CN106495579A - A kind of preparation method of bi-component cement based mending mortar - Google Patents

A kind of preparation method of bi-component cement based mending mortar Download PDF

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Publication number
CN106495579A
CN106495579A CN201610890332.0A CN201610890332A CN106495579A CN 106495579 A CN106495579 A CN 106495579A CN 201610890332 A CN201610890332 A CN 201610890332A CN 106495579 A CN106495579 A CN 106495579A
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China
Prior art keywords
component
filter cake
gained
filtrate
cement based
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CN201610890332.0A
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Inventor
周丽花
许洪祥
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Changzhou Dingri Environmental Protection Technology Co Ltd
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Changzhou Dingri Environmental Protection Technology Co Ltd
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Priority to CN201610890332.0A priority Critical patent/CN106495579A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

The invention discloses a kind of preparation method of bi-component cement based mending mortar, belongs to building material technical field.The present invention is first by corn straw smashing, mix with second pond activated sludge, yellow sand etc. again, filter cake is collected after anaerobic fermentation, then filter cake and cement, Pulvis Talci and calcium chloride solution are mixed in proportion prepared component A, then rice husk fermentation is calcined under hot conditionss, rice hull ash after by calcining is dissolved in sodium hydroxide solution, after being filtered to remove impurity, concentrated by rotary evaporation is obtained B component, during use, component A is mixed in proportion with B component, bi-component cement based mending mortar is obtained final product.Gained mending mortar of the present invention is good with old concrete interface compatibility, is firmly bonded, and can be fully infiltrated in hole, improves the intensity and service life of concrete.

Description

A kind of preparation method of bi-component cement based mending mortar
Technical field
The invention discloses a kind of preparation method of bi-component cement based mending mortar, belongs to building material technical field.
Background technology
Concrete repair, protection and to reinforce industry promoted by the degeneration of xoncrete structure, destruction and defect.The U.S. The concrete for having more than 500,000,000 cubic yards every year is modified.And these concrete are mostly using local different quality former materials Material is built.In addition, design lack of standardization and ignore for working to tight deadlines construction quality problem all be exist.So repair and just exist Institute is unavoidable.Annual U.S. owner is for repairing, the cost in terms of protection and reinforcing is about between 120 hundred million to 180 hundred million dollars.
At present, the construction of many Large Infrastructure Projects of China is all completed in succession and is come into operation, in one period from now on Interior China's building trade will complete by present based on newly-built foundation engineering facility to repairing and renovate these foundation engineerings and set Strategic change based on applying.So the building trade of coming few decades China will face protection, reinforce and maintenance engineering facility Immense pressure.At present, extremely urgent is very big one in the industry and civil buildings that builds before China eighties in 20th century Part is in reinforcing and maintenance timing, and now in some the civilian and engineering workses that builds during construction and use Concrete quality problem, such as voids and pits, cavity, large area damage etc. is frequently encountered, in terms of road and bridge, this phenomenon is more Plus substantially, according to incompletely statistics, existing cement concrete pavement will have 20~30% to all suffer from repairing and improve.
At present, traditional method for repairing and mending be using normal concrete or mortar as patching material, but normal concrete or Mortar all exist one common the characteristics of, i.e. fragility is big and toughness is not enough, is mainly shown as that comprcssive strength is high, tensile strength and glues Knotting strength is low, and elastic modelling quantity is high and deformability is poor, if using it for concrete repair, easily cause interfacial adhesion loosely, open The quality problems such as split and cause concrete to damage once again, be restricted in use.Polymer-modified cement mortar is in recent years The class novel patching material for growing up, it are to mix a small amount of organic polymer in cement mortar, so as to improving cement bonded sand The composite gelled material of slurry properties, compared with conventional cement mortar, its tensile strength is high, elastic modelling quantity is low, wear-resisting, corrosion resistant Erosion, impervious, anti-freezing property are excellent, it is adaptable to which the concrete surface layer caused because of carbonization, cavitation erosion, freeze-thaw damage and chemical attack is opened Split, the repairing of surface deterioration destruction, but in use, air content is difficult to control to, and to ring in production processes of polyalcohol Border also results in pollution, and polymer is relatively costly, cause cannot large area use, another drawback is the compatibility with road surface Difference.
