Anti-stripping agent and preparation method and application thereof
Technical Field
The invention belongs to the field of petroleum industry and basic material chemistry, and particularly relates to an anti-stripping agent, a preparation method and application thereof, which are particularly suitable for an airport asphalt runway.
Background
The airfield runway surface material is divided into two types, namely cement concrete and asphalt concrete, wherein the former is mainly applied to branch airports, and the latter is mainly applied to asphalt concrete finishing of cement runways in trunk airports or branch airports. In China, airports with more than ten million levels of passenger flow mainly adopt asphalt concrete materials as runway pavement materials. The working state of the asphalt concrete material for the airport runway is obviously different from that of the asphalt concrete material for the common highway, and the working state is mainly represented by the following two points: firstly, the high-temperature airflow ejected by the jet aircraft seriously influences the stability of the asphalt concrete material; secondly, after the oil content of the asphalt concrete material is reduced, the surface coarse aggregate is easy to loosen to form foreign invaders (FOD), and once the FOD is sucked into an aircraft engine, serious flight accidents can be caused. Therefore, the improvement of the high-temperature stability and the coarse aggregate shedding resistance of the asphalt concrete material is an important research direction for improving the civil aviation operation safety capability. At present, airport runways in the world are generally paved by polymer modified asphalt with good high-temperature performance so as to deal with the problems of airplane wake baking and road surface deformation and threshing under high shear stress, but the effect is not ideal, and after the airport runway is used for a period of time, the road surface bulges and cracks and the aggregate falls frequently, so that huge flight potential safety hazards and maintenance cost are brought. Therefore, the development of a high-temperature-resistant and anti-stripping asphalt material suitable for being used on an airport runway is urgently needed, a special high-temperature-resistant and anti-stripping evaluation method for the airport asphalt is established, a complete set of systematic and scientific matching technology is formed, and the international and domestic requirements for high-quality asphalt materials in the next thirty years are met.
In order to prevent the asphalt concrete coarse aggregate from falling off to form FOD, the Chinese capital airport adopts a plurality of preventive maintenance measures, such as: atomizing seal, slurry seal and the like, and simultaneously points out that the friction coefficient is reduced after the seal, thereby having influence on the running safety of the runway. As early as 1997, on the basis of analyzing the development history of the asphalt concrete runway in China, people should be pointed out to research and establish the technical standard of the petroleum asphalt and mineral aggregate of the asphalt pavement of the airport and research the modified asphalt and the mixture thereof to reduce the phenomenon of sand and stone shedding, but the problem is not completely solved at present.
Disclosure of Invention
The invention provides a novel anti-stripping agent and a preparation method and application thereof, aiming at the problem of aggregate shedding faced by an airport asphalt runway.
The invention provides an anti-stripping agent which comprises the following raw materials in parts by mass:
5363 parts of polyethylene oxide 3~9,
3 to 14 parts of resin, namely,
alkyl ammonium chloride 2~8 portions,
2 to 10 parts of methacrylate compounds,
1.3 to 2.0 portions of coupling agent,
1.2 to 2.0 parts of hindered phenol compounds,
0.4 to 1.1 portions of aromatic oil.
Preferably, the anti-stripping agent comprises the following raw materials in parts by mass:
5363 parts of polyethylene oxide 4~8,
4 to 13 parts of resin,
alkyl ammonium chloride 3~7 portions,
5363 portions of methacrylate compound 3~9 portions,
1.4 to 1.9 portions of coupling agent,
1.3 to 1.9 portions of hindered phenol compounds,
0.5 to 1.0 portion of aromatic oil.
The molecular weight of the polyethylene oxide is 50-300 ten thousand, and preferably 60-200 ten thousand.
The resin is one or more of petroleum resin, terpene resin, rosin resin, coumarone resin, phenolic resin, polyester resin and polyamide resin.
The alkyl ammonium chloride is one or a mixture of octadecyl trimethyl ammonium chloride and hexadecyl trimethyl ammonium chloride.
The methacrylate compound is one or a mixture of 2-hydroxyethyl methacrylate, 2-ethylhexyl methacrylate and ethyl methacrylate.
The coupling agent is one or more of silane coupling agent (at least one of types KH550, KH560 and KH 570), aluminate coupling agent and titanate coupling agent.
The hindered phenol compound comprises one or more of 2,8-di-tert-butyl-4-methylphenol, tetra- [3- (3,5-di-tert-butyl-4 hydroxyphenyl) propionic acid ] pentaerythritol ester, beta- (3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid octadecyl alcohol ester, 1,3,5- (3,5-di-tert-butyl-4 hydroxyphenyl) s-triazine-2,4,6 (1H, 3H, 5H) trione.
