CN115849869A - Composite energy-saving ecological stone and manufacturing method thereof - Google Patents
Composite energy-saving ecological stone and manufacturing method thereof Download PDFInfo
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Abstract
The invention discloses a composite energy-saving ecological stone and a manufacturing method thereof, and particularly relates to the technical field of composite energy-saving ecological stones, which comprise the following components in parts by weight: 200-280 parts of gasified slag, 20-30 parts of microcrystalline glass powder, 20-30 parts of glass fiber powder, 40-50 parts of potassium-sodium mixed sand, 10-15 parts of ball clay, 10-30 parts of calcined coke, 5-10 parts of adhesive and 20-40 parts of purified water. The invention is prepared by waste gasification slag raw materials, so that the raw materials are effectively saved, the environment is protected, the resources are saved, the strength is ensured to be more excellent, and the internal structure is fully ensured to be more compact, so that the void ratio is effectively improved by mixing, the deformation resistance effect is better, the weight is lighter, rainwater is not easy to permeate, the waterproof effect is better, and the corrosion resistance is better.
Description
Technical Field
The invention relates to the technical field of composite energy-saving ecological stones, in particular to a composite energy-saving ecological stone and a manufacturing method thereof.
Background
Consumers put forward the requirements of light weight, high strength, beautiful appearance and multiple varieties to the decorative materials, and the ecological stone which better meets the requirements of circular economy, energy conservation and environmental protection gradually becomes the mainstream trend of product development in the stone industry, so the ecological stone plays an important role in the using process.
The invention patent of patent publication No. CN114790120A discloses a composite artificial building decorative stone and a production method thereof. The composite artificial stone comprises a base layer, a pattern layer and a transparent layer, and the method comprises the steps of printing a pattern on the surface of the stone by taking the stone as a substrate, paving a transparent base material on the surface of the pattern, and placing an adhesive on the surface of the base material. And waiting for the binder to completely penetrate into the base material layer, and carrying out operations such as vacuumizing, vibrating, curing and the like. The composite artificial stone has firm picture, no fading and oxidation, no easy abrasion and peeling, and high durability.
However, the base layer of the ecological stone is selected from stone materials which need to be mined and are not gasified slag, so that the selected materials are all natural mining raw materials during preparation in the preparation process, the waste cannot be recycled, the energy conservation and environmental protection are poor, and the ecological stone is not beneficial to changing waste into valuable.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention provides a composite energy-saving ecological stone and a manufacturing method thereof.
In order to achieve the purpose, the invention provides the following technical scheme: the composite energy-saving ecological stone is characterized by comprising the following components in parts by weight:
200-280 parts of gasified slag, 20-30 parts of microcrystalline glass powder, 20-30 parts of glass fiber powder, 40-50 parts of potassium-sodium mixed sand, 10-15 parts of ball clay, 10-30 parts of cooked coke, 5-10 parts of adhesive, 20-40 parts of purified water, 10-15 parts of E-44 epoxy resin and 5-10 parts of curing agent.
Preferably, the composition comprises the following components in parts by weight: 220-250 parts of gasified slag, 15-25 parts of microcrystalline glass powder, 15-25 parts of glass fiber powder, 30-40 parts of potassium-sodium mixed sand, 11-13 parts of ball clay 15-25 parts of cooked coke, 6-9 parts of adhesive, 25-30 parts of purified water, 12-14 parts of E-44 epoxy resin and 8-10 parts of curing agent.
Preferably, the composition comprises the following components in parts by weight: 230 parts of gasified slag, 20 parts of microcrystalline glass powder, 20 parts of glass fiber powder, 35 parts of potassium-sodium mixed sand, 12 parts of ball clay, 12 parts of calcined coke, 8 parts of adhesive, 28 parts of purified water, 13 parts of E-44 epoxy resin and 9 parts of curing agent.
