CN115321945A - Manufacturing method of purple sand product with water quality optimization effect - Google Patents
Manufacturing method of purple sand product with water quality optimization effect Download PDFInfo
- Publication number
- CN115321945A CN115321945A CN202210966949.1A CN202210966949A CN115321945A CN 115321945 A CN115321945 A CN 115321945A CN 202210966949 A CN202210966949 A CN 202210966949A CN 115321945 A CN115321945 A CN 115321945A
- Authority
- CN
- China
- Prior art keywords
- purple sand
- water quality
- firing
- tourmaline
- organic framework
- Prior art date
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- Pending
Links
- 239000004576 sand Substances 0.000 title claims abstract description 81
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 64
- 230000000694 effects Effects 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 19
- 238000005457 optimization Methods 0.000 title claims abstract description 19
- 239000013310 covalent-organic framework Substances 0.000 claims abstract description 45
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 45
- 239000011032 tourmaline Substances 0.000 claims abstract description 45
- 229940070527 tourmaline Drugs 0.000 claims abstract description 45
- 239000004575 stone Substances 0.000 claims abstract description 37
- 239000000463 material Substances 0.000 claims abstract description 25
- 238000002360 preparation method Methods 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 90
- 238000010304 firing Methods 0.000 claims description 26
- 239000000843 powder Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 15
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- 231100000252 nontoxic Toxicity 0.000 abstract description 6
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- 239000000047 product Substances 0.000 description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 16
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- 229910052500 inorganic mineral Inorganic materials 0.000 description 10
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- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 6
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
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- LVPYYSKDNVAARK-UHFFFAOYSA-N 4-n-[4-(4-amino-n-(4-aminophenyl)anilino)phenyl]-4-n-(4-aminophenyl)benzene-1,4-diamine Chemical compound C1=CC(N)=CC=C1N(C=1C=CC(=CC=1)N(C=1C=CC(N)=CC=1)C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 LVPYYSKDNVAARK-UHFFFAOYSA-N 0.000 description 2
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
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- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
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- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
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- 238000007670 refining Methods 0.000 description 2
- 229910052604 silicate mineral Inorganic materials 0.000 description 2
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- 239000010703 silicon Substances 0.000 description 2
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- 235000013619 trace mineral Nutrition 0.000 description 2
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- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- RNHDAKUGFHSZEV-UHFFFAOYSA-N 1,4-dioxane;hydrate Chemical compound O.C1COCCO1 RNHDAKUGFHSZEV-UHFFFAOYSA-N 0.000 description 1
- YXCKIFUUJXNFIW-UHFFFAOYSA-N 5-[4-(1,3-dioxo-2-benzofuran-5-yl)phenyl]-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(C2=CC=C(C=C2)C=2C=C3C(=O)OC(C3=CC=2)=O)=C1 YXCKIFUUJXNFIW-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 240000006350 Callirhoe involucrata Species 0.000 description 1
- 235000002259 Callirhoe involucrata Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 235000005087 Malus prunifolia Nutrition 0.000 description 1
- 244000070406 Malus silvestris Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
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- 238000000944 Soxhlet extraction Methods 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
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- 239000012670 alkaline solution Substances 0.000 description 1
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
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- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
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- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
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- 239000010941 cobalt Substances 0.000 description 1
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- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
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- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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- 229910052863 mullite Inorganic materials 0.000 description 1
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- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
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- 238000000746 purification Methods 0.000 description 1
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- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 150000003384 small molecules Chemical group 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229910000231 tourmaline group Inorganic materials 0.000 description 1
- SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/48—Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physical Water Treatments (AREA)
- Non-Alcoholic Beverages (AREA)
Abstract
The invention provides a method for manufacturing a purple sand product with a water quality optimization effect. The tourmaline, medical stone and purple sand product provided by the invention can optimize water quality by drinking water from the tourmaline, medical stone and purple sand tea set, has better taste and is beneficial to human body; in addition, the C-COF has a certain adsorption effect on bacteria, heavy metals and other pollutants, and the adsorption capacity, selectivity, removal efficiency and the like of the C-COF are remarkably improved compared with those of the traditional material. In addition, the COFs material has the advantages of water stability, reproducibility, reusability, large-scale preparation and the like, the C-COF is non-toxic and pollution-free, and the additive is used for the additive of the dark-red enameled pottery and can further improve the water quality optimization effect of the dark-red enameled pottery. The tourmaline, medical stone and purple sand product provided by the invention can be various daily necessities, and is worth further popularization and use.
