Anti-stripping agent and preparation method and application thereof
Technical Field
The invention belongs to the fields of petroleum industry and basic material chemistry, and particularly relates to an anti-stripping agent, a preparation method and application thereof, which are particularly suitable for an airport asphalt runway.
Background
The materials of the runway surface of the airport runway are divided into cement concrete and asphalt concrete, the former is mainly applied to branch airports, and the latter is mainly applied to main line airports or branch airports to carry out asphalt concrete surface treatment on the cement runway. The airports with passenger flow above China millions mainly adopt asphalt concrete materials as runway surface materials. The working state of the asphalt concrete material for the airfield runway is obviously different from that of the asphalt concrete material for the common highway, and the asphalt concrete material mainly comprises the following two points: firstly, high-temperature air flow sprayed by a jet aircraft seriously affects the stability of asphalt concrete materials; secondly, asphalt concrete materials are easy to loosen surface coarse aggregates to form foreign invaders (FODs) after oil content is reduced, and the FODs can cause serious flight accidents once being sucked into aircraft engines. Therefore, the high-temperature stability and the coarse aggregate shedding resistance of the asphalt concrete material are improved, and the method is an important research direction for improving the civil aviation operation safety capability. At present, polymer modified asphalt with better high-temperature performance is widely adopted for paving airport runways worldwide so as to solve the problems of pavement deformation and threshing under the conditions of aircraft wake baking and high shear stress, but the effect is not ideal, and after a period of use, pavement bulges crack and aggregate fall frequently, so that huge flight potential safety hazards and maintenance cost rise. Therefore, development of a high-temperature-resistant and anti-stripping asphalt material suitable for airport runways is urgently needed, a special high-temperature-resistant and anti-stripping evaluation method for airport asphalt is established, a complete set of system scientific matching technology is formed, and the requirements of the next thirty years on high-quality asphalt materials at home and abroad are met.
In order to prevent the asphalt concrete coarse aggregate from falling off to form FOD, the first airport of China adopts a plurality of preventive maintenance measures such as: atomization seal, slurry seal, etc., and simultaneously indicates that the friction coefficient can be reduced after seal, which has an effect on runway operation safety. As early as 1997, on the basis of analyzing the development history of China asphalt concrete runway, the technical standard of making airport asphalt pavement petroleum asphalt and mineral aggregate is pointed out, modified asphalt and mixtures thereof are researched, and the phenomenon of sand and stone falling is reduced, but the problem is not completely solved up to the present.
Disclosure of Invention
Aiming at the problem of aggregate shedding faced by an airport asphalt runway, the invention provides a novel anti-stripping agent, a preparation method and application thereof, and when the novel anti-stripping agent is used for the airport asphalt runway, the anti-shedding performance of asphalt can be obviously improved.
The invention provides an anti-stripping agent which comprises the following raw materials in parts by mass:
3-9 parts of polyethylene oxide,
3-14 parts of resin,
2-8 parts of alkyl ammonium chloride,
2-10 parts of methacrylate compounds,
1.3-2.0 parts of coupling agent,
1.2-2.0 parts of hindered phenol compound,
0.4-1.1 parts of aromatic oil.
Preferably, the anti-stripping agent comprises the following raw materials in parts by mass:
4-8 parts of polyethylene oxide,
4-13 parts of resin,
3-7 parts of alkyl ammonium chloride,
3-9 parts of methacrylate compounds,
1.4-1.9 parts of coupling agent,
1.3-1.9 parts of hindered phenol compound,
0.5-1.0 parts of aromatic oil.
The molecular weight of the polyethylene oxide is 50-300 ten thousand, preferably 60-200 ten thousand.
The resin is one or more of petroleum resin, terpene resin, rosin resin, coumarone resin, phenolic resin, polyester resin and polyamide resin.
The alkyl ammonium chloride is one or two of octadecyl trimethyl ammonium chloride and hexadecyl trimethyl ammonium chloride.
The methacrylate compound is one or a mixture of more than one of 2-hydroxyethyl methacrylate, 2-ethylhexyl methacrylate and ethyl methacrylate.
The coupling agent is one or more of silane coupling agent (at least one of model KH550, KH560 and KH 570), aluminate coupling agent and titanate coupling agent.
The hindered phenol compound comprises one or more of 2, 8-di-tert-butyl-4-methylphenol, tetra- [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid ] pentaerythritol ester, beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid octadecyl ester, and 1,3,5- (3, 5-di-tert-butyl-4-hydroxyphenyl) s-triazine-2, 4,6 (1H, 3H, 5H) trione.
