CN116925455A - Anti-stripping and anti-aging agent, and preparation method and application thereof - Google Patents
Anti-stripping and anti-aging agent, and preparation method and application thereof Download PDFInfo
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- CN116925455A CN116925455A CN202210346980.5A CN202210346980A CN116925455A CN 116925455 A CN116925455 A CN 116925455A CN 202210346980 A CN202210346980 A CN 202210346980A CN 116925455 A CN116925455 A CN 116925455A
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- 238000010438 heat treatment Methods 0.000 claims description 5
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- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 4
- 238000011161 development Methods 0.000 claims description 4
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- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 claims description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 3
- VKJLYEDTHCTCOH-UHFFFAOYSA-N 3-(3-octadecoxy-3-oxopropyl)sulfanylpropanoic acid Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(O)=O VKJLYEDTHCTCOH-UHFFFAOYSA-N 0.000 claims description 3
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003508 Dilauryl thiodipropionate Substances 0.000 claims description 3
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- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
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- 150000004645 aluminates Chemical class 0.000 claims description 3
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 3
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- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 3
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- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 2
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- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/26—Bituminous materials, e.g. tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C9/00—Special pavings; Pavings for special parts of roads or airfields
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/30—Adapting or protecting infrastructure or their operation in transportation, e.g. on roads, waterways or railways
Abstract
The invention discloses an anti-stripping and anti-aging agent, and a preparation method and application thereof. The anti-stripping and anti-aging agent comprises the following raw materials: ethylene-vinyl acetate copolymer, polyethylene oxide, resin, alkyl ammonium chloride, methacrylate compounds, coupling agent and antioxidant. The preparation method of the anti-stripping and anti-aging agent comprises the following steps: and uniformly mixing the materials, and obtaining the anti-stripping and anti-aging agent after mixing, extruding and granulating. The anti-stripping and anti-aging agent is particularly suitable for airport asphalt runways.
Description
Technical Field
The invention belongs to the petroleum industry and the basic material chemistry field, in particular to an anti-stripping and anti-aging agent and a preparation method thereof, which are particularly suitable for airfield runway asphalt.
Background
When the temperature in summer is 40 ℃, the TY-104 aircraft is used for a blowing test, and the highest temperature of the asphalt pavement can reach 141 ℃. At this time, the asphalt pavement is ablated and softened by high-temperature tail gas flow sprayed by the airplane at a plurality of positions, and each ablation area is 3-5 cm 2 . The asphalt runway is continuously subjected to the blowing of the high Wen Wei airflow of the airplane, so that asphalt aging is easy to cause, coarse stone on the surface is further caused to fall off, and once the fallen stone is sucked into an engine of the airplane, serious flight accidents are caused. Therefore, the high-temperature stability and the coarse stone shedding resistance of the asphalt concrete material are improved, and the asphalt concrete material is an important research direction for improving the civil aviation operation safety. At present, polymer modified asphalt with better performance is widely adopted for paving airport asphalt runways worldwide, so that the problems of airplane wake baking, road surface deformation and threshing under high shear stress are solved. However, the practical effect is not ideal, and after a period of use, the pavement bulges, cracks and stone fall frequently occur, so that the potential safety hazard and the maintenance cost are increased. Therefore, there is an urgent need to develop an aging-resistant, anti-falling and aging-resistant asphalt material suitable for use on airport runways.
At present, the researches on the failure mechanism of the airport asphalt concrete pavement and the modified asphalt concrete materials comprise the following steps: the damage cause of the acetic acid-based snow-melting agent to the road surface of asphalt concrete is studied by university of Changan, peng Zixin and the like, and asphalt emulsification caused by acetate is analyzed. The phenomenon of FOD caused by the falling of coarse stones on the pavement of asphalt concrete and engineering treatment measures are analyzed by the university of Tongji Tan Yue and the like. The temperature change rule and the high-temperature stress fatigue characteristic of the tensile strength of the asphalt concrete pavement material are analyzed through a large amount of statistical data in the air force university Weng Xing, and the change of the strength under high-temperature stress is considered to seriously influence the runway safety. The university of the same university Liu Wen, etc., indicates the effect of temperature on runway performance based on comparing various asphalt concrete runway design influencing factors, but no in-depth analysis has been made. At present, no anti-stripping and anti-aging agent is developed specially for the problem of asphalt concrete stone falling off of an airport runway caused by the influence of jet aircraft height Wen Weiliu.