Description
Technical Field
The invention relates to a method for manufacturing a purple sand product with a water quality optimization effect, and belongs to the technical field of manufacturing of purple sand kettles.
Background
The tea set is an indispensable daily article for Chinese people, and is made of glass, ceramics, metal and the like according to materials, and the purple clay teapot is popular with people due to the characteristics of 'all colors and fragrances of tea are contained' and 'the tea is not spoiled at night in summer and night'.
The raw materials for manufacturing the dark-red enameled pottery are purple clay which is originally produced in Jiangsu Wuxi Yixing Ding Shu town and is also named Yixing dark-red enameled pottery. The pottery clay used for making Yixing purple clay is an iron-containing clayey siltstone, which is composed of hydromica, kaolin, quartz, mica chips, iron and other mineral components, and the main chemical components comprise silicon oxide, aluminum oxide, iron oxide, calcium oxide, magnesium oxide, manganese oxide, potassium oxide, sodium oxide and the like. The raw materials fired by the dark-red enameled pottery are soil, and the soil of the dark-red enameled pottery is divided into three types: purple mud, green mud and red mud. Because the amount of iron and silicon is high, the red-purple clay is often purple red after being fired, so the red-purple clay is called as 'purple clay'. The purple clay is an extremely thick raw material which is suitable for being used, and has reasonable chemical composition, mineral composition and particle composition, so that the purple clay has the process advantages of good plasticity, high green strength, small drying shrinkage and the like, and provides good process conditions for various shapes. The purple sand mud forms phases of residual quartz, mica remains, mullite, hematite, double pores and the like after being sintered, and has more crystalline phases and less glass phases, so that the purple sand product has thermal shock resistance, air permeability and higher mechanical strength and has excellent practical functions. The Chinese Yixing purple sand is a treasure of world, and has unique air permeability and plasticity. The tea set made of purple sand has the characteristics of capability of repeatedly brewing by boiled water and cold water without embrittlement, difficult spoiling of tea leaves and the like, and is the best tea set recognized all over the world.
Tourmaline is the general term of tourmaline group minerals, has complex chemical components, and is a silicate mineral with a ring structure of aluminum, sodium, iron, magnesium and lithium characterized by containing boron. The tourmaline has unique properties of piezoelectricity, pyroelectric property, conductivity, far infrared radiation, anion release and the like, can be compounded with other materials by a physical or chemical method to prepare a plurality of functional materials, and is applied to the fields of environmental protection, electronics, medicines, chemical industry, light industry, building materials and the like. The tourmaline is a mineral with electrical property in mineral products, and the micro tourmaline has a positive electrode and a negative electrode. When the external environment changes, such as light irradiation, temperature change, contact with water, and the like, the electrical performance of the composite material is particularly outstanding. The tourmaline has the main functions as follows: (1) Releasing negative ions, regulating ion balance of human body, relaxing body and mind, activating cells, improving natural healing force, and inhibiting oxidation or aging of body; (2) electrolyzing water: the tourmaline can generate weak current when contacting with water, and generate electric decomposition effect on water, so that the water becomes alkalescent (pH value is about 7.4) negative ion water which has better taste and is more beneficial to human health; (3) changing the large molecular groups of the water into small molecular groups: molecules in water do not exist independently, but are combined with each other to form water molecule groups, the water molecule groups in tap water contain about 13 water molecules, the water molecule groups in pure water contain about 10 water molecules, and the water molecule groups treated by tourmaline contain 6-7 water molecules, so that small molecule group water is generally more beneficial to human bodies, and is called as 'energy water' in Japan; (4) emitting far infrared rays: the far infrared rays can permeate deep parts of the body, warm cells, promote blood circulation and smooth metabolism, and the far infrared ray radiation power of the tourmaline is close to 100 percent, which is higher than that of other minerals; (5) contains a plurality of trace elements: tourmaline contains various natural minerals, many of which are the same as those essential to human, and is an excellent source of minerals because of the action of weak current, which are easily absorbed. The functions of the tourmaline are not independent, but can play a composite role to generate various effects.