Preferably, the microcrystalline glass powder and the glass fiber powder are in a powder state, the fineness of the powder state is controlled to be 100-200 meshes, the potassium-sodium mixed sand is prepared by mixing potassium feldspar and sodium feldspar according to a 2:1 ratio, clear water is required to be used for washing and filtering the potassium feldspar and the sodium feldspar before mixing to remove impurities, and the adhesive is mainly prepared from starch, dextrin, polyvinyl alcohol, carboxymethyl cellulose and shellac according to a weight ratio of 10:5:6:15:5, uniformly mixing the starch and the curing agent, wherein the starch is required to be kept at 30-40 ℃ when being mixed, and the curing agent is phenolsulfonic acid.
A method for manufacturing a composite energy-saving ecological stone comprises the following concrete steps:
firstly, when raw materials are ground, putting the gasified slag into a vibration screening machine, removing impurity and dust in the gasified slag, flushing the gasified slag for 5-10min by using clean water until no residual impurity exists on the surface of the gasified slag, brushing the gasified slag by using a brushing machine, dewatering the gasified slag, then sending the gasified slag into a dryer, pouring the gasified slag into a grinding machine, controlling the rotating speed of the grinding machine to be 40-60 r/min, and the grinding time to be 10-30min to obtain gasified slag powder, wherein the fineness of the gasified slag powder is controlled to be 100-200 meshes;
secondly, when the raw materials are mixed, the gasified slag powder, the microcrystalline glass powder, the glass fiber powder, the potassium-sodium mixed sand, the ball clay and the cooked coke are placed into a stirrer, the internal temperature of the stirrer is heated to 40-60 ℃ after the stirring time is 20-30min according to the rotating speed of 40-60 r/min, purified water and E-44 epoxy resin are added to continue to be mixed according to the rotating speed of 60-80 r/min and the stirring time of 10-20min, then the adhesive is extruded and dropped at the speed of one drop per three seconds, and a mixture is formed after the mixing is finished;
step three, when the raw materials are extruded, pouring the mixture into an extruder, extruding the mixture according to the pressure value of 3000-4000Pa, measuring the mixture by using a viscometer when the time interval of each extrusion is five seconds, and waiting for the viscosity of the mixture to be in the range of 4-6 Pa.s;
step four, when the die is formed, the mixture is injected into a die forming machine, a curing agent is added to realize mixing for 5min, the mixture is extruded by using auger transmission according to 1000-2000Pa at the rotating speed of 10-15 r/min, the mixture is extruded out from a rectangular hole, a layer of talcum powder is coated on the outer wall of a lower cutting blade, the lower cutting blade is used for cutting under the pressure of 5000-6000Pa, and the lower cutting blade is not bonded with the rectangular mixture;
step five, firing and forming, namely putting the rectangular mixture into a firing box, gradually heating to 400 ℃ from room temperature at a heating rate of 20C/10 min, and preserving heat for 1 hour when the temperature reaches 100 ℃, wherein the drying stage is as follows: heating to 700 ℃ at the speed of 50C/10 min from 400C, heating to 1200C at the speed of 80C/10 min from 700C, keeping the temperature for 2 hours at 1200C, taking out the composite energy-saving ecological stone, and placing the stone outdoors to cool to 38 ℃.
Preferably, the temperature of the dryer in the first step is set to 40-50 ℃, the drying time is 10-30min, and the dryer door needs to be opened at intervals of five seconds to release steam, heating equipment needs to be used to heat the purified water to 40-50 ℃ before the purified water is added in the second step, a temperature measuring instrument needs to be used for measuring the temperature for 3-5 times, the number of times of measurement of the viscometer in the third step is 3-5 times, the data obtained each time is recorded, and all the data are comprehensively stored in the number of times of data to obtain the average viscosity.
