CN106810104A - A kind of waterproofing agent and preparation method thereof - Google Patents

A kind of waterproofing agent and preparation method thereof Download PDF

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Publication number
CN106810104A
CN106810104A CN201510865447.XA CN201510865447A CN106810104A CN 106810104 A CN106810104 A CN 106810104A CN 201510865447 A CN201510865447 A CN 201510865447A CN 106810104 A CN106810104 A CN 106810104A
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China
Prior art keywords
waterproofing agent
organosilicon
methane
silica
barium hydroxide
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Pending
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CN201510865447.XA
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Chinese (zh)
Inventor
安雪倩
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Tianchang Earthquake Office
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Tianchang Earthquake Office
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Priority to CN201510865447.XA priority Critical patent/CN106810104A/en
Publication of CN106810104A publication Critical patent/CN106810104A/en
Pending legal-status Critical Current

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  • Sealing Material Composition (AREA)
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Abstract

A kind of waterproofing agent, is made up of as following weight percent each component:Carboxylic styrene butadiene latex 15-30%, waterproofing agent of organosilicon 5-20%, silica 2-15%, barium hydroxide 5-10%, dodecyl sodium sulfate 0.2-1%, defoamer 1-3% and deionized water 20-45%.Beneficial effects of the present invention are:Penetration is strong, and hydrophobicity is good, environmentally friendly, and the waterproof layer of formation has lotus leaf water droplet effect, does not influence facade, and active material to penetrate into inside concrete and form the hole that a large amount of insoluble crystal block concrete, plays the effect of permanent waterproof.