The medical stone is a natural ore, is a natural silicate mineral and is non-toxic. The medical stone is a compound mineral or medicinal rock which is nontoxic and harmless to organisms and has certain bioactivity. The main chemical component of medical stone is inorganic aluminosilicate. Maifanitum has adsorption, solubility, regulation, bioactivity, and mineralization effects. China has abundant medical stone resources, and is widely applied due to the strong adsorption force and the water purification effect.
The addition of tourmaline and medical stone into the purple sand mud becomes a new direction in the technical field of purple sand product preparation, and the addition of tourmaline and medical stone makes the purple sand product have the practicability and the process aesthetics of the traditional Yixing purple sand pottery and also have the health-care function of tourmaline and medical stone. However, the use of these two additives is far from sufficient and cannot meet the existing consumption trend. Consumers also put forward more requirements on the dark-red enameled pottery, such as adsorbability, water stability, reusability and the like, thereby achieving the effect of optimizing water quality.
The invention aims to provide a method for manufacturing a purple sand product with a water quality optimization effect.
Disclosure of Invention
Aiming at the defects in the prior art, the technical problem to be solved by the invention is to provide a manufacturing method of a purple sand product with a water quality optimization effect, tea aroma is not lost and cooked soup gas is not generated, tea gas is adsorbed on the kettle wall, tea aroma is generated when boiling water is injected into an empty kettle after long-term use, a certain adsorption effect on bacteria, heavy metals and other pollutants is achieved, the adsorption capacity, selectivity, removal efficiency and the like of the purple sand product are remarkably improved compared with those of traditional materials, and the water quality optimization requirement of consumers on the purple sand product is met.
In order to solve the technical problems, the invention is realized by the following technical scheme:
a manufacturing method of a purple sand product with a water quality optimization effect comprises the following steps:
s1, pretreatment of raw materials: pretreating raw purple sand mud, and simultaneously crushing tourmaline and medical stone;
s2, mixing raw materials: uniformly mixing the pretreated purple sand mud, tourmaline, medical stone and a carbonized graded hole covalent organic framework material (C-COF) to obtain a purple sand mud mixture;
s3, blank making: preparing the purple sand mud mixture obtained in the step S2 into required ware blanks in a manual or mechanical mode, and drying the ware blanks in the shade;
s4, firing of purple sand products: drying the ware blank in the shade, loading the ware blank into a sagger, and firing the ware blank by using a traditional dragon kiln or an electric kiln;
s5, post-processing: after the kiln is opened and the device is taken out, the fired purple sand product is cleaned and finished, and polished and waxed.
The raw material mixture in the step S2 is composed of the following raw materials in percentage by weight:
0.1% -1.5% of carbonized graded-hole covalent organic framework material;
0.1 to 15 percent of tourmaline;
20 to 50 percent of medical stone;
the balance is Yixing purple sand.
On the basis of and as a preferred solution to the above solution, the preparation of the carbonized hierarchical porous covalent organic frameworks (C-COF) comprises the preparation of Covalent Organic Frameworks (COFs) and the carbonization of the material.
In addition to and as a preferred embodiment of the above solution, the covalent organic framework is prepared with spherical Silica (SiO) 2 ) Preparing a hierarchical porous covalent organic framework by taking the nano particles as a sacrificial template, comprising the preparation of spherical silicon dioxide nano particles → composite materials (SiO) 2 @ COFs) preparation → preparation of hierarchical pore covalent organic frameworks → preparation and collection of carbonized hierarchical pore covalent organic frameworks.
On the basis of the scheme, the carbonization of the material is the carbonization of the hierarchical porous covalent organic framework, specifically, the hierarchical porous covalent organic framework powder is placed in a porcelain boat and then transferred to a furnace tube of a tube furnace, and the nitrogen flow is 200 mL-min -1 Heating to 800-1000 ℃ at the speed of 10 ℃ per minute, and then keeping the temperature of 800-1000 ℃ for 5-6h; and taking out the sample after cooling, cooling the sample to room temperature (18-25 ℃) to obtain the carbonized graded-hole covalent organic framework material.