Disclosure of Invention
Aiming at the problem of aggregate shedding faced by airport asphalt runways, the invention provides an anti-stripping and anti-aging agent, and a preparation method and application thereof. When the anti-stripping and anti-aging agent is used for airfield runway asphalt, the anti-stripping and anti-aging performances of the asphalt can be obviously improved.
The invention provides an anti-stripping and anti-aging agent which comprises the following raw materials in parts by weight:
1 to 8 parts of ethylene-vinyl acetate copolymer, 1 to 6 parts of polyethylene oxide, 1 to 7 parts of resin, 1 to 6 parts of alkyl ammonium chloride, 1 to 7 parts of methacrylate compound, 0.2 to 0.7 part of coupling agent and 0.1 to 0.6 part of antioxidant.
The anti-stripping and anti-aging agent of the invention preferably comprises the following raw materials in parts by weight:
1.5 to 7 parts of ethylene-vinyl acetate copolymer, 1.2 to 5 parts of polyethylene oxide, 1.2 to 6 parts of resin, 1.2 to 5 parts of alkyl ammonium chloride, 1.2 to 6 parts of methacrylate compounds, 0.3 to 0.6 part of coupling agent and 0.2 to 0.5 part of antioxidant.
In the ethylene-vinyl acetate copolymer, the mass content of the combined vinyl acetate is 22-25 wt%.
The molecular weight of the polyethylene oxide is 14-430 ten thousand, preferably 15-420 ten thousand.
The resin is one or more selected from petroleum resin, terpene resin, rosin resin, coumarone resin, phenolic resin, polyester resin and polyamide resin.
The alkyl ammonium chloride is selected from one or two of octadecyl trimethyl ammonium chloride and hexadecyl trimethyl ammonium chloride.
The methacrylate compound is one or a mixture of more than one of 2-hydroxyethyl methacrylate, 2-ethylhexyl methacrylate and ethyl methacrylate.
The coupling agent is one or more selected from silane coupling agent, aluminate coupling agent and titanate coupling agent.
The antioxidant is one or more selected from 2, 6-di-tert-butyl-p-cresol, hydroquinone dibenzyl ether, dilauryl thiodipropionate, trisnonylphenyl phosphite, stearyl thiodipropionate and poly (2, 4-trimethyl-1, 2-dihydroxybenzene).
The second aspect of the invention provides a preparation method of the anti-peeling and anti-aging agent, which comprises the following steps:
mixing ethylene-vinyl acetate copolymer, polyethylene oxide, resin, alkyl ammonium chloride, methacrylate compound, coupling agent and antioxidant, mixing, granulating and obtaining the anti-stripping and anti-aging agent.
The mixing is effected by conventional mixing devices, such as kneaders. The mixing conditions were as follows: the mixing temperature is 150-180 ℃ and the mixing time is 50-80 min.
The granulation is carried out by extrusion granulation, and can be realized by a conventional extrusion granulation device, such as a screw extruder. The extrusion granulation conditions were as follows: the extrusion granulating temperature is 150-180 ℃.
The anti-stripping and anti-aging agent prepared by the method provided by the second aspect is granular, and the granularity can be 2-5 mm.
In a third aspect, the invention provides an anti-shedding and anti-aging asphalt, comprising: petroleum asphalt and the anti-stripping and anti-aging agent.
In the anti-falling and anti-aging asphalt, the dosage of the anti-falling and anti-aging agent accounts for 2 to 3 percent of the mass of the anti-falling and anti-aging asphalt.
In the anti-falling and anti-aging asphalt, the petroleum asphalt can be conventional petroleum asphalt for airport runways and is at least one of straight asphalt, oxidized asphalt, blended asphalt and solvent deoiling asphalt.
