CN115975459A - Anti-fouling and anti-sand-falling real stone paint containing traditional Chinese medicine components and preparation method thereof - Google Patents
Anti-fouling and anti-sand-falling real stone paint containing traditional Chinese medicine components and preparation method thereof Download PDFInfo
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- CN115975459A CN115975459A CN202211719192.2A CN202211719192A CN115975459A CN 115975459 A CN115975459 A CN 115975459A CN 202211719192 A CN202211719192 A CN 202211719192A CN 115975459 A CN115975459 A CN 115975459A
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- chinese medicine
- fouling
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- 239000003973 paint Substances 0.000 title claims abstract description 88
- 239000003814 drug Substances 0.000 title claims abstract description 73
- 239000004575 stone Substances 0.000 title claims abstract description 53
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 230000003373 anti-fouling effect Effects 0.000 title claims description 36
- 241000723346 Cinnamomum camphora Species 0.000 claims abstract description 64
- 239000004576 sand Substances 0.000 claims abstract description 42
- 239000007788 liquid Substances 0.000 claims abstract description 33
- 229920006217 cellulose acetate butyrate Polymers 0.000 claims abstract description 28
- 239000000919 ceramic Substances 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 229920002545 silicone oil Polymers 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 7
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- 238000002156 mixing Methods 0.000 claims description 42
- 239000000203 mixture Substances 0.000 claims description 26
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 24
- 239000002270 dispersing agent Substances 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 19
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 12
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- 239000011230 binding agent Substances 0.000 claims description 11
- 239000010977 jade Substances 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 238000005245 sintering Methods 0.000 claims description 9
- 239000002562 thickening agent Substances 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000004480 active ingredient Substances 0.000 claims description 7
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 5
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 5
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 claims description 4
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- IFPMZBBHBZQTOV-UHFFFAOYSA-N 1,3,5-trinitro-2-(2,4,6-trinitrophenyl)-4-[2,4,6-trinitro-3-(2,4,6-trinitrophenyl)phenyl]benzene Chemical compound [O-][N+](=O)C1=CC([N+](=O)[O-])=CC([N+]([O-])=O)=C1C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C(C=2C(=C(C=3C(=CC(=CC=3[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O)C(=CC=2[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O)=C1[N+]([O-])=O IFPMZBBHBZQTOV-UHFFFAOYSA-N 0.000 claims description 3
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 3
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- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 claims description 3
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- JHWGDOLQKUEOKY-UHFFFAOYSA-N 1-acetyloxyhexyl acetate Chemical compound CCCCCC(OC(C)=O)OC(C)=O JHWGDOLQKUEOKY-UHFFFAOYSA-N 0.000 claims description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 2
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 238000004321 preservation Methods 0.000 claims description 2
- KRLNSONREPYDKW-UHFFFAOYSA-N 1-butoxy-1-ethoxypropan-1-ol Chemical compound CCCCOC(O)(CC)OCC KRLNSONREPYDKW-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
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- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 abstract description 4
- 229920000875 Dissolving pulp Polymers 0.000 abstract description 3
- UGZICOVULPINFH-UHFFFAOYSA-N acetic acid;butanoic acid Chemical compound CC(O)=O.CCCC(O)=O UGZICOVULPINFH-UHFFFAOYSA-N 0.000 abstract description 3
- 238000007865 diluting Methods 0.000 abstract description 3
- 230000007774 longterm Effects 0.000 abstract description 3
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- 230000000052 comparative effect Effects 0.000 description 10
- 239000000975 dye Substances 0.000 description 8
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 6
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 6
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
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- 238000001914 filtration Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 239000002966 varnish Substances 0.000 description 4
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 3
- 239000005770 Eugenol Substances 0.000 description 3
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 description 3
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 238000007605 air drying Methods 0.000 description 3
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 3
- 230000002528 anti-freeze Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229930006739 camphene Natural products 0.000 description 3
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 description 3
- 229930008380 camphor Natural products 0.000 description 3
- 229960000846 camphor Drugs 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 229960002217 eugenol Drugs 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000010665 pine oil Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000003809 water extraction Methods 0.000 description 3
- HPUZPAIWNCLQGV-UHFFFAOYSA-N 1-(2-butoxyethoxy)propan-1-ol Chemical compound CCCCOCCOC(O)CC HPUZPAIWNCLQGV-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229940087305 limonene Drugs 0.000 description 2
- 235000001510 limonene Nutrition 0.000 description 2
- 235000014666 liquid concentrate Nutrition 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
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- 239000003921 oil Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- -1 alcohol ester Chemical class 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
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- UBPGILLNMDGSDS-UHFFFAOYSA-N diethylene glycol diacetate Chemical compound CC(=O)OCCOCCOC(C)=O UBPGILLNMDGSDS-UHFFFAOYSA-N 0.000 description 1
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- 230000004883 flower formation Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention provides a stain-resistant and sand-shedding-resistant stone-like paint containing traditional Chinese medicine components and a preparation method thereof, belonging to the technical field of stone-like paints. The cellulose acetate butyrate in the stone-like paint raw material has the function of rapid shaping, can improve the drying rate and avoid the phenomenon of flowering; the inorganic gel has a good effect of coating ceramic colored sand, and can reduce the sand falling rate of the real stone paint; the hydrogenated silicone oil can be condensed into macromolecular siloxane with low surface tension in the film forming process of the stone-like paint, a layer of siloxane film is formed in the holes of the stone-like paint and is dispersed on the hole walls, so that the channels cannot be blocked, and the stone-like paint has good waterproof performance and long-term hydrophobic and oleophobic performance; according to the invention, the traditional Chinese medicine component, namely the oak liquid medicine, is added into the raw materials of the real stone paint, on one hand, the camphor tree liquid medicine can be used as a thinner, and plays a role in diluting and dissolving cellulose acetate butyrate and inorganic gel; on the other hand, the camphor tree liquid medicine can also play roles in purifying air and preventing mosquitoes.