Description

A kind of waterproofing agent and preparation method thereof
Technical field
The present invention relates to building material technical field, more particularly to a kind of crystal type architectural waterproof material.
Background technology
The characteristics of waterproof material has low temperature flexibility, self-healing property and adhesive property good, can normal temperature construction, speed of application is fast and meets environmental requirement.Especially without Hot-melt construction, remove the sorrow of fire from.Waterproof material resistance to low temperature is good, it is adaptable to waterproof of the industry with the roofing of civil building, basement, interior, municipal works, cistern, swimming pool, subway and tunnel, moistureproof and sealing.It is particularly suited for needing the military installations of cold construction and the water-tight corrosion-proof engineering such as oil depot, chemical plant, textile mills, grain depot of naked light should not be employed.
Concrete is a kind of composite porous, it is internal containing substantial amounts of hole and micro-crack, some corrosive mediums (such as villaumite, sulfate) can be in the presence of water as these defects enter inside concrete, these materials can corrode reinforcing bar, badly influence durability and the life-span of concrete structure.
The emphasis that concrete protection considers is exactly water resistance, is broadly divided into flexible water and rigid waterproofing.Flexible water refers to carry out outsourcing waterproof to structure with waterproof roll or water-repellent paint, so as to realize building waterproof.Rigid waterproofing refers to that building structure waterproof is realized by concrete body waterproof, that is, improve the impermeability of concrete, blocks the hole of concrete, prevents moisture from entering inside concrete.The anti-permeability performance by adding waterproofing agent raising concrete main at present, common waterproofing agent mainly has chloride salt, stearic acid salt, waterproofing agent of organic silicon etc..Wherein the impervious effect of chloride salt is fine, but Chloride Attack reinforcing bar, reduce building service life.Stearic acid salt is poor with the impervious effect of organic silicon waterproofing agent, does not reach seepage resistance demand.Organic silicon waterproofing agent has the advantages that penetrating power is strong, hydrophobicity is good but impermeability is poor.
The good and bad jumbled together in current waterproof material market, and especially cement-based penetrant waterproof material is even more uneven, it is impossible to ensure waterproof effect, causes the complaint of a large number of users.So solving the problem of waterproofing industry in the urgent need to a kind of novel concrete base osmotic crystalline waterproof material at present, good economic benefit and social benefit is brought.
The Chinese invention patent of Application No. 201110191320.6 discloses a kind of capillary crystalline waterproofing agent, the invention product only to concrete serve raising density and it is impervious the characteristics of, harm of the sulfate ion to concrete, and product can not be eliminated for milky white liquid is not colorless and transparent.And capillary crystalline waterproof agent prepared by the present invention is colourless transparent liquid, inorganic substances barium hydroxide penetrates into inside concrete reaction generation Barium sulfate crystals and blocks concrete pore, the sulfate ion in concrete is reduced while generation Barium sulfate crystals, infringement of the sulfate to concrete is reduced.
The content of the invention
Technical problem solved by the invention is to provide a kind of waterproofing agent and preparation method thereof, is used by directly brushing, for the waterproof protective treatment of concrete.
To achieve these goals, the present invention is adopted the following technical scheme that:
A kind of waterproofing agent, is made up of as following weight percent each component:Carboxylic styrene butadiene latex 15-30%, waterproofing agent of organosilicon 5-20%, silica 2-15%, barium hydroxide 5-10%, dodecyl sodium sulfate 0.2-1%, defoamer 1-3% and deionized water 20-45%.
The waterproofing agent of organosilicon is water white transparency methane-siliconic acid sodium solution, and methane-siliconic acid sodium content is 20-40%.
Preferably, a kind of waterproofing agent, is made up of as following weight percent each component:Carboxylic styrene butadiene latex 25%, waterproofing agent of organosilicon 15%, silica 1 0%, barium hydroxide 8%, dodecyl sodium sulfate 0.5%, defoamer 2% and deionized water 39.5%.
The waterproofing agent of organosilicon is water white transparency methane-siliconic acid sodium solution, and methane-siliconic acid sodium content is 35%.
The present invention also provides a kind of preparation method of waterproofing agent is:
By weight successively by water, carboxylic styrene butadiene latex, waterproofing agent of organosilicon, silica, dodecyl sodium sulfate, barium hydroxide addition reactor, it is then heated to reaction temperature, stirring, is cooled to after room temperature after being filtered to remove impurity, that is, obtain waterproofing agent of the invention.
The reaction temperature is 60 DEG C~70 DEG C, and mixing time is 30min~60min.
Beneficial effects of the present invention are:Penetration is strong, and hydrophobicity is good, environmentally friendly, and the waterproof layer of formation has lotus leaf water droplet effect, does not influence facade, and active material to penetrate into inside concrete and form the hole that a large amount of insoluble crystal block concrete, plays the effect of permanent waterproof.
Specific embodiment
For the technical scheme for being better understood from technical problem solved by the invention, provided, with reference to embodiments, the present invention will be described in further detail.Specific embodiment described herein is only used to explain implementation of the invention, but is not intended to limit the present invention.
Embodiment 1:
A kind of waterproofing agent, is made up of as following weight percent each component:Carboxylic styrene butadiene latex 20%, waterproofing agent of organosilicon 15%, silica 2%, barium hydroxide 5%, dodecyl sodium sulfate 0.2%, defoamer 1% and deionized water 45%.
The waterproofing agent of organosilicon is water white transparency methane-siliconic acid sodium solution, and methane-siliconic acid sodium content is 20%.
The preparation method of the present embodiment is:
By above-mentioned weight than successively by water, carboxylic styrene butadiene latex, waterproofing agent of organosilicon, silica, dodecyl sodium sulfate, barium hydroxide addition reactor, it is then heated to 60 DEG C of reaction temperature, stirring 30min, is cooled to after room temperature after being filtered to remove impurity, that is, obtain waterproofing agent of the invention.
Embodiment 2:
A kind of waterproofing agent, is made up of as following weight percent each component:Carboxylic styrene butadiene latex 25%, waterproofing agent of organosilicon 15%, silica 1 0%, barium hydroxide 8%, dodecyl sodium sulfate 0.5%, defoamer 2% and deionized water 39.5%.
The waterproofing agent of organosilicon is water white transparency methane-siliconic acid sodium solution, and methane-siliconic acid sodium content is 20-40%.
The preparation method of the present embodiment is:
By above-mentioned weight than successively by water, carboxylic styrene butadiene latex, waterproofing agent of organosilicon, silica, dodecyl sodium sulfate, barium hydroxide addition reactor, it is then heated to 65 DEG C of reaction temperature, stirring 35min, is cooled to after room temperature after being filtered to remove impurity, that is, obtain waterproofing agent of the invention.
Embodiment 3:
A kind of waterproofing agent, is made up of as following weight percent each component:Carboxylic styrene butadiene latex 30%, waterproofing agent of organosilicon 20%, silica 1 0%, barium hydroxide 10%, dodecyl sodium sulfate 1%, defoamer 3% and deionized water 26%.
The waterproofing agent of organosilicon is water white transparency methane-siliconic acid sodium solution, and methane-siliconic acid sodium content is 40%.
The preparation method of the present embodiment is:
By above-mentioned weight than successively by water, carboxylic styrene butadiene latex, waterproofing agent of organosilicon, silica, dodecyl sodium sulfate, barium hydroxide addition reactor, it is then heated to 70 DEG C of reaction temperature, stirring 40min, is cooled to after room temperature after being filtered to remove impurity, that is, obtain waterproofing agent of the invention.
The present invention is described in detail above by specific and preferred embodiment; but those skilled in the art should be understood that; the invention is not limited in embodiment described above; it is all within general principle of the invention; any modification, combination and equivalent for being made etc., are all contained within protection scope of the present invention.