Content of the invention
The invention mainly solves the technical problem of:Go out during preparation and use for conventional cement and mending mortar Existing, with old concrete interface poor compatibility, bonding loosely, using the rear problem for causing concrete to damage once again easy to crack, Provide a kind of preparation method of bi-component cement based mending mortar, the present invention first by corn straw smashing, then with second pond Activated sludge, yellow sand etc. are mixed, and collect filter cake after anaerobic fermentation, then by filter cake and cement, Pulvis Talci and calcium chloride solution press than Example is mixed to prepare component A, then rice husk fermentation is calcined under hot conditionss, by calcining after rice hull ash be dissolved in sodium hydroxide In solution, after being filtered to remove impurity, concentrated by rotary evaporation is obtained B component, during use, component A is mixed in proportion with B component, is obtained final product Bi-component cement based mending mortar.Gained mending mortar of the present invention is good with old concrete interface compatibility, is firmly bonded, can be abundant Penetrate in hole, improve the intensity and service life of concrete.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
(1)2~4kg corn straw is weighed, is added in stalk crasher, is crushed 15~20min, pour gained stalk powder into Sheng Have in the fermentation tank of 4~6L deionized waters, add 0.6~0.8kg second pond activated sludge, 6~8kg yellow sands, then with 3~ 5mL/min speed is passed through nitrogen into fermentation tank, until all air are displaced, with being 180~200r/min after rotating speed, warm Under the conditions of spending for 35~40 DEG C, anaerobic sealed fermenting 5~7 days treats fermentation ends, is heated to 90~95 DEG C, insulation 15~ 20min, sucking filtration, removes filtrate, obtains mixed fermentation thing filter cake while hot;
(2)4~6kg cement is weighed, 600~800g Pulvis Talci, the above-mentioned gained fermented mixture thing filter cakes of 2~3kg, addition are filled 4~6L mass fractions are in the Plastic Drum of 20~25% calcium chloride solutions, with waddy stirring 10~15min of mixing, obtain cement based and repair Component A is starched in stop-off;
(3)2~3L of methane liquid is measured, is filtered, remove filtering residue, gained filtrate is added in fermentation tank, 2~3kg rice husks are added, It is 35~40 DEG C in temperature, under the conditions of rotating speed is 180~200r/min, constant-temperature enclosed fermentation 3~5 days is filtered, removes filtrate, Filter cake 3~5 times is washed with deionized, subsequently filter cake is proceeded in baking oven, dry to constant weight under the conditions of 105~110 DEG C, then Dried filter cake is proceeded to Muffle furnace, with 6~8 DEG C/min ramps to 600~680 DEG C, insulation 45~60min of calcining, Cool to room temperature with the furnace, obtain rice hull ash;
(4)The above-mentioned gained rice hull ash of 600~800g is weighed, the burning for filling that 2~4L mass fractions are 40% sodium hydroxide solution is poured into In cup, then beaker is proceeded to sonic oscillation instrument, with 200~300W power excusing from death 15~20min of dispersion, filter, remove filtering residue, receive Collection filtrate, and filtrate is proceeded in Rotary Evaporators, in temperature be under the conditions of 75~80 DEG C concentrated by rotary evaporation to the 1/4 of original volume, After naturally cool to room temperature, cement based mending mortar B component is obtained, be 1 in mass ratio by gained component A and B component during use:1 Mix homogeneously, you can use.
After testing, gained bi-component cement based mending mortar of the present invention is using after 2h, comprcssive strength up to 35.6~ 36.8MPa, rupture strength up to 6.0~6.2MPa, using 1 day after, comprcssive strength is up to 58.9~62.6MPa, rupture strength Up to 6.8~7.0MPa, using 1 month after, comprcssive strength up to 98.9~100.2MPa, rupture strength up to 9.8~ 10.6MPa.