Description
Technical Field
The invention relates to the technical field of stone-like paint, in particular to anti-fouling and sand-shedding-preventing stone-like paint containing traditional Chinese medicine components and a preparation method thereof.
Background
The stone-like paint is a coating with decorative effect exactly similar to marble and granite, is mainly prepared from natural stone powder with various colors, is applied to the stone-like effect of the outer wall of a building, and is also called liquid stone. The building decorated by the stone paint has natural and real natural color, gives people elegant, harmonious and solemn beauty, and is suitable for indoor and outdoor decoration of various buildings.
The stone-like paint comprises natural stone-like paint, texture paint, ceramic color sand stone-like paint and color matching stone-like paint, and the problems of sand falling, flower formation and easy dirt of a coating exist no matter what kind of stone-like paint. As the main component of the stone-like paint is inorganic particles, sand falling is an inevitable phenomenon, and the sand falling rate becomes the most concerned problem in the stone-like paint market. The sprayed real stone paint can not be used for half a year, a lot of dust can be accumulated on the surface, and the phenomenon of flushing marks and flowering can occur after raining. Meanwhile, mosquitoes are adsorbed on the surface of the outer wall, and the mosquitoes which are killed can be left on the surface of the stone paint when raining and snowing, so that the attractiveness is affected.
Disclosure of Invention
In view of the above, the invention aims to provide an anti-fouling and sand-shedding preventing stone-like paint containing traditional Chinese medicine components and a preparation method thereof.
In order to achieve the above object, the present invention provides the following technical solutions:
the invention provides a stain-resistant and sand-shedding-resistant real stone paint containing traditional Chinese medicine components, which comprises the following components in percentage by mass:
the mass concentration of the active ingredients of the camphor trees in the camphor tree liquid medicine is 9.5-10.5%.
The preparation method of the camphor tree liquid medicine comprises the following steps:
mixing the camphor tree raw material with water, and heating and extracting with water to obtain camphor tree liquid medicine;
the mass ratio of the camphor tree raw material to water is 0.8-1.
Preferably, the preparation method of the ceramic color sand comprises the following steps:
mixing spherical white jade, dye and inorganic binder, and sintering to obtain ceramic colored sand;
the mass ratio of the spherical white jade to the dye to the inorganic binder is 1000-20;
the sintering temperature is 1000-1500 ℃, and the heat preservation time is 25-30 min.
Preferably, the solid content of the silicone-acrylate emulsion is 38-48 wt%.
Preferably, the inorganic gel is magnesium aluminum silicate and/or montmorillonite;
the particle size of the inorganic gel is 200-325 meshes.
Preferably, the particle size of the rutile titanium dioxide is 0.2-0.3 μm; the particle size of the calcined kaolin is 800-1500 meshes.
Preferably, the aqueous dispersant is one or more of a sodium polycarboxylate dispersant, an anionic dispersant and a nonionic dispersant;
the film forming auxiliary agent is one or more of alcohol ester dodeca, ethylene glycol, propylene glycol, hexanediol, monoethylene glycol ether acetate, butoxyethoxypropanol, propylene glycol propyl ether, propylene glycol butyl ether, monoethylene glycol butyl ether acetate, ethylene glycol butyl ether acetate and hexanediol diacetate;
the aqueous amine auxiliary agent is Dow AMP95;
the thixotropic anti-settling agent is one or more of cellulose ether thickening agent, association type alkali swelling thickening agent and polyurethane thickening agent.
The invention provides a preparation method of the anti-fouling and anti-sand-falling real stone paint containing traditional Chinese medicine components, which comprises the following steps:
(1) Mixing a part of camphor tree liquid medicine with cellulose acetate butyrate to obtain a cellulose acetate butyrate solution;
(2) Mixing the rest camphor tree liquid medicine with the inorganic gel to obtain an inorganic gel solution;
(3) Mixing the silicone-acrylate emulsion, a cellulose acetate butyrate solution, a water-based dispersant, a water-based defoaming agent, a water-based amine auxiliary agent and hydrogenated silicone oil to obtain a first mixture;
(4) Mixing the first mixture with an inorganic gel solution, rutile type titanium dioxide and calcined kaolin to obtain a second mixture;
(5) Mixing the second mixture with ceramic color sand and epoxy color sand to obtain a third mixture;
(6) Mixing the third mixture with a bactericide, an antifreezing agent, a film-forming aid and a thixotropic anti-settling agent to obtain the anti-fouling and anti-sand-dropping real stone paint containing the traditional Chinese medicine components;
there is no chronological restriction between the steps (1) to (2).