On the basis of the above scheme and as a preferable scheme of the above scheme, the purple sand mud pretreatment in step S1 comprises: open-air tedding and weathering → primary crushing, crushing → air supply and screening → stirring to form mud → piling and ageing → vacuum pugging.
On the basis of the scheme and as a preferable scheme of the scheme, the fineness of the tourmaline particles crushed in the step S1 is 50-20000 meshes, and the fineness of the medical stone particles crushed is 50-20000 meshes.
In addition to and as a preferred embodiment of the above embodiment, the firing of step S4 includes the following steps:
s401, feeding into a kiln, loading the ware blank into a sagger, and loading and fixing the ware blank through a kiln opening;
s402, firing, namely adding fuel from a firing hole, and firing at the temperature of 600-1700 ℃ for 5-48h; or directly setting the firing temperature and the firing time of the electric kiln;
s403, repeating the step S402 for one to three times;
and S404, opening the kiln and taking out the device, stopping for 15-24 hours after firing, and opening the kiln and taking out the device.
On the basis of the above scheme and as a preferable scheme of the above scheme, the firing temperature is 600-1200 ℃, and the firing time is 10-24h.
The purple clay mud disclosed by the invention is generally divided into purple clay, green clay and red clay, which are commonly called as 'Fugui soil'. The purple sand mud which can be used for firing the purple sand teapot is generally hidden under the rock layer and distributed among mud layers of the first sand mud, and the thickness of the mud layers is different from dozens of centimeters to one meter. According to the analysis of the relevant lithofacies of Shanghai silicate research, the purple sand yellow mud belongs to the kaolin-quartz-mica type, the iron content is very high, and the highest iron content reaches 8.83 percent. Preferably, the purple sand mud of the invention is selected from Yixing purple sand mud produced in Jiangsu.
Compared with the prior art, the technical scheme of the invention has the following beneficial effects:
the tourmaline, medical stone and purple sand product provided by the invention can optimize water quality by drinking water from the tourmaline, medical stone and purple sand tea set, has better taste and is beneficial to human body; in addition, the C-COF has a certain adsorption effect on bacteria, heavy metals and other pollutants, and the adsorption capacity, selectivity, removal efficiency and the like of the C-COF are remarkably improved compared with those of the traditional material. In addition, the COFs material has the advantages of water stability, reproducibility, reusability, large-scale preparation and the like, the C-COF is non-toxic and pollution-free, and the additive is used for the additive of the dark-red enameled pottery and can further improve the water quality optimization effect of the dark-red enameled pottery. The tourmaline, medical stone and purple sand product provided by the invention can be various daily necessities, and is worth further popularization and use.
It should be understood that all combinations of the foregoing concepts and additional concepts described in greater detail below can be considered as part of the subject disclosure unless such concepts are mutually inconsistent.
The foregoing and other aspects, embodiments and features of the present teachings will be more fully understood from the following description. Additional aspects of the present invention, such as features and/or advantages of exemplary embodiments, will be apparent from the description which follows, or may be learned by practice of specific embodiments in accordance with the teachings of the present invention.
Drawings
FIG. 1 is a process flow diagram of the present invention;
FIG. 2 is a flow chart of the preparation of a hierarchical pore COF of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the described embodiments of the invention without any inventive step, are within the scope of protection of the invention. Unless defined otherwise, technical or scientific terms used herein shall have the ordinary meaning as understood by one of ordinary skill in the art to which this invention belongs.
The use of "first," "second," and similar terms in the description and claims of the present application do not denote any order, quantity, or importance, but rather the terms are used to distinguish one element from another. Similarly, the singular forms "a," "an," or "the" do not denote a limitation of quantity, but rather denote the presence of at least one, unless the context clearly dictates otherwise. The terms "comprises," "comprising," or the like, mean that the elements or items listed before "comprises" or "comprising" encompass the features, integers, steps, operations, elements, and/or components listed after "comprising" or "comprising," and do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof. "upper", "lower", "left", "right", and the like are used only to indicate relative positional relationships, and when the absolute position of the object to be described is changed, the relative positional relationships may also be changed accordingly.
