CN115233456A - Coating for finishing fiber fabric and using method thereof - Google Patents

Coating for finishing fiber fabric and using method thereof Download PDF

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Publication number
CN115233456A
CN115233456A CN202211113798.1A CN202211113798A CN115233456A CN 115233456 A CN115233456 A CN 115233456A CN 202211113798 A CN202211113798 A CN 202211113798A CN 115233456 A CN115233456 A CN 115233456A
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CN
China
Prior art keywords
fiber fabric
parts
coating
finishing
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202211113798.1A
Other languages
Chinese (zh)
Inventor
谢佐鹏
朱克俭
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wenling Electric Power Insulation Equipment Co ltd
Zhejiang Taiside Electric Co ltd
Original Assignee
Wenling Electric Power Insulation Equipment Co ltd
Zhejiang Taiside Electric Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wenling Electric Power Insulation Equipment Co ltd, Zhejiang Taiside Electric Co ltd filed Critical Wenling Electric Power Insulation Equipment Co ltd
Priority to CN202211113798.1A priority Critical patent/CN115233456A/en
Priority to PCT/CN2022/119833 priority patent/WO2024055341A1/en
Publication of CN115233456A publication Critical patent/CN115233456A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10Repellency against liquids
    • D06M2200/12Hydrophobic properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention belongs to the field of fabric coatings, and discloses a coating for finishing fiber fabrics, which comprises the following components in parts by mass: 80-120 parts of water; 7-11 parts of a waterproof agent; 8-15 parts of a silicone rubber emulsion; 1-3 parts of titanate coupling agent; 4-6 parts of nano titanium dioxide. Also disclosed is a method of use comprising the steps of: step 1: fully washing the fiber fabric to be treated, and drying the washed fiber; and 2, step: immersing a fiber fabric into the fiber fabric finishing coating according to any one of claims 1 to 5, and continuously overturning to fully impregnate the fiber fabric; and 3, step 3: throwing off redundant paint from the fully impregnated fiber fabric on a centrifuge with low rotating speed; and 4, step 4: putting the liquid-removed fiber fabric into a drying box, gradually heating, opening a fan to enable the temperature of the drying box to be uniform, and then cooling along with a furnace; and 5: and (4) ironing and shaping the dried fiber fabric according to different materials and shapes.