Preferably, the mixing rates in the steps (1), (2), (4), (5) and (6) are independently 800 to 1000 rpm.
Preferably, the mixing rate in the step (3) is 300 to 400 rpm.
The invention provides a stain-resistant sand-shedding-resistant real stone paint containing traditional Chinese medicine components, which comprises the following components in percentage by mass: 4.85 to 7.6 percent of camphor tree liquid medicine; 62 to 70 percent of ceramic color sand; 13 to 17 percent of silicone-acrylate emulsion; 0.5 to 1 percent of cellulose acetate butyrate; 0.5 to 1 percent of inorganic gel; 0.5 to 1 percent of hydrogenated silicone oil; 1 to 2 percent of rutile titanium dioxide; 3 to 5 percent of calcined kaolin; 0.2 to 0.5 percent of water-based dispersant; 0.05 to 0.1 percent of bactericide; 0.1 to 0.2 percent of water-based defoaming agent; 1 to 3 percent of antifreeze; 0.5 to 1 percent of film-forming auxiliary agent; 0.5 to 1 percent of water-based amine auxiliary agent; 1 to 2 percent of thixotropic anti-settling agent; the mass concentration of the effective active ingredients of the camphor trees in the camphor tree liquid medicine is 9.5-10.5%. According to the invention, the cellulose acetate butyrate is added into the raw material of the stone-like paint, the cellulose acetate butyrate has excellent directional arrangement, quick drying and strong water release capacity, and with the help of the cellulose acetate butyrate, the stone-like paint can be quickly shaped and fixed, thereby being beneficial to water release and improving the drying speed of the coating, and further solving the problem of coating blooming. By adding the inorganic gel, the coating has a good effect of coating ceramic color sand, and can reduce the sand falling rate of the stone-like paint. According to the invention, the hydrogenated silicone oil is added, and can be condensed into the high-molecular siloxane with low surface tension in the film forming process of the stone-like paint, so that a layer of siloxane film is formed in the holes of the stone-like paint and is dispersed on the hole walls, a channel cannot be blocked, and the waterproof paint has good waterproof performance. The water-proof and oil-repellent coating can prevent the real stone paint from being damaged due to water seepage, and endows the real stone paint with good long-term water and oil repellency, so that the real stone paint has good dirt resistance. According to the invention, the traditional Chinese medicine component, namely the oak liquid medicine, is added into the raw materials of the real stone paint, on one hand, the camphor tree liquid medicine can be used as a thinner, and plays a role in diluting and dissolving cellulose acetate butyrate and inorganic gel; on the other hand, camphor tree medicinal water contains camphor, camphene, diepoxide hydrocarbon of pine oil, limonene and eugenol, and the camphor tree medicinal water can play roles in purifying air and preventing mosquitoes as a natural stone paint raw material.
The invention provides a preparation method of the stain-resistant sand-shedding-preventing real stone paint containing the traditional Chinese medicine components, and the method is simple to operate, low in cost and suitable for industrial batch production.
Detailed Description
The invention provides a stain-resistant and sand-shedding-resistant real stone paint containing traditional Chinese medicine components, which comprises the following components in percentage by mass:
the mass concentration of the effective active ingredients of the camphor trees in the camphor tree liquid medicine is 9.5-10.5%.
The anti-fouling and anti-sand-dropping stone-like paint containing the traditional Chinese medicine components comprises, by mass, 4.85-7.6% of camphor tree liquid medicine, preferably 5-7%, and more preferably 5.2-5.6%. In the invention, the mass concentration of the effective active ingredients of the camphor trees in the camphor tree liquid medicine is 9.5-10.5%, and preferably 10%. In the invention, the effective active ingredients of the camphor trees comprise one or more of camphor, camphene, diepoxy hydrocarbon of pine oil, lemon hydrocarbon and eugenol.
In the present invention, the preparation method of the camphor tree liquid preferably comprises the following steps:
mixing the camphor tree raw material with water, and heating and extracting with water to obtain the camphor tree liquid medicine.
In the invention, the cinnamomum camphora raw material is preferably cinnamomum camphora branches and/or cinnamomum camphora roots. The camphor tree raw material is preferably cleaned and aired.
In the present invention, the mass ratio of the camphor tree raw material to water is preferably 0.8 to 1. In the invention, the temperature of the heated water extraction is preferably 95-100 ℃, and more preferably 100 ℃; the time is preferably 2 to 2.5 hours, more preferably 2 hours. After the heated water extraction, the invention preferably filters the heated water extraction solution to obtain the camphor tree liquid stock solution. In the present invention, the pore size of the filter screen used for filtration is preferably 200 mesh.
In the invention, the obtained camphor tree liquid medicine stock solution is yellowish, and the pH value is 7.5 +/-0.5. The concentration of the camphor tree liquid concentrate is preferably adjusted by using deionized water, so that the mass concentration of active ingredients of camphor trees in the camphor tree liquid concentrate is 9.5-10.5%.
