-falling sand stone-like paint containing traditional Chinese medicine components and a preparation method thereof, and belongs to the technical field of stone-like paint. The cellulose acetate butyrate in the stone paint raw material has the effect of rapid setting, can improve the drying rate and avoids the phenomenon of bloom; the inorganic gel has good effect of coating ceramic color sand, and can reduce the sand dropping rate of the real stone paint; the hydrogenated silicone oil can be condensed into high molecular siloxane with low surface tension in the process of forming the membrane of the real stone paint, a layer of siloxane film is formed in the pores of the real stone paint and is dispersed on the pore wall, so that the channel cannot be blocked, and the membrane has good waterproof performance and long-term water and oil repellency; according to the invention, the oak medicinal liquid, which is a traditional Chinese medicine component, is added into the raw materials of the real stone paint, so that on one hand, the camphor tree medicinal liquid can serve as a thinner to dilute and dissolve cellulose acetate butyrate and inorganic gel; on the other hand, the camphor tree liquid medicine can also have the effects of purifying air and preventing mosquitoes.
Description
Technical Field
The invention relates to the technical field of stone paint, in particular to an anti-pollution and anti-falling sand stone paint containing traditional Chinese medicine components and a preparation method thereof.
Background
The stone-like paint is a kind of paint with decorative effect similar to marble and granite, and is mainly made up by using natural stone powder with various colours. The building decorated by the real stone paint has natural and true natural color, gives people the aesthetic feeling of elegance, harmony and manor, and is suitable for indoor and outdoor decorations of various buildings.
The stone paint comprises natural stone paint, texture paint, ceramic color sand stone paint and color-mixing stone paint, and the problems of sand falling, flower formation and easy dirtying of the coating exist in any stone paint. Because the main component of the real stone paint is inorganic particles, sand falling is an unavoidable phenomenon, and the sand falling rate becomes the most concern of the real stone paint market. The sprayed stone paint can not be used for half a year, so that a lot of dust can be accumulated on the surface, flushing marks appear after raining, and meanwhile, the phenomenon of flowery appears. Meanwhile, mosquitoes are adsorbed on the surface of the outer wall, and the dead mosquitoes are left on the surface of the stone paint when raining and snowing, so that the attractiveness is affected.
Disclosure of Invention
In view of the above, the invention aims to provide the anti-pollution and anti-falling sand stone paint containing the traditional Chinese medicine components and the preparation method thereof.
In order to achieve the above object, the present invention provides the following technical solutions:
the invention provides an anti-fouling and anti-falling sand stone-like paint containing traditional Chinese medicine components, which comprises the following components in percentage by mass:
the mass concentration of the camphor tree effective active ingredient in the camphor tree medicinal liquid is 9.5-10.5%.
The preparation method of the camphor tree medicinal liquid comprises the following steps of:
mixing the camphor tree raw material with water, heating and extracting to obtain camphor tree medicinal liquid;
the mass ratio of the camphor tree raw material to the water is 0.8-1:3-3.2.
Preferably, the preparation method of the ceramic colored sand comprises the following steps:
mixing spherical white jade, dye and inorganic binder, and sintering to obtain ceramic colored sand;
the mass ratio of the spherical white jade to the dye to the inorganic binder is 1000:10-20:10-20;
the sintering temperature is 1000-1500 ℃, and the heat preservation time is 25-30 min.
Preferably, the solid content of the silicone-acrylic emulsion is 38-48 wt%.
Preferably, the inorganic gel is magnesium aluminum silicate and/or montmorillonite;
the particle size of the inorganic gel is 200-325 meshes.
Preferably, the particle size of the rutile titanium dioxide is 0.2-0.3 mu m; the particle size of the calcined kaolin is 800-1500 meshes.
