CN115362187B - 使用过渡金属双(酚盐)催化剂络合物获得的聚乙烯组合物及生产该聚乙烯组合物的均相方法 - Google Patents

使用过渡金属双(酚盐)催化剂络合物获得的聚乙烯组合物及生产该聚乙烯组合物的均相方法 Download PDF

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CN115362187B
CN115362187B CN202080098844.8A CN202080098844A CN115362187B CN 115362187 B CN115362187 B CN 115362187B CN 202080098844 A CN202080098844 A CN 202080098844A CN 115362187 B CN115362187 B CN 115362187B
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substituted
ethylene
tetrakis
heteroatom
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CN115362187A (zh
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江培军
J·A·M·卡尼奇
J·R·哈格多恩
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ExxonMobil Chemical Patents Inc
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    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
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    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F210/06—Propene
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    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17—Viscosity
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    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/39—Tensile storage modulus E'; Shear storage modulus G'; Tensile loss modulus E''; Shear loss modulus G''; Tensile complex modulus E*; Shear complex modulus G*
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
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  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN202080098844.8A 2020-02-11 2020-08-11 使用过渡金属双(酚盐)催化剂络合物获得的聚乙烯组合物及生产该聚乙烯组合物的均相方法 Active CN115362187B (zh)

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US202062972936P 2020-02-11 2020-02-11
US62/972,936 2020-02-11
PCT/US2020/045823 WO2021162748A1 (en) 2020-02-11 2020-08-11 Polyethylene compositions obtained using transition metal bis(phenolate) catalyst complexes and homogeneous process for production thereof

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Families Citing this family (9)

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Publication number Priority date Publication date Assignee Title
KR20220139378A (ko) * 2020-02-11 2022-10-14 엑손모빌 케미칼 패턴츠 인코포레이티드 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 프로필렌 공중합체 및 그의 균질한 제조 방법
US20250043034A1 (en) 2021-12-17 2025-02-06 ExxonMobil Technology and Engineering Company Processes for Making Polyolefins with Composition Control
EP4519332A1 (en) * 2022-05-04 2025-03-12 ExxonMobil Chemical Patents Inc. Substituted pyridine-2,6-bis (phenylenephenolate) complexes with enhanced solubility that are useful as catalyst components for olefin polymerization
JP2025515175A (ja) * 2022-05-04 2025-05-13 エクソンモービル ケミカル パテンツ インコーポレイテッド オレフィン重合のための触媒構成成分として有用な、溶解度の増大した修飾ピリジン－２，６－ビス（フェニレンフェノラート）錯体
KR20250049337A (ko) 2022-08-09 2025-04-11 엑손모빌 케미칼 패턴츠 인코포레이티드 디페닐실란 가교 c1 대칭 촉매의 제조 방법 및 이로부터 제조된 중합체
CN120303312A (zh) 2022-09-28 2025-07-11 埃克森美孚化学专利公司 用于光伏电池的乙烯共聚物
CN120981495A (zh) * 2023-02-08 2025-11-18 埃克森美孚技术与工程公司 用于共聚的催化剂
KR20260015988A (ko) * 2023-06-06 2026-02-03 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 용액 촉매계 및 이의 용도
KR20260042594A (ko) 2023-08-07 2026-03-31 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 에틸렌 코폴리머 조성물 및 이로 제조된 물품

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180022137A (ko) * 2016-08-23 2018-03-06 주식회사 엘지화학 신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3994015B2 (ja) * 2001-02-21 2007-10-17 三井化学株式会社 オレフィン重合用触媒およびこの触媒を用いるオレフィン重合体の製造方法
KR100844062B1 (ko) * 2001-02-21 2008-07-07 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매 및 이 촉매를 사용하는 올레핀중합체의 제조방법
US6897276B2 (en) * 2002-04-24 2005-05-24 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
WO2008036882A1 (en) * 2006-09-21 2008-03-27 California Institute Of Technology Non-metallocene organometallic complexes and related methods and systems
WO2015009474A1 (en) * 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Ethylene-propylene copolymeric compositions with long methylene sequence lengths
US9394387B2 (en) * 2014-05-15 2016-07-19 Chevron Phillips Chemical Company Lp Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports
WO2016153682A1 (en) * 2015-03-24 2016-09-29 Exxonmobil Chemical Patents Inc. Bisphenolate transition metal complexes, production and use thereof
EP3529287A1 (en) * 2016-10-19 2019-08-28 ExxonMobil Chemical Patents Inc. Mixed catalyst systems and methods of using the same
US11248070B2 (en) * 2019-02-12 2022-02-15 Exxonmobil Chemical Patents Inc. Lewis base catalysts and methods thereof
US11203654B2 (en) * 2019-02-12 2021-12-21 Exxonmobil Chemical Patents Inc. Bis(aryl phenolate) lewis base catalysts and methods thereof
US11214634B2 (en) * 2019-02-12 2022-01-04 Exxonmobil Chemical Patents Inc. Lewis base catalysts and methods thereof
SG11202108010RA (en) * 2019-02-12 2021-08-30 Exxonmobil Chemical Patents Inc Lewis base catalysts and methods thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180022137A (ko) * 2016-08-23 2018-03-06 주식회사 엘지화학 신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물

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CA3167579A1 (en) 2021-08-19
KR20220152225A (ko) 2022-11-15
WO2021162748A1 (en) 2021-08-19
KR102912885B1 (ko) 2026-01-14
CN115362187A (zh) 2022-11-18
US20230287156A1 (en) 2023-09-14
JP2023513581A (ja) 2023-03-31
JP7757293B2 (ja) 2025-10-21
EP4103629A4 (en) 2024-06-05

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