In the invention, on one hand, the camphor tree liquid medicine can be used as a thinner and plays a role in diluting and dissolving cellulose acetate butyrate and inorganic gel; on the other hand, camphor tree medicinal water contains camphor, camphene, diepoxide hydrocarbon of pine oil, limonene and eugenol, and the camphor tree medicinal water can play roles in purifying air and preventing mosquitoes as a natural stone paint raw material.
The anti-fouling and anti-sand-dropping real stone paint containing the traditional Chinese medicine components comprises, by mass, 62-70% of ceramic color sand, preferably 64-68%, and more preferably 65-66%. In the invention, the ceramic color sand is obtained by sintering spherical white jade, dye and binder. In the present invention, the preparation method of the ceramic colored sand preferably comprises the following steps:
mixing the spherical white jade, the dye and the inorganic binder, and sintering to obtain the ceramic colored sand.
In the present invention, the particle size of the spherical white jade is preferably 20 to 120 mesh, and more preferably 50 to 100 mesh. In the present invention, the inorganic binder is preferably SiO 2 、ZrO 2 And TiO 2 One or more of them.
In the invention, the mass ratio of the spherical white jade to the dye to the inorganic binder is preferably 1000-20, more preferably 1000-18.
In the present invention, the sintering temperature is preferably 1000 to 1500 ℃, more preferably 1200 to 1400 ℃, and the holding time is preferably 25 to 30min, more preferably 26 to 28min.
In the present invention, after the sintering, the ceramic color sand obtained in the present invention is preferably filtered, washed and dried. The present invention preferably uses a 60 mesh filter screen for filtration. In the present invention, the detergent used for the washing is preferably ethanol; the drying is preferably air drying.
The anti-fouling and anti-dropping sand real stone paint containing the traditional Chinese medicine components comprises 13-17% of silicone-acrylate emulsion, preferably 14-16%, and more preferably 15% by mass. In the present invention, the silicone-acrylic emulsion preferably has a solid content of 38 to 48wt%, more preferably 40 to 45wt%. In the invention, the silicone-acrylic emulsion plays a role in film formation.
The anti-fouling and sand-shedding-preventing really stone paint containing the traditional Chinese medicine components comprises 0.5-1% of cellulose acetate butyrate by mass percentage, and preferably 0.6-0.8%. In the invention, the cellulose acetate butyrate has a quick qualitative effect, can improve the drying rate and avoids the phenomenon of flowering.
The anti-fouling and sand-shedding-preventing real stone paint containing the traditional Chinese medicine components comprises 0.5-1% of inorganic gel, preferably 0.6-0.8% by mass. In the present invention, the inorganic gel is preferably magnesium aluminum silicate; the particle size of the inorganic gel is preferably 200 to 325 mesh. In the invention, the inorganic gel has a good effect of coating the ceramic color sand, and can reduce the sand falling rate of the real stone paint.
The anti-fouling and sand-falling-preventing real stone paint containing the traditional Chinese medicine components comprises 0.5-1% of hydrogenated silicone oil by mass percentage, and preferably 0.6-0.8%. In the invention, the hydrogenated silicone oil can be condensed into high molecular siloxane with low surface tension in the film forming process of the stone-like paint, a layer of siloxane film is formed in the holes of the stone-like paint and is dispersed on the hole walls, so that the channels cannot be blocked, and the hydrogenated silicone oil also has good waterproof performance. The water-permeable and oil-repellent natural stone paint can prevent damage to the natural stone paint due to water seepage, and meanwhile, the natural stone paint is endowed with good long-term water and oil repellency, so that the natural stone paint has good stain resistance.
The anti-fouling and anti-sand-falling really stone paint containing the traditional Chinese medicine components comprises 1-2% of rutile titanium dioxide by mass percentage, preferably 1.2-1.8%, and more preferably 1.5%. In the invention, the particle size of the rutile titanium dioxide is preferably 0.2-0.3 μm. In the invention, the rutile titanium dioxide is used for enhancing the covering power and the coating rate of the real stone paint.
The anti-fouling and anti-dropping sand real stone paint containing the traditional Chinese medicine components comprises 3-5% of calcined kaolin, preferably 3.5-4.5%, and more preferably 4% by mass. In the present invention, the particle size of the calcined kaolin is preferably 800 to 1500 mesh, and more preferably 1000 to 1200 mesh. In the invention, the calcined kaolin has the function of coacting with titanium dioxide, so that the covering power of the coating is obviously improved.
The anti-fouling and anti-dropping sand real stone paint containing the traditional Chinese medicine components comprises 0.2-0.5% of water-based dispersant by mass percentage, and preferably 0.3-0.4%. In the invention, the aqueous dispersant is preferably one or more of a sodium polycarboxylate type dispersant, an anionic dispersant and a nonionic dispersant.
The anti-fouling and anti-sand-falling stone-like paint containing the traditional Chinese medicine components comprises 0.05-0.1% of bactericide by mass percentage, and preferably 0.06-0.08%. In the invention, the bactericide is preferably one or more of inorganic bactericide, organic sulfur bactericide, organic phosphorus bactericide, organic arsenic bactericide, azole bactericide and antibiotic bactericide. In the present invention, the type of the bactericide is preferably Guangdong Di 206.