Purple mud extracted from an ore bed is commonly called raw mud. The block-like rock is loosened by open air tedding and weathering, and then is primarily crushed and crushed, and is subjected to air supply and screening according to the number of particles required by the product. The screened mud ash is stirred into a lump of jing mud by a stirrer, and is piled up and aged, and the rotten mud is vacuumized to be pugged, so that the mud becomes cooked mud for blank making, and the step of pretreating the red porcelain raw mud is completed. In the process of refining and preparing the purple sand mud, the water quality of the used water is very exquisite. The quality of the water quality can directly affect the quality of the product. The red porcelain clay has good plasticity, high green strength and small drying and firing shrinkage of the green body. Ceramic technologists mix several pugs in different proportions, sometimes neutralize the pugs with coarse silt or steel sand, which is more attractive. Dark-red enameled pottery is not always purple, presents various wonderful colors after being fired at high temperature, and comprises cinnabar red, date red, red copper, crabapple red, iron gray lead, sunflower, dark green, blue and the like. The dark-red enameled pottery is not coated with uranium. The baked dark-red enameled pottery has ideal heat insulation and air permeability and is an ideal appliance for making tea.
The Covalent Organic Framework (COF) has excellent stability and unique structural design, so that the hierarchical pore COFs have great application prospects in many fields. As a porous material, the COFs have a certain adsorption effect on bacteria, heavy metals and other pollutants, and the adsorption capacity, selectivity, removal efficiency and the like of the COFs are remarkably improved compared with those of the traditional material. In addition, COFs also have important characteristics such as water stability, recyclability, reusability, and mass production. The carbonized COFs material (C-COF) is non-toxic and pollution-free, and is used as an additive of the dark-red enameled pottery, so that the dark-red enameled pottery has a water quality optimization effect. The preparation process of the carbonized hierarchical pore covalent organic framework material (C-COF) comprises the following steps:
first step, siO 2 Preparation of nanoparticles
2.0mL of tetraethoxysilane was dissolved in 50mL of anhydrous ethanol, stirred on a magnetic stirrer, and then 1.4mLH was added dropwise 2 O and 2.0mLNH 3 ·H 2 And O, mixing the solution. After reacting for 15-20 hours at 40-50 ℃, the solution turns into milky turbid state. Then centrifugally separating, alternately washing with water and 95% ethanol, and vacuum drying at 60-80 deg.C for 3-5h to obtain white spherical SiO 2 NPs。
Second step, composite Material (SiO) 2 @ COFs) preparation
SiO2@ COFs are prepared based on a mild mechanochemical synthesis: first, p-toluenesulfonic acid (PTSA, 317.6-637.1mg,1.67-3.35 mmol) and N, N, N ', N' -tetrakis (4-aminophenyl) -1,4-phenylenediamine (TPDA, 71.0-142.0mg,0.15-3.0 mmol) were ground thoroughly in a mortar for 15-20 minutes. In the present invention, 317.6mg and 1.67mmol of p-toluenesulfonic acid and 71.0mg and 0.15mmol of N, N' -tetrakis (4-aminophenyl) -1,4-phenylenediamine are preferably used. Then 700.0-900mg of prepared SiO is added 2 NPs serve as hard templates. The mixture was milled for an additional 15-20 minutes to form a uniform gray powder. Then, 64.3mg, 0.30mmol [1,1' -biphenyl ] were added]4,4' -dicarboxaldehyde, further ground for 18-20 minutes until the color changes from gray to black, forming uniform SiO 2 @ COFs amorphous precursor. Then 70. Mu.L of water was dispersed and added to the mixed solution, and the mixture was ground uniformly and stirred for 10-15 minutes, and the addition of water produced a clear color change from off-white to purple. Finally, the mixture was transferred to an autoclave and heated at 120-150 ℃ for 2-3 days to give a dark powder. After cooling the powder to room temperature, it was washed by soxhlet extraction with hot water and 1,4-dioxane to remove PTSA and residual monomers. Finally, the prepared SiO 2 The @ COFs composite material was dried at 60-80 ℃ for 3-5 hours under vacuum.
