CN109748537A - A kind of graphene high-performance lacquer and preparation method thereof - Google Patents
A kind of graphene high-performance lacquer and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a kind of graphene high-performance lacquer and preparation method thereof, feature is that its quality permillage is as follows: component A: deionized water 70--130 ‰, defoaming agent 1--3 ‰, dispersing agent 4--7 ‰, graphene 0.1--1 ‰, thickener 3--8 ‰, water-base resin 110--180 ‰, coalescing agent 5--10 ‰, natural colour sand 550--750 ‰ and sliver 0--200 ‰；B component: curing agent 700-800 ‰ and coalescing agent 200-300 ‰；Preparation method includes that deionized water is added in dispersion cylinder by (1), sequentially adds defoaming agent, dispersing agent, graphene, water-base resin, coalescing agent and thickener after mixing evenly, color sand and/or sliver is added；(2) it in curing agent and coalescing agent being added in dispersion cylinder, stirs evenly, advantage is that have excellent stain resistance, adhesive force, splitting resistance, water resistance, alkali resistance and temperature variation resistant etc..
Description
Technical field
The present invention relates to a kind of decoration of exterior wall coating more particularly to a kind of graphene high-performance lacquer and its preparation sides
Method.
Background technique
Lacquer is the coating that a kind of decorative effect exactly likes marble, granite.The main natural stone for using various colors
Sand is formulated, applied to the imitation stone effect of external wall, therefore also known as liquid stone.Building after lacquer finishing, tool
There is natural true natural colour, give graceful, harmonious, serious aesthetic feeling, be suitable for the indoor and outdoor decoration of all kinds of buildings,
Especially decorated on curved-surface building object, it is vivid, there is a kind of effect of back to nature.Graphene is only one carbon atom
The two-dimensional material of thickness has special honeycomb lattice structure form, it is also the highest substance of mechanical strength known to the mankind, than
Diamond is also hard, and taller upper 100 times of the intensity steel more best than the world.It also has a good flexibility, high thermal conductivity,
Chemical stabilization, the performances such as physical barrier and shielding.
Lacquer on the market is all one-component lacquer type organic coating at present, and one-component resin film forming is volatilized mainly by water and solvent
Afterwards, resin particle mutually accumulates film forming, and the film forming of two-component paint is the group in two kinds of components, is chemically reacted, and hands over
It is unified into film.This species diversity is in one-component resin paint, and paint film is easy that there are many defects, for example paint film porosity is big, hardness is low,
It is easy to cause microbial growth, pollution resistance decline, while water-fast, alkaline-resisting and ageing-resistant aspect is also not so good as two-component paint film.Therefore
The shortcomings that based on one-component lacquer type organic coating, has seriously affected decorative effect and service life of the lacquer as exterior coating.
Summary of the invention
Technical problem to be solved by the invention is to provide it is a kind of with excellent stain resistance, adhesive force, splitting resistance,
Graphene high-performance lacquer of water resistance, alkali resistance and temperature variation resistant and preparation method thereof.
The technical scheme of the invention to solve the technical problem is: a kind of graphene high-performance lacquer, by group
Divide A and component B composition, quality permillage is as follows:
The defoaming agent is any one in organic silicon defoaming agent and mineral oil antifoam agent, and the dispersing agent is
Non-ionic macromolecule dispersing agent.
The graphene is pure graphene powder, graphene oxide powder, high molecular material composite graphite alkene powder, micro-
Any one in meter level or nanoscale pigments and fillers composite graphite alkene powder and graphene aqueous slurry.
The thickener is hydroxyethyl cellulose, hydroxypropyl methyl cellulose, nonionic polyurethane thickener, alkali soluble
One of swollen thickener, fumed silica, bentonite, hectorite and polyamide wax or two kinds.
The water-base resin is water-based fluorocarbon resin, aqueous alkide resin, water-based hydroxyl acrylic acid dispersion and aqueous
One of polyurethane/acrylic acid composite dispersion or a variety of mixtures.
The coalescing agent be benzyl alcohol, propylene glycol, propylene glycol monomethyl ether, propylene glycol methyl ether acetate, propandiol butyl ether,
One or more of butyl acetic acid esters and dipropylene glycol methyl ether acetate mixture.