The invention has the technical effects and advantages that:
1. according to the invention, the gasified slag is placed into the vibration screening machine, impurity and dust in the gasified slag are removed, the gasified slag is washed for 5min by using clear water until no residual impurity is left on the surface of the gasified slag, the gasified slag is brushed and dehydrated by using the brushing machine and then sent into the drying machine, the strength of the gasified slag can be effectively improved by mixing the microcrystalline glass powder and the glass fiber powder, and the gasified slag is prepared from the waste gasified slag raw material, so that the raw material is effectively saved, the environment is protected, the resource is saved, and the strength of the gasified slag is ensured to be more excellent;
2. the method adopts the steps that potassium-sodium mixed sand, ball clay and cooked coke are put into a stirrer, the tightness of the connection in the stirrer is effectively improved after the stirring time is 20min according to the rotating speed of 40r/min, then the temperature is gradually increased to 400 ℃ at the temperature rising speed of 20C/10 min through the room temperature, and the temperature is kept for 1 hour when the temperature reaches 100 ℃, and the drying stage is: from 400C, the mixture is heated to 700C at a speed of 50C/10 min for firing, so that the internal structure is fully ensured to be more compact, the void ratio is effectively improved by mixing, the deformation resistance effect is better, and the weight is lighter;
3. according to the invention, the internal temperature of a heating stirrer is 40 ℃, purified water and E-44 epoxy resin are added and continuously heated to 50 ℃ according to the rotating speed of 80r/min, heating equipment is required to be used for heating the purified water before the purified water is added, and a temperature measuring instrument is required to measure 5 times, so that the purified water is uniformly mixed without temperature difference after entering, bubbles generated by expansion with heat and contraction with cold are avoided, the integral structure is enabled to drop by extrusion of an adhesive at the speed of one drop for three seconds, and then the curing is realized by a curing agent for 5min, and a layer of waterproof material is formed from inside to outside, so that rainwater is not easy to permeate, the waterproof effect is good, and the corrosion resistance is good;
to sum up, through the mutual influence of a plurality of above-mentioned effects, effective material saving, environmental protection more saves the resource and guarantees its intensity, anti deformation, water-proof effects, and the corrosion resistance effect is more excellent.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Embodiment 1, a composite energy-saving ecological stone, comprising the following components in parts by weight:
200 parts of gasified slag, 20 parts of microcrystalline glass powder, 20 parts of glass fiber powder, 40 parts of potassium-sodium mixed sand, 10 parts of ball clay and 10 parts of cooked coke.
Furthermore, the microcrystalline glass powder and the glass fiber powder are in a powder state, the fineness of the powder state is controlled to be 100 meshes, the potassium-sodium mixed sand is formed by mixing potassium feldspar and sodium feldspar according to a 2:1 ratio, the potassium feldspar and the sodium feldspar need to be washed by clear water before mixing, impurities are removed through filtration, and the adhesive is mainly prepared from starch, dextrin, polyvinyl alcohol, carboxymethyl cellulose and shellac according to a weight ratio of 10:5:6:15:5, uniformly mixing the starch and the curing agent, wherein the starch is required to be kept at 30 ℃ when being mixed, and the curing agent is phenolsulfonic acid.
A method for manufacturing a composite energy-saving ecological stone comprises the following concrete steps:
firstly, when raw materials are ground, putting the gasified slag into a vibration screening machine, removing impurity and dust in the gasified slag, washing for 5min by using clear water until no residual impurity exists on the surface of the gasified slag, brushing and dehydrating the gasified slag by using a brushing machine, and then sending the gasified slag into a dryer, setting the temperature of the dryer to 40 ℃, setting the drying time to 10min, opening a bin gate of the dryer to release steam at intervals of five seconds, pouring the gasified slag into a grinding machine, controlling the rotating speed of the grinding machine to be 40r/min, and grinding for 10min to obtain gasified slag powder, wherein the fineness of the gasified slag powder is controlled to be 100 meshes;
secondly, when the raw materials are mixed, the gasified slag powder, the microcrystalline glass powder, the glass fiber powder, the potassium-sodium mixed sand, the ball clay and the cooked coke are placed into a stirrer, the internal temperature of the stirrer is heated to 40 ℃ after 20min of stirring according to the rotating speed of 40r/min, purified water and E-44 epoxy resin are added, the purified water is heated to 50 ℃ by heating equipment before being added, the temperature is measured for 5 times by a temperature measuring instrument, the stirring time is 20min of mixing, the adhesive is extruded and dropped at the speed of one drop in three seconds, and a mixture is formed after the mixing is finished;
