CN115975414A - High-performance waterproof agent and production method thereof - Google Patents
High-performance waterproof agent and production method thereof Download PDFInfo
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- CN115975414A CN115975414A CN202111196540.8A CN202111196540A CN115975414A CN 115975414 A CN115975414 A CN 115975414A CN 202111196540 A CN202111196540 A CN 202111196540A CN 115975414 A CN115975414 A CN 115975414A
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- sodium
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- waterproof agent
- performance
- secondary alkyl
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 36
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229920001495 poly(sodium acrylate) polymer Chemical group 0.000 claims abstract description 22
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical group [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 22
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 21
- 239000011734 sodium Substances 0.000 claims abstract description 21
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 21
- XYRAEZLPSATLHH-UHFFFAOYSA-N trisodium methoxy(trioxido)silane Chemical compound [Na+].[Na+].[Na+].CO[Si]([O-])([O-])[O-] XYRAEZLPSATLHH-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003651 drinking water Substances 0.000 claims abstract description 17
- 235000020188 drinking water Nutrition 0.000 claims abstract description 17
- FXSGDOZPBLGOIN-UHFFFAOYSA-N trihydroxy(methoxy)silane Chemical compound CO[Si](O)(O)O FXSGDOZPBLGOIN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 125000005227 alkyl sulfonate group Chemical group 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000010410 layer Substances 0.000 claims description 15
- 239000012535 impurity Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 239000011229 interlayer Substances 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- 239000010451 perlite Substances 0.000 claims description 4
- 235000019362 perlite Nutrition 0.000 claims description 4
- 239000010963 304 stainless steel Substances 0.000 claims description 3
- 229910000589 SAE 304 stainless steel Inorganic materials 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 230000002940 repellent Effects 0.000 claims 2
- 239000005871 repellent Substances 0.000 claims 2
- 239000002344 surface layer Substances 0.000 claims 2
- 239000006260 foam Substances 0.000 claims 1
- 238000009413 insulation Methods 0.000 claims 1
- 239000012774 insulation material Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 238000004321 preservation Methods 0.000 abstract description 8
- 238000010438 heat treatment Methods 0.000 abstract description 6
- 239000007864 aqueous solution Substances 0.000 abstract description 3
- 239000012467 final product Substances 0.000 abstract description 3
- 230000035515 penetration Effects 0.000 abstract description 3
- 239000002861 polymer material Substances 0.000 abstract description 3
- 240000002853 Nelumbo nucifera Species 0.000 abstract description 2
- 235000006508 Nelumbo nucifera Nutrition 0.000 abstract description 2
- 235000006510 Nelumbo pentapetala Nutrition 0.000 abstract description 2
- 239000012190 activator Substances 0.000 abstract description 2
- 238000007689 inspection Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 1
- 235000015424 sodium Nutrition 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
- 239000000463 material Substances 0.000 description 7
- 230000035699 permeability Effects 0.000 description 6
- 239000011449 brick Substances 0.000 description 3
- 238000005553 drilling Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000003129 oil well Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 125000005372 silanol group Chemical group 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- CAQWNKXTMBFBGI-UHFFFAOYSA-N C.[Na] Chemical compound C.[Na] CAQWNKXTMBFBGI-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000011150 reinforced concrete Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-performance waterproof agent and a production method thereof, wherein the high-performance waterproof agent comprises the following raw materials: methyl silicic acid, sodium hydroxide, drinking water, sodium secondary alkyl sulfonate and sodium polyacrylate. The invention adopts a non-heating heat preservation mode for production, and can reduce the heating cost. The sodium secondary alkyl sulfonate is an excellent penetrant, the waterproof penetration depth can be increased by adding the sodium secondary alkyl sulfonate activator, the sodium polyacrylate belongs to a high polymer material, the purity of the sodium polyacrylate can be purified by adding the sodium polyacrylate, and meanwhile, the sodium secondary alkyl sulfonate and the sodium polyacrylate can be fused into a system after being diluted in an aqueous solution and passing through 70-90 ℃, and the system can improve the performance of the waterproof agent, so that the final product achieves a better use effect, and the high-efficiency high-quality organosilicon waterproof agent is produced. And (3) effect inspection: 10 times of water and 1 time of sodium methylsilicate are mixed, then the mixture is sprayed on the ground, and after drying, the ground is sprayed with water to show lotus leaf-shaped water drops, thereby showing excellent waterproofness.
