CN115820341A - Essence for costustoot rhyme, preparation method and application thereof - Google Patents
Essence for costustoot rhyme, preparation method and application thereof Download PDFInfo
- Publication number
- CN115820341A CN115820341A CN202211332711.XA CN202211332711A CN115820341A CN 115820341 A CN115820341 A CN 115820341A CN 202211332711 A CN202211332711 A CN 202211332711A CN 115820341 A CN115820341 A CN 115820341A
- Authority
- CN
- China
- Prior art keywords
- essence
- enzymolysis
- composite
- solvent
- costustoot
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000002131 composite material Substances 0.000 claims abstract description 97
- 239000002994 raw material Substances 0.000 claims abstract description 97
- 235000019504 cigarettes Nutrition 0.000 claims abstract description 46
- 239000002904 solvent Substances 0.000 claims abstract description 44
- 108090000790 Enzymes Proteins 0.000 claims abstract description 42
- 102000004190 Enzymes Human genes 0.000 claims abstract description 42
- 229940088598 enzyme Drugs 0.000 claims abstract description 42
- 241000218636 Thuja Species 0.000 claims abstract description 22
- 241001446503 Pterocarpus Species 0.000 claims abstract description 19
- 235000009984 Pterocarpus indicus Nutrition 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 241001544576 Pterocarpus macrocarpus Species 0.000 claims abstract description 17
- 108010059892 Cellulase Proteins 0.000 claims abstract description 13
- 108090001060 Lipase Proteins 0.000 claims abstract description 13
- 239000004367 Lipase Substances 0.000 claims abstract description 13
- 102000004882 Lipase Human genes 0.000 claims abstract description 13
- 108010059820 Polygalacturonase Proteins 0.000 claims abstract description 13
- 229940106157 cellulase Drugs 0.000 claims abstract description 13
- 108010093305 exopolygalacturonase Proteins 0.000 claims abstract description 13
- 235000019421 lipase Nutrition 0.000 claims abstract description 13
- 239000000284 extract Substances 0.000 claims description 40
- 239000000796 flavoring agent Substances 0.000 claims description 30
- 238000000199 molecular distillation Methods 0.000 claims description 26
- 241000208125 Nicotiana Species 0.000 claims description 21
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- 235000019505 tobacco product Nutrition 0.000 claims description 19
- 238000000605 extraction Methods 0.000 claims description 18
- 239000003205 fragrance Substances 0.000 claims description 16
- 239000002023 wood Substances 0.000 claims description 16
- 238000001914 filtration Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- 239000000706 filtrate Substances 0.000 claims description 10
- 238000004108 freeze drying Methods 0.000 claims description 6
- 230000000391 smoking effect Effects 0.000 abstract description 7
- 230000033764 rhythmic process Effects 0.000 abstract description 3
- 235000019634 flavors Nutrition 0.000 description 24
- 150000001875 compounds Chemical class 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 241000750718 Pterocarpus santalinus Species 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 7
- 230000001953 sensory effect Effects 0.000 description 7
- 239000000779 smoke Substances 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 235000013599 spices Nutrition 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 235000019640 taste Nutrition 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 4
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 4
- 244000272264 Saussurea lappa Species 0.000 description 4
- 235000006784 Saussurea lappa Nutrition 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 4
- 229930007744 linalool Natural products 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- GRWFGVWFFZKLTI-UHFFFAOYSA-N α-pinene Chemical compound CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 229960005233 cineole Drugs 0.000 description 3
- 235000009508 confectionery Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 210000000214 mouth Anatomy 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
- GRWFGVWFFZKLTI-IUCAKERBSA-N 1S,5S-(-)-alpha-Pinene Natural products CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- HBEDSQVIWPRPAY-UHFFFAOYSA-N 2,3-dihydrobenzofuran Chemical compound C1=CC=C2OCCC2=C1 HBEDSQVIWPRPAY-UHFFFAOYSA-N 0.000 description 2
- SEPQTYODOKLVSB-UHFFFAOYSA-N 3-methylbut-2-enal Chemical compound CC(C)=CC=O SEPQTYODOKLVSB-UHFFFAOYSA-N 0.000 description 2
- CHWNEIVBYREQRF-UHFFFAOYSA-N 4-Ethyl-2-methoxyphenol Chemical compound CCC1=CC=C(O)C(OC)=C1 CHWNEIVBYREQRF-UHFFFAOYSA-N 0.000 description 2
- 235000011470 Adenanthera pavonina Nutrition 0.000 description 2
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- 206010013911 Dysgeusia Diseases 0.000 description 2
- 241000220485 Fabaceae Species 0.000 description 2
- 235000008109 Thuja occidentalis Nutrition 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 2
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 description 2
- 229930008380 camphor Natural products 0.000 description 2
- 229960000846 camphor Drugs 0.000 description 2
- 239000011162 core material Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 235000001510 limonene Nutrition 0.000 description 2
- 229940087305 limonene Drugs 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000004949 mass spectrometry Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- LZEPVVDVBJUKSG-UHFFFAOYSA-N pterocarpan Chemical compound C1=CC=C2C3COC4=CC=CC=C4C3OC2=C1 LZEPVVDVBJUKSG-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 230000000638 stimulation Effects 0.000 description 2