Preferably, the aqueous dispersing agent is one or more of a polycarboxylic acid sodium salt type dispersing agent, an anionic dispersing agent and a nonionic dispersing agent;
the film forming auxiliary agent is one or more of alcohol ester twelve, ethylene glycol, propylene glycol, hexanediol, ethylene glycol diethyl ether acetate, butoxyethoxypropanol, propylene glycol propyl ether, propylene glycol butyl ether, ethylene glycol butyl ether acetate and diacetic acid hexanediol ester;
the aqueous amine auxiliary agent is a ceramic AMP95;
the thixotropic anti-settling agent is one or more of cellulose ether thickening agent, associative alkali swelling thickening agent and polyurethane thickening agent.
The invention provides a preparation method of the anti-fouling and anti-falling sand stone-like paint containing traditional Chinese medicine components, which comprises the following steps:
(1) Mixing a part of camphor tree liquid medicine with cellulose acetate butyrate to obtain a cellulose acetate butyrate solution;
(2) Mixing the residual camphor tree liquid medicine with inorganic gel to obtain inorganic gel solution;
(3) Mixing the silicone-acrylic emulsion, the cellulose acetate butyrate solution, the water-based dispersing agent, the water-based defoaming agent, the water-based amine auxiliary agent and the hydrogenated silicone oil to obtain a first mixture;
(4) Mixing the first mixture with an inorganic gel solution, rutile type titanium dioxide and calcined kaolin to obtain a second mixture;
(5) Mixing the second mixture with ceramic colored sand, epoxy colored sand to obtain a third mixture;
(6) Mixing the third mixture with a bactericide, an antifreezing agent, a film forming auxiliary agent and a thixotropic anti-settling agent to obtain the anti-fouling anti-falling sand stone-like paint containing traditional Chinese medicine components;
there is no limitation on the time sequence between the steps (1) to (2).
Preferably, the mixing rate in the steps (1), (2), (4), (5) and (6) is independently 800-1000 rpm.
Preferably, the mixing rate in the step (3) is 300-400 rpm.
The invention provides an anti-fouling and anti-falling sand stone-like paint containing traditional Chinese medicine components, which comprises the following components in percentage by mass: 4.85 to 7.6 percent of camphor tree liquid medicine; 62-70% of ceramic color sand; 13-17% of silicone-acrylic emulsion; cellulose acetate butyrate 0.5-1%; 0.5 to 1 percent of inorganic gel; 0.5 to 1 percent of hydrogenated silicone oil; 1-2% of rutile titanium dioxide; 3-5% of calcined kaolin; 0.2 to 0.5 percent of water-based dispersing agent; 0.05 to 0.1 percent of bactericide; 0.1 to 0.2 percent of water-based defoaming agent; 1-3% of antifreezing agent; 0.5 to 1 percent of film forming auxiliary agent; 0.5 to 1 percent of aqueous amine auxiliary agent; 1-2% of thixotropic anti-settling agent; the mass concentration of the camphor tree effective active ingredient in the camphor tree medicinal liquid is 9.5-10.5%. According to the invention, the cellulose acetate butyrate is added into the raw material of the real stone paint, has excellent directional arrangement, quick drying and strong water release capacity, and the real stone paint can be quickly shaped and fixed with the help of the cellulose acetate butyrate, so that the water release is facilitated, the drying speed of the coating is improved, and the phenomenon of paint bloom is solved. According to the invention, the inorganic gel is added, so that the ceramic color sand coating effect is good, and the sand dropping rate of the real stone paint can be reduced. According to the invention, by adding the hydrogenated silicone oil, the hydrogenated silicone oil can be condensed into high molecular siloxane with low surface tension in the process of forming the film of the real stone paint, a layer of siloxane film is formed in the pores of the real stone paint and is dispersed on the pore walls, so that the pore walls are not blocked, and the high molecular siloxane has good waterproof performance. The anti-fouling paint can prevent damage of the real stone paint caused by water seepage, and endow the real stone paint with good long-term water and oil repellency, so that the real stone paint has good anti-fouling property. According to the invention, the oak medicinal liquid, which is a traditional Chinese medicine component, is added into the raw materials of the real stone paint, so that on one hand, the camphor tree medicinal liquid can serve as a thinner to dilute and dissolve cellulose acetate butyrate and inorganic gel; on the other hand, the camphor tree liquid medicine contains camphor, camphene, terpineol, lemon hydrocarbon and eugenol, and can be used as a raw material of the real stone paint to achieve the effects of purifying air and preventing mosquitoes.