The invention has the beneficial effects as follows:
(1)The features such as gained cement based mending mortar of the present invention has early-strong-fast-hard, volume stability, adhesive property good, after repairing Open to traffic by 24h, easy construction, maintenance are simple, can be used in mixed way with most of portland cement;
(2)Gained mending mortar compact structure of the present invention, with excellent corrosion resistance, drying shrinkage compared with ordinary cement sill Property and anti-permeability performance, while shock resistance is good, can large-scale promotion use.
Specific embodiment
2~4kg corn straw is weighed, is added in stalk crasher, is crushed 15~20min, gained stalk powder is poured into Fill in the fermentation tank of 4~6L deionized waters, add 0.6~0.8kg second pond activated sludge, 6~8kg yellow sands, then with 3~ 5mL/min speed is passed through nitrogen into fermentation tank, until all air are displaced, with being 180~200r/min after rotating speed, warm Under the conditions of spending for 35~40 DEG C, anaerobic sealed fermenting 5~7 days treats fermentation ends, is heated to 90~95 DEG C, insulation 15~ 20min, sucking filtration, removes filtrate, obtains mixed fermentation thing filter cake while hot;Weigh 4~6kg cement, 600~800g Pulvis Talci, 2~ The above-mentioned gained fermented mixture thing filter cakes of 3kg, add and fill the Plastic Drum that 4~6L mass fractions are 20~25% calcium chloride solutions In, with waddy stirring 10~15min of mixing, obtain cement based mending mortar component A;2~3L of methane liquid is measured, is filtered, remove filter Slag, gained filtrate is added in fermentation tank, 2~3kg rice husks are added, and is 35~40 DEG C in temperature, and rotating speed is 180~200r/ Under the conditions of min, constant-temperature enclosed fermentation 3~5 days is filtered, removes filtrate, is washed with deionized filter cake 3~5 times, subsequently will filter Cake is proceeded in baking oven, dries to constant weight, then dried filter cake is proceeded to Muffle furnace, with 6~8 under the conditions of 105~110 DEG C DEG C/min ramps to 600~680 DEG C, insulation calcining 45~60min, cool to room temperature with the furnace, obtain rice hull ash;Weigh 600 The above-mentioned gained rice hull ash of~800g, pours into and fills in the beaker that 2~4L mass fractions are 40% sodium hydroxide solution, then by beaker Sonic oscillation instrument is proceeded to, with 200~300W power excusing from death 15~20min of dispersion, is filtered, is removed filtering residue, collect filtrate, and will filter Liquid is proceeded in Rotary Evaporators, in temperature be under the conditions of 75~80 DEG C concentrated by rotary evaporation to the 1/4 of original volume, after naturally cool to room Temperature, obtains cement based mending mortar B component, is 1 during use in mass ratio by gained component A and B component:1 mix homogeneously, you can make With.
