CN115891097A - High-performance wood-plastic composite material one-step extrusion molding energy-saving equipment - Google Patents
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
本发明公开了高性能木塑复合材料一步法挤出成型节能装备,包括正反双向螺纹异向锥型双螺杆径向出料挤出装置,入料器和大开槽均间同向锥型双螺杆挤出机;正反双向螺纹异向锥型双螺杆径向出料挤出装置位于上部,混合料通过入料器进入大开槽均间同向锥型双螺杆挤出机,该挤出机的螺杆的螺棱和螺槽的宽度比不大于1:4,螺棱和螺棱交叉处有均匀的间隙。本节能装备解决了现有挤出装备螺杆剪切对木质纤维造成降破碎,无法保留木质纤维原始形态,使得木质纤维对木塑的增强效果难以完全发挥的技术缺陷,解决了两步法工艺中物料从熔融状态降温储存,再加热熔融过程中的热量损耗问题,以更节能的方式生产出高性能的长木质纤维增强的木塑复合材料。
The invention discloses high-performance wood-plastic composite material one-step extrusion forming energy-saving equipment, including positive and negative two-way thread different-direction conical twin-screw radial discharge extrusion device, a feeder and a large slot uniformly conical in the same direction Twin-screw extruder; the positive and negative two-way thread different-direction conical twin-screw radial discharge extrusion device is located on the upper part, and the mixed material enters the large slot uniformly conical twin-screw extruder through the feeder. The width ratio of the screw flight and the screw groove of the extruded screw is not more than 1:4, and there is a uniform gap at the intersection of the screw flight and the flight. This energy-saving equipment solves the technical defect that the existing extruding equipment screw shears the wood fiber to reduce the crushing and cannot retain the original shape of the wood fiber, which makes it difficult to fully exert the reinforcing effect of the wood fiber on the wood-plastic, and solves the problem in the two-step process The material is cooled and stored from the molten state, and the heat loss problem in the reheating and melting process is used to produce high-performance long wood fiber-reinforced wood-plastic composite materials in a more energy-saving manner.
Description
技术领域technical field
本发明涉及新材料制造设备领域,具体涉及高性能木塑复合材料一步法挤出成型节能装备。The invention relates to the field of new material manufacturing equipment, in particular to energy-saving equipment for one-step extrusion molding of high-performance wood-plastic composite materials.
背景技术Background technique
木塑复合材料(简称木塑)是一类以热塑性聚合物为基体,以木质纤维为填充增强材料,通过熔融复合,采用挤出、注塑或模压等成型工艺而制备的复合材料,材性兼具木材和塑料的双重优点,是一类综合性能突出而生态和经济效益显著的环境友好材料。被广泛应用于建筑、园林景观、装饰装修、物流包装等行业。Wood-plastic composite material (referred to as wood-plastic) is a kind of composite material made of thermoplastic polymer as matrix, wood fiber as filling and reinforcing material, through melt compounding, extrusion, injection molding or compression molding and other molding processes. With the double advantages of wood and plastic, it is a kind of environmentally friendly material with outstanding comprehensive performance and remarkable ecological and economic benefits. It is widely used in construction, garden landscape, decoration, logistics packaging and other industries.
木塑复合材料的成型工艺主要采用二步法挤出成型,先将木质纤维和热塑性塑料经平行双螺杆高速剪切、熔融复合造粒,等造粒料冷却后,再利用异向锥形双螺杆较大的平移输送能力进行挤出成型。木塑复合材料的力学性能,在一定范围内跟木质纤维的长度或长径比成正比,木质纤维的长度越大、长径比越高,其增强效果越好,但是平行双螺杆的高速剪切作用会破坏木质纤维的原始形态,将木质纤维剪短破碎成粉末状颗粒,同时发生剪切热降解,使得木质纤维的增强效果大幅降低。热塑性聚合物分子链在螺杆的强力剪切作用下也会发生断裂,强度降低。此外,冷却的木塑粒料进入异向锥形双螺杆挤成型时,需进行二次加热熔融塑化,造成热量损耗和劳动力增加,同时,异向锥形双螺杆的塑化段还会对物料造成二次剪切,最终造成整体产品品质下降,能耗高升,成本增加。The molding process of wood-plastic composite materials mainly adopts two-step extrusion molding. First, the wood fiber and thermoplastic are sheared at high speed by parallel twin-screws, melted and compounded to make granules, and after the granulated materials are cooled, the different-direction conical twin The large translational conveying capacity of the screw is used for extrusion molding. The mechanical properties of wood-plastic composite materials are directly proportional to the length or aspect ratio of wood fibers within a certain range. The longer the length of wood fibers and the higher the aspect ratio, the better the reinforcement effect, but the parallel twin-screw high-speed shear The shearing action will destroy the original form of wood fibers, shorten and break wood fibers into powdery particles, and shear thermal degradation will occur at the same time, which will greatly reduce the reinforcement effect of wood fibers. The thermoplastic polymer molecular chain will also be broken under the strong shearing action of the screw, and the strength will be reduced. In addition, when the cooled wood-plastic pellets enter the counter-rotating conical twin-screw extrusion molding, secondary heating, melting and plasticizing is required, resulting in heat loss and labor increase. At the same time, the plasticizing section of the counter-rotating conical twin-screw will also The material causes secondary shearing, which ultimately leads to a decrease in the overall product quality, an increase in energy consumption, and an increase in cost.