The natural colour sand be 10--20 mesh natural colour sand, 20--40 mesh natural colour sand, 40--80 mesh natural colour sand,
At least one of 80--120 mesh natural colour sand and 120--180 mesh natural colour sand, the sliver are lamella size in 1-3mm
At least one of sliver, 3-6mm sliver, 6-8mm sliver, 8-10mm sliver, 10-13mm sliver and 13-15mm sliver.
The curing agent is isocyanates.
The mixing mass ratio of the component A and the B component is (5-9): 1.
The preparation method of above-mentioned graphene high-performance lacquer, it is characterised in that the following steps are included:
(1) deionized water is added in dispersion cylinder, defoaming agent and dispersing agent is added while stirring, stone is then added
Black alkene is dispersed, revolving speed 1000--1500rpm, jitter time 20min；Then be added water-base resin, coalescing agent and
Thickener after mixing evenly, by the sliver of the natural colour sand and/or different colours of different colours and mesh number and size, proportionally
It is added in dispersion cylinder, revolving speed 400--600rpm, then time 5--8min is packaged to be component A；
(2) B component being made of curing agent and coalescing agent is added in the component A in dispersion cylinder, is stirred evenly i.e.
Graphene high-performance lacquer is obtained, wherein the mixing mass ratio of the component A and the B component is (5-9): 1.
Compared with the prior art, the advantages of the present invention are as follows:
(1) two-component lacquer is to be chemically reacted, be cross-linked by the group in molecule during film curing
Film possesses the performance that one-component lacquer type organic coating paint film is unable to reach, and two-component lacquer type organic coating is that the group in molecule participates in chemical reaction,
Along with the arrangement mode that intersects of graphene labyrinth structure formula in paint film, and the crosslinking film forming carried out, hardness of paint film are high,
Scraping and wiping resistance performance is good, and since paint film porosity is low, more excellent effect is shown in terms of water-fast, alkaline-resisting and pollution resistance
Fruit.
(2) the special two-dimensional structure of graphene allows to occur with the phospholipid molecule on bacterial cell membrane very strong mutual
Effect, and then the phospholipid molecule on bacterial cell membrane is directly extracted, the cell membrane for eventually leading to bacterium loses integrality, cell membrane
Interior substance outflow and it is dead.Due to the antisepsis and sterilization effect that graphene itself has, the growth of microorganism can effectively prevent, and
And surface of the paint film can also be prevented for a long time mouldy after paint film is dry, inhibit algae bio growth, therefore reduce to environment pair
The addition of human body nocuousness anticorrosion and bactericidal agent, enhances the stain resistance of lacquer.
(3) the very thin lamellar structure of graphene, the interlaced arrangement mode in paint film assign it also and have and is good
Physical barrier and shielding improve water-fast, the alkali resistance of paint film；And since graphene can also absorb some ultra violet rays, benefit
With high pyroconductivity, heat can be scattered and be conducted in surface of the paint film rapidly, therefore improve the weatherability of paint film.
(4) the special performance of graphene also improves the adhesive force, splitting resistance, scratch resistance of lacquer, to extend
The service life of lacquer, especially can adapt to the more severe area of weather.
(5) preparation method of graphene high-performance lacquer coating of the invention has graphene dispersion uniform, it is artificial and
The advantages of cost of material is low, simple production process is more widely applied it to improve existing lacquer production efficiency,
And the system no longer needs to reduce operational procedure using finish, shortens the construction period.
Specific embodiment
Present invention is further described in detail with reference to embodiments.
Embodiment 1
A kind of graphene high-performance lacquer, is made of component A and component B, and quality permillage is as follows:
,
Preparation method includes the following steps:
(1) will deionized water 70.0Kg be added dispersion cylinder in, sequentially added under the state that stirs at low speed defoaming agent 3.0Kg,
Dispersing agent 4.0Kg, 2wt% graphene aqueous slurry 5.0Kg, revolving speed 1000--1500rpm, jitter time 20min；Then
Revolving speed is reduced, water-based fluorocarbon resin 161.9Kg, Lauryl Alcohol ester coalescing agent 5.0Kg and non-ionic associative type polyurethane is added
Thickener 6.0Kg, revolving speed 600--800rpm, after mixing evenly, by 40--80 mesh Chrysan Yellow natural colour sand 480.0Kg, 80--
120 mesh Snow Flower White 150Kg, 80--120 mesh Chrysan Yellow natural colour sand 120.0Kg, are added in dispersion cylinder, revolving speed 400--
600rpm, time 5--8min, obtains component A；
(2) isocyanate curing agent 700Kg and coalescing agent is can be dispersed into (by benzyl alcohol 150Kg and propylene glycol monomethyl ether in water
150Kg composition) mixing, obtain B component；
(3) component A and B component 5:1 in mass ratio are mixed evenly to get graphene high-performance lacquer is arrived.