step three, when the raw materials are extruded, pouring the mixture into an extruder, extruding the mixture according to a pressure value of 4000Pa, wherein the time interval of each extrusion is five seconds, measuring the mixture by using a viscometer for 5 times, recording data obtained each time, comprehensively taking all data for the data times to obtain average viscosity, and obtaining the viscosity of the mixture within a 6Pa s interval;
step four, when the die is formed, the mixture is injected into a die forming machine, a curing agent is added to realize mixing for 5min, the mixture is extruded from a rectangular hole by using auger transmission at the rotating speed of 15r/min according to 2000Pa, a layer of talcum powder is coated on the outer wall of a lower cutting blade, the lower cutting blade is used for cutting under the pressure of 5000Pa, and the lower cutting blade is not bonded with the rectangular mixture;
step five, firing and forming, namely putting the rectangular mixture into a firing box, gradually heating to 400 ℃ from room temperature at a heating rate of 20C/10 min, and preserving heat for 1 hour when the temperature reaches 100 ℃, wherein the drying stage is as follows: heating to 700 ℃ at the speed of 50 ℃ per 10 minutes from 400 ℃, heating to 1200 ℃ at the speed of 80 ℃ per 10 minutes from 700 ℃, keeping the temperature of 1200 ℃ for 2 hours, taking out the composite energy-saving ecological stone, and placing the stone outdoors to cool to 38 ℃.
Embodiment 2, a composite energy-saving ecological stone, comprising the following components in parts by weight:
220 parts of gasified slag, 15 parts of microcrystalline glass powder, 15 parts of glass fiber powder, 30 parts of potassium-sodium mixed sand, 11 parts of ball clay, 15 parts of calcined coke, 6 parts of adhesive, 25 parts of purified water, 12 parts of E-44 epoxy resin and 8 parts of curing agent.
Furthermore, the microcrystalline glass powder and the glass fiber powder are in a powder state, the fineness of the microcrystalline glass powder and the glass fiber powder is controlled to be 100 meshes in the powder state, the potassium-sodium mixed sand is formed by mixing potassium feldspar and sodium feldspar according to a 2:1 proportion, clear water is required to be used for washing and filtering the potassium feldspar and the sodium feldspar to remove impurities before mixing, and the adhesive is mainly prepared from starch, dextrin, polyvinyl alcohol, carboxymethyl cellulose and shellac according to a weight ratio of 10:5:6:15:5, uniformly mixing the starch and the curing agent, wherein the starch is required to be kept at 30 ℃ when being mixed, and the curing agent is phenolsulfonic acid.
A method for manufacturing a composite energy-saving ecological stone comprises the following concrete steps:
firstly, when raw materials are ground, putting the gasified slag into a vibration screening machine, removing impurity and dust in the gasified slag, washing for 5min by using clear water until no residual impurity exists on the surface of the gasified slag, brushing and dewatering the gasified slag by using a brushing machine, then sending the gasified slag into a dryer, setting the drying temperature of the dryer to be 40 ℃, drying for 10min, opening a bin door of the dryer to release steam at intervals of five seconds, pouring the gasified slag into a grinding machine, controlling the rotating speed of the grinding machine to be 40r/min, and grinding for 10min to obtain gasified slag powder, wherein the fineness of the gasified slag powder is controlled to be 100 meshes;
secondly, when the raw materials are mixed, the gasified slag powder, the microcrystalline glass powder, the glass fiber powder, the potassium-sodium mixed sand, the ball clay and the cooked coke are placed into a stirrer, the internal temperature of the stirrer is heated to 40 ℃ after 20min of stirring according to the rotating speed of 40r/min, purified water and E-44 epoxy resin are added, the purified water is heated to 50 ℃ by heating equipment before being added, the temperature is measured for 5 times by a temperature measuring instrument, the stirring time is 20min of mixing, the adhesive is extruded and dropped at the speed of one drop in three seconds, and a mixture is formed after the mixing is finished;
step three, when the raw materials are extruded, pouring the mixture into an extruder, extruding the mixture according to a pressure value of 4000Pa, wherein the time interval of each extrusion is five seconds, measuring the mixture by using a viscometer for 5 times, recording data obtained each time, comprehensively taking all data for the data times to obtain average viscosity, and obtaining the viscosity of the mixture within a 6Pa s interval;
step four, when the die is formed, the mixture is injected into a die forming machine, a curing agent is added to realize mixing for 5min, the mixture is extruded from a rectangular hole by using auger transmission at the rotating speed of 15r/min according to 2000Pa, a layer of talcum powder is coated on the outer wall of a lower cutting blade, the lower cutting blade is used for cutting under the pressure of 5000Pa, and the lower cutting blade is not bonded with the rectangular mixture;
step five, firing and forming, namely putting the rectangular mixture into a firing box, gradually heating to 400 ℃ from room temperature at a heating rate of 20C/10 min, and preserving heat for 1 hour when the temperature reaches 100 ℃, wherein the drying stage is as follows: heating to 700 ℃ at the speed of 50C/10 min from 400C, heating to 1200C at the speed of 80C/10 min from 700C, keeping the temperature for 2 hours at 1200C, taking out the composite energy-saving ecological stone, and placing the stone outdoors to cool to 38 ℃.