Example 1
2kg corn straw is weighed, is added in stalk crasher, is crushed 15min, gained stalk powder is poured into and fills 4L deionizations In the fermentation tank of water, 0.6kg second pond activated sludge, 6kg yellow sands is added, then is passed through into fermentation tank with 3mL/min speed Nitrogen, until displace all air, with being 180r/min after rotating speed, under the conditions of temperature is 35 DEG C, anaerobic sealed fermenting 5 My god, fermentation ends are treated, 90 DEG C are heated to, 15min is incubated, while hot sucking filtration, filtrate is removed, is obtained mixed fermentation thing filter cake;Claim 4kg cement is taken, and 600g Pulvis Talci, the above-mentioned gained fermented mixture thing filter cakes of 2kg are added and 4L mass fractions filled for 20% chlorination In the Plastic Drum of calcium solution, with waddy stirring mixing 10min, cement based mending mortar component A is obtained;Methane liquid 2L is measured, is filtered, Filtering residue is removed, gained filtrate is added in fermentation tank, 2kg rice husks are added, be 35 DEG C in temperature, rotating speed is 180r/min conditions Under, constant-temperature enclosed fermentation 3 days is filtered, removes filtrate, is washed with deionized filter cake 3 times, subsequently proceeds to filter cake in baking oven, Dry to constant weight under the conditions of 105 DEG C, then dried filter cake is proceeded to Muffle furnace, with 6 DEG C/min ramps to 600 DEG C, Insulation calcining 45min, cools to room temperature with the furnace, obtains rice hull ash;The above-mentioned gained rice hull ash of 600g is weighed, is poured into and is filled 2L mass point During number is for the beaker of 40% sodium hydroxide solution, then beaker is proceeded to sonic oscillation instrument, with 200W power excusing from death dispersion 15min, mistake Filter, removes filtering residue, collects filtrate, and filtrate is proceeded in Rotary Evaporators, and under the conditions of temperature is for 75 DEG C, concentrated by rotary evaporation is to original The 1/4 of volume, after naturally cool to room temperature, obtains cement based mending mortar B component, and gained component A and B component are pressed matter during use Amount is than being 1:1 mix homogeneously, you can use.
After testing, using after 2h, comprcssive strength resists gained bi-component cement based mending mortar of the present invention up to 35.6MPa Folding intensity up to 6.0MPa, using 1 day after, comprcssive strength up to 58.9MPa, rupture strength up to 6.8MPa, using 1 month Afterwards, up to 98.9MPa, rupture strength is up to 9.8MPa for comprcssive strength.
Example 2
3kg corn straw is weighed, is added in stalk crasher, is crushed 18min, gained stalk powder is poured into and fills 5L deionizations In the fermentation tank of water, 0.7kg second pond activated sludge, 7kg yellow sands is added, then is passed through into fermentation tank with 4mL/min speed Nitrogen, until displace all air, with being 190r/min after rotating speed, under the conditions of temperature is 38 DEG C, anaerobic sealed fermenting 6 My god, fermentation ends are treated, 92 DEG C are heated to, 18min is incubated, while hot sucking filtration, filtrate is removed, is obtained mixed fermentation thing filter cake;Claim 5kg cement is taken, and 700g Pulvis Talci, the above-mentioned gained fermented mixture thing filter cakes of 2.5kg are added and 5L mass fractions filled for 22% chlorine Change in the Plastic Drum of calcium solution, with waddy stirring mixing 12min, obtain cement based mending mortar component A;Methane liquid 2.5L is measured, Filter, remove filtering residue, gained filtrate is added in fermentation tank, 2.5kg rice husks are added, be 38 DEG C in temperature, rotating speed is 190r/ Under the conditions of min, constant-temperature enclosed fermentation 4 days is filtered, removes filtrate, is washed with deionized filter cake 4 times, subsequently proceeds to filter cake In baking oven, dry to constant weight under the conditions of 108 DEG C, then dried filter cake is proceeded to Muffle furnace, with 7 DEG C/min ramps extremely 660 DEG C, insulation calcining 50min cools to room temperature with the furnace, obtains rice hull ash;The above-mentioned gained rice hull ash of 700g is weighed, is poured into and is filled 3L Mass fraction is in the beaker of 40% sodium hydroxide solution, then beaker is proceeded to sonic oscillation instrument, with the excusing from death dispersion of 250W power 18min, filters, and removes filtering residue, collects filtrate, and filtrate is proceeded in Rotary Evaporators, rotates under the conditions of temperature is for 78 DEG C The 1/4 of original volume is concentrated into, after naturally cool to room temperature, cement based mending mortar B component is obtained, by gained component A and B during use Component is 1 in mass ratio:1 mix homogeneously, you can use.