Description

Coating for finishing fiber fabric and using method thereof
Technical Field
The invention belongs to the field of fabric coatings, and particularly relates to a coating for finishing fiber fabrics and a using method thereof.
Background
When live working, particularly high-voltage live working, the quality and the performance of working clothes of working personnel are good and bad, and the smoothness of a line and the personal safety are directly related. Particularly, the multifunctional work clothes are needed to be used in field work in wet or rainy seasons. Existing work clothes for workers typically use a fabric and apply a coating thereto.
CN1478949A discloses a coating for finishing of electrical insulating cloth, which comprises the following components in parts by weight: water: 100 parts of fluorocarbon surfactant: 3-7 parts of adhesive: 2-7 parts of catalyst: 0.5 to 1.2 portions. The fluorocarbon surfactant is TG521 type fluorocarbon surfactant; the adhesive is melamine and KH560 silane coupling agent; triethylene tetramine is used as a catalyst; also contains a penetrating agent: isopropyl alcohol; also contains dialkyl dimethyl ammonium salt softening agent. After the cloth is finished by the coating, the electric insulation performance index is good, so that the finished cloth is suitable for manufacturing industrial clothing worn by various live-wire work, and safety guarantee is provided for live-wire work operators. Because the cloth finished by the dipping agent has good waterproof, oil-proof and antifouling performances, the cloth dipping agent provides convenient and reliable conditions for field operation, wet and rainy season operation. However, the finishing cloth has poor air permeability and no antistatic function, and has potential safety hazards under the background that the operation safety is increasingly required to be improved.
Disclosure of Invention
In order to solve the technical problems in the prior art, the invention aims to provide a waterproof, breathable, ultraviolet-proof and antistatic coating for finishing fiber fabrics. The specific technical scheme is as follows:
the coating for finishing the fiber fabric comprises the following components in parts by mass:
80-120 parts of water;
7-11 parts of a waterproof agent;
8-15 parts of silicone rubber emulsion;
1-3 parts of titanate coupling agent;
4-6 parts of nano titanium dioxide.
Further, the waterproof agent is selected from one or more of a waterproof agent AG-710, a waterproof agent AG-7500, a waterproof agent AG-7600, a waterproof agent AG415, a waterproof agent AG-950 and a waterproof agent AG-E061.
Further, the titanate coupling agent is preferably a chelate type titanate coupling agent.
Furthermore, the particle size of the nano titanium dioxide is 10-12 nanometers.
Further, firstly adding a waterproofing agent into the silicone rubber emulsion, mixing and stirring, gradually adding the nano titanium dioxide into a stirrer with the rotating speed of not less than 300 revolutions per minute, dispersing and stirring for 30 minutes, then adding the titanate coupling agent, dispersing and stirring for not less than 60 minutes, and finally adding the water for dispersing and stirring for 30 minutes.
The application method of the coating for finishing the fiber fabric comprises the following steps:
step 1: fully washing the fiber fabric to be treated, and drying the washed fiber;
step 2: immersing a fiber fabric into the fiber fabric finishing coating according to any one of claims 1 to 5, and continuously overturning to fully impregnate the fiber fabric;
and 3, step 3: throwing off redundant paint on the fully soaked fiber fabric on a centrifuge with low rotating speed to keep the liquid carrying capacity of the fabric at 70-75%;
and 4, step 4: putting the deliquored fiber fabric into a drying box, gradually raising the temperature, opening a fan to enable the temperature of the drying box to be uniform, and then cooling along with a furnace;
and 5: and (4) ironing and shaping the dried fiber fabric according to different materials and shapes.
Further, in step 1, the drying temperature is more than 100 ℃ and not less than 2 hours.
Further, in step 4, the drying temperature and time are as follows:
1. normal temperature → 60 ℃,50min;
2.60℃→110℃ 80min;
3.110℃→160℃20min。
the invention provides a coating which endows fiber fabrics, especially garment materials, with rain-proof, ventilation, ultraviolet resistance, static resistance and other functions and a using method thereof. Belongs to the scientific and technological innovation of the textile multifunctional finishing industry. The method comprises the complete use methods of textile purification treatment, the matching of a coating formula and auxiliary materials, a temperature rise curve and the like.
Detailed Description
The following describes in detail specific embodiments of the present invention. It should be understood that the detailed description and specific examples, while indicating the present invention, are given by way of illustration and explanation only, not limitation.
Example 1
The coating for finishing the fiber fabric comprises the following components in parts by mass:
80 parts of water;
10 parts of a waterproof agent AG-710;
12 parts of a silicone rubber emulsion;
1 part of titanate coupling agent;
5 parts of nano titanium dioxide;
wherein the titanate coupling agent is preferably a chelate titanate coupling agent, and the particle size of the nano titanium dioxide is 10-12 nanometers.
The configuration method comprises the following steps: adding a waterproofing agent AG-710 into the silicone rubber emulsion, mixing and stirring, gradually adding the nano titanium dioxide into a stirrer with the rotation speed of not less than 300 revolutions per minute, dispersing and stirring for 30 minutes, adding the titanate coupling agent, dispersing and stirring for not less than 60 minutes, and finally adding water for dispersing and stirring for 30 minutes.
Example 2
The fiber fabric finishing coating comprises the following components in parts by mass:
100 parts of water;
waterproofing agent AG-7500 parts;
8 parts of a silicone rubber emulsion;
13 parts of titanate coupling agent;
6 parts of nano titanium dioxide;
wherein the titanate coupling agent is preferably a chelate titanate coupling agent, and the particle size of the nano titanium dioxide is 10-12 nanometers.