发明内容Contents of the invention
本发明的目的在于克服现有技术的至少一个不足,提供一种高性能木塑复合材料一步法挤出成型节能装备。The object of the present invention is to overcome at least one deficiency of the prior art, and provide a high-performance wood-plastic composite material one-step extrusion molding energy-saving equipment.
本发明所采取的技术方案是:The technical scheme that the present invention takes is:
高性能木塑复合材料一步法挤出成型节能装备,包括正反双向螺纹异向锥型双螺杆径向出料挤出装置,入料器,大开槽均间同向锥型双螺杆挤出机,High-performance wood-plastic composite material one-step extrusion molding energy-saving equipment, including positive and negative two-way thread counter-rotating conical twin-screw radial discharge extrusion device, feeder, large slot uniformly conical twin-screw extrusion machine,
所述正反双向螺纹异向锥型双螺杆径向出料挤出装置位于上部,其螺杆包括工作部和尾部,工作部的螺纹为正向螺纹,尾部的螺纹为反向螺纹,所述正反双向螺纹异向锥型双螺杆径向出料挤出装置的第一出料口与所述入料器的第一进料口相连通;The positive and negative two-way thread different-direction conical twin-screw radial discharge extrusion device is located on the upper part, and its screw rod includes a working part and a tail part. The thread of the working part is a forward thread, and the thread of the tail part is a reverse thread. The first discharge port of the reverse two-way threaded counter-conical twin-screw radial discharge extrusion device is connected with the first feed port of the feeder;
所述入料器的第二出料口下方连通有所述大开槽均间同向锥型双螺杆挤出机的第二进料口;Below the second discharge port of the feeder is communicated with the second feed port of the large slotted uniform co-direction conical twin-screw extruder;
所述大开槽均间同向锥型双螺杆挤出机的螺杆的螺棱和螺槽的宽度比不大于1:4,螺棱和螺棱交叉处有均匀的间隙。The width ratio of the flight to the groove of the screw of the large-grooved co-rotating conical twin-screw extruder is not greater than 1:4, and there is a uniform gap at the intersection of the flight and the flight.
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述入料器包括一固定平台,所述固定平台设有一滑动架,所述滑动架连接有料筒。In some examples of energy-saving equipment for one-step extrusion molding of high-performance wood-plastic composite materials, the feeder includes a fixed platform, and the fixed platform is provided with a sliding frame, and the sliding frame is connected to a barrel.
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述螺棱和螺槽的宽度比为1:(4~8)。In some examples of high-performance wood-plastic composite material one-step extrusion molding energy-saving equipment, the width ratio of the screw rib and the screw groove is 1: (4-8).
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述大开槽均间同向锥型双螺杆挤出机的螺杆的螺棱的宽度为 10~15 mm。In some examples of energy-saving equipment for one-step extrusion molding of high-performance wood-plastic composite materials, the width of the flight of the screw of the large-slotted co-rotating conical twin-screw extruder is 10-15 mm.
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述大开槽均间同向锥型双螺杆挤出机的螺杆的螺槽的宽度为 60~100 mm。In some examples of energy-saving equipment for one-step extrusion molding of high-performance wood-plastic composite materials, the width of the grooves of the screws of the large-slotted co-rotating conical twin-screw extruder is 60-100 mm.
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述间隙的宽度为不低于10mm。In some examples of high-performance wood-plastic composite material one-step extrusion molding energy-saving equipment, the width of the gap is not less than 10 mm.