After testing, using after 2h, comprcssive strength resists gained bi-component cement based mending mortar of the present invention up to 36.2MPa Folding intensity up to 6.1MPa, using 1 day after, comprcssive strength up to 60.6MPa, rupture strength up to 6.9MPa, using 1 month Afterwards, up to 99.8MPa, rupture strength is up to 10.2MPa for comprcssive strength.
Example 3
4kg corn straw is weighed, is added in stalk crasher, is crushed 20min, gained stalk powder is poured into and fills 6L deionizations In the fermentation tank of water, 0.8kg second pond activated sludge, 8kg yellow sands is added, then is passed through into fermentation tank with 5mL/min speed Nitrogen, until displace all air, with being 200r/min after rotating speed, under the conditions of temperature is 40 DEG C, anaerobic sealed fermenting 7 My god, fermentation ends are treated, 95 DEG C are heated to, 20min is incubated, while hot sucking filtration, filtrate is removed, is obtained mixed fermentation thing filter cake;Claim 6kg cement is taken, and 800g Pulvis Talci, the above-mentioned gained fermented mixture thing filter cakes of 3kg are added and 6L mass fractions filled for 25% chlorination In the Plastic Drum of calcium solution, with waddy stirring mixing 15min, cement based mending mortar component A is obtained;Methane liquid 3L is measured, is filtered, Filtering residue is removed, gained filtrate is added in fermentation tank, 3kg rice husks are added, be 40 DEG C in temperature, rotating speed is 200r/min conditions Under, constant-temperature enclosed fermentation 5 days is filtered, removes filtrate, is washed with deionized filter cake 5 times, subsequently proceeds to filter cake in baking oven, Dry to constant weight under the conditions of 110 DEG C, then dried filter cake is proceeded to Muffle furnace, with 8 DEG C/min ramps to 680 DEG C, Insulation calcining 60min, cools to room temperature with the furnace, obtains rice hull ash;The above-mentioned gained rice hull ash of 800g is weighed, is poured into and is filled 4L mass point During number is for the beaker of 40% sodium hydroxide solution, then beaker is proceeded to sonic oscillation instrument, with 300W power excusing from death dispersion 20min, mistake Filter, removes filtering residue, collects filtrate, and filtrate is proceeded in Rotary Evaporators, and under the conditions of temperature is for 80 DEG C, concentrated by rotary evaporation is to original The 1/4 of volume, after naturally cool to room temperature, obtains cement based mending mortar B component, and gained component A and B component are pressed matter during use Amount is than being 1:1 mix homogeneously, you can use.
After testing, using after 2h, comprcssive strength resists gained bi-component cement based mending mortar of the present invention up to 36.8MPa Folding intensity up to 6.2MPa, using 1 day after, comprcssive strength up to 62.6MPa, rupture strength up to 7.0MPa, using 1 month Afterwards, up to 100.2MPa, rupture strength is up to 10.6MPa for comprcssive strength.

Claims (1)

1. a kind of preparation method of bi-component cement based mending mortar, it is characterised in that concrete preparation process is:
(1)2~4kg corn straw is weighed, is added in stalk crasher, is crushed 15~20min, pour gained stalk powder into Sheng Have in the fermentation tank of 4~6L deionized waters, add 0.6~0.8kg second pond activated sludge, 6~8kg yellow sands, then with 3~ 5mL/min speed is passed through nitrogen into fermentation tank, until all air are displaced, with being 180~200r/min after rotating speed, warm Under the conditions of spending for 35~40 DEG C, anaerobic sealed fermenting 5~7 days treats fermentation ends, is heated to 90~95 DEG C, insulation 15~ 20min, sucking filtration, removes filtrate, obtains fermented mixture thing filter cake while hot;
(2)4~6kg cement is weighed, 600~800g Pulvis Talci, the above-mentioned gained fermented mixture thing filter cakes of 2~3kg, addition are filled 4~6L mass fractions are in the Plastic Drum of 20~25% calcium chloride solutions, with waddy stirring 10~15min of mixing, obtain cement based and repair Component A is starched in stop-off;