Embodiment 3, a composite energy-saving ecological stone, comprising the following components in parts by weight:
230 parts of gasified slag, 20 parts of microcrystalline glass powder, 20 parts of glass fiber powder, 35 parts of potassium-sodium mixed sand, 12 parts of ball clay, 12 parts of cooked coke, 8 parts of adhesive, 28 parts of purified water, 13 parts of E-44 epoxy resin and 9 parts of curing agent.
Furthermore, the microcrystalline glass powder and the glass fiber powder are in a powder state, the fineness of the powder state is controlled to be 100 meshes, the potassium-sodium mixed sand is formed by mixing potassium feldspar and sodium feldspar according to a 2:1 ratio, the potassium feldspar and the sodium feldspar need to be washed by clear water before mixing, impurities are removed through filtration, and the adhesive is mainly prepared from starch, dextrin, polyvinyl alcohol, carboxymethyl cellulose and shellac according to a weight ratio of 10:5:6:15:5, uniformly mixing the starch and the curing agent, wherein the starch is required to be kept at 30 ℃ when being mixed, and the curing agent is phenolsulfonic acid.
A method for manufacturing a composite energy-saving ecological stone comprises the following concrete steps:
firstly, when raw materials are ground, putting the gasified slag into a vibration screening machine, removing impurity and dust in the gasified slag, washing for 5min by using clear water until no residual impurity exists on the surface of the gasified slag, brushing and dewatering the gasified slag by using a brushing machine, then sending the gasified slag into a dryer, setting the drying temperature of the dryer to be 40 ℃, drying for 10min, opening a bin door of the dryer to release steam at intervals of five seconds, pouring the gasified slag into a grinding machine, controlling the rotating speed of the grinding machine to be 40r/min, and grinding for 10min to obtain gasified slag powder, wherein the fineness of the gasified slag powder is controlled to be 100 meshes;
secondly, when the raw materials are mixed, the gasified slag powder, the microcrystalline glass powder, the glass fiber powder, the potassium-sodium mixed sand, the ball clay and the cooked coke are placed into a stirrer, the internal temperature of the stirrer is heated to 40 ℃ after 20min of stirring according to the rotating speed of 40r/min, purified water and E-44 epoxy resin are added, the purified water is heated to 50 ℃ by heating equipment before being added, the temperature is measured for 5 times by a temperature measuring instrument, the stirring time is 20min of mixing, the adhesive is extruded and dropped at the speed of one drop in three seconds, and a mixture is formed after the mixing is finished;
step three, when the raw materials are extruded, pouring the mixture into an extruder, extruding the mixture according to a pressure value of 4000Pa, wherein the time interval of each extrusion is five seconds, measuring the mixture by using a viscometer for 5 times, recording data obtained each time, comprehensively taking all data for the data times to obtain average viscosity, and obtaining the viscosity of the mixture within a 6Pa s interval;
step four, when the die is formed, the mixture is injected into a die forming machine, a curing agent is added to realize mixing for 5min, the mixture is extruded from a rectangular hole by using auger transmission at the rotating speed of 15r/min according to 2000Pa, a layer of talcum powder is coated on the outer wall of a lower cutting blade, the lower cutting blade is used for cutting under the pressure of 5000Pa, and the lower cutting blade is not bonded with the rectangular mixture;
step five, firing and forming, namely putting the rectangular mixture into a firing box, gradually heating to 400 ℃ from room temperature at a heating rate of 20C/10 min, and preserving heat for 1 hour when the temperature reaches 100 ℃, wherein the drying stage is as follows: heating to 700 ℃ at the speed of 50C/10 min from 400C, heating to 1200C at the speed of 80C/10 min from 700C, keeping the temperature for 2 hours at 1200C, taking out the composite energy-saving ecological stone, and placing the stone outdoors to cool to 38 ℃.