Description
Technical Field
The invention relates to a waterproof agent, in particular to a high-performance sodium methylsilicate waterproof agent and a production method thereof.
Background
Sodium methylsilicate is a novel rigid building waterproof material and has good penetration crystallinity. The mechanism of the high-efficiency waterproof function is as follows: the silanol group in the molecular structure reacts with the silanol group in the silicate material for dehydration and crosslinking, thereby realizing the reverse capillary effect to form an excellent hydrophobic layer. Meanwhile, the material has the functions of micro-expansion and compactness increasing, and can be widely applied to the following fields:
1. the waterproof and moistureproof composite material is widely suitable for roofs, inner and outer walls, floors, toilets, kitchens, basements and warehouses and is also suitable for the barrier and seepage prevention of reinforced concrete structures;
2. for underground civil air defense engineering: such as culverts, bridges, dams, tunnels, large hydropower stations and water diversion works, to reduce water erosion and prevent weathering;
3. for various pools: such as swimming pools, clean water tanks, sewage tanks, water towers, etc.;
4. for superabsorbent inorganic aggregates: such as perlite plates, roof bricks, cement bricks, high-rise building light brick veneers, asbestos, inorganic fabrics, heat-insulating materials and the like, so that the waterproof and moistureproof effects are remarkable;
5. the water-soluble building paint is used for water resistance, color protection, pollution prevention and aging prevention, and is widely used for exterior wall veneering;
6. the additive used for emulsion paint, water glass and 107 glue can ensure that the emulsion paint has obvious hydrophobicity and can keep stable bonding strength;
7. the slurry is used for petroleum drilling, the viscosity and the density of the slurry can be adjusted, the collapse of the drilling can be effectively prevented, and the drilling rate is improved;
8. the device is used for pumping and injecting an oil production layer at the later stage of an oil well, and prevents a crust skeleton of the oil production layer from collapsing, so that oil far away from the oil well can be smoothly produced;
9. used for other special purposes for reducing water absorption and resisting permeability and water.
The sodium methyl silicate stock solution in the market still has obvious waterproof performance when 8 times of water is added, but the waterproof function is obviously reduced when the water is more than 8 times, and when the sodium methyl silicate stock solution is used for high-quality materials such as inorganic fabrics and the like, higher-quality sodium methyl silicate is needed, namely, the purity is high, impurities are few, and the liquid permeability is high; as well as permeability in terms of performance and more excellent waterproofing effect. Therefore, the method has good market prospect for improving the quality of the sodium methylsilicate on the premise of not increasing the cost of the sodium methylsilicate.
The currently common method for producing sodium methylsilicate is as follows: one heating and stirring tank, methyl silicic acid, sodium hydroxide, a catalyst and water are mixed, heated and stirred for 5 hours, a finished product of sodium methyl silicate is obtained after cooling, the finished product of sodium methyl silicate has turbidity, the permeability is poor after filtering, impurities obviously exist, the sodium methyl silicate can only be used for conventional waterproof action, and the power consumption during heating also causes the increase of production cost.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide a high-performance sodium methyl silicate waterproof agent and a production method thereof.
In order to achieve the above object, one of the technical solutions of the present invention is:
a high-performance waterproof agent comprises the following raw materials in parts by weight: 15-20 parts of methyl silicic acid, 15-20 parts of sodium hydroxide, 55-65 parts of drinking water, 4-6 parts of sodium secondary alkyl sulfonate and 0.5-1 part of sodium polyacrylate.
Preferably, the high-performance waterproof agent comprises the following raw materials in parts by weight: 17.5 parts of methyl silicic acid, 17.5 parts of sodium hydroxide, 59.5 parts of drinking water, 5 parts of sodium secondary alkyl sulfonate and 0.5 part of sodium polyacrylate.
The solid content of the methylsilicic acid was 60%.
The molecular weight of the sodium polyacrylate is 1200 ten thousand.