The fourth aspect of the invention provides a preparation method of the anti-falling and anti-aging asphalt, which comprises the following steps: heating and melting petroleum asphalt, adding the anti-stripping and anti-aging agent, stirring until the mixture is uniform, and then developing to obtain the anti-stripping and anti-aging asphalt.
In the preparation method, the petroleum asphalt has the heating and melting temperature of 140-160 ℃, the stirring temperature of 140-160 ℃ and the stirring time of 50-80 min. The development temperature is 140-160 ℃ and the development time is 4-7 hours.
The anti-stripping and anti-aging agent is particularly suitable for application in airfield runway asphalt.
The anti-falling and anti-aging asphalt provided by the invention is suitable for application on airport runways.
The invention has the following beneficial effects:
1. the anti-stripping and anti-aging agent not only can remarkably improve the anti-stripping performance of asphalt, but also has strong adaptability to the high Wen Weiliu environment of an airplane, can improve the anti-stripping performance of an airport asphalt runway, reduce the stripping of aggregate, and can reduce the incidence rate of flight accidents.
2. The anti-stripping and anti-aging agent is granular and is easy to transport and store.
3. In the preparation method of the anti-stripping and anti-aging agent, the coupling agent is used as an initiator, and ethylene-vinyl acetate copolymer, polyethylene oxide, resin, alkyl ammonium chloride, methacrylate compounds, antioxidants and the like are reacted in a kneader and in the screw extrusion process, and all the components are matched with each other, so that all the substances can be combined fast and well, the formed product has higher viscosity and flexibility, and also has better polarity, so that the anti-stripping and anti-aging agent can enable asphalt to have better high-temperature stripping resistance and anti-aging capability in a high-temperature environment.
Detailed Description
The following examples are given to illustrate the technical aspects of the present invention in detail, but the present invention is not limited to the following examples. In the invention, the weight percent is the mass fraction.
In the invention, the simulation experiment method of the aircraft height Wen Weiliu comprises the following steps: with aircraft engines (such as newer engines), the tail links a straight barrel of high temperature resistant material with heating. During the experiment, put into metal tray after melting the pitch that waits to test, the flat spreading is the film form, and film thickness is 3mm + -0.3 mm. The tray with the asphalt film is arranged at the bottom in the cylinder body and is firmly fixed. The bottom of the cylinder body has a heating function, so that the temperature of asphalt in the tray is maintained at 60+/-20 ℃ (the temperature of Wen Shilu table in summer simulation). The engine is started, so that high-temperature tail gas of the engine enters from one end of the straight cylinder, the other end of the straight cylinder is discharged, the high-temperature tail gas is blown over the asphalt membrane, the blowing is continued for 30 minutes, and the blowing is stopped for 10 minutes, so that the process is continuously repeated for a plurality of times. One experimental period was 240 hours from the initial start of blowing. And then taking out the asphalt, analyzing each performance, and comparing the performance with the performance before the simulation experiment. The method simulates the condition of asphalt on an airport runway (especially in a take-off section) when the asphalt is purged by high-temperature tail gas of an airplane for a long time, and examines the change of asphalt properties, especially the change of anti-falling performance.
In the invention, the asphalt adhesion strength is obtained by testing with a drawing tester. The instrument and the test method are as follows:
instrument and equipment: drawing tester with model PosiTest AT-A, tester parameters: a draw rate of 150psi/s; test range 0-2000psi; the test method is as follows:
weighing asphalt with the mass of 0.03g on the experimental surface of the spindle; placing the spindle with asphalt on an electric heating plate, after asphalt is melted, uniformly smearing the asphalt within 10 seconds, simultaneously rapidly transferring the preheated white steel plate to a horizontal operation table, buckling the spindle coated with the uniform asphalt on the white steel plate, standing and cooling to room temperature (about 1 h). The liquid asphalt spreads evenly under the action of spindle gravity, and after cooling, the spindle and the white steel plate are bonded, and the thickness of the asphalt film is about 0.1mm. The white steel plate cooled to room temperature and the spindle were put in an environmental box (temperature: 20 ℃ C.; relative humidity: 50 Rh%) and kept AT constant temperature for 1 hour, and then taken out, and the adhesion was measured using a Positest AT-A tester. The drawing strength value at the time of separating the spindle from the metal plate was recorded. The anti-falling performance of the asphalt is represented by the numerical value, and the larger the numerical value is, the better the anti-falling performance is.
Example 1
15.0kg of ethylene-vinyl acetate copolymer with 25wt% of combined vinyl acetate and 12.0kg of polyethylene oxide with 15 ten thousand molecular weight, 12.0kg of petroleum resin, 12.0kg of octadecyl trimethyl ammonium chloride, 12.0kg of 2-hydroxyethyl methacrylate, 3.0kg of titanate coupling agent and 2.0kg of hydroquinone dibenzyl ether are weighed and put into a preheated kneader for mixing, wherein the mixing temperature is 152 ℃ and the mixing time is 52min; then extruding and granulating, wherein the extrusion temperature is 152 ℃. Cutting into granules with granularity of 2mm to obtain the anti-stripping and anti-aging agent. The amounts of the components used for preparing the anti-stripping and anti-aging agent are shown in Table 1.
Example 2
70.0kg of ethylene-vinyl acetate copolymer with the mass content of 22wt% of combined vinyl acetate, 50.0kg of polyethylene oxide with the molecular weight of 420 ten thousand, 60.0kg of phenolic resin, 50.0kg of cetyltrimethylammonium chloride, 60.0kg of 2-ethylhexyl methacrylate, 6.0kg of silane coupling agent (KH 560) and 5.0kg of dilauryl thiodipropionate are weighed and placed into a preheated kneader for mixing, wherein the mixing temperature is 178 ℃ and the mixing time is 78min; then extruding and granulating, wherein the extrusion temperature is 178 ℃. Cutting into granules with granularity of 2mm to obtain the anti-stripping and anti-aging agent. The amounts of the components used for preparing the anti-stripping and anti-aging agent are shown in Table 1.
Example 3
45.0kg of ethylene-vinyl acetate copolymer with 23wt% of combined vinyl acetate and 32.0kg of polyethylene oxide with 200 ten thousand molecular weight, 37.0kg of polyamide resin, 31.0kg of octadecyl trimethyl ammonium chloride, 36.0kg of ethyl methacrylate, 4.5kg of aluminate coupling agent and 3.5kg of octadecyl thiodipropionate are weighed and placed in a preheated kneader for mixing, wherein the mixing temperature is 165 ℃ and the mixing time is 65min; then extruding and granulating, wherein the extrusion temperature is 165 ℃. Cutting into granules with granularity of 2mm to obtain the anti-stripping and anti-aging agent. The amounts of the components used for preparing the anti-stripping and anti-aging agent are shown in Table 1.
Example 4
The anti-flaking and anti-aging agent obtained in example 1 was added to a petroleum asphalt (Qilu 90A) produced by Qilu petrochemical company and melted at 142 ℃ and having a penetration of 87dmm at 25 ℃): the weight ratio of the anti-stripping and anti-aging agent is 97:3. stirring at a constant temperature of 142 ℃ for 52min, and then developing at a constant temperature of 142 ℃ for 4 hours to obtain the anti-falling and anti-aging asphalt.
The adhesion strength of the anti-falling and anti-aging asphalt was measured by a tensile tester, and the results are shown in Table 2. The asphalt was subjected to a simulation experiment in an aircraft high Wen Weiliu environment, and after one period of experiment, a drawing experiment was performed, and the results are shown in table 2.
Example 5
The anti-spalling and anti-aging agent obtained in example 2 was added to 158 ℃ molten petroleum asphalt (ziluting 90A) having a penetration of 87dmm at 25 ℃ produced by ziluting company: the weight ratio of the anti-stripping and anti-aging agent is 97.5:2.5. stirring at a constant temperature of 158 ℃ for 78min, and then developing at 158 ℃ for 7 hours to obtain the anti-falling and anti-aging asphalt.
The adhesion strength of the anti-falling and anti-aging asphalt was measured by a tensile tester, and the results are shown in Table 2. The asphalt was subjected to a simulation experiment in an aircraft high Wen Weiliu environment, and after one period of experiment, a drawing experiment was performed, and the results are shown in table 2.
Example 6
The anti-flaking and anti-aging agent obtained in example 3 was added to 150℃molten petroleum asphalt (Qilu 90A) having a penetration of 87dmm at 25℃produced by Qilu petrochemical Co., ltd.: the weight ratio of the anti-stripping and anti-aging agent is 98:2. stirring at constant temperature of 150 ℃ for 65min, and then developing at constant temperature of 150 ℃ for 5.5 hours to obtain the anti-falling and anti-aging asphalt.
The adhesion strength of the anti-falling and anti-aging asphalt was measured by a tensile tester, and the results are shown in Table 2. The asphalt was subjected to a simulation experiment in an aircraft high Wen Weiliu environment, and after one period of experiment, a drawing experiment was performed, and the results are shown in table 2.
Comparative example 1
For comparison, asphalt (Qilu 90A) produced by Qilu petrochemical company and having a penetration of 87dmm at 25 ℃ was tested for adhesion strength by a tensile tester, and the results are shown in Table 2; and the simulation experiment of Qilu 90A under the environment of aircraft height Wen Weiliu is also carried out, and the drawing experiment is carried out after one period of experiment, and the result is shown in Table 2.
Comparative example 2
For comparison, a commercial anti-spalling agent JW-AS1 produced by Shenzhen Jia Cheng Wei was added to a 158 ℃ molten petroleum asphalt (Qilu 90A) produced by Qilu petrochemical company and having a penetration of 87dmm at 25 ℃: the weight ratio of the commercial anti-stripping agent is 97.5:2.5. stirring at a constant temperature of 158 ℃ for 78min, and then developing at 158 ℃ for 7 hours to obtain the anti-shedding asphalt.
The asphalt was tested for adhesion strength by a pull tester, and the results are shown in table 2. The asphalt was subjected to a simulation experiment in an aircraft high Wen Weiliu environment, and after one period of experiment, a drawing experiment was performed, and the results are shown in table 2.
TABLE 1 preparation of the amounts of the anti-spalling and anti-aging agent components
Weight of material/kg | Example 1 | Examples2 | Example 3 |
Ethylene-vinyl acetate copolymer | 15.0 | 70.0 | 45.0 |
Polyethylene oxide | 12.0 | 50.0 | 32.0 |
Resin composition | 12.0 | 60.0 | 37.0 |
Alkyl ammonium chloride | 12.0 | 50.0 | 31.0 |
Methacrylate compounds | 12.0 | 60.0 | 36.0 |
Coupling agent | 3.0 | 6.0 | 4.5 |
Antioxidant | 2.0 | 5.0 | 3.5 |
Table 2 asphalt drawing test results
Adhesion strength/psi | Example 4 | Example 5 | Example 6 | Comparative example 1 | Comparative example 2 |
No simulation experiments were performed | 491 | 533 | 564 | 363 | 406 |
After simulation experiment | 527 | 565 | 597 | 281 | 415 |
As can be seen from table 2, the addition of the anti-stripping and anti-aging agent of the invention to asphalt can significantly improve the adhesion strength and anti-stripping performance of asphalt; after a period of aircraft height Wen Weiliu simulation experiment, the adhesion strength of the asphalt added with the anti-stripping and anti-aging agent is not reduced, but is increased, so that the anti-stripping and anti-aging agent not only can improve the anti-stripping performance of the asphalt, but also has stronger anti-aging capability and strong adaptability to the aircraft height Wen Weiliu environment. The asphalt without the anti-stripping and anti-aging agent has obviously reduced adhesion strength after simulation experiments, which indicates that the anti-aging capability is weaker; after a certain commercial anti-stripping agent is added, compared with the anti-stripping anti-aging agent provided by the invention, the anti-stripping anti-aging agent has smaller improvement range of adhesion strength, and after a simulation experiment, the anti-stripping anti-aging agent has smaller improvement range of adhesion strength.
Claims (17)
1. An anti-stripping and anti-aging agent comprises the following raw materials in parts by weight: 1 to 8 parts of ethylene-vinyl acetate copolymer, 1 to 6 parts of polyethylene oxide, 1 to 7 parts of resin, 1 to 6 parts of alkyl ammonium chloride, 1 to 7 parts of methacrylate compound, 0.2 to 0.7 part of coupling agent and 0.1 to 0.6 part of antioxidant.
2. The anti-peeling and anti-aging agent according to claim 1, wherein: the material comprises the following raw materials in parts by weight: 1.5 to 7 parts of ethylene-vinyl acetate copolymer, 1.2 to 5 parts of polyethylene oxide, 1.2 to 6 parts of resin, 1.2 to 5 parts of alkyl ammonium chloride, 1.2 to 6 parts of methacrylate compounds, 0.3 to 0.6 part of coupling agent and 0.2 to 0.5 part of antioxidant.
3. An anti-peeling and anti-aging agent according to claim 1 or 2, characterized in that: in the ethylene-vinyl acetate copolymer, the mass content of the combined vinyl acetate is 22-25 wt%.
4. An anti-peeling and anti-aging agent according to claim 1 or 2, characterized in that: the molecular weight of the polyethylene oxide is 14-430 ten thousand, preferably 15-420 ten thousand.
5. An anti-peeling and anti-aging agent according to claim 1 or 2, characterized in that: the resin is one or more selected from petroleum resin, terpene resin, rosin resin, coumarone resin, phenolic resin, polyester resin and polyamide resin.
6. An anti-peeling and anti-aging agent according to claim 1 or 2, characterized in that: the alkyl ammonium chloride is selected from one or two of octadecyl trimethyl ammonium chloride and hexadecyl trimethyl ammonium chloride.
7. An anti-peeling and anti-aging agent according to claim 1 or 2, characterized in that: the methacrylate compound is one or a mixture of more than one of 2-hydroxyethyl methacrylate, 2-ethylhexyl methacrylate and ethyl methacrylate.
8. The anti-peeling and anti-aging agent according to claim 1 or 2, wherein the coupling agent is one or more selected from the group consisting of silane coupling agents, aluminate coupling agents, titanate coupling agents.
9. The anti-peeling-aging agent according to claim 1 or 2, characterized in that: the antioxidant is one or more selected from 2, 6-di-tert-butyl-p-cresol, hydroquinone dibenzyl ether, dilauryl thiodipropionate, trisnonylphenyl phosphite, stearyl thiodipropionate and poly (2, 4-trimethyl-1, 2-dihydroxybenzene).
10. An anti-peeling and anti-aging agent according to claim 1 or 2, characterized in that: the anti-stripping and anti-aging agent is granular.
11. A process for preparing the anti-spalling and anti-aging agent according to any one of claims 1 to 10, comprising:
mixing ethylene-vinyl acetate copolymer, polyethylene oxide, resin, alkyl ammonium chloride, methacrylate compound, coupling agent and antioxidant, mixing, granulating and obtaining the anti-stripping and anti-aging agent.
12. The method of claim 11, wherein: the mixing conditions were as follows: the mixing temperature is 150-180 ℃ and the mixing time is 50-80 min; and/or, the granulation adopts extrusion granulation, and the extrusion granulation temperature is 150-180 ℃.
13. An anti-shedding and anti-aging asphalt comprising: petroleum asphalt and the anti-spalling and anti-aging agent according to any one of claims 1 to 10.
14. The anti-shedding and anti-aging asphalt according to claim 13, wherein: in the anti-falling and anti-aging asphalt, the dosage of the anti-falling and anti-aging agent accounts for 2 to 3 percent of the mass of the anti-falling and anti-aging asphalt.
15. A method for preparing the anti-shedding and anti-aging asphalt as claimed in claim 13 or 14, comprising: heating and melting petroleum asphalt, adding the anti-stripping and anti-aging agent, stirring until the mixture is uniform, and then developing to obtain the anti-stripping and anti-aging asphalt.
16. The method of preparing as claimed in claim 15, wherein: the petroleum asphalt is heated and melted at 140-160 ℃, stirred at 140-160 ℃ for 50-80 min; the development temperature is 140-160 ℃ and the development time is 4-7 hours.
17. Use of an anti-spalling and anti-ageing agent according to any one of claims 1 to 10 or an anti-spalling and anti-ageing asphalt according to any one of claims 13 to 14 in an airport runway.
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