Comparative example 1:
the following components are added in sequence according to the parts by weight: 200 parts of gasified slag, 20 parts of microcrystalline glass powder, 20 parts of glass fiber powder, 40 parts of potassium-sodium mixed sand, 10 parts of ball clay, 10 parts of cooked coke, 5 parts of adhesive, 20 parts of purified water, 10 parts of E-44 epoxy resin and 5 parts of curing agent.
Five kinds of composite energy-saving ecological stones can be obtained through the three groups of embodiments, the three kinds of composite energy-saving ecological stones are respectively tested, and different changes of the composite energy-saving ecological stones in the three groups of embodiments are obtained as a result, wherein the composite energy-saving ecological stone in embodiment 3 is best in strength, better in anti-deformation effect, lighter in weight and better in waterproof effect, and in the testing process, the obtained parameters are as follows:
| crush index value/N | Void fraction/%) | Water absorption/%) | |
| Existing ecological stone | 12 | 10 | 5 |
| Example 1 | 14 | 8 | 2 |
| Example 2 | 18 | 6 | 1.5 |
| Example 3 | 20 | 4 | 1 |
(wherein the crush index value is calculated by (δ a) = (m 0-m 1)/m 0 × 100%, the crush index indicates the ability of the stone to resist crushing, and the strength corresponding thereto is indirectly estimated), the void ratio is calculated by (void ratio = (1- ρ/ρ a) × 100%), and the water absorption ratio is calculated by (water absorption ratio calculation formula W = (B-G)/G × 100%; W is the water absorption ratio expressed in percentage, G is the weight of the sample after drying, expressed in grams, B is the weight of the sample after being saturated with moisture, expressed in grams, expressed in physical quantity indicating the degree of water absorption of the object at normal atmospheric pressure, expressed in percentage, and the property of the material capable of absorbing moisture in water is referred to as water absorption) or more than (GB/T14685-2010).
From the data, the edible mixed salt prepared in the embodiment 3 of the invention has an obvious and excellent effect on the composite energy-saving ecological stone in the testing process, can effectively improve the strength of the composite energy-saving ecological stone by mixing the gasified slag, the microcrystalline glass powder and the glass fiber powder, can be prepared from waste gasified slag raw materials, effectively saves raw materials, is more environment-friendly and resource-saving, and has better effects on environmental protection and energy saving.
Claims (10)
1. The composite energy-saving ecological stone is characterized by comprising the following components in parts by weight:
200-280 parts of gasified slag, 20-30 parts of microcrystalline glass powder, 20-30 parts of glass fiber powder, 40-50 parts of potassium-sodium mixed sand, 10-15 parts of ball clay, 10-30 parts of cooked coke, 5-10 parts of adhesive, 20-40 parts of purified water, 10-15 parts of E-44 epoxy resin and 5-10 parts of curing agent.
2. The composite energy-saving ecological stone as claimed in claim 1, which is characterized by comprising the following components in parts by weight: 220-250 parts of gasified slag, 15-25 parts of microcrystalline glass powder, 15-25 parts of glass fiber powder, 30-40 parts of potassium-sodium mixed sand, 11-13 parts of ball clay, 15-25 parts of cooked coke, 6-9 parts of adhesive, 25-30 parts of purified water, 12-14 parts of E-44 epoxy resin and 8-10 parts of curing agent.