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述间隙宽度为10~15 mm。In some examples of high-performance wood-plastic composite material one-step extrusion molding energy-saving equipment, the gap width is 10-15 mm.
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述正反双向螺纹异向锥型双螺杆径向出料挤出装置的第一出料口为径向出料口,位于工作部正向螺纹和尾部反向螺纹的交界处。In some examples of energy-saving equipment for one-step extrusion molding of high-performance wood-plastic composite materials, the first outlet of the forward and reverse bidirectional threaded counter-rotating conical twin-screw radial outlet extrusion device is a radial outlet , located at the junction of the forward thread of the working part and the reverse thread of the tail.
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述第一出料口设有物料模具,模具设有通孔,物料通过所述模具的通孔被挤出。In some examples of high-performance wood-plastic composite material one-step extrusion molding energy-saving equipment, the first outlet is provided with a material mold, and the mold is provided with a through hole, and the material is extruded through the through hole of the mold.
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述入料器具有至少一个观察窗。In some examples of energy-saving equipment for one-step extrusion molding of high-performance wood-plastic composite materials, the feeder has at least one observation window.
本发明的有益效果是:The beneficial effects of the present invention are:
本发明的高性能木塑复合材料一步法挤出成型节能装备,解决了现有挤出装备螺杆剪切对木质纤维造成降解破碎,无法保留木质纤维原始形态,使得木质纤维对木塑的增强效果难以完全发挥的技术缺陷,解决了两步法工艺中物料从熔融状态降温储存,再加热熔融过程中的热量损耗问题,以更节能的方式生产出高性能的长木质纤维增强的木塑复合材料。The energy-saving equipment for one-step extrusion molding of high-performance wood-plastic composite materials of the present invention solves the problem of degradation and fragmentation of wood fibers caused by screw shearing in existing extrusion equipment, and cannot retain the original form of wood fibers, so that wood fibers can enhance the wood-plastic effect The technical defect that is difficult to fully exploit solves the problem of heat loss during the cooling and storage of materials from the molten state in the two-step process, and the heat loss during reheating and melting, and produces high-performance long wood fiber reinforced wood-plastic composite materials in a more energy-saving way .
附图说明Description of drawings
图1是本发明一些实例一步法挤出成型节能装备整体的结构示意图。Figure 1 is a schematic diagram of the overall structure of some examples of one-step extrusion molding energy-saving equipment of the present invention.
图2是正反双向螺纹异向锥型双螺标径向出料挤出装置的结构示意图。Fig. 2 is a structural schematic diagram of a double-screw radial discharge extrusion device with forward and reverse two-way threads and different directions.
图3是入料器的结构示意图。Figure 3 is a schematic structural view of the feeder.
图4是大开槽均间同向锥型双螺杆挤出机的结构示意图。Fig. 4 is a schematic structural view of a conical twin-screw extruder with large slots and uniform space.
附图标记:Reference signs:
正反双向螺纹异向锥型双螺杆径向出料挤出装置-1、螺筒-11、异向锥型螺杆-12、延伸轴悬架轴承箱-13、第一出料口(径向出料口)-14、物料模具-15、轴承-16;Positive and negative two-way thread counter-rotating conical twin-screw radial discharge extrusion device-1, screw barrel-11, counter-rotating conical screw-12, extension shaft suspension bearing box-13, the first discharge port (radial Outlet)-14, material mold-15, bearing-16;
入料器-2、入料口(第一进料口)-21、固定平台-22、滑动架-23、料筒-24Feeder-2, material inlet (first material inlet)-21, fixed platform-22, sliding frame-23, barrel-24
大开槽均间同向锥型双螺杆挤出机-3、螺棱-31、螺槽-32、间隙-33。Conical twin-screw extruder with large slots, uniform space and the same direction - 3, screw edge - 31, screw groove - 32, gap - 33.
图5是不同处理后杨木纤维的SEM照片。Figure 5 is the SEM photos of poplar wood fibers after different treatments.
具体实施方式Detailed ways
下面详细描述本发明的实施方式,实施方式的示例在附图中示出,其中相同或类似的标号自始至终表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施方式是示例性的,仅用于解释本发明,而不能理解为对本发明的限制。Embodiments of the present invention are described in detail below, and examples of the embodiments are shown in the drawings, wherein the same or similar reference numerals denote the same or similar elements or elements having the same or similar functions throughout. The embodiments described below by referring to the figures are exemplary only for explaining the present invention and should not be construed as limiting the present invention.