Embodiment 2
A kind of graphene high-performance lacquer, is made of component A and component B, and quality permillage is as follows:
Preparation method includes the following steps:
(1) will deionized water 83.0Kg be added dispersion cylinder in, sequentially added under the state that stirs at low speed defoaming agent 2.4Kg,
Dispersing agent 5.2Kg, nano mica powder composite graphite alkene powder 1.0Kg, revolving speed 1000--1500rpm, jitter time are
20min；Then revolving speed is reduced, water-based hydroxyl acrylic acid dispersion 150.0Kg, propandiol butyl ether 7.0Kg, gas phase titanium dioxide is added
Silicon thickener 0.4Kg and polyamide wax thickener 3.6Kg, revolving speed 600--800rpm after mixing evenly avenge 40--80 mesh
Grey 320.0Kg, 80--120 mesh Chinese red natural colour sand 120.0Kg, 120-180 mesh Chinese red natural colour sand 110Kg, 1--
The pure grassland green natural sliver 97.4Kg of 3mm dark fund color natural sliver 100.0Kg and 3--5mm is added in dispersion cylinder, and revolving speed is
400--600rpm, time 5--8min, obtains component A；
(2) isocyanate curing agent 800Kg and butyl acetic acid esters 80Kg, propylene glycol monomethyl ether is can be dispersed into water
120Kg mixing, obtains B component；
(3) A, B component 9:1 in mass ratio are mixed evenly and obtain graphene high-performance lacquer.
Embodiment 3
A kind of graphene high-performance lacquer, is made of component A and component B, and quality permillage is as follows:
,
Preparation method includes the following steps:
(1) will deionized water 108.0Kg be added dispersion cylinder in, sequentially added under the state that stirs at low speed defoaming agent 1.9Kg,
Dispersing agent 7.0Kg, pure graphene powder 0.5Kg, revolving speed 1000--1500rpm, jitter time 20min；Revolving speed is reduced, is added
Enter aqueous polyurethane/acrylic acid composite dispersion 130.0Kg, dipropylene glycol methyl ether acetate 9.0Kg, propylene glycol 1Kg and swelling
Native thickener 3.0Kg, revolving speed 600--800rpm, after mixing evenly, by the black natural colour sand 60.0Kg of 10--20 mesh Bao Zheng,
20--40 mesh Yellow Tiger Skin natural colour sand 90.0Kg, 40--80 mesh white marble natural colour sand 400.0Kg, 80--120 mesh white marble day
Right color sand 100.0Kg, 1--3mm dark fund color natural sliver 30.0Kg and 8--10mm pure white natural sliver 59.6Kg is added to point
It dissipates in cylinder, revolving speed 400--600rpm, time 5--8min obtain component A；
(2) by aqueous aromatic modified isocyanate curing agent 750Kg and dipropylene glycol methyl ether acetate 250Kg, B is obtained
Component；
(3) A, B component 7:1 in mass ratio are mixed evenly and obtain graphene high-performance lacquer, can directly into
Row spraying.
Embodiment 4
A kind of graphene high-performance lacquer, is made of component A and component B, and quality permillage is as follows:
,
Preparation method includes the following steps:
(1) deionized water 120.0Kg is added in dispersion cylinder, sequentially adds graphene under the state that stirs at low speed and defoams in advance
Agent 1.5Kg, dispersing agent 5.0Kg, PVP composite graphite alkene powder 0.8Kg, revolving speed 1000--1500rpm, jitter time are
20min；Then revolving speed is reduced, aqueous alkide resin 110.0Kg, benzyl alcohol 1.0Kg, propandiol butyl ether 2.0Kg diethyl two is added
Alcohol butyl ether acetic acid esters 2.0Kg and non-ionic associative type polyurethane thickener 3.5Kg, alkali swollen thickener 4.5Kg, revolving speed are
600--800rpm, after mixing evenly, by 40--80 mesh violet natural colour sand 340.0Kg, 80--120 mesh violet natural color
The blackish green compound sliver 60.0Kg of the compound sliver 140.0Kg and 10--13mm of sand 239.7Kg, 3--6mm pure white is added to dispersion
In cylinder, revolving speed 400--600rpm, time 5--8min obtain component A.