- -1 tincture Substances 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- BIJUQTKPTMHITN-UHFFFAOYSA-N 1,3,3-trimethyl-2-(2-methylcyclopropyl)cyclohexene Chemical compound CC1CC1C1=C(C)CCCC1(C)C BIJUQTKPTMHITN-UHFFFAOYSA-N 0.000 description 1
- WEEGYLXZBRQIMU-UHFFFAOYSA-N 1,8-cineole Natural products C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 1
- QIYRGBNUCNZLNY-UHFFFAOYSA-N 1-(6-methyl-3,4-dihydro-2h-pyran-2-yl)ethanone Chemical compound CC(=O)C1CCC=C(C)O1 QIYRGBNUCNZLNY-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000218691 Cupressaceae Species 0.000 description 1
- WEEGYLXZBRQIMU-WAAGHKOSSA-N Eucalyptol Chemical compound C1C[C@H]2CC[C@]1(C)OC2(C)C WEEGYLXZBRQIMU-WAAGHKOSSA-N 0.000 description 1
- 241001582888 Lobus Species 0.000 description 1
- YLZYAUCOYZKLMA-UHFFFAOYSA-N O-Methyl-maackiain Natural products O1C2=CC=3OCOC=3C=C2C2C1C1=CC=C(OC)C=C1OC2 YLZYAUCOYZKLMA-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- SLEPYIDGMPDTFO-UHFFFAOYSA-N Pterocarpin Natural products COc1ccc2C3Oc4c5OCOc5ccc4C3COc2c1 SLEPYIDGMPDTFO-UHFFFAOYSA-N 0.000 description 1
- 240000000513 Santalum album Species 0.000 description 1
- 235000008632 Santalum album Nutrition 0.000 description 1
- ACWQBUSCFPJUPN-UHFFFAOYSA-N Tiglaldehyde Natural products CC=C(C)C=O ACWQBUSCFPJUPN-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 229930003935 flavonoid Natural products 0.000 description 1
- 150000002215 flavonoids Chemical class 0.000 description 1
- 235000017173 flavonoids Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000008601 oleoresin Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- YLZYAUCOYZKLMA-SJCJKPOMSA-N pterocarpin Chemical compound O1C2=CC=3OCOC=3C=C2[C@H]2[C@@H]1C1=CC=C(OC)C=C1OC2 YLZYAUCOYZKLMA-SJCJKPOMSA-N 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000013441 quality evaluation Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 238000000194 supercritical-fluid extraction Methods 0.000 description 1
- 235000019605 sweet taste sensations Nutrition 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- RRBYUSWBLVXTQN-UHFFFAOYSA-N tricyclene Chemical compound C12CC3CC2C1(C)C3(C)C RRBYUSWBLVXTQN-UHFFFAOYSA-N 0.000 description 1
- RRBYUSWBLVXTQN-VZCHMASFSA-N tricyclene Natural products C([C@@H]12)C3C[C@H]1C2(C)C3(C)C RRBYUSWBLVXTQN-VZCHMASFSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002916 wood waste Substances 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Fats And Perfumes (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
The invention provides an essence for costustoot rhyme, a preparation method and application thereof, wherein the preparation raw materials of the essence for costustoot rhyme comprise: composite raw materials, an enzymolysis solvent and a composite enzyme; the composite raw materials comprise pterocarpus microphyllus, pterocarpus macrocarpus, laotia laotica and thuja; the complex enzyme comprises cellulase, pectinase and lipase; the solid-liquid ratio of the composite raw material to the enzymolysis solvent is 1 (8-12); the mass ratio of the complex enzyme to the composite raw material is 0.5-2. The costustoot essence extracted from the raw materials has rich aroma components and outstanding aroma and rhythm, can endow unique and non-moldable aroma, and can improve the smoking quality of cigarettes.
Description
Technical Field
The invention belongs to the technical field of tobacco products, and particularly relates to an essence for costustoot rhyme, and a preparation method and application thereof.
Background
In the production process of tobacco products, the tobacco flavor and fragrance are indispensable additives. The additive for tobacco can be divided into natural perfume and artificial perfume according to different sources. The common flavors include flowery scent, costustoot, fruity, bean-fragrant, sweet and the like. The wood note is one of the main notes of the tobacco essence and flavor, and can obviously enhance the characteristic aroma of tobacco products. At present, most of the wood-flavor spices used in the tobacco flavor and fragrance are artificial spices, and the artificial spices have poor comfort due to single chemical components. The natural perfume is various extracts extracted from various flowers, fruits, branches, rhizomes and the like of natural plants by various extraction methods including solvent extraction, steam distillation, supercritical extraction and other technologies, and is an organic mixture. The natural spice has rich fragrance and complex components, has vivid natural fragrance, natural and comfortable fragrance and better harmony, plays a role in blending the essence and the spice of the cigarette, and is highly favored by blending flavorists. The flavor and fragrance technology is a key factor for forming cigarette style characteristics and reflecting product differentiation, so with the continuous development of Chinese cigarettes, the demand of natural plant flavors with outstanding characteristics and excellent quality is increasing day by day.
The natural perfume has different properties due to different preparation processes, and is divided into essential oil, absolute oil, extract, tincture, oleoresin and the like. At present, the application of the natural costustoot tobacco flavor in tobacco products is rarely reported, and the natural costustoot tobacco flavor is mainly agilawood tobacco products, and because the agilawood extract has high cost, the agilawood cigarettes are high in price, and smoking consumers are few.
Disclosure of Invention
In view of the above, the invention aims to provide the essence for wood rhyme, the preparation method and the application thereof.