The aromatic oil is a component rich in aromatic hydrocarbon, wherein the content of the aromatic hydrocarbon is more than 70 percent by mass fraction, and the aromatic hydrocarbon can be selected from one or a mixture of more of reduced tetra-line extract oil, furfural refined extract oil, phenol refined extract oil or catalytic cracking slurry oil.
The anti-stripping agent is a paste at normal temperature.
In a second aspect, the present invention provides a method for preparing the anti-stripping agent, including:
uniformly mixing polyethylene oxide, resin, alkyl ammonium chloride, methacrylate compounds, a coupling agent, a hindered phenol compound and aromatic oil, then mixing, and extruding to obtain the anti-stripping agent.
The mixing is realized by using a conventional mixing device, such as a kneader and a bottom self-carrying extrusion structure of the kneader. The mixing conditions were as follows: the mixing temperature is 130-160 ℃, and the mixing time is 40-90min.
The extrusion temperature is 130-160 ℃.
In a third aspect, the present invention provides a pitch resistant to stripping, comprising: petroleum asphalt and the above anti-stripping agent.
In the anti-stripping asphalt, the dosage of the anti-stripping agent accounts for 2-3% of the mass of the anti-stripping asphalt.
In the anti-stripping asphalt, the petroleum asphalt can be conventional petroleum asphalt used for airport runways and is at least one of straight-run asphalt, oxidized asphalt, blended asphalt and solvent deoiled asphalt.
The fourth aspect of the invention provides a preparation method of the anti-falling asphalt, which comprises the following steps: heating and melting petroleum asphalt, adding the anti-stripping agent, and stirring until the mixture is uniformly mixed to obtain the anti-stripping asphalt.
In the preparation method of the anti-falling asphalt, the heating and melting temperature of the asphalt is 130-160 ℃, the stirring temperature is 130-160 ℃, and the stirring time can be 40-90min.
The anti-stripping agent is particularly suitable for being applied to asphalt of airport runways.
The anti-stripping asphalt provided by the invention is suitable for being used as asphalt for airfield runways.
The invention has the following advantages:
1. the novel anti-stripping agent provided by the invention not only can obviously improve the anti-stripping performance of asphalt, but also has strong adaptability to the high-temperature wake environment of an airplane, can improve the anti-stripping performance of an asphalt runway in an airport, reduces the stripping of aggregate, and can reduce the incidence rate of flight accidents.
2. The anti-stripping agent is pasty at normal temperature, development is not needed in the process of preparing the anti-stripping asphalt by using the anti-stripping agent, the production time of the anti-stripping asphalt is shortened, the working efficiency is improved, the adhesion strength of the asphalt can be further improved, the low-temperature extensibility of the asphalt can be improved, and frost heaving and cracking of a pavement can be avoided.
3. In the preparation method of the novel anti-stripping agent, polyethylene oxide, resin, alkyl ammonium chloride, methacrylate compound and hindered phenol compound are subjected to graft reaction in a kneader and in a screw extrusion process under the assistance of a coupling agent, so that the substances can be quickly and well combined, the formed product has high viscosity and flexibility and good polarity, and the anti-stripping agent can enable asphalt to have better high-temperature shedding resistance in a high-temperature environment. The methacrylate compound is added, so that the adhesion strength between the asphalt and stone is further enhanced. The addition of hindered phenol compounds can improve the anti-aging capability of the substances containing unsaturated bonds, thereby improving the anti-stripping agent and the anti-heat aging capability of asphalt. Under the action of aromatic oil, the components are easier to fuse, the reaction condition is reduced, the energy is saved, the low-temperature extensibility of the asphalt can be improved, and frost cracking of the pavement in winter is avoided. Therefore, the anti-stripping agent of the invention comprehensively strengthens the adhesion strength of asphalt to stone materials from multiple aspects and improves the high-temperature shedding resistance of the asphalt in airports.
4. The preparation conditions of the novel anti-stripping agent are more mild, the mixing reaction time in the preparation process of the anti-stripping agent is greatly shortened, and the production efficiency is improved.
Detailed Description
The following examples are given to illustrate the technical aspects of the present invention in detail, but the present invention is not limited to the following examples. In the present invention, wt% is a mass fraction.