Third step, preparing a hierarchical pore COF
By reaction from SiO 2 Removal of SiO in @ COFs 2 NPs obtained HCOFs. SiO2 2 NPs are susceptible to alkaline solutions (pH)>8.5 Dissolving in waterAnd (5) solving. In preparing hierarchical pore COF, siO 2 @ COFs was dispersed in 30mL of 1M NaOH solution, sonicated for 5min, and the above steps repeated 4-6 times. Finally, the collected solid was washed to neutrality with water and dried at 60-80 ℃ under vacuum for 5-6 hours to obtain a hierarchical pore COF. The process flow is shown in FIG. 2.
Step four, preparation of C-COF
The prepared graded-hole COF powder was placed in a porcelain boat and then transferred to a furnace tube of a tube furnace. Under nitrogen flow of 200 mL/min -1 Heating to 800-1000 ℃ at the speed of 10 ℃ per minute, and then keeping the temperature at 800-1000 ℃ for 5-6h; and taking out after cooling, cooling the sample to room temperature (18-25 ℃) to obtain the carbonized hierarchical porous covalent organic framework material (C-COF).
The present invention is preferably: heating was carried out to 900 ℃ at a rate of 10 ℃ per minute. Under the same conditions, the temperature is kept at 900 ℃ for 5-6h; taking out after cooling, and standing in a vacuum oven at 60-80 ℃ for 12-18 hours, wherein the operation yield is 65-70%. Then, the sample was cooled to room temperature (18-25 ℃ C.) to obtain C-COF.
Fifth step, C-COF post-treatment
CCOF powder was suspended in 100ml of distilled water, and the resulting mixture was sonicated in a sonication bath for 20 to 30 minutes and then left to stand for 20 to 24 hours. Removing supernatant, heating at 120-150 deg.C for precipitation for 20-24 hr, and collecting product to obtain pure C-COF.
Furthermore, the fineness of tourmaline powder and medical stone powder is preferably 1000 meshes. Mixing tourmaline powder, medical stone powder, C-COF and purple sand mud.
Further, the purple sand product is fired according to the process flow shown in fig. 1.
The present invention is described in further detail below with reference to examples. The examples are as follows:
example 1
Mixing 3 g of C-COF,45 g of 600-mesh tourmaline powder, 350 g of 1000-mesh medical stone powder and 455 g of high-quality pre-treated purple sand mud, manually refining the mixture into a purple sand teapot mold blank according to the traditional process, drying in the shade, placing the purple sand teapot mold blank in a temperature-controlled electric kiln, firing at 1150 ℃ for 12 hours, discharging the purple sand teapot mold blank out of the kiln, and firing at 800 ℃ for 10 hours to prepare the tourmaline medical stone purple sand teapot.
Example 2:
1 g of C-COF,10 g of 1000-mesh tourmaline powder, 30 g of medical stone powder and 50 g of high-quality pre-treated purple sand mud are mixed, manually refined into a purple sand teacup mold blank according to the traditional process, dried in the shade, placed in a temperature-controlled electric furnace, baked at 900 ℃ for 16 hours, taken out of a kiln and trimmed, and then baked at 600 ℃ for 10 hours to prepare the tourmaline medical stone purple sand teacup.
Example 3:
2 g of C-COF,20 g of 500-mesh tourmaline powder, 185 g of 300-mesh medical stone powder and 200 g of high-quality pre-treated first-class purple sand mud are mixed, manually refined into a purple sand wine pot and a wine cup mold blank according to the traditional process, dried in the shade, placed in a temperature-controlled electric furnace, fired at 800 ℃ for 20 hours, taken out of the furnace and finished, and then fired at 800 ℃ for 10 hours to prepare the tourmaline medical stone purple sand wine set.
Example 4:
4 g of C-COF,40 g of 100-mesh tourmaline powder, 1000 g of 300-mesh medical stone powder and 3000 g of pre-treated purple sand mud are mixed to prepare a purple sand flowerpot mold blank in a mechanical blank making mode, and the purple sand flowerpot mold blank is placed in a temperature control electric furnace after being dried in the shade and is baked for 8 hours at 1150 ℃ to prepare the tourmaline medical stone purple sand flowerpot.