The invention provides an essence for costustoot rhyme, which is prepared from the following raw materials:
composite raw materials, an enzymolysis solvent and a composite enzyme;
the composite raw materials comprise pterocarpus microphyllus, pterocarpus macrocarpus, laotia laotica and thuja;
the complex enzyme comprises cellulase, pectinase and lipase;
the solid-liquid ratio of the composite raw material to the enzymolysis solvent is 1 (8-12); the mass ratio of the complex enzyme to the composite raw material is 0.5-2.
In the invention, the mass ratio of the small-leaf red sandalwood, the big-fruit red sandalwood, the Laotian big branch and the thuja is (10-20): (25-35) (30-45): (20-30);
pterocarpus microphyllus and Pterocarpus macrocarpus of the same genus, leguminosae, pterocarpus of Papilionaceae; laotian big ramulus et folium seu folium Laotidis Laotifoliae is of genus Pterocarpus belonging to subfamily Papilionaceae of Leguminosae, and Thuja is of genus Thuja belonging to family Cupressaceae. Pterocarpus lobus, pterocarpus macrocarpus, laotia laos and Thuja are mainly produced in Myanmar, thailand, laotia laos, cambodia and Vietnam. The core material is the preferable material for manufacturing solid wood furniture, high-end musical instruments, art designing ornaments and the like. The bark and the root can be used as medicines, have pungent taste, warm nature and strong fragrance of nontoxic heartwood, have the effects of concentrating the mind and resisting fatigue, and the like, contain 3-5% of volatile oil, mainly contain various active ingredients such as terpene, terpene alcohol, flavonoid and the like, and are valuable medicinal materials and valuable spices. In the processing process of the forestry industry heartwood, a large amount of leftover materials and wood shavings can be generated and are not effectively utilized, so that the waste of resources is caused. The leftover materials and wood shavings generated by the processing are used for preparing the extract, and a novel special-color wood fragrance raw material for cigarettes is developed and developed, so that the economic and practical value of the novel special-color wood fragrance raw material can be improved.
The mass ratio of the cellulase to the pectinase to the lipase is (2.5-3.5) to (1.8-2.2) to 1.
In the invention, the enzymolysis solvent is ethanol with the mass concentration of 40-70%.
The invention provides a preparation method of essence for wood fragrance note, which comprises the following steps:
mixing the composite raw material and an enzymolysis solvent, adding the composite enzyme, and carrying out enzymolysis to obtain an enzymolysis solution;
standing the enzymolysis solution, and filtering to obtain filtrate and residue;
recovering solvent from the filtrate under reduced pressure to obtain extract 1; freeze drying the residue and then supercritical CO 2 Extracting to obtain an extract 2;
and (3) mixing the extract 1 and the extract 2, and then performing molecular distillation to recover light components to obtain the essence for wood fragrance.
The composite raw materials adopted by the invention are treated by ultrasonic composite enzyme, so that the content of macromolecular substances such as cellulose, pectin, wax fat and the like in the extract can be reduced, the aroma quality of the extract is improved, and meanwhile, the method has the advantages of low ultrasonic treatment temperature, short time, high extraction efficiency, cost saving, easiness in industrial production and the like.
The invention adopts the enzymolysis residue of the composite raw material and adopts the combination of freeze drying and supercritical CO 2 Extraction and molecular distillation, freeze drying for retaining fragrance loss, and supercritical CO 2 The extraction and molecular distillation targeted separation technology can directionally improve the aroma quality of the costustoot flavor for cigarettes, effectively reduce the pollution of organic solvents to the environment, simultaneously has simple and convenient process operation, removes macromolecular substances such as plant pigments and the like through targeted separation, greatly improves the appearance state, the aroma quality and other aspects, and has stronger and pure aroma.
By implementing the method, a large amount of leftover materials and wood shavings generated in the processing process of the forestry industry core material can be fully utilized, volatile aroma components in the wood waste are extracted, the utilization rate of wood is improved, meanwhile, the wood-flavor tobacco flavor is added into a tobacco product, the smoking taste and the taste characteristics of smoke can be improved, the tobacco flavor can be enriched, the wood-flavor tobacco flavor is harmonious with the tobacco flavor, the smoke is fine and soft, the comfort of the oral cavity and the throat is effectively improved, the wood-flavor and the smoking taste are endowed to the tobacco product, and a wide prospect is opened for the production of the tobacco flavor and flavor.
The invention mixes the composite raw material and the enzymolysis solvent, and then adds the composite enzyme for enzymolysis to obtain the enzymolysis liquid. In the specific embodiment of the invention, the composite raw material is a mixture of 20 mass ratios of pterocarpus microphyllus, pterocarpus macrocarpus, laos large sour branch and thuja; or the mixture of pterocarpus microphyllus, pterocarpus macrophyllus, laos large sour branch and thuja in the mass ratio of 10; or the mixture of pterocarpus microphyllus, pterocarpus macrophyllus, laos large sour branch and thuja in the mass ratio of 15; or the mass ratio of the mixture of pterocarpus microphyllus, pterocarpus macrocarpus, laos large sour branch and thuja.
The invention makes the enzymolysis liquid stand and filter to obtain chlorine liquid and residue. The invention preferably stands still, is cooled and then is filtered.
The invention recovers the solvent from the filtrate under reduced pressure to obtain the extract 1. The temperature of the decompression recovered solvent is 45-60 ℃.
The invention carries out freeze drying on the residue and then carries out supercritical CO 2 Extracting to obtain extract 2. The freeze-drying is carried out until the water content is lower than 12wt%. The supercritical CO 2 The temperature of extraction is 40-50 ℃, and the supercritical CO is adopted 2 The extraction pressure is 18-30 MPa, and supercritical CO is adopted 2 The extraction time is 60-120 min. In a specific embodiment, supercritical CO 2 The extraction temperature is 50 ℃, 40 ℃ or 45 ℃; supercritical CO 2 The extraction pressure is 30MPa, 18MPa, 25MPa or 23MPa; supercritical CO 2 The extraction time is 120min, 60min, or 90min.