在本发明的描述中,需要理解的是,涉及到方位描述,例如上、下、前、后、左、右等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In the description of the present invention, it should be understood that the orientation descriptions, such as up, down, front, back, left, right, etc. indicated orientations or positional relationships are based on the orientations or positional relationships shown in the drawings, and are only In order to facilitate the description of the present invention and simplify the description, it does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and thus should not be construed as limiting the present invention.
在本发明的描述中,若干的含义是一个或者多个,多个的含义是两个以上,大于、小于、超过等理解为不包括本数,以上、以下、以内等理解为包括本数。如果有描述到第一、第二只是用于区分技术特征为目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量或者隐含指明所指示的技术特征的先后关系。In the description of the present invention, several means one or more, and multiple means two or more. Greater than, less than, exceeding, etc. are understood as not including the original number, and above, below, within, etc. are understood as including the original number. If the description of the first and second is only for the purpose of distinguishing the technical features, it cannot be understood as indicating or implying the relative importance or implicitly indicating the number of the indicated technical features or implicitly indicating the order of the indicated technical features relation.
此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”以及“第二”的特征可以明示或者隐含地包括一个或者更多个特征。In addition, the terms "first" and "second" are used for descriptive purposes only, and cannot be interpreted as indicating or implying relative importance or implicitly specifying the quantity of indicated technical features. Thus, features defined as "first" and "second" may explicitly or implicitly include one or more features.
在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“连接”应做广义理解,例如,可以是固定连接或活动连接,也可以是可拆卸连接或不可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接或可以相互通信;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通、间接连通或两个元件的相互作用关系。In the description of the present invention, it should be noted that unless otherwise specified and limited, the term "connection" should be understood in a broad sense, for example, it can be a fixed connection or a movable connection, or a detachable connection or a non-detachable connection , or integrally connected; can be mechanically connected, can also be electrically connected or can communicate with each other; can be directly connected, can also be indirectly connected through an intermediary, can be internal communication of two components, indirect communication or two components interaction relationship.
下文的公开提供了许多不同的实施方式或例子用来实现本发明的不同方案。The following disclosure provides many different embodiments or examples for implementing different aspects of the present invention.
参照图1~4,高性能木塑复合材料一步法挤出成型节能装备,包括正反双向螺纹异向锥型双螺杆径向出料挤出装置1,入料器2,大开槽均间同向锥型双螺杆挤出机3,Referring to Figures 1 to 4, high-performance wood-plastic composite material one-step extrusion molding energy-saving equipment, including positive and negative two-way thread counter-rotating conical twin-screw radial
所述正反双向螺纹异向锥型双螺杆径向出料挤出装置1位于上部,包括螺筒11,其异向锥型螺杆12包括工作部和尾部,工作部的螺纹为正向螺纹,尾部的螺纹为反向螺纹,所述正反双向螺纹异向锥型双螺杆径向出料挤出装置1的第一出料口15与所述入料器2的第一进料口21相连通;The positive and negative two-way thread counter-rotating conical twin-screw radial
所述入料器2的第二出料口下方连通有所述大开槽均间同向锥型双螺杆挤出机3的第二进料口;Below the second discharge port of the
所述大开槽均间同向锥型双螺杆挤出机的螺杆的螺棱31和螺槽32的宽度比不大于1:4,螺棱31和螺棱交31叉处有均匀的间隙33。The width ratio of the
更具体的,反向螺纹后有延伸轴伸出螺筒11,螺筒11外部安装有延伸轴悬架轴承箱13,由四组轴承16将双螺杆的两根延伸轴悬架旋转。More specifically, after the reverse thread, the extension shaft extends out of the