(3) it by aqueous aliphatic modified isocyanate curing agent 720Kg and propandiol butyl ether 200Kg, benzyl alcohol 80Kg, obtains
To B component.
A, B component are mixed evenly according to 6:1 and obtain graphene high-performance lacquer, can directly be sprayed.
Embodiment 5
A kind of graphene high-performance lacquer, is made of component A and component B, and quality permillage is as follows:
,
Preparation method includes the following steps:
(1) will deionized water 130.0Kg be added dispersion cylinder in, sequentially added under the state that stirs at low speed defoaming agent 1.5Kg,
Dispersing agent 5.5Kg, graphene oxide 0.6Kg, revolving speed 1000--1500rpm, jitter time 20min；Then revolving speed is reduced,
Water-based hydroxyl acrylic acid dispersion 180.0Kg, propylene glycol methyl ether acetate 8.0Kg and the thickening of non-ionic associative type polyurethane is added
Agent 2.0Kg, polyamide wax 3.0Kg, revolving speed 600--800rpm, after mixing evenly, by 40--80 mesh chicken red blood natural colour sand
420.0Kg, 80--120 mesh chicken red blood natural colour sand 180.0Kg, 6--8mm golden red natural sliver 50.0Kg and 13--15mm are pure
The compound sliver 19.4Kg of white is added in dispersion cylinder, and revolving speed 400--600rpm, time 5--8min obtain component A；
(2) isocyanate curing agent 770Kg and propylene glycol methyl ether acetate 115.0Kg, dipropylene glycol first is can be dispersed into water
Ether acetate 115Kg, obtains B component；
(3) component A and B component 8:1 in mass ratio are mixed evenly and obtain graphene high-performance lacquer, it can be straight
Tap into capable spraying.
It is integration test result and existing lacquer main indicator contrast table according to various embodiments below
After the implementation of the various embodiments of the test, the performance of graphene high-performance lacquer of the invention and existing lacquer product
Performance is compared, and antibacterial effect is prominent, in terms of alkali resistance, water resistance, high-low temperature resistant change, impact resistance, ageing-resistant and adhesive force all
It is significantly improved.
Above-mentioned defoaming agent is any one in organic silicon defoaming agent and mineral oil antifoam agent.Dispersing agent is non-ionic
Macromolecule dispersing agent.Graphene is pure graphene powder, graphene oxide powder, high molecular material composite graphite alkene powder, micro-
Any one in meter level or nanoscale pigments and fillers composite graphite alkene powder and graphene aqueous slurry.Thickener is that ethoxy is fine
Tie up element, hydroxypropyl methyl cellulose, nonionic polyurethane thickener, alkali swollen thickener, fumed silica, bentonite,
One of hectorite and polyamide wax or two kinds.Water-base resin is water-based fluorocarbon resin, aqueous alkide resin, water-based hydroxyl
One of acrylic acid dispersion and aqueous polyurethane/acrylic acid composite dispersion or a variety of mixtures.Coalescing agent is benzene first
Alcohol, propylene glycol, propylene glycol monomethyl ether, propylene glycol methyl ether acetate, propandiol butyl ether, butyl acetic acid esters and dipropylene glycol
One or more of methyl ether acetate mixture.Natural colour sand be 10--20 mesh natural colour sand, 20--40 mesh natural colour sand,
At least one of 40--80 mesh natural colour sand, 80--120 mesh natural colour sand and 120--180 mesh natural colour sand, sliver is lamella
Size in 1-3mm sliver, 3-6mm sliver, 6-8mm sliver, 8-10mm sliver, 10-13mm sliver and 13-15mm sliver extremely
Few one kind.
Above description is not limitation of the present invention, and the present invention is also not limited to the example above.The art it is common
Within the essential scope of the present invention, the variations, modifications, additions or substitutions made also should belong to protection of the invention to technical staff
Range.