Claims (6)

1. a kind of waterproofing agent, it is characterised in that be made up of as following weight percent each component:Carboxylic styrene butadiene latex 15-30%, waterproofing agent of organosilicon 5-20%, silica 2-15%, barium hydroxide 5-10%, dodecyl sodium sulfate 0.2-1%, defoamer 1-3% and deionized water 20-45%.
2. a kind of waterproofing agent according to claim 1, it is characterised in that the waterproofing agent of organosilicon is water white transparency methane-siliconic acid sodium solution, methane-siliconic acid sodium content is 20-40%.
3. a kind of waterproofing agent according to claim 1, it is characterised in that be made up of as following weight percent each component:Carboxylic styrene butadiene latex 25%, waterproofing agent of organosilicon 15%, silica 1 0%, barium hydroxide 8%, dodecyl sodium sulfate 0.5%, defoamer 2% and deionized water 39.5%.
4. a kind of waterproofing agent according to claim 3, it is characterised in that the waterproofing agent of organosilicon is water white transparency methane-siliconic acid sodium solution, methane-siliconic acid sodium content is 35%.
5. a kind of waterproofing agent described in claim 1, it is characterised in that its preparation method is:
By weight successively by water, carboxylic styrene butadiene latex, waterproofing agent of organosilicon, silica, dodecyl sodium sulfate, barium hydroxide addition reactor, it is then heated to reaction temperature, stirring, is cooled to after room temperature after being filtered to remove impurity, that is, obtain waterproofing agent of the invention.
6. the preparation method of a kind of waterproofing agent according to claim 5, it is characterised in that the reaction temperature is 60 DEG C~70 DEG C, mixing time is 30min~60min.
CN201510865447.XA 2015-12-02 2015-12-02 A kind of waterproofing agent and preparation method thereof Pending CN106810104A (en)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108863154A (en) * 2018-06-20 2018-11-23 河南阳光防水科技有限公司 Self-healing capillary crystalline waterproof agent
CN109053224A (en) * 2018-10-30 2018-12-21 青岛明象新材料技术有限公司 A kind of graphene nano silicon metal waterproofing agent and preparation method thereof
CN109135452A (en) * 2018-06-20 2019-01-04 河南阳光防水科技有限公司 Elastic infiltration solidification waterproofing agent
CN110256908A (en) * 2019-06-20 2019-09-20 上饶市春宇科技有限公司 A kind of environment-friendly type waterproofing agent and its processing method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108863154A (en) * 2018-06-20 2018-11-23 河南阳光防水科技有限公司 Self-healing capillary crystalline waterproof agent
CN109135452A (en) * 2018-06-20 2019-01-04 河南阳光防水科技有限公司 Elastic infiltration solidification waterproofing agent
CN109053224A (en) * 2018-10-30 2018-12-21 青岛明象新材料技术有限公司 A kind of graphene nano silicon metal waterproofing agent and preparation method thereof
CN110256908A (en) * 2019-06-20 2019-09-20 上饶市春宇科技有限公司 A kind of environment-friendly type waterproofing agent and its processing method

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Application publication date: 20170609

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