由于入料的物料是热料,使得不需要通常双螺杆的压缩混炼段效能,螺棱31和螺槽32的宽度比在1:4以上后螺槽32宽大,使得条状物料能方便地进入螺槽32被输送,螺棱31和螺槽32交叉处地均匀间隙33,使得物料在全程不发生剪切,保持物料中木质纤维的原始形态,锥型螺杆具有的正向输送和高压缩力方便物料建压挤出成型,实现压缩密实、挤出稳定。Since the feed material is hot material, it does not need the performance of the usual twin-screw compression mixing section. The width ratio of the
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述螺棱31和螺槽32的宽度比为1:(4~8)。这一宽度比下,可以更好地保持木质纤维的原始形态,进而提高木塑复合材料的性能。In some examples of high-performance wood-plastic composite material one-step extrusion molding energy-saving equipment, the width ratio of the
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述大开槽均间同向锥型双螺杆挤出机3的螺杆的螺棱31的宽度为 10~15 mm。这样保证螺棱31工作时有足够的强度,也可以更好地保持木质纤维的原始形态。In some examples of energy-saving equipment for one-step extrusion molding of high-performance wood-plastic composite materials, the width of the
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述大开槽均间同向锥型双螺杆挤出机3的螺杆的螺槽32的宽度为 60~100 mm。这样可以保证推送原料时具有较大的容积,同时也减少了对木质纤维的损伤。In some examples of energy-saving equipment for one-step extrusion molding of high-performance wood-plastic composite materials, the width of the
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述间隙33的宽度为不低于10mm。In some examples of high-performance wood-plastic composite material one-step extrusion molding energy-saving equipment, the width of the
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述间隙33宽度为10~15 mm。In some examples of high-performance wood-plastic composite material one-step extrusion molding energy-saving equipment, the width of the
间隙33的设置使用螺棱31与螺棱31运动交叉时不对物料产生剪切,这样可以更好地保持木质纤维的原始形态,进而提高木塑复合材料的性能。The
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述第一出料口14设有物料模具15,模具设有通孔,物料通过所述模具的通孔被挤出。这样使得物料可以呈长条状进入大开槽均间同向锥型双螺杆挤出机的螺杆。In some examples of high-performance wood-plastic composite material one-step extrusion molding energy-saving equipment, the
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述正反双向螺纹异向锥型双螺杆径向出料挤出装置的第一出料口为径向出料口14,位于工作部正向螺纹和尾部反向螺纹的交界处。利用异向锥型螺杆工作段的高效混炼塑化、高压缩低剪切特性,使混合好的物料进入入料口后被异向旋转的锥型双螺杆压缩混炼,并由正向输送螺纹向前输送,到达反向螺纹处时,被反向螺纹压缩,在螺筒部分的径向出料口14,进入出料口的物料模具15,模具上的分排圆孔使的物料成圆条状挤出,整个塑化输送和挤出过程中最大程度削弱螺杆剪切对木质纤维的降解破坏,达到混炼均匀、塑化完全的效果。In some examples of energy-saving equipment for one-step extrusion molding of high-performance wood-plastic composite materials, the first outlet of the forward and reverse bidirectional threaded counter-rotating conical twin-screw radial outlet extrusion device is a
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述入料器2包括一固定平台22,所述固定平台22设有一滑动架23,所述滑动架23连接有料筒24。这样在大开槽均间同向锥型双螺杆挤出机3的第二进料口堵塞时,可以方便的转移料筒24,进而对第二进料口进行清理。In some examples of energy-saving equipment for one-step extrusion molding of high-performance wood-plastic composite materials, the
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,料筒由透明材料制成,如由玻璃制成,这样可以方便地观察进料情况。特别的,料筒由双层玻璃构成,这样具有更好的保温效果。In some examples of energy-saving equipment for one-step extrusion of high-performance wood-plastic composite materials, the barrel is made of transparent materials, such as glass, so that the feeding situation can be easily observed. In particular, the barrel is made of double-layer glass, which has a better thermal insulation effect.
在一些高性能木塑复合材料一步法挤出成型节能装备的实例中,所述入料器具有至少一个观察窗。这样可以方便地观察进料情况。In some examples of energy-saving equipment for one-step extrusion molding of high-performance wood-plastic composite materials, the feeder has at least one observation window. This makes it easy to observe the feeding situation.
下面结合实例,进一步说明本发明的技术方案。Below in conjunction with example, further illustrate the technical scheme of the present invention.