Claims (10)
1. a kind of graphene high-performance lacquer, it is characterised in that be made of component A and component B, quality permillage is as follows:
2. a kind of graphene high-performance lacquer according to claim 1, it is characterised in that: the defoaming agent is organic
Any one in silicon class defoaming agent and mineral oil antifoam agent, the dispersing agent are non-ionic macromolecule dispersing agent.
3. a kind of graphene high-performance lacquer according to claim 1, it is characterised in that: the graphene is pure stone
Black alkene powder, graphene oxide powder, high molecular material composite graphite alkene powder, micron order or nanoscale pigments and fillers composite graphite
Any one in alkene powder and graphene aqueous slurry.
4. a kind of graphene high-performance lacquer according to claim 1, it is characterised in that: the thickener is hydroxyl second
Base cellulose, hydroxypropyl methyl cellulose, nonionic polyurethane thickener, alkali swollen thickener, fumed silica, swelling
One of soil, hectorite and polyamide wax or two kinds.
5. a kind of graphene high-performance lacquer according to claim 1, it is characterised in that: the water-base resin is water
In property fluorocarbon resin, aqueous alkide resin, water-based hydroxyl acrylic acid dispersion and aqueous polyurethane/acrylic acid composite dispersion
One or more mixtures.
6. a kind of graphene high-performance lacquer according to claim 1, it is characterised in that: the coalescing agent is benzene
Methanol, propylene glycol, propylene glycol monomethyl ether, propylene glycol methyl ether acetate, propandiol butyl ether, butyl acetic acid esters and dipropyl two
One or more of alcohol methyl ether acetate mixture.
7. a kind of graphene high-performance lacquer according to claim 1, it is characterised in that: the natural colour sand is
10--20 mesh natural colour sand, 20--40 mesh natural colour sand, 40--80 mesh natural colour sand, 80--120 mesh natural colour sand and 120--
At least one of 180 mesh natural colour sands, the sliver are lamella size in 1-3mm sliver, 3-6mm sliver, 6-8mm rock
At least one of piece, 8-10mm sliver, 10-13mm sliver and 13-15mm sliver.
8. a kind of graphene high-performance lacquer according to claim 1, it is characterised in that: the curing agent is isocyanide
Acid esters.
9. a kind of graphene high-performance lacquer according to claim 1, it is characterised in that: the component A and described
B component mixing mass ratio be (5-9): 1.
10. a kind of preparation method of graphene high-performance lacquer of any of claims 1-9, it is characterised in that packet
Include following steps:
(1) deionized water is added in dispersion cylinder, defoaming agent and dispersing agent is added while stirring, graphene is then added
Dispersed, revolving speed 1000--1500rpm, jitter time 20min；Then water-base resin, coalescing agent and thickening is added
After mixing evenly, the sliver of the natural colour sand and/or different colours of different colours and mesh number and size is proportionally added for agent
Into dispersion cylinder, then revolving speed 400--600rpm, time 5--8min are packaged to be component A；
(2) B component being made of curing agent and coalescing agent is added in the component A in dispersion cylinder, stirs evenly and obtains
Graphene high-performance lacquer, wherein the mixing mass ratio of the component A and the B component is (5-9): 1.
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| CN110282911A (en) * | 2019-07-22 | 2019-09-27 | 龚卫伟 | A kind of graphene exterior wall true stone paint |
| CN110981282A (en) * | 2019-12-02 | 2020-04-10 | 安徽富瑞雪化工科技股份有限公司 | Anticorrosive antibacterial stone-like paint and preparation method thereof |
| CN111072321A (en) * | 2020-01-20 | 2020-04-28 | 山东赛德丽新材料股份有限公司 | Preparation method of nano self-cleaning real stone paint |
| CN111620602A (en) * | 2020-05-30 | 2020-09-04 | 湖北美利佳涂料有限公司 | Real stone paint coating and preparation method thereof |
| CN113563747A (en) * | 2021-07-20 | 2021-10-29 | 安徽朗凯奇防水科技股份有限公司 | Waterproof real stone paint and preparation method thereof |
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| CN110282911A (en) * | 2019-07-22 | 2019-09-27 | 龚卫伟 | A kind of graphene exterior wall true stone paint |
| CN110981282A (en) * | 2019-12-02 | 2020-04-10 | 安徽富瑞雪化工科技股份有限公司 | Anticorrosive antibacterial stone-like paint and preparation method thereof |
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