The tourmaline, medical stone and purple sand product provided by the invention has strong natural air permeability; the tourmaline has an electromagnetic field similar to that of a human body, not only keeps the characteristics of simplicity, elegance, beauty and practicability of the traditional purple sand product, but also has the health-care functions of releasing negative ions and far infrared rays of the tourmaline, enabling water to be ionized into alkaline negative ion water, enabling water molecular groups to be small and the like; the medical stone has the mineralization and health care functions, can dissolve out more than 20 mineral substances and trace elements which are beneficial to human bodies, such as potassium, sodium, calcium, magnesium, copper, zinc, iron, manganese, strontium, cobalt, phosphorus, silicon, sulfur, iodine, selenium and the like, accelerate the release of beneficial components in the tea and improve the water quality; as a porous material, the COFs have a certain adsorption effect on bacteria, heavy metals and other pollutants, and the adsorption capacity, selectivity, removal efficiency and the like of the COFs are remarkably improved compared with those of the traditional material. In addition, COFs also have important characteristics such as water stability, recyclability, reusability, and mass production. The carbonized C-COF is non-toxic and pollution-free, is used as an additive of the dark-red enameled pottery, and can further improve the effects of adsorbing heavy metal ions and optimizing water quality of the dark-red enameled pottery. The purple sand tea set using the tourmaline, the medical stone and the C-COF material can optimize water quality, has better taste and is beneficial to human body; the tourmaline medical stone purple sand teapot is used for making tea, so that the tea has more fragrant and elegant taste; the wine drinking by using the tourmaline, medical stone and purple sand wine set can make the wine taste more mellow and rich; the cigarette is put into a tourmaline purple sand appliance for storage, so that the taste of the cigarette is more smooth; the flowerpot and the fish tank made of the tourmaline, medical stone and purple sand can make flowers and plants grow more exuberantly, fishes and the like more active. The purple sand product provided by the invention can be various daily necessities, brings health and pleasure to the life of people, and is worthy of popularization and use.
The foregoing detailed description of the preferred embodiments of the invention has been presented. It should be understood that numerous modifications and variations could be devised by those skilled in the art in light of the present teachings without departing from the inventive concepts. Therefore, the technical solutions available to those skilled in the art through logic analysis, reasoning and limited experiments based on the prior art according to the concept of the present invention should be within the scope of protection defined by the claims.
Claims (8)
1. A manufacturing method of a purple sand product with a water quality optimization effect is characterized by comprising the following steps:
s1, pretreatment of raw materials: pretreating raw purple sand mud, and simultaneously crushing tourmaline and medical stone;
s2, mixing raw materials: uniformly mixing the pretreated purple sand mud, tourmaline, medical stone and carbonized graded hole covalent organic framework material to obtain a purple sand mud mixture;
s3, blank making: making the purple sand mud mixture obtained in the step S2 into a required ware blank in a manual or mechanical mode, and drying the ware blank in the shade;
s4, firing the purple sand product: drying the ware blank in the shade, loading the ware blank into a sagger, and firing the ware blank by using a traditional dragon kiln or an electric kiln;
s5, post-processing: after the kiln is opened and the device is taken out, the fired purple sand product is cleaned and finished, and polished and waxed.
The raw material mixture in the step S2 is composed of the following raw materials in percentage by weight:
0.1% -1.5% of carbonized graded-hole covalent organic framework material;
0.1 to 15 percent of tourmaline;
20 to 50 percent of medical stone;
the balance is Yixing purple sand.
2. The method for manufacturing a purple sand product with a water quality optimization effect according to claim 1, wherein the preparation of the carbonized graded pore covalent organic framework material comprises preparation of a covalent organic framework and carbonization of the material.
3. The method for manufacturing the purple sand product with the water quality optimization effect according to claim 2, wherein the preparation of the covalent organic framework adopts spherical silica nanoparticles as sacrificial templates to prepare the hierarchical pore covalent organic framework, and comprises the steps of preparation of the spherical silica nanoparticles → preparation of a composite material → preparation of the hierarchical pore covalent organic framework → preparation and collection of carbonized hierarchical pore covalent organic framework materials.