实施例1Example 1
一种采用本发明高性能木塑复合材料一步法挤出成型节能装备生产的PE基木塑复合材料的制造方法,包括以下步骤:A method for manufacturing a PE-based wood-plastic composite material produced by the one-step extrusion molding energy-saving equipment of the high-performance wood-plastic composite material of the present invention, comprising the following steps:
将65份杨木纤维(40~80目)、18份HDPE、10份MAPE、5份滑石粉、1.7份润滑剂、0.3份抗氧剂充分混合均匀,加入到正反双向螺纹异向锥型双螺杆径向出料挤出机的料斗,经熔融复合造粒,热的PE基木塑粒料经可视入料器,落入大开槽均间同向锥型双螺杆挤出机的喂料口,经挤出成型得到PE基木塑复合材料,整个过程一步完成,PE基木塑粒料未经历冷却再加热熔融。Mix 65 parts of poplar wood fiber (40~80 mesh), 18 parts of HDPE, 10 parts of MAPE, 5 parts of talcum powder, 1.7 parts of lubricant, and 0.3 parts of antioxidant, and add them to the positive and negative two-way threaded counter-cone type The hopper of the twin-screw radial discharge extruder is melted and compounded to granulate, and the hot PE-based wood-plastic pellets fall into the hopper of the large-slotted uniformly conical twin-screw extruder through the visible feeder. The feeding port is extruded to obtain PE-based wood-plastic composite materials. The whole process is completed in one step. The PE-based wood-plastic pellets are not cooled and then heated and melted.
制备得到的PE基木塑复合材料的拉伸性能、弯曲性能、冲击性能、蠕变恢复率、吸水率、吸水尺寸变化率和生产能耗等性能测试结果,以及杨木纤维挤出前后的尺寸测试结果如表1 所示。The tensile properties, bending properties, impact properties, creep recovery rate, water absorption rate, water absorption dimensional change rate and production energy consumption of the prepared PE-based wood-plastic composite materials, as well as the dimensions of poplar fibers before and after extrusion The test results are shown in Table 1.
实施例2Example 2
一种采用本发明高性能木塑复合材料一步法挤出成型节能装备生产的PP基木塑地板的制造方法,包括以下步骤:A method for manufacturing a PP-based wood-plastic floor using one-step extrusion molding of high-performance wood-plastic composite material of the present invention and energy-saving equipment, comprising the following steps:
将65份杨木纤维(40~80目)、18份PP、10份MAPP、5份滑石粉、1.7份润滑剂、0.3份抗氧剂充分混合均匀,加入到正反双向螺纹异向锥型双螺杆径向出料挤出机的料斗,经熔融复合造粒,热的PP基木塑粒料经可视入料器,落入大开槽均间同向锥型双螺杆挤出机的喂料口,经挤出成型得到PP基木塑复合材料,整个过程一步完成,PP基木塑粒料未经历冷却再加热熔融。Mix 65 parts of poplar fiber (40~80 mesh), 18 parts of PP, 10 parts of MAPP, 5 parts of talcum powder, 1.7 parts of lubricant, and 0.3 parts of antioxidant, and add them to the positive and negative two-way threaded counter-cone type The hopper of the twin-screw radial discharge extruder is melted and compounded to granulate, and the hot PP-based wood-plastic pellets fall into the hopper of the large-slotted uniformly conical twin-screw extruder through the visible feeder. The feeding port is extruded to obtain PP-based wood-plastic composite materials. The whole process is completed in one step, and the PP-based wood-plastic pellets have not undergone cooling and then heating and melting.
制备得到的PP基木塑复合材料的拉伸性能、弯曲性能、冲击性能、蠕变恢复率、吸水率、吸水尺寸变化率和生产能耗等性能测试结果,以及杨木纤维挤出前后的尺寸测试结果如表2所示。The performance test results of the prepared PP-based wood-plastic composite materials such as tensile properties, bending properties, impact properties, creep recovery rate, water absorption rate, water absorption dimensional change rate and production energy consumption, as well as the dimensions of poplar fibers before and after extrusion The test results are shown in Table 2.
对比例1Comparative example 1
一种采用本二步法挤出装备生产的PE基木塑地板的制造方法,包括以下步骤:A method for manufacturing PE-based wood-plastic flooring produced by the two-step extrusion equipment, comprising the following steps:
S1、将65份杨木纤维(40~80目)、18份HDPE、10份MAPE、5份滑石粉、1.7份润滑剂、0.3份抗氧剂充分混合均匀后,采用传统平行双螺杆挤出机熔融复合,在出料口得到热的PE基木塑粒料,经二级或三级旋风分离器冷却得到PE基木塑粒料,储存备用;S1. After fully mixing 65 parts of poplar fiber (40~80 mesh), 18 parts of HDPE, 10 parts of MAPE, 5 parts of talcum powder, 1.7 parts of lubricant, and 0.3 parts of antioxidant, extrude with traditional parallel twin-screw Machine melting and compounding, hot PE-based wood-plastic pellets are obtained at the discharge port, cooled by a secondary or tertiary cyclone separator to obtain PE-based wood-plastic pellets, and stored for later use;
S2、将上述PE基木塑粒料加入到锥形双螺杆或单螺杆挤出机喂料口,经加热熔融后挤出成型得到PE基木塑复合材料。S2. Add the above-mentioned PE-based wood-plastic pellets to the feeding port of a conical twin-screw or single-screw extruder, heat and melt them, and extrude to obtain a PE-based wood-plastic composite material.