The invention combines the extract 1 and the extract 2, and then carries out molecular distillation to recover light components, thereby obtaining the essence for wood fragrance. The temperature of the molecular distillation is 55-65 ℃, the rotating speed of a rotor adopted by the molecular distillation is 350-450 rpm, and the feeding speed is 3-8 mL/min.
The invention provides an application of an essence for costustoot cigarettes in tobacco products;
the essence for the costustoot rhyme cigarette is the essence for the wood rhyme in the technical scheme or the essence for the costustoot rhyme prepared by the preparation method in the technical scheme.
In the invention, the mass percentage content of the costustoot tobacco flavor in the tobacco product is 0.001-0.01%, preferably 0.003-0.006%. The costustoot flavor for cigarettes is preferably diluted by adopting a composite solvent and then sprayed on the cut tobacco for perfuming the cigarettes; the composite solvent is a composite solvent of ethanol, propylene glycol and glycerol, wherein the volume ratio of the ethanol to the propylene glycol to the glycerol is 5:3:2.
the invention provides an essence for costustoot rhyme, which is prepared from the following raw materials: composite raw materials, an enzymolysis solvent and a composite enzyme; the composite raw materials comprise pterocarpus microphyllus, pterocarpus macrocarpus, laotia laotica and thuja; the complex enzyme comprises cellulase, pectinase and lipase; the solid-liquid ratio of the composite raw material to the enzymolysis solvent is 1 (8-12); the mass ratio of the complex enzyme to the composite raw material is 0.5-2. The costustoot essence extracted from the raw materials has rich aroma components and outstanding aroma and rhythm, can endow unique and non-moldable aroma, and can improve the smoking quality of cigarettes.
Drawings
FIG. 1 is a schematic view of a preparation process of an essence for Aucklandia lappa (L.) Kuntze cigarettes provided by the invention;
FIG. 2 is a total ion flow diagram of the woody flavor prepared in example 4 of the present invention;
fig. 3 is a total ion flow diagram of the woody note flavor prepared in comparative example 1 of the present invention.
Detailed Description
In order to further illustrate the present invention, the following examples are provided to describe in detail the essence for woody flavor, its preparation method and its application, but they should not be construed as limiting the scope of the present invention.
Example 1 preparation of an essence for Aucklandia lappa Ledeb cigarette
The composite material is prepared from the following raw materials in parts by mass: 20 parts of pterocarpus santalinus; 25 parts of pterocarpus macrocarpus; 45 parts of Laos big ramulus cinnamomi; 20 parts of arborvitae.
(1) Ultrasonic compound enzyme treatment of compound raw materials: weighing 500g of composite raw materials, adding an enzymolysis solvent, wherein the solid-liquid ratio is 1:12, the solvent is 70% ethanol, then adding a complex enzyme which is 2.0% of the total weight of the composite raw materials, the complex enzyme is cellulase, pectinase and lipase, the proportion of the complex enzyme is 3;
(2) Composite raw material enzymolysis liquid treatment: standing the treated composite raw material, cooling, filtering, and recovering solvent from the filtrate under reduced pressure at 60 deg.C to obtain concentrated extract 1-a;
(3) Pretreatment of composite raw material enzymolysis residues: treating the composite raw material residue after the filtration in the previous step by a freeze dryer to remove water, wherein the water content is controlled below 12%;
(4) Supercritical CO of composite raw material enzymolysis residue 2 Extraction: taking the dried composite raw material residue in the previous step and performing supercritical CO 2 Extracting, supercritical CO 2 Extracting at 50 deg.C under 30MPa for 60min to obtain extract 1-b;
(5) Molecular distillation treatment of the composite raw material extract: mixing the extract 1-a and extract 1-b, dissolving completely with 5 times of recovered solvent, and performing molecular distillation under the following conditions: distilling at 65 deg.C, rotating at 450r/min, feeding at 8mL/min, and recovering molecular distillation light components to obtain essence 1-c for preparing radix aucklandiae tobacco.
Example 2: preparation of essence for radix aucklandiae cigarettes
The composite material is prepared from the following raw materials in parts by mass: 10 parts of pterocarpus santalinus; 35 parts of pterocarpus macrocarpus; 30 parts of Laos big ramulus cinnamomi; 20 parts of thuja.
(1) Ultrasonic compound enzyme treatment of a compound raw material: weighing 500g of composite raw materials, adding an enzymolysis solvent, wherein the solid-liquid ratio is 1:8, the solvent is 40% ethanol, then adding 0.5% of a composite enzyme in the total weight of the composite raw materials, the composite enzyme is cellulase, pectinase and lipase, the proportion of the composite enzyme is 3;
(2) Composite raw material enzymolysis liquid treatment: standing the treated composite raw material, cooling, filtering, and recovering solvent from the filtrate under reduced pressure at 45 deg.C to obtain concentrated extract 2-a;
(3) Pretreatment of composite raw material enzymolysis residues: treating the composite raw material residue after the filtration in the previous step by a freeze dryer to remove water, wherein the water content is controlled below 12%;
(4) Supercritical CO of composite raw material enzymolysis residue 2 Extraction: taking the dried composite raw material residue in the previous step and performing supercritical CO 2 Extracting, supercritical CO 2 Extracting at 40 deg.C under 18MPa for 120min to obtain extract 2-b;
(5) Molecular distillation treatment of the composite raw material extract: mixing the extract 2-a and extract 2-b, dissolving with 2 times of recovered solvent, and performing molecular distillation under the following conditions: the distillation temperature is 55 ℃, the rotor speed is 350r/min, the feeding speed is 3mL/min, and the recovered molecular distillation light components are the essence 2-c for preparing costustoot rhyme cigarettes.