The invention relates to an aircraft high-temperature wake flow simulation experiment method, which comprises the following steps: the tail part of the engine is linked with a straight cylinder type cylinder body made of high-temperature resistant materials with a heating function by using an airplane engine (such as a renewed engine). During the experiment, the asphalt to be tested is placed in a metal tray after being melted, and is spread flatly to form a film, and the thickness of the film is 3mm +/-0.3 mm. And (3) placing the tray filled with the asphalt film at the bottom in the cylinder body, and firmly fixing. The bottom of barrel has the heating function, guarantees that the pitch temperature in the tray maintains 60 degrees centigrade +/-20 ℃ (road surface temperature when simulation summer high temperature). Starting the engine, enabling high-temperature tail gas of the engine to enter from one end of the straight cylinder, discharging from the other end of the straight cylinder, enabling the high-temperature tail gas to be blown over the asphalt membrane for 30 minutes and stopping for 10 minutes, and continuously repeating the steps for multiple times. One experimental period was 240 hours from the initial start of blowing. And then taking out the asphalt, analyzing various performances, and comparing the performances with the performances before the simulation experiment. Therefore, the condition of asphalt on an airport runway (particularly a takeoff section) when the asphalt is subjected to high-temperature tail gas blowing of an airplane for a long time is simulated, and the change of the asphalt property, particularly the change of the anti-falling performance is inspected.
In the present invention, the adhesion strength of asphalt is measured by a pull tester. The instrument and test method are as follows:
instruments and equipment: the drawing tester with the model of Positest AT-A has the following parameters: a draw rate of 150psi/s; the test range is 0-2000psi; the test method is as follows:
weighing 0.03g of asphalt on an experimental surface of a spindle; placing the spindle attached with the asphalt on an electric hot plate, after the asphalt is melted, uniformly coating the asphalt within 10s, simultaneously quickly transferring the preheated white steel plate to a horizontal operation table, covering the spindle coated with the asphalt uniformly on the white steel plate, standing and cooling to room temperature (about 1 h). The liquid asphalt is uniformly spread under the action of the gravity of the spindle, the spindle and the white steel plate are bonded after cooling, and the thickness of the asphalt film is about 0.1mm. The white steel plate and the spindle cooled to room temperature were placed in an environmental chamber (temperature: 20 ℃; relative humidity: 50 Rh%) and were taken out after constant temperature for 1 hour, and the adhesiveness was tested using a Positest AT-A tester. The value of the pull strength at the moment of separation of the spindle from the metal sheet is recorded. The anti-falling performance of the asphalt is characterized by the numerical value, and the larger the numerical value is, the better the anti-falling performance is.
Example 1
41.0kg of polyethylene oxide with the molecular weight of 61 ten thousand, 41.0kg of C5 petroleum resin, 31.0kg of octadecyl trimethyl ammonium chloride, 31.0kg of 2-hydroxyethyl methacrylate, 14.1kg of silane coupling agent (KH 560), 13.1kg of 2,8-di-tert-butyl-4-methylphenol and 5.1 kg of minus four-line extract oil are weighed and placed in a preheating kneader for kneading, the kneading temperature is 135 ℃, and the kneading time is 40min; then extruding at 135 ℃ to obtain the anti-stripping agent. The distribution ratio of each component is shown in table 1.
Example 2
Weighing 60.0kg of polyethylene oxide with the molecular weight of 190 ten thousand, 85.0kg of terpene resin, 50.0 kg of hexadecyl trimethyl ammonium chloride, 60.0kg of 2-ethylhexyl methacrylate, 16.5kg of aluminate coupling agent, 16.0kg of tetra- [3- (3,5-di-tert-butyl-4 hydroxyphenyl) propionic acid ] pentaerythritol ester and 7.5kg of furfural refined extract oil, placing the materials into a preheated kneader for mixing, wherein the mixing temperature is 158 ℃, and the mixing time is 88min; and then extruding at the extrusion temperature of 158 ℃ to obtain the anti-stripping agent. The proportions of the components are shown in Table 1.
Example 3
Weighing 78.0kg of polyethylene oxide with the molecular weight of 120 ten thousand, 128.0kg of polyamide resin, 68.0 kg of octadecyl trimethyl ammonium chloride, 88.0kg of ethyl methacrylate, 19.0kg of titanate coupling agent, 19.8kg of beta- (3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid octadecyl alcohol ester and 9.8kg of catalytic cracking slurry oil, placing the materials into a pre-heated kneader for mixing at the mixing temperature of 145 ℃ for 75min; then extruded at an extrusion temperature of 145 ℃. Obtaining the anti-stripping agent. The distribution ratio of each component is shown in table 1.