The invention provides the preparation method of the anti-fouling and anti-falling sand stone-like paint containing the traditional Chinese medicine components, which is simple to operate, low in cost and suitable for industrialized mass production.
Detailed Description
The invention provides an anti-fouling and anti-falling sand stone-like paint containing traditional Chinese medicine components, which comprises the following components in percentage by mass:
the mass concentration of the camphor tree effective active ingredient in the camphor tree medicinal liquid is 9.5-10.5%.
The stain-resistant sand-falling-preventing stone-like paint containing traditional Chinese medicine components comprises 4.85-7.6% of camphor tree liquid medicine, preferably 5-7% of camphor tree liquid medicine, and more preferably 5.2-5.6% of camphor tree liquid medicine. In the invention, the mass concentration of the camphor tree effective active ingredient in the camphor tree liquid medicine is 9.5-10.5%, preferably 10%. In the invention, the camphor tree effective active ingredient comprises one or more of camphor, camphene, terpineol, limonene and eugenol.
In the invention, the preparation method of the camphor tree medicinal liquid preferably comprises the following steps of:
mixing the camphor tree raw material with water, heating and extracting to obtain camphor tree medicinal liquid.
In the invention, the camphor tree raw material is preferably camphor tree branches and/or camphor tree roots. The camphor tree raw material is preferably cleaned and dried.
In the invention, the mass ratio of the camphor tree raw material to water is preferably 0.8-1:3-3.2, and more preferably 1:3. In the present invention, the temperature of the heated water extraction is preferably 95 to 100 ℃, more preferably 100 ℃; the time is preferably 2 to 2.5 hours, more preferably 2 hours. After the heated water extraction, the invention preferably filters the obtained heated water extraction liquid to obtain camphor tree medicinal water stock solution. In the present invention, the pore size of the filter screen used for the filtration is preferably 200 mesh.
In the invention, the obtained camphor tree medicinal water stock solution is microscopic yellow, and the pH value is 7.5+/-0.5. The concentration of the camphor tree medicinal liquid stock solution is preferably regulated by deionized water, so that the mass concentration of the camphor tree active ingredient in the camphor tree medicinal liquid is 9.5-10.5%.
In the invention, on one hand, camphor tree medicinal water can be used as a thinner material to play roles in diluting and dissolving cellulose acetate butyrate and inorganic gel; on the other hand, the camphor tree liquid medicine contains camphor, camphene, terpineol, lemon hydrocarbon and eugenol, and can be used as a raw material of the real stone paint to achieve the effects of purifying air and preventing mosquitoes.
The anti-fouling and anti-falling sand stone-like paint containing the traditional Chinese medicine components comprises, by mass, 62-70% of ceramic colored sand, preferably 64-68%, and more preferably 65-66%. In the invention, the ceramic colored sand is obtained by sintering spherical white jade, dye and binder. In the invention, the preparation method of the ceramic colored sand preferably comprises the following steps:
mixing spherical white jade, dye and inorganic binder, and sintering to obtain ceramic colored sand.
In the present invention, the particle size of the spherical white jade is preferably 20 to 120 mesh, more preferably 50 to 100 mesh. In the present invention, the inorganic binder is preferably SiO 2 、ZrO 2 And TiO 2 One or more of them.
In the invention, the mass ratio of the spherical white jade to the dye to the inorganic binder is preferably 1000:10-20:10-20, more preferably 1000:15-18:15-18.
In the present invention, the sintering temperature is preferably 1000 to 1500 ℃, more preferably 1200 to 1400 ℃, and the holding time is preferably 25 to 30min, more preferably 26 to 28min.
In the present invention, the present invention preferably filters, washes and dries the obtained ceramic colored sand after the sintering. The present invention preferably uses a 60 mesh filter screen for filtration. In the present invention, the detergent used for the washing is preferably ethanol; the drying mode is preferably air drying.