One of the technical schemes of the invention is as follows: the utility model provides a production method of high performance waterproof agent, first methylsilicic acid, sodium hydroxide, secondary alkyl sodium sulfonate and polyacrylic acid sodium add double-deck heat preservation tank together, then add one-third drinking water, add one-third drinking water after the stirring 6 hours the second time, at this moment, undissolved raw materials has all softened, jar body charge door seals and keeps warm, continue to stir 4 hours, add remaining drinking water, stir 10 minutes and stop stirring, cool to the room temperature, there is foamy impurity on the top layer of the tank mixture this moment, the bottom has precipitation impurity, the intermediate level is limpid methylsilicate sodium liquid, remove the impurity of top layer and bottom, the limpid liquid in intermediate level is high performance waterproof agent.
Further, the water temperature for the second water addition was 90 ℃.
The tank body of the double-layer heat-preservation tank is made of 304 stainless steel, the net thickness of the interlayer is 100mm, and the interlayer is filled with perlite heat-preservation material.
The invention has the beneficial effects that:
sodium polyacrylate belongs to a high polymer material, sodium secondary alkyl sulfonate is an excellent penetrating agent, and when the sodium secondary alkyl sulfonate is diluted in an aqueous solution, the sodium secondary alkyl sulfonate and the aqueous solution are fused into a system at 70-90 ℃, and the system can improve the performance of a waterproof agent, so that a final product achieves a better using effect. The practice result shows that compared with the existing sodium methyl silicate, the sodium methyl silicate produced by the invention has more excellent waterproof effect, can still achieve excellent waterproof effect after being mixed with 10 times of water, can be used for high-end waterproof products, and has lower dosage, better permeability and dosage saving.
Detailed Description
The following examples are provided to further illustrate the embodiments of the present invention.
The solid content of methylsilicic acid was 60%.
The molecular weight of the sodium polyacrylate is 1200 ten thousand.
The tank body of the double-layer heat-preservation tank is made of 304 stainless steel, the net thickness of the interlayer is 100mm, and the interlayer is filled with perlite heat-preservation material.
Example 1
A high-performance waterproof agent comprises the following raw materials in parts by weight: 17.5 parts of methyl silicic acid, 17.5 parts of sodium hydroxide, 59.5 parts of drinking water, 5 parts of secondary alkyl sodium sulfonate and 0.5 part of sodium polyacrylate.
The preparation method comprises the following steps: adding methylsilicic acid, sodium hydroxide, secondary alkyl sodium sulfonate and sodium polyacrylate together in the double-deck heat preservation jar, then adding one third of drinking water, add one third of drinking water (the temperature is 90 ℃) the second time after stirring 6 hours, at this moment, undissolved raw materials has all softened, jar body charge door seals and keeps warm, continue stirring 4 hours, add remaining drinking water, the stirring is stopped stirring for 10 minutes, cool to the room temperature, there is foamy impurity on the top layer of the tank mixture this moment, the bottom has precipitation impurity, the intermediate level is clear methyl sodium silicate liquid, detach the impurity of top layer and bottom, the limpid liquid in intermediate level is high performance waterproof agent promptly.
Example 2
A high-performance waterproof agent comprises the following raw materials in parts by weight: 15 parts of methyl silicic acid, 15 parts of sodium hydroxide, 55 parts of drinking water, 4 parts of secondary alkyl sodium sulfonate and 0.5 part of sodium polyacrylate.
The preparation method is the same as that of example 1.
Example 3
A high-performance waterproof agent comprises the following raw materials in parts by weight: 20 parts of methyl silicic acid, 20 parts of sodium hydroxide, 65 parts of drinking water, 6 parts of secondary alkyl sodium sulfonate and 1 part of sodium polyacrylate.
The preparation method is the same as that of example 1.
The invention adopts a non-heating heat preservation mode for production, and can reduce the heating cost. The sodium secondary alkyl sulfonate is an excellent penetrant, the waterproof penetration depth can be increased by adding the sodium secondary alkyl sulfonate activator, the sodium polyacrylate belongs to a high polymer material, the purity of the sodium polyacrylate can be purified by adding the sodium polyacrylate, and meanwhile, the sodium secondary alkyl sulfonate and the sodium polyacrylate can be fused into a system after being diluted in water and passing through 70-90 ℃, and the system can improve the performance of the waterproof agent, so that the final product achieves a better use effect, and the organosilicon waterproof agent with higher efficiency and higher quality is produced. And (3) effect inspection: 10 times of water is mixed with 1 time of the sodium methylsilicate waterproofing agent, then the mixture is sprayed on the ground, and after the mixture is dried, the water sprayed on the ground shows lotus leaf-shaped water drops, so that the water resistance is excellent. And because the sodium methylsilicate prepared by the invention has small and few impurities and high permeability, the material has wider application range.