3. The composite energy-saving ecological stone as claimed in claim 1, which is characterized by comprising the following components in parts by weight: 230 parts of gasified slag, 20 parts of microcrystalline glass powder, 20 parts of glass fiber powder, 35 parts of potassium-sodium mixed sand, 12 parts of ball clay, 12 parts of cooked coke, 8 parts of adhesive, 28 parts of purified water, 13 parts of E-44 epoxy resin and 9 parts of curing agent.
4. The composite energy-saving ecological stone as claimed in claim 1, wherein: the microcrystalline glass powder and the glass fiber powder are in a powder state, and the fineness of the powder state is controlled to be 100-200 meshes.
5. The composite energy-saving ecological stone as claimed in claim 1, wherein: the potassium-sodium mixed sand is prepared by mixing potassium feldspar and albite according to the proportion of 2:1, and the potassium feldspar and the albite need to be washed by clear water and filtered to remove impurities before mixing.
6. The composite energy-saving ecological stone as claimed in claim 1, wherein: the adhesive is mainly prepared from starch, dextrin, polyvinyl alcohol, carboxymethyl cellulose and shellac according to the weight ratio of 10:5:6:15:5, uniformly mixing the starch and the curing agent, wherein the starch is required to be kept at 30-40 ℃ when being mixed, and the curing agent is phenolsulfonic acid.
7. The composite energy-saving ecological stone according to any one of claims 1 to 6, further comprising a manufacturing method of the composite energy-saving ecological stone, and the concrete preparation steps are as follows:
firstly, when raw materials are ground, putting the gasified slag into a vibration screening machine, removing impurity and dust in the gasified slag, flushing the gasified slag for 5-10min by using clean water until no residual impurity exists on the surface of the gasified slag, brushing the gasified slag by using a brushing machine, dewatering the gasified slag, then sending the gasified slag into a dryer, pouring the gasified slag into a grinding machine, controlling the rotating speed of the grinding machine to be 40-60 r/min, and the grinding time to be 10-30min to obtain gasified slag powder, wherein the fineness of the gasified slag powder is controlled to be 100-200 meshes;
secondly, when the raw materials are mixed, the gasified slag powder, the microcrystalline glass powder, the glass fiber powder, the potassium-sodium mixed sand, the ball clay and the cooked coke are placed into a stirrer, the internal temperature of the stirrer is heated to 40-60 ℃ after the stirring time is 20-30min according to the rotating speed of 40-60 r/min, purified water and E-44 epoxy resin are added to continue to be mixed according to the rotating speed of 60-80 r/min and the stirring time of 10-20min, then the adhesive is extruded and dropped at the speed of one drop per three seconds, and a mixture is formed after the mixing is finished;
step three, when extruding the raw materials, pouring the mixture into an extruder, extruding the mixture according to the pressure value of 3000-4000Pa, measuring the mixture by using a viscometer when the extrusion interval time of each time is five seconds, and waiting for the viscosity of the mixture to be in the interval of 4-6Pa s;
step four, when the die is formed, the mixture is injected into a die forming machine, a curing agent is added to realize mixing for 5min, the mixture is extruded from a rectangular hole site by using auger transmission at the rotating speed of 10 r/min-15 r/min according to 1000-2000Pa, a layer of talcum powder is coated on the outer wall of the lower cutting blade, the lower cutting blade is used for cutting under the pressure of 5000-6000Pa, and the lower cutting blade is not bonded with the rectangular mixture;
step five, firing and forming, namely putting the rectangular mixture into a firing box, gradually heating to 400 ℃ from room temperature at a heating rate of 20C/10 min, and preserving heat for 1 hour when the temperature reaches 100 ℃, wherein the drying stage is as follows: heating to 700 ℃ at the speed of 50C/10 min from 400C, heating to 1200C at the speed of 80C/10 min from 700C, keeping the temperature for 2 hours at 1200C, taking out the composite energy-saving ecological stone, and placing the stone outdoors to cool to 38 ℃.