The anti-fouling and anti-falling sand stone-like paint containing the traditional Chinese medicine components comprises 13-17% of silicone-acrylic emulsion, preferably 14-16% of silicone-acrylic emulsion, and more preferably 15% of silicone-acrylic emulsion. In the present invention, the solids content of the silicone-acrylic emulsion is preferably 38 to 48wt%, more preferably 40 to 45wt%. In the invention, the silicone-acrylic emulsion plays a role of film formation.
The anti-fouling and anti-falling sand stone-like paint containing the traditional Chinese medicine components comprises 0.5-1% of cellulose acetate butyrate, preferably 0.6-0.8% by mass. In the invention, the cellulose acetate butyrate has the effect of quick qualitative, can improve the drying rate and avoids the phenomenon of bloom.
The anti-fouling and anti-falling sand stone-like paint containing traditional Chinese medicine components comprises 0.5-1% of inorganic gel, preferably 0.6-0.8% by mass. In the present invention, the inorganic gel is preferably magnesium aluminum silicate; the particle size of the inorganic gel is preferably 200 to 325 mesh. In the invention, the inorganic gel has good effect of coating ceramic color sand, and can reduce the sand dropping rate of the real stone paint.
The stain-resistant sand-falling-preventing stone-like paint containing traditional Chinese medicine components comprises 0.5-1% of hydrogenated silicone oil, preferably 0.6-0.8% by mass. In the invention, the hydrogenated silicone oil can be condensed into high molecular siloxane with low surface tension in the process of forming the membrane of the real stone paint, a layer of siloxane film is formed in the pores of the real stone paint and is dispersed on the pore wall, so that the channel is not blocked, and the membrane has good waterproof performance. The anti-fouling paint can prevent damage of the real stone paint caused by water seepage, and endow the real stone paint with good long-term water and oil repellency, so that the real stone paint has good anti-fouling property.
The anti-fouling and anti-falling sand stone-like paint containing traditional Chinese medicine components comprises 1-2% of rutile titanium dioxide, preferably 1.2-1.8%, and more preferably 1.5% by mass. In the invention, the particle size of the rutile titanium dioxide is preferably 0.2-0.3 mu m. In the invention, the rutile titanium dioxide has the function of enhancing the covering power and the coating rate of the real stone paint.
The stain-resistant sand-falling-preventing stone-like paint containing traditional Chinese medicine components comprises 3-5% of calcined kaolin, preferably 3.5-4.5%, and more preferably 4% by mass. In the present invention, the particle size of the calcined kaolin is preferably 800 to 1500 mesh, more preferably 1000 to 1200 mesh. In the invention, the calcined kaolin has the function of acting together with the titanium dioxide, so that the covering power of the paint is obviously improved.
The anti-fouling and anti-falling sand stone-like paint containing the traditional Chinese medicine components comprises 0.2-0.5% of water-based dispersing agent, preferably 0.3-0.4% by mass. In the present invention, the aqueous dispersant is preferably one or more of a polycarboxylic acid sodium salt type dispersant, an anionic dispersant and a nonionic dispersant.
The stain-resistant sand-falling-preventing stone-like paint containing traditional Chinese medicine components comprises 0.05-0.1% of bactericide, preferably 0.06-0.08% by mass. In the present invention, the bactericide is preferably one or more of an inorganic bactericide, an organic sulfur bactericide, an organic phosphorus bactericide, an organic arsenic bactericide, an azole bactericide and an antibiotic bactericide. In the present invention, the type of the bactericide is preferably Guangdong Dimei 206.
The anti-fouling and anti-falling sand stone-like paint containing traditional Chinese medicine components comprises 0.1-0.2% of water-based defoamer, preferably 0.12-0.18% of water-based defoamer, and more preferably 0.15% of water-based defoamer. In the present invention, the aqueous defoaming agent is preferably one or more of a lower alcohol or ester type defoaming agent, an organic polar compound type defoaming agent, a mineral oil type defoaming agent and an organosilicon type defoaming agent, more preferably a mineral oil type defoaming agent. In the present invention, the aqueous antifoaming agent is preferably of the type basf a111.