The anti-fouling and anti-dropping sand real stone paint containing the traditional Chinese medicine components comprises 0.1-0.2% of water-based defoaming agent, preferably 0.12-0.18%, and more preferably 0.15% by mass. In the invention, the aqueous defoaming agent is preferably one or more of a lower alcohol or ester defoaming agent, an organic polar compound defoaming agent, a mineral oil defoaming agent and a silicone defoaming agent, and more preferably a mineral oil defoaming agent. In the present invention, the type of the aqueous defoaming agent is preferably basf a111.
The anti-fouling and sand-shedding prevention stone paint containing the traditional Chinese medicine components comprises 1-3% of an antifreezing agent by mass percentage, preferably 1.5-2.5%, and more preferably 2%. In the present invention, the antifreeze is preferably Rodiya FT-100 in type.
The anti-fouling and sand-shedding-preventing real stone paint containing the traditional Chinese medicine components comprises 0.5-1% of film-forming auxiliary agent by mass percentage, and preferably 0.6-0.8%. In the invention, the film forming auxiliary agent is preferably one or more of alcohol ester twelve, glycol, propylene glycol, hexanediol, monoethylene glycol ether acetate, butoxyethoxypropanol, propylene glycol propyl ether, propylene glycol butyl ether, butyl monoethylene glycol ether acetate, butyl glycol ether acetate and diglycol diacetate.
The anti-fouling and sand-shedding-preventing real stone paint containing the traditional Chinese medicine components comprises 0.5-1% of water-based amine auxiliary agent by mass percentage, and more preferably 0.6-0.8%. In the present invention, the main component of the aqueous amine-based auxiliary is preferably 2-amino-2-methyl-1-propanol. . In the invention, the type of the aqueous amine auxiliary agent is preferably Dow AMP95. In the invention, the water-based amine auxiliary agent has the function of adjusting the pH value of the real stone paint.
The anti-fouling and anti-sand-dropping real stone paint containing the traditional Chinese medicine components comprises 1-2% of thixotropic anti-settling agent, preferably 1.2-1.8%, and more preferably 1.5% by mass. In the invention, the thixotropic anti-settling agent is preferably one or more of cellulose ether thickening agent, association type alkali swelling thickening agent and polyurethane thickening agent. In the present invention, the thixotropic anti-settling agent is preferably of the type Xiao Chao AC603. In the invention, the thixotropic anti-settling agent mainly plays roles of preventing settling and increasing the viscosity and thixotropy of the coating, so that the sprayed stone-like paint can be shaped on the wall surface and cannot fall or flow.
The invention provides a preparation method of the anti-fouling and anti-sand-falling real stone paint containing traditional Chinese medicine components, which comprises the following steps:
(1) Mixing a part of camphor tree liquid medicine with cellulose acetate butyrate to obtain a cellulose acetate butyrate solution;
(2) Mixing the rest camphor tree liquid medicine with the inorganic gel to obtain an inorganic gel solution;
(3) Mixing silicone-acrylate emulsion, cellulose acetate butyrate solution, water-based dispersant, water-based defoamer, water-based amine auxiliary agent and hydrogenated silicone oil to obtain a first mixture;
(4) Mixing the first mixture with an inorganic gel solution, rutile type titanium dioxide and calcined kaolin to obtain a second mixture;
(5) Mixing the second mixture with ceramic color sand and epoxy color sand to obtain a third mixture;
(6) Mixing the third mixture with a bactericide, an antifreezing agent, a film-forming aid and a thixotropic anti-settling agent to obtain the anti-fouling and anti-sand-dropping real stone paint containing the traditional Chinese medicine components;
there is no chronological restriction between the steps (1) to (2).
According to the invention, a part of camphor tree liquid medicine is mixed with cellulose acetate butyrate to obtain a cellulose acetate butyrate solution. In the present invention, the amount of the part of camphor tree sap is 10 to 30% by mass of the total camphor tree sap, and more preferably 15 to 25% by mass of the total camphor tree sap.
In the present invention, the mixing is preferably performed by stirring; the rotation speed of the mixing is preferably 800-1000 rpm, and more preferably 900 rpm; the invention has no special requirement on the mixing time, and can ensure that the cellulose acetate butyrate is completely dissolved. In the present invention, the concentration of the cellulose acetate butyrate solution is preferably 18 to 22wt%, more preferably 20wt%.
The invention mixes the rest camphor tree liquid medicine with inorganic gel to obtain inorganic gel solution. In the present invention, the mixing is preferably performed by stirring; the rotation speed of the mixing is preferably 800 to 1000 rpm, more preferably 900 rpm. In the present invention, the concentration of the inorganic gel solution is preferably 18 to 22wt%, more preferably 20wt%.
The silicone-acrylic emulsion, the cellulose acetate butyrate solution, the water-based dispersant, the water-based defoamer, the water-based amine assistant and the hydrogenated silicone oil are mixed to obtain a first mixture. In the present invention, the mixing is preferably performed by stirring; the rotation speed of the mixing is preferably 300 to 400 rpm, more preferably 350 rpm, and the time is preferably 5 to 10min, more preferably 6 to 8min.