(3)2~3L of methane liquid is measured, is filtered, remove filtering residue, gained filtrate is added in fermentation tank, 2~3kg rice husks are added, It is 35~40 DEG C in temperature, under the conditions of rotating speed is 180~200r/min, constant-temperature enclosed fermentation 3~5 days is filtered, removes filtrate, Filter cake 3~5 times is washed with deionized, subsequently filter cake is proceeded in baking oven, dry to constant weight under the conditions of 105~110 DEG C, then Dried filter cake is proceeded to Muffle furnace, with 6~8 DEG C/min ramps to 600~680 DEG C, insulation 45~60min of calcining, Cool to room temperature with the furnace, obtain rice hull ash;
(4)The above-mentioned gained rice hull ash of 600~800g is weighed, the burning for filling that 2~4L mass fractions are 40% sodium hydroxide solution is poured into In cup, then beaker is proceeded to sonic oscillation instrument, with 200~300W power excusing from death 15~20min of dispersion, filter, remove filtering residue, receive Collection filtrate, and filtrate is proceeded in Rotary Evaporators, in temperature be under the conditions of 75~80 DEG C concentrated by rotary evaporation to the 1/4 of original volume, After naturally cool to room temperature, cement based mending mortar B component is obtained, be 1 in mass ratio by gained component A and B component during use:1 Mix homogeneously, you can use.
CN201610890332.0A 2016-10-13 2016-10-13 A kind of preparation method of bi-component cement based mending mortar Pending CN106495579A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107117895A (en) * 2017-04-21 2017-09-01 周益铭 A kind of preparation method of contraction-free grouting concrete
CN107382182A (en) * 2017-06-28 2017-11-24 常州市雄泰纺织品有限公司 A kind of high viscosity cracking resistance water-keeping mortar and preparation method thereof
CN111943622A (en) * 2020-08-12 2020-11-17 重庆富皇建筑工业化制品有限公司 Full-machine-made sand wet-mixed mortar and processing method thereof

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CN102531508A (en) * 2011-12-12 2012-07-04 亚士漆(上海)有限公司 Self-leveling terrace mortar powder and preparation method thereof, and terrace construction method
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CN103803918A (en) * 2013-12-20 2014-05-21 同济大学 Porcelain powder waste mixed cement-based tiny-expansion crack repairing mortar and using method thereof
CN104829170A (en) * 2015-01-05 2015-08-12 潍坊德霖建材科技有限公司 Preparation method of high-performance anti-corrosion repairing mortar
CN105819791A (en) * 2016-03-21 2016-08-03 同济大学 Cement base thermal insulation mortar containing rice straw fibers and application method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4787187B2 (en) * 2007-02-22 2011-10-05 電気化学工業株式会社 Rapid hardened mortar and repair method using the same
CN102531508A (en) * 2011-12-12 2012-07-04 亚士漆(上海)有限公司 Self-leveling terrace mortar powder and preparation method thereof, and terrace construction method
CN103803918A (en) * 2013-12-20 2014-05-21 同济大学 Porcelain powder waste mixed cement-based tiny-expansion crack repairing mortar and using method thereof
CN103771796A (en) * 2013-12-30 2014-05-07 北京天维宝辰化学产品有限公司 Thin-layer pavement patching mortar
CN104829170A (en) * 2015-01-05 2015-08-12 潍坊德霖建材科技有限公司 Preparation method of high-performance anti-corrosion repairing mortar
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107117895A (en) * 2017-04-21 2017-09-01 周益铭 A kind of preparation method of contraction-free grouting concrete
CN107382182A (en) * 2017-06-28 2017-11-24 常州市雄泰纺织品有限公司 A kind of high viscosity cracking resistance water-keeping mortar and preparation method thereof
CN111943622A (en) * 2020-08-12 2020-11-17 重庆富皇建筑工业化制品有限公司 Full-machine-made sand wet-mixed mortar and processing method thereof

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Application publication date: 20170315

RJ01 Rejection of invention patent application after publication