Example 3: preparation of essence for costustoot cigarettes
The composite material is prepared from the following raw materials in parts by mass: 15 parts of pterocarpus santalinus; 35 parts of pterocarpus macrocarpus; 35 parts of Laos big ramulus cinnamomi; 30 parts of thuja.
(1) Ultrasonic compound enzyme treatment of compound raw materials: weighing 500g of composite raw materials, adding an enzymolysis solvent, wherein the solid-liquid ratio is 1:10, the solvent is 60% ethanol, then adding a complex enzyme which is 1.5% of the total weight of the composite raw materials, the complex enzyme is cellulase, pectinase and lipase, the proportion of the complex enzyme is 3;
(2) Composite raw material enzymolysis liquid treatment: standing the treated composite raw material, cooling, filtering, and recovering solvent from the filtrate under reduced pressure at 55 deg.C to obtain concentrated extract 3-a;
(3) Pretreatment of composite raw material enzymolysis residues: treating the composite raw material residue after the filtration in the previous step by a freeze dryer to remove water, wherein the water content is controlled below 12%;
(4) Supercritical CO of composite raw material enzymolysis residue 2 And (3) extraction: taking the dried composite raw material residue in the previous step and performing supercritical CO 2 Extracting, supercritical CO 2 Extracting at 45 deg.C under 25MPa for 90min to obtain extract 3-b;
(5) Molecular distillation treatment of the composite raw material extract: mixing the extracts 3-a and 3-b, dissolving completely with 4 times of recovered solvent, and performing molecular distillation under the following conditions: the distillation temperature is 60 ℃, the rotor speed is 400r/min, the feeding speed is 6mL/min, and the recovered molecular distillation light component is the essence 3-c for preparing costustoot rhyme cigarettes.
Example 4: preparation of essence for costustoot cigarettes
The composite material is prepared from the following raw materials in parts by mass: 15 parts of pterocarpus santalinus; 30 parts of pterocarpus macrocarpus; 35 parts of Laos big ramulus cinnamomi; 25 parts of thuja.
(1) Ultrasonic compound enzyme treatment of a compound raw material: weighing 500g of composite raw materials, adding an enzymolysis solvent, wherein the solid-liquid ratio is 1:10, the solvent is 50% ethanol, then adding 1.0% of a complex enzyme in the total weight of the composite raw materials, the complex enzyme is cellulase, pectinase and lipase, the proportion of the complex enzyme is 3;
(2) Composite raw material enzymolysis liquid treatment: standing the treated composite raw material, cooling, filtering, and recovering solvent from the filtrate at 50 deg.C under reduced pressure to obtain concentrated extract 4-a;
(3) Pretreatment of composite raw material enzymolysis residues: treating the composite raw material residue after the filtration in the previous step by a freeze dryer to remove water, wherein the water content is controlled below 12%;
(4) Supercritical CO of composite raw material enzymolysis residue 2 Extraction: taking the dried composite raw material residue in the previous step and performing supercritical CO 2 Extracting, supercritical CO 2 Extracting at 45 deg.C under 23MPa for 90min to obtain extract 4-b;
(5) Molecular distillation treatment of the composite raw material extract: mixing the extracts 4-a and 4-b, dissolving completely with 3 times of recovered solvent, and performing molecular distillation under the following conditions: distilling at 60 deg.C, rotating at 400r/min, feeding at 5mL/min, and recovering molecular distillation light components to obtain essence 4-c for preparing radix aucklandiae tobacco.
Comparative example 1: preparation of essence for costustoot cigarettes
The composite material is prepared from the following raw materials in parts by mass: 15 parts of pterocarpus santalinus; 30 parts of pterocarpus macrocarpus; 35 parts of Laos big ramulus cinnamomi; 25 parts of thuja.
(1) Ultrasonic compound enzyme treatment of a compound raw material: weighing 500g of composite raw materials, adding an enzymolysis solvent, wherein the solid-liquid ratio is 1:10, the solvent is 50% ethanol, then adding 1.0% of a complex enzyme in the total weight of the composite raw materials, the complex enzyme is cellulase, pectinase and lipase, the proportion of the complex enzyme is 1;
(2) Composite raw material enzymolysis liquid treatment: standing the processed composite raw material, cooling, filtering, and recovering solvent from the filtrate under reduced pressure at 50 deg.C to obtain concentrated extract 5-a;
(3) Pretreatment of composite raw material enzymolysis residues: treating the composite raw material residue after the filtration in the previous step by a freeze dryer to remove water, wherein the water content is controlled below 12%;
(4) Supercritical CO of composite raw material enzymolysis residue 2 Extraction: taking the dried composite raw material residue in the previous step, and performing supercritical CO 2 Extracting, supercritical CO 2 Extracting at 45 deg.C under 23MPa for 90min to obtain extract 5-b;
(5) Molecular distillation treatment of the composite raw material extract: mixing the extracts 5-a and 5-b, dissolving with 3 times of recovered solvent, and performing molecular distillation under the following conditions: distilling at 60 deg.C, rotating at 400r/min, feeding at 5mL/min, and recovering molecular distillation light components to obtain essence 5-c for preparing radix aucklandiae tobacco.