Claims (7)
1. The high-performance waterproof agent is characterized by comprising the following raw materials in parts by weight: 15-20 parts of methyl silicic acid, 15-20 parts of sodium hydroxide, 55-65 parts of drinking water, 4-6 parts of sodium secondary alkyl sulfonate and 0.5-1 part of sodium polyacrylate.
2. The high-performance waterproof agent according to claim 1, which is characterized by comprising the following raw materials in parts by weight: 17.5 parts of methyl silicic acid, 17.5 parts of sodium hydroxide, 59.5 parts of drinking water, 5 parts of sodium secondary alkyl sulfonate and 0.5 part of sodium polyacrylate.
3. The high-performance water repellent agent according to claim 1 or 2, wherein the solids content of methylsilicic acid is 60%.
4. The high performance water repellent agent according to claim 1 or 2, wherein the molecular weight of sodium polyacrylate is 1200 ten thousand.
5. A production method of a high-performance waterproof agent as claimed in claim 1 or 2, wherein methylsilicic acid, sodium hydroxide, secondary alkyl sodium sulfonate and sodium polyacrylate are added together into a double-layer heat-insulating tank, then one third of drinking water is added, after stirring for 6 hours, one third of drinking water is added for the second time, at this time, undissolved raw materials are all softened, the tank charging opening is sealed and heat-insulated, stirring is continued for 4 hours, the rest drinking water is added, stirring is stopped for 10 minutes, cooling is performed to room temperature, at this time, foam impurities are formed on the surface layer of a mixture in the tank, precipitated impurities are formed on the bottom layer, the clear methylsilicate sodium liquid is used as the middle layer, and the impurities on the surface layer and the bottom layer are removed, and the clear liquid of the middle layer is the high-performance waterproof agent.
6. The method of claim 5, wherein the second addition of water is carried out at a temperature of 90 ℃.
7. The production method of claim 5, wherein the double-layer insulation tank body is made of 304 stainless steel, the net thickness of the interlayer is 100mm, and the interlayer is filled with perlite insulation material.
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CN202111196540.8A CN115975414A (en) | 2021-10-14 | 2021-10-14 | High-performance waterproof agent and production method thereof |
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CN202111196540.8A CN115975414A (en) | 2021-10-14 | 2021-10-14 | High-performance waterproof agent and production method thereof |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101921288A (en) * | 2010-07-23 | 2010-12-22 | 朱光皓 | Pasty high-efficiency methyl silanol potassium sodium waterproof agent and preparation method thereof |
CN103570272A (en) * | 2012-07-31 | 2014-02-12 | 邱小平 | Nano permeable silicone waterproofing agent and preparation method of waterproofing agent |
CN105236918A (en) * | 2015-09-16 | 2016-01-13 | 桂林市和鑫防水装饰材料有限公司 | Novel capillary crystalline waterproofing agent |
CN107163643A (en) * | 2017-07-19 | 2017-09-15 | 合肥广民建材有限公司 | A kind of new water repellent and preparation method thereof |
-
2021
- 2021-10-14 CN CN202111196540.8A patent/CN115975414A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101921288A (en) * | 2010-07-23 | 2010-12-22 | 朱光皓 | Pasty high-efficiency methyl silanol potassium sodium waterproof agent and preparation method thereof |
CN103570272A (en) * | 2012-07-31 | 2014-02-12 | 邱小平 | Nano permeable silicone waterproofing agent and preparation method of waterproofing agent |
CN105236918A (en) * | 2015-09-16 | 2016-01-13 | 桂林市和鑫防水装饰材料有限公司 | Novel capillary crystalline waterproofing agent |
CN107163643A (en) * | 2017-07-19 | 2017-09-15 | 合肥广民建材有限公司 | A kind of new water repellent and preparation method thereof |
Non-Patent Citations (3)
Title |
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路锋,聂江涛: "甲基硅酸钠(有机硅防水剂)的应用研究", 江西化工, no. 02, pages 325 - 34 * |
郑书忠等: "水处理药剂及其应用", 中国石化出版社, pages: 356 - 357 * |
陈建强, 范钱君, 张立华: "有机硅建筑防水剂的研究与发展", 浙江化工, no. 02, pages 23 - 24 * |
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