The aromatic hydrocarbon oil is a component rich in aromatic hydrocarbon, wherein the content of the aromatic hydrocarbon is more than 70% by mass percent, and the aromatic hydrocarbon oil can be one or a mixture of more than one of four-line reduction extraction oil, furfural refined extraction oil, phenol refined extraction oil and catalytic cracking slurry oil.
The anti-stripping agent is a paste at normal temperature.
The second aspect of the present invention provides a method for preparing the anti-spalling agent, comprising:
uniformly mixing polyethylene oxide, resin, alkyl ammonium chloride, methacrylate compounds, a coupling agent, hindered phenol compounds and aromatic hydrocarbon oil, then mixing, extruding and obtaining the anti-stripping agent.
The mixing is achieved by a conventional mixing device, such as a kneader, the bottom of which is provided with an extrusion structure. The mixing conditions were as follows: the mixing temperature is 130-160 ℃, and the mixing time is 40-90 min.
The extrusion temperature is 130-160 ℃.
In a third aspect, the present invention provides an anti-sloughing asphalt comprising: petroleum asphalt and the anti-spalling agent.
In the anti-falling asphalt, the dosage of the anti-falling agent accounts for 2% -3% of the mass of the anti-falling asphalt.
In the anti-shedding asphalt, the petroleum asphalt can be conventional petroleum asphalt for airport runways, and is at least one of straight asphalt, oxidized asphalt, blended asphalt and solvent deoiling asphalt.
The fourth aspect of the invention provides a method for preparing the anti-shedding asphalt, comprising the following steps: heating and melting petroleum asphalt, adding the anti-stripping agent, and stirring until the mixture is uniformly mixed to obtain the anti-stripping asphalt.
In the preparation method of the anti-falling asphalt, the asphalt is heated and melted at 130-160 ℃, the stirring temperature is 130-160 ℃, and the stirring time can be 40-90 min.
The anti-stripping agent is particularly suitable for application in airfield runway asphalt.
The anti-falling asphalt provided by the invention is suitable for being used as airfield runway asphalt.
The invention has the following advantages:
1. the novel anti-stripping agent not only can remarkably improve the anti-stripping performance of asphalt, but also has strong adaptability to the high Wen Weiliu environment of an airplane, can improve the anti-stripping performance of an airport asphalt runway, reduces the stripping of aggregate, and can reduce the incidence rate of flight accidents.
2. The anti-stripping agent is pasty at normal temperature, does not need to develop in the process of preparing the anti-stripping asphalt by using the anti-stripping agent, shortens the production time of the anti-stripping asphalt, improves the working efficiency, can further improve the adhesion strength of the asphalt, can also improve the low-temperature extensibility of the asphalt, and avoids the occurrence of frost heaving and cracking of a pavement in winter.
3. In the preparation method of the novel anti-stripping agent, polyethylene oxide, resin, alkyl ammonium chloride, methacrylate compounds and hindered phenol compounds are subjected to grafting reaction in a kneader and in the screw extrusion process under the assistance of a coupling agent, so that all substances can be combined quickly and well, and a formed product has higher viscosity and flexibility and better polarity, so that the anti-stripping agent can enable asphalt to have better high-temperature anti-stripping performance in a high-temperature environment. The addition of the methacrylate compound further enhances the adhesion strength between asphalt and stone. The addition of the hindered phenol compound can improve the anti-aging capability of the substance containing unsaturated bonds, thereby improving the anti-aging capability of the anti-stripping agent and asphalt. Under the action of aromatic hydrocarbon oil, the components are easier to fuse, the reaction condition is reduced, the energy is saved, the low-temperature extensibility of asphalt can be improved, and the occurrence of frost heaving and cracking of the pavement in winter is avoided. Therefore, the anti-stripping agent of the invention comprehensively strengthens the adhesion strength of asphalt to stone from multiple aspects and improves the high-temperature stripping resistance of airport asphalt.
4. The preparation condition of the novel anti-stripping agent is more gentle, the mixing reaction time in the preparation process of the anti-stripping agent is greatly shortened, and the production efficiency is improved.
Detailed Description
The following examples are given to illustrate the technical aspects of the present invention in detail, but the present invention is not limited to the following examples. In the invention, the weight percent is the mass fraction.