The first mixture is mixed with an inorganic gel solution, rutile type titanium dioxide and calcined kaolin to obtain a second mixture. In the present invention, the mixing is preferably performed by stirring; the mixing speed is preferably 800 to 1000 rpm, more preferably 900 rpm, and the time is preferably 5 to 10min, more preferably 6 to 8min.
The second mixture is mixed with the ceramic color sand and the epoxy color sand to obtain a third mixture. In the present invention, the mixing is preferably performed by stirring. In the present invention, the rotation speed of the mixing is preferably 800 to 1000 rpm, more preferably 900 rpm, and the time is preferably 30 to 40min, more preferably 35min.
The third mixture is mixed with a bactericide, an antifreezing agent, a film forming aid and a thixotropic anti-settling agent to obtain the anti-fouling and anti-sand-falling stone-like paint containing the traditional Chinese medicine components. In the present invention, the mixing is preferably performed by stirring; the mixing speed is preferably 800 to 1000 rpm, more preferably 900 rpm, and the time is preferably 10 to 15min, more preferably 12 to 14min.
The anti-fouling and anti-sand-shedding stone-like paint containing traditional Chinese medicine components and the preparation method thereof provided by the invention are described in detail by the following examples, but the anti-fouling and anti-sand-shedding stone-like paint containing traditional Chinese medicine components and the preparation method thereof are not understood to limit the protection scope of the invention.
Examples
The examples and comparative examples used the following raw material manufacturers and models:
silicone-acrylic emulsion (SD-5281 Jiangsuoda);
cellulose acetate butyrate (CAB-381-2 Istman);
inorganic gel (magnesium aluminum silicate Zhejiang Anji);
an aqueous dispersant (5040 Nostolacaceae);
aqueous defoamer (a 111 basf);
film-forming additives (alcohol ester Dodeca Kay chemical industry);
a bactericide (206 Guangdong dime);
rutile titanium dioxide (996 python);
calcined kaolin (SX-80A san Xin);
hydrogenated silicone oil (Jiangxi Rui);
aqueous amine adjuvant (AMP 95 dow);
thixotropic anti-settling agent (AC 603 zodiac);
antifreeze (FT-100 luodiya).
The preparation method of the camphor tree liquid medicine comprises the following steps:
cleaning lignum Cinnamomi Camphorae, root, and branch, stacking in outdoor shade and ventilating place, air drying for 60 days, and decocting after the water content in inner layer and surface is air dried.
The formula is as follows: blocky camphor trees, roots and branches: 1 ton, tap water: 3 tons.
The process comprises the following steps: 1. putting the camphor tree block material into a 5-cubic boiler, adding 3 tons of tap water into the boiler, and covering the boiler cover;
2. natural gas is adopted for heating, and when the water in the whole boiler is boiled to reach 100 ℃, heat is supplied at constant temperature.
3. Decocting with slow fire for 2 hr, detecting the yellowish color of lignum Cinnamomi Camphorae liquid with pH of 7.5 + -0.5, and extinguishing.
4. And (3) introducing cooling water, vacuumizing the camphor tree liquid medicine to a blending kettle (in the extraction process, filtering by adopting a 200-mesh filter screen), detecting effective components, and controlling the effective components to be 10%.
The preparation method of the ceramic color sand comprises the following steps:
uniformly stirring spherical white jade (20-120 meshes), a binder and dyes with various colors; and (3) placing the uniformly stirred mixture obtained in the first step into a rotary kiln at 1450 ℃, sintering for 30min, cooling, and filtering by adopting a 60-mesh filter screen. And cleaning the fired and cleaned ceramic colored sand by using an ethanol solvent, cleaning redundant dye on the surface, and air-drying to obtain the ceramic colored sand particles. In the preparation method, the binder is inorganic ceramic resin (main component: siO) 2 、ZrO 2 、TiO 2 ) (ii) a The mass ratio of the spherical white jade to the dye to the binder is respectively 1000:15:20.
the raw material compositions of examples 1 to 3 and comparative examples 1 to 2 are shown in table 1. As comparative example 3, a real stone paint prepared according to patent CN20171053613.6 was used.
TABLE 1 raw material compositions of examples 1 to 3 and comparative examples 1 to 2
The preparation methods of the real stone paints of the examples 1 to 3 and the comparative examples 1 to 4 are as follows:
(1) Slowly adding cellulose acetate butyrate into camphor tree medicinal water, and stirring at 800 rpm until the cellulose is fully dissolved to prepare 20% CAB solution;
(2) Slowly adding inorganic gel into camphor tree medicinal water, stirring at 1000 r/min until the inorganic gel is pasty, and preparing into 20% inorganic gel solution;
(3) Adding the silicone-acrylate emulsion, 20 percent CAB, a water-based dispersant, a water-based defoamer, a water-based multifunctional assistant and hydrogenated silicone oil into a production cylinder, and stirring for 8 minutes at 400 revolutions per minute;
(4) Adding 20% inorganic gel solution, rutile type titanium dioxide and calcined kaolin, stirring for 10 minutes at 1000 rpm, and detecting that no particles exist;
(5) Slowly adding the self-made ceramic color sand, and stirring at the medium speed of 1000 rpm for 30 minutes.