Comparative example 2: preparation of essence for costustoot cigarettes
The composite material is prepared from the following raw materials in parts by mass: 15 parts of pterocarpus santalinus; 30 parts of pterocarpus macrocarpus; laos big lopper 35 parts; 25 parts of thuja.
On the premise of keeping other conditions unchanged, the method is different from the embodiment 4 in that the complex enzyme component is lack of cellulase, the complex enzyme is pectinase and lipase, the proportion of the complex enzyme is 2:1, and the recovered molecular distillation light component is the essence 6-c for preparing the costustoot rhyme cigarettes.
Comparative example 3: preparation of essence for costustoot cigarettes
The composite material is prepared from the following raw materials in parts by mass: 15 parts of pterocarpus santalinus; 30 parts of pterocarpus macrocarpus; 35 portions of Laos big lopper.
On the premise of keeping other conditions unchanged, the method is different from the embodiment 4 in that thuja is absent in the components of the composite raw materials, the composite raw materials are pterocarpus microphyllus, pterocarpus macrophyllus and laos large sour branches, and the recovered molecular distillation light components are the essence 7-c for preparing costustoot rhymes cigarettes.
Comparative example 4: preparation of essence for costustoot cigarettes
The composite material is prepared from the following raw materials in parts by mass: 15 parts of pterocarpus santalinus; 30 parts of pterocarpus macrocarpus; 35 parts of Laos big ramulus cinnamomi; 25 parts of arborvitae; 10 parts of agilawood.
On the premise of keeping other conditions unchanged, the difference from the embodiment 4 is that agilawood is added into the components of the composite raw material, and the recovered molecular distillation light component is the essence 8-c for preparing the costustoot rhyme cigarette.
Example 5: the invention analyzes the components of the costustoot rhyme essence prepared in the example 4
GC/MS conditions: capillary column HP-5MS (30000 mm. Times.0.25 mm. Times.0.00025 mm); the temperature of a sample inlet is 220 ℃; carrier gas He,1mL/min; programmed temperature rise of 45 ℃ (2 min) → 6 ℃/min → 150 ℃ (2 min) → 8 ℃/min → 250 ℃ (15 min); the sample injection amount is 1 mu L, and the split ratio is 10; the transmission line temperature is 260 ℃; ionization mode EI, ionization energy 70eV; the ion source temperature is 230 ℃; the temperature of a four-level bar is 160 ℃; the mass range is 45-500 aum, and the solvent delay time is 2min.
The costustoot rhyme essence prepared in example 4 is analyzed by GC-MS, and the total ion flow chart of the aroma components is shown in figure 2. The specific analysis results are shown in table 1:
table 1 aroma components of aucklandia rhyme essence prepared in example 4
It can be known from the total ion flow diagram that the costustoot essence prepared in example 4 contains many kinds of compounds, and by using the method of 2 analyses of Nist and Wiley spectral library search and manual mass spectrometry, as can be seen from table 1, 56 chemical components are identified after comprehensive analysis, and the main components are alpha-pinene, beta-myrcene, limonene, linalool, camphor, linalool, beta-eucalyptol, homopterin, meidi pterocarpan, palmitic acid and the like. The compounds are important aroma substances, have great influence on aroma characteristics, and can embody elegant sandalwood and faint scent.
Example 6: analysis of Components of Aucklandia lappa Roth essence prepared in comparative example 1 of the present invention
The GC/MS conditions are the same as in example 5, the costustoot rhyme essence prepared in the comparative example 1 is analyzed by adopting GC-MS, and the total ion flow chart of the aroma components is shown in figure 3. The specific analysis results are shown in table 2:
table 2 perfuming ingredients of the woody flavor prepared in comparative example 1
It can be known from the total ion flow diagram that the types of the compounds contained in the costustoot essence prepared in the comparative example 1 are less than those in the example 4, and by utilizing the method of 2 analysis methods of Nist and Wiley spectral library search and manual mass spectrometry, as can be seen from table 2, 51 chemical components are identified after comprehensive analysis, wherein the contents of main aroma substances such as alpha-pinene, limonene, linalool, camphor, linalool, beta-cineol, eucalyptol, homopterin, meidilantin, pterocarpin and the like are lower than those in the example 4; 3-methyl-2-butenal, tricyclene, 2-acetyl-6-methyl-2,3-dihydropyran, 2,3-dihydrobenzofuran, 4-ethyl-2-methoxyphenol, 1,3,3-trimethyl-2- (2-methylcyclopropyl) -cyclohexene and other compounds are detected, and the olefin, phenol and heterocyclic compounds are not important aroma substances, have negative influence on aroma characteristics and taste characteristics, and are characterized by insufficiently pure and elegant aroma, and obvious offensive gas and irritation.
Example 7: flavoring sensory evaluation effect of costustoot tobacco essence on tobacco products
The essence for costustoot rhyme cigarettes prepared in the examples 1 to 4 and the comparative examples 1 to 4 is applied to tobacco products, the cigarettes are rolled into finished products, and the cigarettes are balanced for 48 hours in a constant temperature and humidity box (the relative humidity is 60 +/-5 percent, and the temperature is 20 +/-2 ℃). The sensory quality of the cigarettes is evaluated by referring to a YC/T497-2014 cigarette Chinese style sensory evaluation method and a YC/T496-2014 cigarette sensory comfort evaluation method, and the cigarettes are evaluated by 7 or more professional technicians with national or provincial cigarette sensory quality evaluation qualification certificates, and the evaluation results are shown in Table 3.