制备得到的PE基木塑地板的拉伸性能、弯曲性能、冲击性能、蠕变恢复率、吸水率、吸水尺寸变化率和生产能耗等性能测试结果,以及杨木纤维挤出前后的尺寸测试结果如表1所示。Performance test results of the prepared PE-based wood-plastic floor, such as tensile properties, bending properties, impact properties, creep recovery rate, water absorption rate, water absorption dimensional change rate and production energy consumption, as well as dimensional tests of poplar fibers before and after extrusion The results are shown in Table 1.
对比例2Comparative example 2
一种采用本二步法挤出装备生产的PE基木塑地板的制造方法,包括以下步骤:A method for manufacturing PE-based wood-plastic flooring produced by the two-step extrusion equipment, comprising the following steps:
S1、将65份杨木纤维(40~80目)、18份PP、10份MAPE、5份滑石粉、1.7份润滑剂、0.3份抗氧剂充分混合均匀后,采用传统平行双螺杆挤出机熔融复合,在出料口得到热的PP基木塑粒料,经二级或三级旋风分离器冷却得到PP基木塑粒料,储存备用;S1. After fully mixing 65 parts of poplar fiber (40~80 mesh), 18 parts of PP, 10 parts of MAPE, 5 parts of talcum powder, 1.7 parts of lubricant, and 0.3 parts of antioxidant, extrude by traditional parallel twin-screw Machine melting and compounding, hot PP-based wood-plastic pellets are obtained at the discharge port, cooled by a secondary or tertiary cyclone separator to obtain PP-based wood-plastic pellets, and stored for later use;
S2、将上述PP基木塑粒料加入到锥形双螺杆或单螺杆挤出机喂料口,经加热熔融后挤出成型得到PP基木塑复合材料。S2. Add the above-mentioned PP-based wood-plastic pellets to the feeding port of a conical twin-screw or single-screw extruder, heat and melt them, and extrude to obtain a PP-based wood-plastic composite material.
制备得到的PP基木塑地板的拉伸性能、弯曲性能、冲击性能、蠕变恢复率、吸水率、吸水尺寸变化率和生产能耗等性能测试结果,以及杨木纤维挤出前后的尺寸测试结果如表2所示。The performance test results of the prepared PP-based wood-plastic flooring such as tensile properties, bending properties, impact properties, creep recovery rate, water absorption rate, water absorption dimensional change rate and production energy consumption, as well as dimensional tests before and after extrusion of poplar fibers The results are shown in Table 2.
图5是不同处理后杨木纤维的SEM照片,其中:Fig. 5 is the SEM photo of poplar fiber after different treatments, wherein:
(a):未经挤出加工的40~80目杨木纤维的原始SEM照片;(a): The original SEM photo of 40-80 mesh poplar fibers without extrusion processing;
(b):实施列1中PE木塑材料的液氮催断面SEM照片;(b): SEM photo of the liquid nitrogen-catalyzed section of the PE wood-plastic material in Example 1;
(C):实施列1中PE木塑材料的液氮冷冻切面SEM照片;(C): SEM photo of the liquid nitrogen frozen section of the PE wood-plastic material in Example 1;
(d):从实施列1的PE木塑材料中提取的杨木纤维的SEM照片;(d): SEM photo of poplar fiber extracted from the PE wood-plastic material of Example 1;
(e):对比例1中PE木塑材料的液氮催断面SEM照片;(e): SEM photo of the liquid nitrogen-catalyzed section of the PE wood-plastic material in Comparative Example 1;
(f):对比例1中PE木塑材料的液氮冷冻切面SEM照片;(f): SEM photo of the liquid nitrogen frozen section of the PE wood-plastic material in Comparative Example 1;
(g):从对比例1中的PE木塑材料中提取的杨木纤维的SEM照片。(g): SEM photograph of poplar fiber extracted from the PE wood-plastic material in Comparative Example 1.