The stain-resistant sand-falling-preventing stone-like paint containing traditional Chinese medicine components comprises 1-3% of antifreezing agent, preferably 1.5-2.5%, and more preferably 2%. In the invention, the model of the antifreezing agent is preferably Roditia FT-100.
The anti-fouling and anti-falling sand stone-like paint containing traditional Chinese medicine components comprises 0.5-1% of film forming auxiliary agent, preferably 0.6-0.8% by mass. In the present invention, the film forming auxiliary agent is preferably one or more of alcohol ester twelve, ethylene glycol, propylene glycol, hexylene glycol, ethylene glycol diethyl ether acetate, butoxyethoxypropanol, propylene glycol propyl ether, propylene glycol butyl ether, ethylene glycol butyl ether acetate and diacetic acid hexylene glycol ester.
The stain-resistant sand-falling-preventing stone-like paint containing traditional Chinese medicine components comprises 0.5-1% of aqueous amine auxiliary agent, and more preferably 0.6-0.8% by mass. In the present invention, the main component of the aqueous amine auxiliary is preferably 2-amino-2-methyl-1-propanol. . In the present invention, the aqueous amine auxiliary is preferably of the type of Dow AMP95. In the invention, the function of the aqueous amine auxiliary agent is to adjust the pH value of the real stone paint.
The anti-fouling and anti-falling sand stone-like paint containing the traditional Chinese medicine components comprises 1-2% of thixotropic anti-settling agent, preferably 1.2-1.8% of thixotropic anti-settling agent and more preferably 1.5% of anti-fouling and anti-falling sand stone-like paint containing the traditional Chinese medicine components. In the invention, the thixotropic anti-settling agent is preferably one or more of cellulose ether thickening agent, associative alkali swelling thickening agent and polyurethane thickening agent. In the present invention, the thixotropic anti-settling agent is preferably of the type AC603 of the schottky. In the invention, the thixotropic anti-settling agent mainly plays roles of preventing settling, increasing the viscosity and thixotropy of the paint, so that the sprayed real stone paint can be shaped on a wall surface and cannot drop and flow.
The invention provides a preparation method of the anti-fouling and anti-falling sand stone-like paint containing traditional Chinese medicine components, which comprises the following steps:
(1) Mixing a part of camphor tree liquid medicine with cellulose acetate butyrate to obtain a cellulose acetate butyrate solution;
(2) Mixing the residual camphor tree liquid medicine with inorganic gel to obtain inorganic gel solution;
(3) Mixing the silicone-acrylic emulsion, the cellulose acetate butyrate solution, the water-based dispersing agent, the water-based defoaming agent, the water-based amine auxiliary agent and the hydrogenated silicone oil to obtain a first mixture;
(4) Mixing the first mixture with an inorganic gel solution, rutile type titanium dioxide and calcined kaolin to obtain a second mixture;
(5) Mixing the second mixture with ceramic colored sand, epoxy colored sand to obtain a third mixture;
(6) Mixing the third mixture with a bactericide, an antifreezing agent, a film forming auxiliary agent and a thixotropic anti-settling agent to obtain the anti-fouling anti-falling sand stone-like paint containing traditional Chinese medicine components;
there is no limitation on the time sequence between the steps (1) to (2).
According to the invention, a part of camphor tree liquid medicine is mixed with cellulose acetate butyrate to obtain a cellulose acetate butyrate solution. In the present invention, the part of the camphor tree liquid accounts for 10 to 30% of the total mass of the camphor tree liquid, more preferably 15 to 25%.
In the present invention, the mixing means is preferably stirring mixing; the rotational speed of the mixing is preferably 800 to 1000 rpm, more preferably 900 rpm; the invention has no special requirement on the mixing time, and can ensure that the cellulose acetate butyrate is completely dissolved. In the present invention, the concentration of the cellulose acetate butyrate solution is preferably 18 to 22wt%, more preferably 20wt%.
The invention mixes the residual camphor tree liquid medicine with inorganic gel to obtain inorganic gel solution. In the present invention, the mixing means is preferably stirring mixing; the rotational speed of the mixing is preferably 800 to 1000 rpm, more preferably 900 rpm. In the present invention, the concentration of the inorganic gel solution is preferably 18 to 22wt%, more preferably 20wt%.