8. The manufacturing method of the composite energy-saving ecological stone as claimed in claim 7, wherein the manufacturing method comprises the following steps: in the step one, the temperature of the dryer is set to be 40-50 ℃, the drying time is 10-30min, and the drying process needs to be carried out for five seconds to open a bin door of the dryer to release steam.
9. The manufacturing method of the composite energy-saving ecological stone as claimed in claim 7, wherein the manufacturing method comprises the following steps: heating equipment is needed to heat the purified water to 40-50 ℃ before adding the purified water in the second step, and a temperature measuring instrument is needed to measure the temperature for 3-5 times.
10. The manufacturing method of the composite energy-saving ecological stone as claimed in claim 7, wherein the manufacturing method comprises the following steps: and in the third step, the measurement times of the viscometer are 3-5 times, the data obtained each time are recorded, and all the data are comprehensively recorded in the data times to obtain the average viscosity.
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| CN117381942A (en) * | 2023-10-10 | 2024-01-12 | 广州市恒宏生态建材有限公司 | Preparation process of environment-friendly and wear-resistant inorganic ecological stone |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0891901A (en) * | 1994-09-21 | 1996-04-09 | Tomokatsu Yohena | Artificial stone |
| CN1153148A (en) * | 1995-12-29 | 1997-07-02 | 王珣 | Method for producing artificial stone |
| CN102167616A (en) * | 2011-01-06 | 2011-08-31 | 浙江兰亭高科股份有限公司 | Special artificial stone raw material formula and production process thereof |
| CN103204661A (en) * | 2013-03-20 | 2013-07-17 | 安徽瑞翔石英制品有限公司 | High-impact-resistant artificial quartz stone plate and production process thereof |
| CN105271945A (en) * | 2015-09-29 | 2016-01-27 | 广西钟山县中源石业有限公司 | Artificial granite and making method thereof |
| CN109279820A (en) * | 2018-10-18 | 2019-01-29 | 合肥慧林建材有限公司 | A kind of heat preservation fireproofing material and preparation method thereof |
| CN111454051A (en) * | 2020-04-07 | 2020-07-28 | 山东狮子王陶瓷科技有限公司 | Ecological stone and preparation method thereof |
| CN114180588A (en) * | 2021-12-01 | 2022-03-15 | 山西大学 | Method for preparing magnetic zeolite by using red mud in cooperation with carbon-containing aluminum-silicon waste |
-
2022
- 2022-12-10 CN CN202211584942.XA patent/CN115849869B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0891901A (en) * | 1994-09-21 | 1996-04-09 | Tomokatsu Yohena | Artificial stone |
| CN1153148A (en) * | 1995-12-29 | 1997-07-02 | 王珣 | Method for producing artificial stone |
| CN102167616A (en) * | 2011-01-06 | 2011-08-31 | 浙江兰亭高科股份有限公司 | Special artificial stone raw material formula and production process thereof |
| CN103204661A (en) * | 2013-03-20 | 2013-07-17 | 安徽瑞翔石英制品有限公司 | High-impact-resistant artificial quartz stone plate and production process thereof |
| CN105271945A (en) * | 2015-09-29 | 2016-01-27 | 广西钟山县中源石业有限公司 | Artificial granite and making method thereof |
| CN109279820A (en) * | 2018-10-18 | 2019-01-29 | 合肥慧林建材有限公司 | A kind of heat preservation fireproofing material and preparation method thereof |
| CN111454051A (en) * | 2020-04-07 | 2020-07-28 | 山东狮子王陶瓷科技有限公司 | Ecological stone and preparation method thereof |
| CN114180588A (en) * | 2021-12-01 | 2022-03-15 | 山西大学 | Method for preparing magnetic zeolite by using red mud in cooperation with carbon-containing aluminum-silicon waste |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117381942A (en) * | 2023-10-10 | 2024-01-12 | 广州市恒宏生态建材有限公司 | Preparation process of environment-friendly and wear-resistant inorganic ecological stone |
| CN117381942B (en) * | 2023-10-10 | 2024-05-03 | 广州市恒宏生态建材有限公司 | Preparation process of environment-friendly and wear-resistant inorganic ecological stone |
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|---|---|
| CN115849869B (en) | 2023-08-22 |
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