4. The method for manufacturing a purple sand product with a water quality optimization effect according to claim 2, wherein the material carbonization is the carbonization of a hierarchical pore covalent organic framework, specifically, hierarchical pore covalent organic framework powder is placed in a porcelain boat, then transferred to a furnace tube of a tube furnace, heated to 800-1000 ℃ at a nitrogen flow rate of 200mL min-1 and a speed of 10 ℃ per minute, and then kept at the temperature of 800-1000 ℃ for 5-6h; and taking out the sample after cooling, and cooling the sample to room temperature to obtain the carbonized graded-hole covalent organic framework material.
5. The manufacturing method of purple sand product with water quality optimization effect according to claim 1, wherein the pretreatment of purple sand mud in step S1 comprises the following steps: open-air tedding and weathering → primary crushing, crushing → air supply and screening → stirring to form mud → piling and ageing → vacuum pugging.
6. The method for manufacturing purple sand product with water quality optimization effect as claimed in claim 1, wherein the fineness of the tourmaline particles crushed in step S1 is 50 mesh-20000 mesh, and the fineness of the pulverized medical stone particles is 50 mesh-20000 mesh.
7. The method for manufacturing the purple sand product with the water quality optimization effect according to claim 1, wherein the firing in the step S4 comprises the following steps:
s401, feeding into a kiln, loading the ware blank into a sagger, and loading and fixing the ware blank through a kiln opening;
s402, firing, namely adding fuel from a firing hole, and firing at the temperature of 600-1700 ℃ for 5-48h; or directly setting the firing temperature and the firing time of the electric kiln;
s403, repeating the step S402 for one to three times;
and S404, opening the kiln and taking out the device, stopping for 15-24 hours after firing, and opening the kiln and taking out the device.
8. The method for manufacturing purple sand product with water quality optimization effect according to claim 7, wherein the firing temperature is 600-1200 ℃ and the firing time is 10-24h.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102786288A (en) * | 2012-07-26 | 2012-11-21 | 上海长洲盛锦文化传播有限公司 | Red porcelain product for removing pesticide residues and heavy metal in fruits and vegetables |
| CN105152628A (en) * | 2015-09-30 | 2015-12-16 | 上海长洲盛锦文化传播有限公司 | Mothproof ceramic product capable of preserving freshness and removing peculiar smells and preparation method |
| CN110590350A (en) * | 2019-09-20 | 2019-12-20 | 景德镇陶瓷大学 | Purple sand filtration water purification material with multifunctional health care function and manufacturing method thereof |
| CN111227586A (en) * | 2018-11-28 | 2020-06-05 | 陈水夫 | Health-preserving dark-red enameled pottery |
| CN111410511A (en) * | 2020-05-07 | 2020-07-14 | 江苏碧城紫砂科技有限公司 | Selenium-rich purple clay teapot pug and preparation method thereof |
-
2022
- 2022-08-11 CN CN202210966949.1A patent/CN115321945A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102786288A (en) * | 2012-07-26 | 2012-11-21 | 上海长洲盛锦文化传播有限公司 | Red porcelain product for removing pesticide residues and heavy metal in fruits and vegetables |
| CN105152628A (en) * | 2015-09-30 | 2015-12-16 | 上海长洲盛锦文化传播有限公司 | Mothproof ceramic product capable of preserving freshness and removing peculiar smells and preparation method |
| CN111227586A (en) * | 2018-11-28 | 2020-06-05 | 陈水夫 | Health-preserving dark-red enameled pottery |
| CN110590350A (en) * | 2019-09-20 | 2019-12-20 | 景德镇陶瓷大学 | Purple sand filtration water purification material with multifunctional health care function and manufacturing method thereof |
| CN111410511A (en) * | 2020-05-07 | 2020-07-14 | 江苏碧城紫砂科技有限公司 | Selenium-rich purple clay teapot pug and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| WEI LI ET AL.: "SiO2 templates-derived hierarchical porous COFs sample pretreatment tool for non-targeted analysis of chemicals in foods", 《JOURNAL OF HAZARDOUS MATERIALS》 * |
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Application publication date: 20221111 |