从图5可以看出,经本发明的高性能木塑复合材料一步法挤出成型节能装备的螺杆剪切塑化后,杨木纤维的尺寸和形态基本上保持了原始状态,而经传统二步法挤出装备的螺杆剪切塑化后,纤维被严重剪切破坏,变成小碎片。It can be seen from Fig. 5 that after the screw shearing and plasticizing of the high-performance wood-plastic composite material one-step extrusion molding energy-saving equipment of the present invention, the size and shape of the poplar fiber basically maintain the original state, while the traditional two After the screw of the step extrusion equipment is sheared and plasticized, the fibers are severely sheared and damaged and become small fragments.
表1Table 1
表2 Table 2
从表1和2的实验数据可以看出,杨木纤维经传统二步法挤出装备的螺杆剪切后,纤维长度、直径和长径比均显著减小,而经本发明的高性能木塑复合材料一步法挤出成型节能装备的螺杆剪切后,基本上保留率其原始值。且经本发明的高性能木塑复合材料一步法挤出成型节能装备挤出得到的木塑复合材料的拉伸性能、弯曲性能、冲击性能、蠕变恢复率、吸水尺寸稳定性均明显高于二步法,生产能耗等性能测试结果,而本发明一步法挤出成型的能耗比传统二步法降低了20%左右。As can be seen from the experimental data in Tables 1 and 2, after the poplar fiber is sheared by the screw of the traditional two-step extrusion equipment, the fiber length, diameter and aspect ratio all significantly reduce, while the high-performance wood fiber of the present invention The plastic composite material is extruded by one-step extrusion molding, and the screw of the energy-saving equipment basically retains its original value after shearing. And the tensile performance, bending performance, impact performance, creep recovery rate and water absorption dimensional stability of the wood-plastic composite material obtained by extruding the high-performance wood-plastic composite material in one-step extrusion molding energy-saving equipment of the present invention are all significantly higher than Two-step method, production energy consumption and other performance test results, and the energy consumption of the one-step extrusion molding of the present invention is reduced by about 20% compared with the traditional two-step method.
以上是对本发明所作的进一步详细说明,不可视为对本发明的具体实施的局限。对于本发明所属技术领域的普通技术人员来说,在不脱离本发明构思的简单推演或替换,都在本发明的保护范围之内。The above is a further detailed description of the present invention, and should not be regarded as a limitation to the specific implementation of the present invention. For those of ordinary skill in the technical field to which the present invention belongs, simple deduction or replacement without departing from the concept of the present invention is within the protection scope of the present invention.
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Citations (6)
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US20030021915A1 (en) * | 2001-06-15 | 2003-01-30 | Vivek Rohatgi | Cellulose - polymer composites and related manufacturing methods |
US20130065053A1 (en) * | 2010-04-28 | 2013-03-14 | Wpc Corporation | Method for producing composite pellet for extrusion molding, and composite pellet for extrusion molding produced by the method |
CN202826362U (en) * | 2012-10-23 | 2013-03-27 | 金世源 | Internal air-exhaust-type parallel counter-rotating multi-screw extruder |
CN103522518A (en) * | 2013-01-14 | 2014-01-22 | 许黎明 | Multifunctional wood-plastic composite material one-step method extruder |
CN105619750A (en) * | 2013-10-29 | 2016-06-01 | 吴红平 | Working method for EVA adhesive film extruder with feeding two-way regulating function |
JP2020011452A (en) * | 2018-07-18 | 2020-01-23 | 住友林業株式会社 | Manufacturing method of compression molding of cellulose fiber |
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Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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US20030021915A1 (en) * | 2001-06-15 | 2003-01-30 | Vivek Rohatgi | Cellulose - polymer composites and related manufacturing methods |
US20130065053A1 (en) * | 2010-04-28 | 2013-03-14 | Wpc Corporation | Method for producing composite pellet for extrusion molding, and composite pellet for extrusion molding produced by the method |
CN202826362U (en) * | 2012-10-23 | 2013-03-27 | 金世源 | Internal air-exhaust-type parallel counter-rotating multi-screw extruder |
CN103522518A (en) * | 2013-01-14 | 2014-01-22 | 许黎明 | Multifunctional wood-plastic composite material one-step method extruder |
CN105619750A (en) * | 2013-10-29 | 2016-06-01 | 吴红平 | Working method for EVA adhesive film extruder with feeding two-way regulating function |
JP2020011452A (en) * | 2018-07-18 | 2020-01-23 | 住友林業株式会社 | Manufacturing method of compression molding of cellulose fiber |
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