The preparation method comprises the steps of mixing silicone-acrylic emulsion, cellulose acetate butyrate solution, a water-based dispersing agent, a water-based defoaming agent, a water-based amine auxiliary agent and hydrogenated silicone oil to obtain a first mixture. In the present invention, the mixing means is preferably stirring mixing; the rotational speed of the mixing is preferably 300 to 400 rpm, more preferably 350 rpm, and the time is preferably 5 to 10min, more preferably 6 to 8min.
The first mixture is mixed with an inorganic gel solution, rutile type titanium dioxide and calcined kaolin to obtain a second mixture. In the present invention, the mixing means is preferably stirring mixing; the rotational speed of the mixing is preferably 800 to 1000 rpm, more preferably 900 rpm, and the time is preferably 5 to 10min, more preferably 6 to 8min.
The second mixture is mixed with ceramic colored sand, epoxy colored sand, and a third mixture is obtained. In the present invention, the mixing means is preferably stirring mixing. In the present invention, the rotational speed of the mixing is preferably 800 to 1000 rpm, more preferably 900 rpm, and the time is preferably 30 to 40min, more preferably 35min.
According to the invention, the third mixture is mixed with the bactericide, the antifreezing agent, the film forming auxiliary agent and the thixotropic anti-settling agent to obtain the anti-fouling anti-falling sand real stone paint containing the traditional Chinese medicine components. In the present invention, the mixing means is preferably stirring mixing; the rotational speed of the mixing is preferably 800 to 1000 rpm, more preferably 900 rpm, and the time is preferably 10 to 15min, more preferably 12 to 14min.
The anti-fouling and anti-falling sand stone paint containing traditional Chinese medicine components and the preparation method thereof provided by the invention are described in detail below by combining examples, but the anti-fouling and anti-falling sand stone paint containing traditional Chinese medicine components and the preparation method thereof are not to be construed as limiting the protection scope of the invention.
Examples
The raw materials used in the examples and comparative examples were as follows:
silicone-acrylic emulsion (SD-5281 Jiang Susheng);
cellulose acetate butyrate (CAB-381-2 isman);
inorganic gel (magnesium aluminum silicate Zhejiang Anji);
aqueous dispersants (5040 noronaceae);
aqueous defoamer (a 111 basf);
film forming aids (alcohol ester dodecaKain chemical);
germicides (206 Guangdong Dimei);
rutile titanium dioxide (996 Long Mang);
calcined kaolin (SX-80A three xin);
hydrogenated silicone oil (Jiangxi Rui);
aqueous amine adjuvants (AMP 95 dow);
thixotropic anti-settling agents (AC 603 schottky);
antifreeze (FT-100 Roditia).
The preparation method of the camphor tree medicinal liquid comprises the following steps:
cleaning Cinnamomum camphora, root and branch, stacking in outdoor shade and ventilating place, air drying for 60 days, and decocting after the water in inner layer and surface is air-dried.
The formula comprises the following components: blocky camphor tree, root, branch: 1 ton of tap water: 3 tons.
The process comprises the following steps: 1. putting camphor tree blocks into a 5-cube boiler, adding 3 tons of tap water into the boiler, and covering a boiler cover;
2. natural gas is adopted for heating, and when the whole boiler water is boiled to 100 ℃, the constant temperature is used for heating.
3. Decocting with slow fire for 2 hr, detecting microscopic yellow color of the camphora medicinal liquid, and extinguishing fire with pH value of 7.5+ -0.5.
4. Introducing cooling water, vacuum pumping the camphor tree liquid into a blending kettle (filtering with 200 mesh filter screen in the extraction process), detecting effective components, and controlling the effective components to be 10%.
The preparation method of the ceramic colored sand comprises the following steps:
uniformly stirring spherical white jade (20-120 meshes), a binder and dyes with various colors; and (3) placing the mixture uniformly stirred in the first step into a rotary kiln at 1450 ℃ to be sintered for 30min, cooling, and filtering by adopting a 60-mesh filter screen. And then cleaning the ceramic colored sand after being burned by adopting an ethanol solvent, cleaning superfluous dye on the surface, and air-drying to obtain ceramic colored sand particles. In the preparation method, inorganic ceramic resin (main component: siO) is selected as binder 2 、ZrO 2 、TiO 2 ) The method comprises the steps of carrying out a first treatment on the surface of the The mass ratio of the spherical white jade to the dye to the binder is 1000:15:20.
the compositions of the raw materials of examples 1 to 3 and comparative examples 1 to 2 are shown in Table 1. The stone lacquer prepared in patent CN20171053613.6 was used as comparative example 3.
TABLE 1 raw material compositions of examples 1-3 and comparative examples 1-2
The preparation methods of the real stone paint of examples 1-3 and comparative examples 1-4 are as follows:
(1) Slowly adding cellulose acetate butyrate into the camphor tree liquid medicine, stirring at 800 rpm until the cellulose is fully dissolved, and preparing 20% CAB solution;
(2) Slowly adding inorganic gel into the camphor tree medicinal liquid, stirring at 1000 rpm until the inorganic gel is pasty, and preparing into 20% inorganic gel solution;
(3) Adding silicone-acrylic emulsion, 20% CAB, a water-based dispersing agent, a water-based defoaming agent, a water-based multifunctional auxiliary agent and hydrogenated silicone oil into a production cylinder, and stirring for 8 minutes at 400 rpm;
(4) Adding 20% inorganic gel solution, rutile type titanium dioxide and calcined kaolin, stirring for 10 minutes at 1000 rpm, and detecting no particles;
(5) The self-made ceramic colored sand is slowly added, and stirred for 30 minutes at a medium speed of 1000 rpm.
(6) Adding the bactericide, the antifreezing agent, the film-forming auxiliary agent and the thixotropic anti-settling agent into a production cylinder, and stirring at a medium speed of 800 revolutions per minute for 15 minutes.
Performance testing
(1) Firstly, carrying out seal primer and primer construction on an integrated plate, drying for 12 hours, then spraying water-based real stone paint, generally spraying for 2-3 times, and detecting appearance, surface drying time, real drying time, low-temperature film forming property and luster after construction; and drying for 7 days under natural environment conditions to detect comprehensive properties (water resistance, temperature denaturation resistance, dirt sticking resistance and artificial aging resistance).
(2) Sand removal rate test: comparative test experimental tools were performed on examples 1-5 and comparative patent examples: real stone paint spray gun
Experimental materials: 2kg each of product, 6 sheets of 1 square plastic film
Experimental conditions: the spraying areas are 0.5 square meter each
Tool-to-gun distance: 1 to 1.2m
The experimental method comprises the following steps: spraying the real stone paint by adopting a real stone paint spray gun until 2kg of real stone paint is used up, and spreading a plastic film below the wall surface for collecting the rebound and falling coating gravel.
At the end of the experiment, the collected paint grit was weighed, W, divided by 2000 and multiplied by 100 to give the sand removal rate.
(3) The overall performance is respectively carried out according to the following standards: the low temperature storage stability is performed according to GB6573.3, the thermal storage stability is performed according to GB6573.3, the initial drying crack resistance is performed according to GB14907, the surface drying is performed according to GB9272, the water resistance is performed according to GB1733, the alkali resistance is performed according to GB9265, the heat resistance denaturation is performed according to JG/T25-2017, the stain resistance is performed according to GB9780, the adhesive strength is performed according to GB9978, the artificial aging resistance is performed according to 1766, the purified air is performed according to GB50325, and the mosquito repellent efficacy is performed according to GB 18116.
The results of the formation tests of the examples and comparative examples are shown in Table 2.
Table 2 results of formation test of examples and comparative examples
As can be seen from comparative examples 1-2, the coating adopts the real stone paint prepared from cellulose acetate butyrate CAB, inorganic gel and self-made ceramic colored sand, has excellent sand falling resistance, can not generate the phenomenon of flowery during any spraying, improves the water resistance and the bonding strength after the cellulose acetate butyrate is added, and also improves the weather resistance of the ceramic colored sand. As can be seen from comparative examples 3 to 4, when inorganic gel and cellulose acetate butyrate were not added, they had a large influence on the sand fall resistance, the bloom and the adhesive strength. From examples 1 to 3, the surface anti-fouling performance of the paint film is obviously improved, and the water resistance and the artificial aging resistance are both greatly improved after the hydrogenated silicone oil is added. The whole coating preparation process adopts camphor tree liquid medicine as a thinner, and adds two performances of air purification and mosquito prevention on the basis of the performance of the original coating. The camphor tree-based coating with the drug effect is utilized as a medicinal material, the traditional Chinese medicine city policy planning is completely met, and the product is detected by a third party and is greatly popularized in the market.
The foregoing is merely a preferred embodiment of the present invention and it should be noted that modifications and adaptations to those skilled in the art may be made without departing from the principles of the present invention, which are intended to be comprehended within the scope of the present invention.
Claims (4)
1. An anti-fouling and anti-falling sand stone-like paint containing traditional Chinese medicine components comprises the following components in percentage by mass:
the inorganic gel is magnesium aluminum silicate and/or montmorillonite, and the particle size of the inorganic gel is 200-325 meshes;
the grain diameter of the rutile titanium dioxide is 0.2-0.3 mu m; the particle size of the calcined kaolin is 800-1500 meshes;
the aqueous dispersing agent is one or more of a polycarboxylate sodium salt type dispersing agent, an anionic dispersing agent and a nonionic dispersing agent;
the solid content of the silicone-acrylic emulsion is 38-48 wt%;
the film forming auxiliary agent is one or more of alcohol ester twelve, propylene glycol propyl ether and propylene glycol butyl ether;
the aqueous amine auxiliary agent is a ceramic AMP95;
the thixotropic anti-settling agent is one or more of cellulose ether thickening agents and polyurethane thickening agents;
the mass concentration of the camphor tree effective active components in the camphor tree medicinal liquid is 9.5-10.5%;
the preparation method of the camphor tree medicinal liquid comprises the following steps of:
mixing the camphor tree raw material with water, heating and extracting to obtain camphor tree medicinal liquid;
the mass ratio of the camphor tree raw material to the water is 0.8-1:3-3.2;
the preparation method of the ceramic colored sand comprises the following steps:
mixing spherical white jade, dye and inorganic binder, and sintering to obtain ceramic colored sand;
the mass ratio of the spherical white jade to the dye to the inorganic binder is 1000:10-20:10-20;
the sintering temperature is 1000-1500 ℃, and the heat preservation time is 25-30 min.
2. The preparation method of the anti-fouling and anti-falling sand stone-like paint containing traditional Chinese medicine components as claimed in claim 1, comprising the following steps:
(1) Mixing a part of camphor tree liquid medicine with cellulose acetate butyrate to obtain a cellulose acetate butyrate solution;
(2) Mixing the residual camphor tree liquid medicine with inorganic gel to obtain inorganic gel solution;
(3) Mixing the silicone-acrylic emulsion, the cellulose acetate butyrate solution, the water-based dispersing agent, the water-based defoaming agent, the water-based amine auxiliary agent and the hydrogenated silicone oil to obtain a first mixture;
(4) Mixing the first mixture with an inorganic gel solution, rutile type titanium dioxide and calcined kaolin to obtain a second mixture;
(5) Mixing the second mixture with ceramic colored sand, epoxy colored sand to obtain a third mixture;
(6) Mixing the third mixture with a bactericide, an antifreezing agent, a film forming auxiliary agent and a thixotropic anti-settling agent to obtain the anti-fouling anti-falling sand stone-like paint containing traditional Chinese medicine components;
there is no limitation on the time sequence between the steps (1) to (2).
3. The process according to claim 2, wherein the rate of mixing in steps (1), (2), (4), (5), (6) is independently 800 to 1000 rpm.
4. The method according to claim 2, wherein the mixing rate in the step (3) is 300 to 400 rpm.
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