(6) Adding the bactericide, the antifreezing agent, the film-forming assistant and the thixotropic anti-settling agent into a production cylinder, and stirring at the medium speed of 800 rpm for 15 minutes.
Performance testing
(1) Firstly, constructing an integrated plate with a seal primer and a primer, drying the integrated plate for 12 hours, and then spraying a water-based stone paint for 2 to 3 times, wherein the appearance, the surface drying time, the actual drying time, the low-temperature film-forming property and the gloss can be detected after construction; and (4) drying for 7 days under natural environment conditions to detect comprehensive properties (water resistance, temperature change resistance, stain resistance and artificial aging resistance).
(2) And (3) sand falling rate test: examples 1-5 and comparative patent examples were subjected to comparative test experimental tools: real mineral varnish spray gun
Experimental materials: each 2kg of the product and 6 pieces of plastic film with the square of 1
The experimental conditions are as follows: each spraying area is 0.5 square meter
Distance between tool and spray gun: 1 to 1.2m
The experimental method comprises the following steps: adopt real mineral varnish spray gun spraying real mineral varnish, use up until 2kg real mineral varnish, tile plastic film in the wall below for collect the coating gravel that the bounce-back dropped.
At the end of the experiment, the collected paint gravel is weighed to obtain the weight W, and the weight W is divided by 2000 and multiplied by 100 percent to obtain the sand falling rate.
(3) The overall performance was performed according to the following criteria: low temperature storage stability is performed according to GB6573.3, thermal storage stability is performed according to GB6573.3, initial dry crack resistance is performed according to GB14907, surface drying is performed according to GB9272, water resistance is performed according to GB1733, alkali resistance is performed according to GB9265, temperature change resistance is performed according to JG/T25-2017, contamination resistance is performed according to GB9780, adhesive strength is performed according to GB9978, artificial aging resistance is performed according to 1766, purified air is performed according to GB50325, and mosquito prevention effect is performed according to GB 18416.
The results of the formation test of examples and comparative examples are shown in table 2.
Table 2 formation test results of examples and comparative examples
Compared with the prior art, the coating adopts CAB, inorganic gel and stone-like paint made of self-made ceramic color sand, has excellent sand falling prevention performance, can not generate the phenomenon of flowering in any spraying, improves the water resistance and the bonding strength after the addition of the cellulose acetate butyrate, and improves the weather resistance of the ceramic color sand. As can be seen from comparative examples 3 to 4, when inorganic gel and cellulose acetate butyrate were not added, the sand drop resistance, the blooming property, and the adhesive strength were greatly affected. As can be seen from examples 1 to 3, after the hydrogenated silicone oil is added, the antifouling property of the surface of the paint film is obviously improved, and the water resistance and the artificial aging resistance are both greatly improved. The whole coating manufacturing process adopts camphor tree liquid medicine as a thinner, and two performances of air purification and mosquito prevention are added on the basis of the performance of the original coating. The product utilizes camphor trees as medicinal materials, has a coating with medicinal efficacy, completely accords with the policy planning of the traditional Chinese medicine city, is detected by a third party, and has been widely popularized in the market.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and amendments can be made without departing from the principle of the present invention, and these modifications and amendments should also be considered as the protection scope of the present invention.
Claims (10)
1. The anti-fouling and sand-falling-preventing real stone paint containing the traditional Chinese medicine components comprises the following components in percentage by mass:
the mass concentration of the effective active ingredients of the camphor trees in the camphor tree liquid medicine is 9.5-10.5%.
2. The anti-fouling and anti-sand-falling stone-like paint containing traditional Chinese medicine components as claimed in claim 1, wherein the preparation method of the camphor tree liquid medicine comprises the following steps:
mixing the camphor tree raw material with water, and heating and extracting with water to obtain camphor tree liquid medicine;
the mass ratio of the camphor tree raw material to water is 0.8-1.
3. The anti-fouling and anti-sand-falling real stone paint containing traditional Chinese medicine components as claimed in claim 1, wherein the preparation method of the ceramic color sand comprises the following steps:
mixing spherical white jade, dye and inorganic binder, and sintering to obtain ceramic colored sand;
the mass ratio of the spherical white jade to the dye to the inorganic binder is 1000-20;
the sintering temperature is 1000-1500 ℃, and the heat preservation time is 25-30 min.
4. The anti-fouling and anti-sand-falling real stone paint containing traditional Chinese medicine components as claimed in claim 1, wherein the solid content of the silicone acrylic emulsion is 38-48 wt%.
5. The anti-fouling and anti-sand-falling really stone paint containing the traditional Chinese medicine components as claimed in claim 1, wherein the inorganic gel is magnesium aluminum silicate and/or montmorillonite;
the particle size of the inorganic gel is 200-325 meshes.