Table 3 application of Aucklandia lappa Roth tobacco flavor in tobacco products evaluation result
The results show that the costustoot rhyme tobacco essence subjected to specific treatment is added to the tobacco products in the embodiments 1 to 4, so that the costustoot rhyme of the cigarettes can be increased, the richness of smoke is improved, the aroma is strong and pure, the smoke is slightly sweet, the smoke is fine and soft, the offensive odor and the irritation are reduced, the harmony is good, the aftertaste is cleaner, the discomfort of the oral cavity and the throat can be effectively improved, and the tobacco products are endowed with the characteristic wood rhyme and the smoking taste.
Example 8: flavoring sensory evaluation effect of costustoot tobacco essence on tobacco products
On the basis of the costustoot flavor for cigarettes in the embodiment 4, the influence of different addition amounts of the costustoot flavor for cigarettes on the sensory quality of tobacco products is examined, and the result is shown in a table 4:
TABLE 4 results of the test
The result shows that the proper amount of the costustoot essence for cigarettes is added into the tobacco products, so that the aroma quality of cigarettes can be effectively improved, the richness of smoke is obviously improved, the costustoot and sweet aroma are increased, the characteristic aroma of the costustoot is obvious, the stimulation of the throat and the oral cavity can be effectively reduced, the fineness and softness of the smoke are improved, the sweet taste is increased, the aftertaste is improved, the stimulation is reduced, the natural aroma of the cigarettes is harmonious, the aroma-increasing and aroma-supplementing effect on the cigarettes is obvious, and the optimal using amount is 0.003-0.006%.
From the above examples, the invention provides an essence for radix aucklandiae rhyme, which is prepared from the following raw materials: composite raw materials, an enzymolysis solvent and a composite enzyme; the composite raw materials comprise pterocarpus microphyllus, pterocarpus macrocarpus, laotia laotica and thuja; the complex enzyme comprises cellulase, pectinase and lipase; the solid-liquid ratio of the composite raw material to the enzymolysis solvent is 1 (8-12); the mass ratio of the complex enzyme to the composite raw material is 0.5-2. The costustoot essence extracted from the raw materials has rich aroma components and outstanding aroma and rhythm, can endow unique and non-moldable aroma, and can improve the smoking quality of cigarettes.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (10)
1. An essence for radix aucklandiae rhyme is prepared from the following raw materials:
composite raw materials, an enzymolysis solvent and a composite enzyme;
the composite raw materials comprise pterocarpus microphyllus, pterocarpus macrocarpus, laotia laotica and thuja;
the complex enzyme comprises cellulase, pectinase and lipase;
the solid-liquid ratio of the composite raw material to the enzymolysis solvent is 1 (8-12); the mass ratio of the complex enzyme to the composite raw material is 0.5-2.
2. The essence for costustoot rhyme as claimed in claim 1, wherein the mass ratio of pterocarpus microphyllus, pterocarpus macrophyllus, laos large sour branch and thuja is (10-20): (25-35 (30-45): (20-30);
the mass ratio of the cellulase to the pectinase to the lipase is (2.5-3.5) to (1.8-2.2) to 1.
3. The essence for radix aucklandiae rhyme according to claim 1, wherein the enzymolysis solvent is ethanol with a mass concentration of 40-70%.
4. A method for preparing the essence for wood note according to any one of claims 1 to 3, comprising the steps of:
mixing the composite raw material and an enzymolysis solvent, adding the composite enzyme, and carrying out enzymolysis to obtain an enzymolysis liquid;
standing the enzymolysis solution, and filtering to obtain filtrate and residue;
recovering solvent from the filtrate under reduced pressure to obtain extract 1; freeze drying the residue and then supercritical CO 2 Extracting to obtain extract 2;
and (3) mixing the extract 1 and the extract 2, and then performing molecular distillation to recover light components to obtain the essence for wood fragrance.
5. The preparation method according to claim 4, wherein the enzymolysis is ultrasonic enzymolysis;
the temperature of the ultrasonic enzymolysis is 40-60 ℃, and the time of the ultrasonic enzymolysis is 30-60 min.
6. The method according to claim 4, wherein the temperature of the solvent recovered under reduced pressure is 45 to 60 ℃.
7. The method of claim 4, wherein the supercritical CO is 2 The temperature of extraction is 40-50 ℃, and supercritical CO is adopted 2 The extraction pressure is 18-30 MPa, and supercritical CO is adopted 2 The extraction time is 60-120 min.
8. The method of claim 4, wherein the molecular distillation temperature is 55 to 65 ℃.
9. An application of essence for radix aucklandiae tobacco in tobacco products;
the essence for wood-fragrance cigarettes is the essence for wood-fragrance cigarettes as defined in any one of claims 1 to 3 or the essence for costustoot prepared by the preparation method as defined in any one of claims 4 to 8.