In the invention, the simulation experiment method of the aircraft height Wen Weiliu comprises the following steps: with aircraft engines (such as newer engines), the tail links a straight barrel of high temperature resistant material with heating. During the experiment, the asphalt to be tested is melted and then placed in a metal tray, and the asphalt is spread flatly to form a film with the thickness of 3mm plus or minus 0.3 mm. The tray with the asphalt film is arranged at the bottom in the cylinder body and is firmly fixed. The bottom of the cylinder body has a heating function, so that the temperature of asphalt in the tray is maintained at 60+/-20 ℃ (the temperature of Wen Shilu table in summer simulation). The engine is started, so that high-temperature tail gas of the engine enters from one end of the straight cylinder, the other end of the straight cylinder is discharged, the high-temperature tail gas is blown over the asphalt membrane, the blowing is continued for 30 minutes, and the blowing is stopped for 10 minutes, so that the process is continuously repeated for a plurality of times. One experimental period was 240 hours from the initial start of blowing. And then taking out the asphalt, analyzing each performance, and comparing the performance with the performance before the simulation experiment. The method simulates the condition of asphalt on an airport runway (especially in a take-off section) when the asphalt is purged by high-temperature tail gas of an airplane for a long time, and examines the change of asphalt properties, especially the change of anti-falling performance.
In the invention, the asphalt adhesion strength is obtained by testing with a drawing tester. The instrument and the test method are as follows:
instrument and equipment: drawing tester with model PosiTest AT-A, tester parameters: a draw rate of 150psi/s; test range 0-2000psi; the test method is as follows:
weighing asphalt with the mass of 0.03g on the experimental surface of the spindle; placing the spindle with asphalt on an electric heating plate, after asphalt is melted, uniformly smearing the asphalt within 10 seconds, simultaneously rapidly transferring the preheated white steel plate to a horizontal operation table, buckling the spindle coated with the uniform asphalt on the white steel plate, standing and cooling to room temperature (about 1 h). The liquid asphalt spreads evenly under the action of spindle gravity, and after cooling, the spindle and the white steel plate are bonded, and the thickness of the asphalt film is about 0.1mm. The white steel plate cooled to room temperature and the spindle were put in an environmental box (temperature: 20 ℃ C.; relative humidity: 50 Rh%) and kept AT constant temperature for 1 hour, and then taken out, and the adhesion was measured using a Positest AT-A tester. The drawing strength value at the time of separating the spindle from the metal plate was recorded. The anti-falling performance of the asphalt is represented by the numerical value, and the larger the numerical value is, the better the anti-falling performance is.
Example 1
41.0kg of polyethylene oxide with the molecular weight of 61 ten thousand, 41.0kg of C5 petroleum resin, 31.0kg of octadecyl trimethyl ammonium chloride, 31.0kg of 2-hydroxyethyl methacrylate, 14.1kg of silane coupling agent (KH 560), 13.1kg of 2, 8-di-tert-butyl-4-methylphenol and 5.1 kg of four-wire reduced extraction oil are weighed and placed in a preheated kneader for mixing, wherein the mixing temperature is 135 ℃ and the mixing time is 40min; then extruding, wherein the extruding temperature is 135 ℃, and the anti-stripping agent is obtained. The proportions of the components are shown in Table 1.
Example 2
60.0kg of polyethylene oxide with the molecular weight of 190 ten thousand, 85.0kg of terpene resin, 50.0 kg kg of hexadecyl trimethyl ammonium chloride, 60.0kg of 2-ethylhexyl methacrylate, 16.5kg of aluminate coupling agent, 16.0kg of tetra- [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid ] pentaerythritol ester and 7.5kg of refined extracted oil of furfural are weighed and placed in a preheated kneader for mixing, wherein the mixing temperature is 158 ℃ and the mixing time is 88min; then extruding, wherein the extruding temperature is 158 ℃, and the anti-stripping agent is obtained. The proportions of the components are shown in Table 1.
Example 3
78.0kg of polyethylene oxide with the molecular weight of 120 ten thousand, 128.0kg of polyamide resin, 68.0 kg of octadecyl trimethyl ammonium chloride, 88.0kg of ethyl methacrylate, 19.0kg of titanate coupling agent, 19.8kg of beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) octadecyl propionate and 9.8kg of catalytic cracking slurry oil are weighed and put into a preheated kneader for mixing, wherein the mixing temperature is 145 ℃ and the mixing time is 75min; then extruding, wherein the extrusion temperature is 145 ℃. Obtaining the anti-stripping agent. The proportions of the components are shown in Table 1.
Example 4
The anti-spalling agent obtained in example 1 was added to a molten petroleum asphalt (zilu 70) having a penetration of 70dmm at 25 ℃ produced by zilupetrifaction corporation: the weight ratio of the anti-stripping agent is 97:3. stirring at constant temperature of 132 ℃ for 42 min to obtain the anti-falling asphalt.
The adhesion strength of the anti-falling asphalt was measured by a pull tester, and the results are shown in Table 2. The anti-shedding asphalt is subjected to a simulation experiment under the environment of aircraft height Wen Weiliu, and a drawing experiment is performed after one period of experiment, and the results are shown in Table 2.
Example 5
The anti-spalling agent obtained in example 2 was added to a molten petroleum asphalt (ziluting 70) having a penetration of 70dmm at 25℃produced by ziluting corporation: the weight ratio of the anti-stripping agent is 97.5:2.5. stirring at constant temperature of 158 ℃ for 85 min to obtain the anti-falling asphalt.
The adhesion strength of the anti-falling asphalt was measured by a pull tester, and the results are shown in Table 2. The anti-shedding asphalt is subjected to a simulation experiment under the environment of aircraft height Wen Weiliu, and a drawing experiment is performed after one period of experiment, and the results are shown in Table 2.
Example 6
The anti-spalling agent obtained in example 3 was added to a molten petroleum asphalt (ziluting 70) having a penetration of 70dmm at 25℃produced by ziluting corporation: the weight ratio of the anti-stripping agent is 98:2. stirring at constant temperature of 145 ℃ for 65 min to obtain the anti-falling asphalt.
The adhesion strength of the anti-falling asphalt was measured by a pull tester, and the results are shown in Table 2. The anti-shedding asphalt is subjected to a simulation experiment under the environment of aircraft height Wen Weiliu, and a drawing experiment is performed after one period of experiment, and the results are shown in Table 2.
Comparative example 1
For comparison, the adhesion strength of the 70A asphalt (Qilu 70) produced by Qilu petrochemical company, as measured by a tensile tester, is also shown in Table 2; and 70A-grade asphalt (Qilu 70) produced by Qilu petrochemical company is subjected to simulation experiment under the environment of aircraft height Wen Weiliu, and after one period of experiment, drawing experiments are respectively carried out, and the results are shown in Table 2.
Comparative example 2
For comparison, commercial anti-shedding agent PAVE192 manufactured by intel vitex corporation was added to a molten petroleum asphalt (zilu 70A) having a penetration of 70dmm at 25 ℃ manufactured by zilupetrifaction corporation: the weight ratio of the anti-stripping agent is 97.5:2.5. stirring at constant temperature of 158 ℃ for 85 min to obtain the anti-falling asphalt.
The adhesion strength of the anti-falling asphalt was measured by a pull tester, and the results are shown in Table 2. The anti-shedding asphalt is subjected to a simulation experiment under the environment of aircraft height Wen Weiliu, and a drawing experiment is performed after one period of experiment, and the results are shown in Table 2.
Table 1 preparation of the anti-spalling agent composition
Weight of material/kg
|
Example 1
|
Example 2
|
Example 3
|
Polyethylene oxide
|
41.0
|
60.0
|
78.0
|
Resin composition
|
41.0
|
85.0
|
128.0
|
Alkyl ammonium chloride
|
31.0
|
50.0
|
68.0
|
Methacrylate compounds
|
31.0
|
60.0
|
88.0
|
Coupling agent
|
14.1
|
16.5
|
19.0
|
Hindered phenol compound
|
13.1
|
16.0
|
19.8
|
Aromatic oil
|
5.1
|
7.5
|
9.8 |
Table 2 asphalt drawing test results
Adhesion strength/psi
|
Example 4
|
Example 5
|
Example 6
|
Comparative example 1
|
Comparative example 2
|
No simulation experiments were performed
|
543
|
552
|
576
|
380
|
430
|
After simulation experiment
|
571
|
590
|
603
|
308
|
305 |
As can be seen from table 2, the addition of the anti-stripping agent of the invention to asphalt can significantly improve the adhesion strength and anti-stripping performance of asphalt; after a period of aircraft height Wen Weiliu simulation experiment, the adhesion strength of asphalt added with the anti-stripping agent is not reduced, but is increased, so that the anti-stripping agent not only can improve the anti-stripping performance of asphalt, but also has strong adaptability to the aircraft height Wen Weiliu environment. Asphalt without the anti-stripping agent is obviously reduced in adhesion strength after simulation experiments; after a certain commercial anti-stripping agent is added, compared with the anti-stripping agent provided by the invention, the improvement range of the adhesive strength is smaller, and the adhesive strength is reduced after a simulation experiment.