Example 4
The anti-stripping agent obtained in example 1 was added to molten petroleum asphalt with a penetration of 70dmm at 25 ℃ (ziru 70) manufactured by ziru petrochemical company, petroleum asphalt: the weight ratio of the anti-stripping agent is 97:3. stirring at constant temperature of 132 deg.C for 42 min to obtain anti-stripping asphalt.
The adhesion strength of the anti-drop asphalt was measured by a pull tester, and the results are shown in Table 2. The anti-dropping asphalt is subjected to a simulation experiment under the high-temperature wake environment of an airplane, and a drawing test is carried out after a period of test, and the result is shown in table 2.
Example 5
The anti-stripping agent obtained in example 2 was added to molten petroleum asphalt produced by the company ziru petrochemical having a penetration of 70dmm at 25 ℃ (ziru 70), and the ratio of petroleum asphalt: the weight ratio of the anti-stripping agent is 97.5:2.5. stirring at constant temperature of 158 ℃ for 85 min to obtain the anti-stripping asphalt.
The adhesion strength of the anti-drop asphalt was measured by a pull tester, and the results are shown in Table 2. The anti-drop asphalt is subjected to a simulation experiment under the high-temperature wake flow environment of an airplane, a drawing test is carried out after a period of test, and the result is shown in table 2.
Example 6
The anti-stripping agent obtained in example 3 was added to molten petroleum asphalt produced by the company ziru petrochemical having a penetration of 70dmm at 25 ℃ (ziru 70), and the ratio of petroleum asphalt: the weight ratio of the anti-stripping agent is 98:2. stirring at the constant temperature of 145 ℃ for 65 min to obtain the anti-stripping asphalt.
The adhesion strength of the anti-drop asphalt was measured by a pull tester, and the results are shown in Table 2. The anti-dropping asphalt is subjected to a simulation experiment under the high-temperature wake environment of an airplane, and a drawing test is carried out after a period of test, and the result is shown in table 2.
Comparative example 1
For comparison, the adhesion strength of a pull tester test of grade 70A bitumen (zilu 70) produced by zilu petrochemical company is also listed in table 2; 70A-grade asphalt (Qilu 70) produced by the Qilu petrochemical company is also subjected to a simulation experiment in the high-temperature wake environment of an airplane, and drawing experiments are respectively carried out after a period of experiment, and the results are shown in Table 2.
Comparative example 2
For comparison, commercial anti-sloughing agent PAVE192 from invitrogen corporation was added to molten petroleum asphalt with a penetration of 70dmm at 25 ℃ from zilu petrochemical corporation (zilu 70A), petroleum asphalt: the weight ratio of the anti-stripping agent is 97.5:2.5. stirring at constant temperature of 158 ℃ for 85 min to obtain the anti-stripping asphalt.
The adhesion strength of the anti-drop asphalt was measured by a pull tester, and the results are shown in Table 2. The anti-dropping asphalt is subjected to a simulation experiment under the high-temperature wake environment of an airplane, and a drawing test is carried out after a period of test, and the result is shown in table 2.
TABLE 1 preparation of anti-stripping agent component ratios
Weight of material/kg
|
Example 1
|
Example 2
|
Example 3
|
Polyethylene oxide
|
41.0
|
60.0
|
78.0
|
Resin composition
|
41.0
|
85.0
|
128.0
|
Alkyl ammonium chloride
|
31.0
|
50.0
|
68.0
|
Methacrylate compound
|
31.0
|
60.0
|
88.0
|
Coupling agent
|
14.1
|
16.5
|
19.0
|
Hindered phenol compound
|
13.1
|
16.0
|
19.8
|
Aromatic oil
|
5.1
|
7.5
|
9.8 |
TABLE 2 Pitch Pull test results
Adhesion Strength/psi
|
Example 4
|
Example 5
|
Example 6
|
Comparative example 1
|
Comparative example 2
|
No simulation experiment was performed
|
543
|
552
|
576
|
380
|
430
|
After the simulation experiment
|
571
|
590
|
603
|
308
|
305 |
As can be seen from Table 2, the addition of the anti-stripping agent of the present invention to asphalt significantly improves the adhesion strength and anti-stripping performance of asphalt; after a period of airplane high-temperature wake simulation experiment, the adhesion strength of the asphalt added with the anti-stripping agent is not reduced but increased, which shows that the anti-stripping agent can improve the anti-stripping performance of the asphalt and has strong adaptability to airplane high-temperature wake environment. The adhesion strength of the asphalt without the anti-stripping agent is obviously reduced after a simulation experiment; after a certain commercial anti-stripping agent is added, compared with the anti-stripping agent disclosed by the invention, the improvement range of the adhesive strength is smaller, and the adhesive strength is reduced after a simulation experiment.