10. The application of the essence for the wood-flavor cigarettes as claimed in claim 9, wherein the essence for the wood-flavor cigarettes is contained in the tobacco products in a mass percentage of 0.001-0.01%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211332711.XA CN115820341B (en) | 2022-10-28 | 2022-10-28 | Essence for costustoot charm cigarettes, and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211332711.XA CN115820341B (en) | 2022-10-28 | 2022-10-28 | Essence for costustoot charm cigarettes, and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115820341A true CN115820341A (en) | 2023-03-21 |
| CN115820341B CN115820341B (en) | 2024-02-02 |
Family
ID=85525721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211332711.XA Active CN115820341B (en) | 2022-10-28 | 2022-10-28 | Essence for costustoot charm cigarettes, and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115820341B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20130002109A (en) * | 2011-06-28 | 2013-01-07 | 이수제약(주) | Method for manufacturing cartridge solution composite of electronic non-smoking cigarette and cartridge solution composite of electronic non-smoking cigarette manufactured by this |
| CN103146482A (en) * | 2013-03-21 | 2013-06-12 | 红云红河烟草(集团)有限责任公司 | Tobacco flavor with sweetening function and application thereof |
| CN104004594A (en) * | 2014-06-11 | 2014-08-27 | 深圳烟草工业有限责任公司 | Spice for costustoot flavored cigarettes based on aquilaria leaves, as well as preparation method and application of spice |
| CN106036982A (en) * | 2016-07-20 | 2016-10-26 | 湖北中烟工业有限责任公司 | Preparation method for bay leaf extractive for tobacco and application thereof |
| CN112251290A (en) * | 2020-10-19 | 2021-01-22 | 甘肃烟草工业有限责任公司 | Thyme and benzoin composite essence for cigarettes and preparation method and application thereof |
| CN113773908A (en) * | 2021-09-23 | 2021-12-10 | 云南中烟新材料科技有限公司 | Preparation method and application of jasmine extract with antioxidant activity |
-
2022
- 2022-10-28 CN CN202211332711.XA patent/CN115820341B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20130002109A (en) * | 2011-06-28 | 2013-01-07 | 이수제약(주) | Method for manufacturing cartridge solution composite of electronic non-smoking cigarette and cartridge solution composite of electronic non-smoking cigarette manufactured by this |
| CN103146482A (en) * | 2013-03-21 | 2013-06-12 | 红云红河烟草(集团)有限责任公司 | Tobacco flavor with sweetening function and application thereof |
| CN104004594A (en) * | 2014-06-11 | 2014-08-27 | 深圳烟草工业有限责任公司 | Spice for costustoot flavored cigarettes based on aquilaria leaves, as well as preparation method and application of spice |
| CN106036982A (en) * | 2016-07-20 | 2016-10-26 | 湖北中烟工业有限责任公司 | Preparation method for bay leaf extractive for tobacco and application thereof |
| CN112251290A (en) * | 2020-10-19 | 2021-01-22 | 甘肃烟草工业有限责任公司 | Thyme and benzoin composite essence for cigarettes and preparation method and application thereof |
| CN113773908A (en) * | 2021-09-23 | 2021-12-10 | 云南中烟新材料科技有限公司 | Preparation method and application of jasmine extract with antioxidant activity |
Non-Patent Citations (1)
| Title |
|---|
| 李力群等: "采用超临界CO2 萃取 - 分子蒸馏技术对云产玫瑰油的提取 分离及GC - TOFMS 分析", 《香料香精化妆品》, vol. 1, no. 5, pages 17 - 21 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115820341B (en) | 2024-02-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104140889B (en) | A kind of preparation method of rose absolute | |
| CN103525558B (en) | Tea flower essence with fruity flavor characteristic and application thereof to cigarettes | |
| CN105029681A (en) | Natural perfume refining fluid suitable for cigarette fluid of electronic cigarettes and cigarette fluid and preparation method thereof | |
| CN103478894A (en) | Camellia extract composition with spicy fragrance and application of same to cigarettes | |
| CN103468410A (en) | Tea flower extract composition and its use in cigarette | |
| CN103484248A (en) | Tea flower essence with fresh and sweet characteristics, and application of essence in cigarettes | |
| CN107637858B (en) | Plant aroma-causing substance extracted by improved water extraction and alcohol precipitation method, and extraction method and application thereof | |
| CN101209985A (en) | Method for extracting carotinoid from tobacco leaf by overcritical CO2 and application of the carotinoid in perfuming cigarette | |
| CN102732381B (en) | Preparation method of fermented tobacco Dendranthema indicum essential oil | |
| CN101569438A (en) | Method for preparing mulberry cigarette flavor | |
| CN101637303A (en) | Lemon extract, preparation method thereof and application thereof in cigarette flavoring | |
| CN115558548B (en) | Rosin-flavored essence for cigarettes and preparation method and application thereof | |
| CN110358630B (en) | Spice with fresh and spicy flavor for cigarettes, preparation method of spice and application of spice in cigarettes | |
| CN115011410B (en) | Schisandra chinensis branch spice, preparation method thereof and cigarette | |
| CN115820341B (en) | Essence for costustoot charm cigarettes, and preparation method and application thereof | |
| CN103060090B (en) | Tobacco spice with faint scent style, preparing and using methods thereof, and cigarettes | |
| CN106753912A (en) | A kind of shinyleaf yellowhorn oil handmade soap and preparation method thereof | |
| CN110724599A (en) | Green tea essence and preparation method thereof | |
| CN114098141B (en) | Electronic atomized liquid containing borneol plant components and preparation method thereof | |
| CN109181876B (en) | Efficient preparation method of rose absolute for flavoring tobacco | |
| CN114098139B (en) | Electronic atomized liquid with rich and durable mouth feeling and preparation method thereof | |
| CN114082217B (en) | Preparation method and application of flos Abelmoschi Manihot extract | |
| CN110734808A (en) | fragrant and fragrant glyceryl triacetate | |
| CN106387987B (en) | A kind of preparation method and applications of red tangerine extract | |
| CN114794527B (en) | Sophora flower extract, preparation method thereof and cigarette flavoring |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |