CN115537279A - 一种低能耗塑料表面清洗剂 - Google Patents
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Classifications
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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Abstract
本发明公开了一种低能耗塑料表面清洗剂，属于清洗剂技术领域，低能耗塑料表面清洗剂包括如下原料：烷基聚葡萄糖苷、氨基蔗糖酯、低泡异构醇嵌段聚醚、氨基三乙酸钠、无机碱、三乙醇胺、杀菌剂、疏水剂、抑泡剂、去离子水，塑料表面清洗剂的制备方法是通过各原料适当重量配比，在特定的温度压力下反应一段时间产生协同作用，对塑料工件加工过程中的脱模剂、润滑脂、胶质、灰尘等具有明显的乳化渗透剥离效果，对塑料部件无腐蚀，清洗效果好，无刺激性气味，不含铬酸盐、亚硝酸盐、磷酸盐，对环境友好。常温喷淋清洗，具有低能耗、大容量、长寿命等特点。
Description
技术领域
本发明属于清洗剂技术领域，特别涉及一种低能耗塑料表面清洗剂。
背景技术
塑料是节能型材料，具有价格低、性能优异(密度低、隔热吸音、防震、电绝缘性和耐化学药品性优良、生产能耗低)，所以在工业和民用生产生活中应用广泛，尤其在汽车上的用量越来越大，可减轻汽车自重、提高燃料效率、缩短加工时间、降低能耗、提高资源利用效率，塑料制品必须经过适当加工成型，才能成为具有一定形状和功能的车用塑料部件，塑料部件在压缩模型、层压成型、挤出成型、注射成型、吹塑成型等工艺脱模后表面会沾染脱模剂、润滑脂及灰尘等污染物，塑料部件表面的清洗洁净度严重影响接下来的装配和喷涂。
传统的塑料清洗剂往往采用强酸性或者强碱性方案，能耗高的同时还会对塑料部件产生腐蚀，对操作者和清洗设备也会产生伤害和腐蚀，清洗废水含有毒害成分，对环境不友好，针对这些缺点研发人员作出了改进，采用弱酸弱碱方案，试图解决清洗中存在的弊端，弱酸性清洗剂采用中温清洗，能耗高，由于弱酸性的清洗剂抑菌效果相对较差，主洗槽和漂洗槽短期就会有大量菌繁殖，不但影响了工件的洁净度还易对操作人员产生过敏症状，影响健康。弱碱性清洗剂采用高温清洗，能耗高，塑料部件表面残留多，不易漂洗，影响后道组装或喷涂。
中国专利(申请号为201410283891.6)公开了一种塑料清洗剂，每升塑料清洗剂含下述组分：壬基酚聚氧乙烯醚100-200g，草酸60-80g，脂肪醇聚氧乙烯醚5-10g，烷基酚聚氧乙烯醚1-5g，硫脲3-7g，丙二醇甲醚20-50g，乙二胺四乙酸二钠5-10g，乙酸戊酯10-20g，余量为水。该发明清洗剂呈弱酸性中温使用能耗高，抑菌效果差，污水处理难度大。
中国专利(申请号为201110106733.X)公开了一种塑料清洗剂，按重量百分比包括：20～50％的无水硫酸钠，20～50％的五水偏硅酸钠，1～30％的十二烷基苯磺酸钠1～30％的化纤清洗剂7960，该发明清洗剂采用高温清洗，能耗高，难漂洗，残留多。
发明内容
本发明的目的是解决现有技术中的缺陷，提供一种低能耗、高净洗力、大容量、长寿命、易降解的低能耗塑料表面多功能清洗剂，能够在室温条件下清洗塑料部件，低泡抑菌无腐蚀，清洗部件表面无残留，提高喷涂质量。
为了实现上述技术方案，本发明采用以下技术方案：
一种低能耗塑料表面清洗剂，包含如下原料：烷基聚葡萄糖苷5-15份、氨基蔗糖酯5-12份、低泡异构醇嵌段聚醚6-10份、氨基三乙酸钠2-4份、无机碱1-5份、三乙醇胺2-4份、杀菌剂0.1-2份、疏水剂1-4份、抑泡剂2-5份、去离子水45-65份，以上份数均为重量份数。
优选的，所述烷基聚葡萄糖苷为APG0810、APG0814、APG1214、APG0816、APG1216、APG1618其中至少一种。
优选的，所述氨基蔗糖酯为AG1202。
优选的，所述低泡异构醇嵌段聚醚为L31、L35、L38、L44、L64、L68其中至少一种。
优选的，所述无机碱为碳酸钠、碳酸氢钠、氢氧化钾、氢氧化钠其中至少一种。
优选的，所述杀菌剂为芦荟提取物、爱菊提取物、脱氢乙酸钠、季铵盐、吡啶硫酮钠、异噻唑啉酮其中至少一种。
优选的，所述疏水剂为脂肪酸皂、聚烯烃、氟碳聚合物其中至少一种。
优选的，所述抑泡剂为聚醚、聚酰胺、高碳醇其中至少一种。
更进一步说明，其制备方法包括：按比例向水中加入烷基聚葡萄糖苷、氨基蔗糖酯、低泡异构醇嵌段聚醚搅拌混合均匀后升温到80℃，常压搅拌120分钟后降温到40℃，依次加入去离子水、氨基三乙酸钠、无机碱、三乙醇胺、杀菌剂、疏水剂、抑泡剂继续搅拌30分钟即得。
有益效果：
本发明一种低能耗塑料表面清洗剂原料在80℃条件下产生协同作用，在清洗过程中发挥明显的乳化渗透能力，同时随着剩余原料的依次加入有具有了优异的常温螯合、疏水、抑泡、杀菌能力，在1：50的稀释比例下可提供大于99.9％的净洗效率，在特定的温度压力下反应一段时间产生协同作用，对塑料工件加工过程中的脱模剂、润滑脂、胶质、灰尘等具有明显的乳化渗透剥离效果，对塑料部件无腐蚀，清洗效果好，无刺激性气味，不含铬酸盐、亚硝酸盐、磷酸盐，对环境友好。常温喷淋清洗，具有低能耗、大容量、长寿命等特点。
具体实施方式
下面通过具体实施方式，对本发明实施例中的技术方案进行清楚完整的描述，所描述的实施例仅仅是本发明一部分实施例，而不是全部实施例。
实施例1
本发明实施例中，一种低能耗塑料表面清洗剂，按重量份原料包含烷基聚葡萄糖苷APG0810共12份、氨基蔗糖酯6份、低泡异构醇嵌段聚醚L44共4份、L68共4份、氨基三乙酸钠2份、碳酸氢钠2份、三乙醇胺2份、芦荟提取物0.2份、脂肪酸皂1份、聚醚3份、去离子水63.8份，将烷基聚葡萄糖苷、氨基蔗糖酯、低泡异构醇嵌段聚醚搅拌混合均匀后升温到90℃，常压搅拌100分钟后降温到50℃，依次加入去离子水、氨基三乙酸钠、碳酸氢钠、三乙醇胺、芦荟提取物、脂肪酸皂、聚醚继续搅拌40分钟，即得。
实施例2
本发明实施例中，一种低能耗塑料表面清洗剂，按重量份原料包含烷基聚葡萄糖苷APG0810共6份、APG1214共8份、氨基蔗糖酯8份、低泡异构醇嵌段聚醚L31共4份、L44共2份、L64共4份、氨基三乙酸钠3份、碳酸氢钠4份、三乙醇胺4份、异噻唑啉酮0.3份、氟碳聚合物2份、高碳醇4份、去离子水50.7份，将烷基聚葡萄糖苷、氨基蔗糖酯、低泡异构醇嵌段聚醚搅拌混合均匀后升温到80℃，常压搅拌120分钟后降温到40℃，依次加入去离子水、氨基三乙酸钠、碳酸氢钠、三乙醇胺、异噻唑啉酮、氟碳聚合物、高碳醇继续搅拌30分钟，即得。
实施例3
本发明实施例中，一种低能耗塑料表面清洗剂，按重量份原料包含烷基聚葡萄糖苷APG0810共4份、APG0816共6份、氨基蔗糖酯6份、低泡异构醇嵌段聚醚L31共2份、L44共3份、L64共4份、氨基三乙酸钠3份、碳酸钠4份、三乙醇胺4份、季铵盐0.5份、聚烯烃2份、聚酰胺4份、去离子水57.5份，将烷基聚葡萄糖苷、氨基蔗糖酯、低泡异构醇嵌段聚醚搅拌混合均匀后升温到70℃，常压搅拌80分钟后降温到45℃，依次加入去离子水、氨基三乙酸钠、碳酸钠、三乙醇胺、季铵盐、聚烯烃、聚酰胺继续搅拌30分钟，即得。
实施例4
本发明实施例中，一种低能耗塑料表面清洗剂，按重量份原料包含烷基聚葡萄糖苷APG0810共6份、APG1216共8份、氨基蔗糖酯8份、低泡异构醇嵌段聚醚L35共2份、L38共4份、L64共4份、氨基三乙酸钠4份、碳酸钠3份、三乙醇胺4份、脱氢乙酸钠1份、氟碳聚合物2份、高碳醇4份、去离子水50份。将烷基聚葡萄糖苷、氨基蔗糖酯、低泡异构醇嵌段聚醚搅拌混合均匀后升温到70℃，常压搅拌80分钟后降温到45℃，依次加入去离子水、氨基三乙酸钠、碳酸钠、三乙醇胺、、脱氢乙酸钠、氟碳聚合物、高碳醇继续搅拌30分钟，即得。
应用实例
本发明应用实例中，一种低能耗塑料表面清洗剂，稀释比例1：50，先向清洗槽中加入1000kg水，再向清洗槽中投入本品50kg，测定混合液的PH值和电导率，不同的稀释比例PH值和电导率参考表一。
| <u>PH值</u> | <u>8.0</u> | <u>8.5</u> | <u>9.0</u> | <u>9.5</u> |
| <u>稀释比例</u> | <u>1：50</u> | <u>1：35</u> | <u>1：20</u> | <u>原液</u> |
| <u>电导(us/cm)</u> | <u>605</u> | <u>642</u> | <u>684</u> | <u>8160</u> |
表一、不同浓度电导和PH值对应关系
脱脂处理工艺条件：
喷淋清洗时间：2～10分钟；清洗剂在低温下(≥18℃)依然具有优异的净洗力。
Claims (8)
1.一种低能耗塑料表面清洗剂，其特征在于，包括如下原料：烷基聚葡萄糖苷5-15份、氨基蔗糖酯5-12份、低泡异构醇嵌段聚醚6-10份、氨基三乙酸钠2-4份、无机碱1-5份、三乙醇胺2-4份、杀菌剂0.1-2份、疏水剂1-4份、抑泡剂2-5份、去离子水45-65份，以上份数均为重量份数。
2.根据权利要求1所述的一种低能耗塑料表面清洗剂，其特征在于，其特征在于，所述烷基聚葡萄糖苷包含APG0810、APG0814、APG1214、APG0816、APG1216、APG1618其中至少一种。
3.根据权利要求1所述的一种低能耗塑料表面清洗剂，其特征在于，所述氨基蔗糖酯为AG1202。
4.根据权利要求1所述的一种低能耗塑料表面清洗剂，其特征在于，所述低泡异构醇嵌段聚醚包含L31、L35、L38、L44、L64、L68其中至少一种。
5.根据权利要求1所述的一种低能耗塑料表面清洗剂，其特征在于，所述无机碱包含碳酸钠、碳酸氢钠、氢氧化钾、氢氧化钠其中至少一种。
6.根据权利要求1所述的一种低能耗塑料表面清洗剂，其特征在于，所述杀菌剂包含芦荟提取物、爱菊提取物、脱氢乙酸钠、季铵盐、吡啶硫酮钠、异噻唑啉酮其中至少一种。
7.根据权利要求1所述的一种低能耗塑料表面清洗剂，其特征在于，所述疏水剂包含脂肪酸皂、聚烯烃、氟碳聚合物其中至少一种。
8.根据权利要求1所述的一种低能耗塑料表面清洗剂，其特征在于，所述抑泡剂包含聚醚、聚酰胺、高碳醇其中至少一种。
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