6. The anti-fouling and anti-sand-dropping really stone paint containing traditional Chinese medicine components as claimed in claim 1, wherein the particle size of the rutile titanium dioxide is 0.2-0.3 μm; the particle size of the calcined kaolin is 800-1500 meshes.
7. The anti-fouling and anti-sand-falling real stone paint containing the traditional Chinese medicine components as claimed in claim 1, wherein the aqueous dispersant is one or more of a sodium polycarboxylate dispersant, an anionic dispersant and a non-ionic dispersant;
the film forming auxiliary agent is one or more of alcohol ester dodeca, ethylene glycol, propylene glycol, hexanediol, monoethylene glycol ether acetate, butoxy ethoxy propanol, propylene glycol propyl ether, propylene glycol butyl ether, monoethylene glycol butyl ether acetate, ethylene glycol butyl ether acetate and hexanediol diacetate;
the aqueous amine auxiliary agent is Dow AMP95;
the thixotropic anti-settling agent is one or more of cellulose ether thickening agent, association type alkali swelling thickening agent and polyurethane thickening agent.
8. The preparation method of the anti-fouling and anti-sand-falling really stone paint containing traditional Chinese medicine components as claimed in any one of claims 1 to 7, which comprises the following steps:
(1) Mixing a part of camphor tree liquid medicine with cellulose acetate butyrate to obtain a cellulose acetate butyrate solution;
(2) Mixing the rest camphor tree liquid medicine with the inorganic gel to obtain an inorganic gel solution;
(3) Mixing the silicone-acrylate emulsion, a cellulose acetate butyrate solution, a water-based dispersant, a water-based defoaming agent, a water-based amine auxiliary agent and hydrogenated silicone oil to obtain a first mixture;
(4) Mixing the first mixture with an inorganic gel solution, rutile type titanium dioxide and calcined kaolin to obtain a second mixture;
(5) Mixing the second mixture with ceramic color sand and epoxy color sand to obtain a third mixture;
(6) Mixing the third mixture with a bactericide, an antifreezing agent, a film-forming assistant and a thixotropic anti-settling agent to obtain the anti-fouling and anti-sand-falling stone-like paint containing traditional Chinese medicine components;
there is no chronological restriction between the steps (1) to (2).
9. The method of claim 8, wherein the mixing rates in steps (1), (2), (4), (5) and (6) are independently 800 to 1000 rpm.
10. The method according to claim 8, wherein the mixing rate in the step (3) is 300 to 400 rpm.
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103555035A (en) * | 2013-10-09 | 2014-02-05 | 三棵树涂料股份有限公司 | Cockroach-proof emulsion paint and preparation method thereof |
| WO2014047428A1 (en) * | 2012-09-21 | 2014-03-27 | Segetis, Inc. | Cleaning, surfactant, and personal care compositions |
| CN105219243A (en) * | 2015-10-28 | 2016-01-06 | 漳州三德利油漆涂料有限公司 | Plant sterilization function for expelling pests type aqueous woodware paint and preparation method thereof |
| CN107129187A (en) * | 2017-07-04 | 2017-09-05 | 成都虹润制漆有限公司 | True mineral varnish of ceramic colorful sand and preparation method thereof |
| WO2019023113A1 (en) * | 2017-07-24 | 2019-01-31 | Dow Global Technologies Llc | Personal care polyacrylate oil gel composition |
| CN109810673A (en) * | 2018-12-13 | 2019-05-28 | 深圳市恒河新材料有限公司 | A kind of dust suppression moisturizer and preparation method thereof |
| CN111234612A (en) * | 2020-03-06 | 2020-06-05 | 北京仲基应用技术研究院有限公司 | Long-acting insect-expelling and purifying functional coating and preparation method and construction method thereof |
-
2022
- 2022-12-30 CN CN202211719192.2A patent/CN115975459B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014047428A1 (en) * | 2012-09-21 | 2014-03-27 | Segetis, Inc. | Cleaning, surfactant, and personal care compositions |
| CN103555035A (en) * | 2013-10-09 | 2014-02-05 | 三棵树涂料股份有限公司 | Cockroach-proof emulsion paint and preparation method thereof |
| CN105219243A (en) * | 2015-10-28 | 2016-01-06 | 漳州三德利油漆涂料有限公司 | Plant sterilization function for expelling pests type aqueous woodware paint and preparation method thereof |
| CN107129187A (en) * | 2017-07-04 | 2017-09-05 | 成都虹润制漆有限公司 | True mineral varnish of ceramic colorful sand and preparation method thereof |
| WO2019023113A1 (en) * | 2017-07-24 | 2019-01-31 | Dow Global Technologies Llc | Personal care polyacrylate oil gel composition |
| CN109810673A (en) * | 2018-12-13 | 2019-05-28 | 深圳市恒河新材料有限公司 | A kind of dust suppression moisturizer and preparation method thereof |
| CN111234612A (en) * | 2020-03-06 | 2020-06-05 | 北京仲基应用技术研究院有限公司 | Long-acting insect-expelling and purifying functional coating and preparation method and construction method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 林锐;刘朝辉;林壮文;贾艺凡;王飞;: "水性丙烯酸涂料的改性及其功能化应用研究进展", 表面技术, no. 01, pages 11 - 14 * |
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