The configuration method comprises the following steps: adding a waterproofing agent AG-7500 into the silicon rubber emulsion, mixing and stirring, gradually adding the nano titanium dioxide into a stirrer with the rotating speed of not less than 300 revolutions per minute, dispersing and stirring for 30 minutes, adding a titanate coupling agent, dispersing and stirring for not less than 60 minutes, and finally adding water for dispersing and stirring for 30 minutes.
Example 3
The coating for finishing the fiber fabric comprises the following components in parts by mass:
120 parts of water;
7 parts of a waterproof agent AG-7600;
15 parts of a silicone rubber emulsion;
2 parts of titanate coupling agent;
4 parts of nano titanium dioxide;
wherein the titanate coupling agent is preferably a chelate titanate coupling agent, and the particle size of the nano titanium dioxide is 10-12 nanometers.
The configuration method comprises the following steps: adding a waterproofing agent AG-7600 into the silicone rubber emulsion, mixing and stirring, gradually adding the nano titanium dioxide into a stirrer with the rotating speed of not less than 300 revolutions per minute, dispersing and stirring for 30 minutes, adding a titanate coupling agent, dispersing and stirring for not less than 60 minutes, and finally adding water for dispersing and stirring for 30 minutes.
Example 4
The fiber fabric finishing coating comprises the following components in parts by mass:
110 parts of water;
415 parts of a waterproof agent AG;
14 parts of a silicone rubber emulsion;
3 parts of titanate coupling agent;
6 parts of nano titanium dioxide;
wherein the titanate coupling agent is preferably a chelate titanate coupling agent, and the particle size of the nano titanium dioxide is 10-12 nanometers.
The configuration method comprises the following steps: adding a waterproofing agent AG415 into the silicon rubber emulsion, mixing and stirring, gradually adding the nano titanium dioxide into a stirrer with the rotating speed of not less than 300 revolutions per minute, dispersing and stirring for 30 minutes, adding a titanate coupling agent, dispersing and stirring for not less than 60 minutes, and finally adding water for dispersing and stirring for 30 minutes.
Example 5
The fiber fabric finishing coating comprises the following components in parts by mass:
85 parts of water;
9 parts of a waterproof agent AG-950;
10 parts of a silicone rubber emulsion;
1 part of titanate coupling agent;
6 parts of nano titanium dioxide;
wherein the titanate coupling agent is preferably a chelate titanate coupling agent, and the particle size of the nano titanium dioxide is 10-12 nanometers.
The configuration method comprises the following steps: adding a waterproofing agent AG-950 into the silicone rubber emulsion, mixing and stirring, gradually adding the nano titanium dioxide into a stirrer with the rotation speed of not less than 300 revolutions per minute, dispersing and stirring for 30 minutes, adding the titanate coupling agent, dispersing and stirring for not less than 60 minutes, and finally adding water for dispersing and stirring for 30 minutes.
Example 6
The fiber fabric finishing coating comprises the following components in parts by mass:
110 parts of water;
11 parts of a waterproof agent AG-E061;
15 parts of a silicone rubber emulsion;
3 parts of titanate coupling agent;
6 parts of nano titanium dioxide;
wherein the titanate coupling agent is preferably a chelate titanate coupling agent, and the particle size of the nano titanium dioxide is 10-12 nanometers.
The configuration method comprises the following steps: adding a waterproofing agent AG-E061 into the silicone rubber emulsion, mixing and stirring, gradually adding nano titanium dioxide into a stirrer with the rotating speed of not less than 300 revolutions per minute, dispersing and stirring for 30 minutes, adding a titanate coupling agent, dispersing and stirring for not less than 60 minutes, and finally adding water for dispersing and stirring for 30 minutes.
Example 7
The invention also provides a using method of the coating for finishing the fiber fabric, which is used for finishing the fiber fabric, so that the fiber fabric has the functions of water resistance, air permeability, ultraviolet resistance, static resistance and the like. The method comprises the following steps:
step 1: fully washing the fiber fabric to be treated with water to remove residues of fiber and residual materials of the fabric in the production process, such as release agent, coloring agent, softening agent and the like, so as to ensure the purity of the fiber fabric; meanwhile, the fiber water after the water washing needs to be dried; the drying temperature is more than 100 ℃ and is not less than 2 hours;
and 2, step: soaking the fiber fabric into the coating for finishing the fiber fabric, and continuously overturning to fully soak the fiber fabric;
and step 3: throwing off redundant paint on the fully impregnated fiber fabric on a centrifuge with low rotating speed to keep the liquid carrying amount of the fabric at 70-75%;
and 4, step 4: and (3) putting the liquid-removed fiber fabric into a drying box, gradually heating, and opening a fan to ensure that the temperature of the drying box is uniform. The drying temperature and time are as follows:
1. normal temperature → 60 ℃,50min;
2.60℃→110℃ 80min;
3.110℃→160℃20min;
then cooling along with the furnace;
and 5: and (4) ironing and shaping the dried fiber fabric according to different materials and shapes.
The treated fiber fabric has good waterproof, breathable, ultraviolet-proof and antistatic performances according to national standard evaluation, and is very environment-friendly.
The above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it should be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and these modifications or substitutions do not depart from the scope of the embodiments of the present invention in nature.

Claims (8)

1. The coating for finishing the fiber fabric comprises the following components in parts by mass:
80-120 parts of water;
7-11 parts of a waterproof agent;
8-15 parts of silicone rubber emulsion;
1-3 parts of titanate coupling agent;
4-6 parts of nano titanium dioxide.
2. A coating for finishing a fiber fabric according to claim 1, characterized in that:
the water-proofing agent is selected from one or more of water-proofing agent AG-710, water-proofing agent AG-7500, water-proofing agent AG-7600, water-proofing agent AG415, water-proofing agent AG-950 and water-proofing agent AG-E061.
3. A coating for finishing a fiber fabric according to claim 1, characterized in that:
the titanate coupling agent is preferably a chelating titanate coupling agent.
4. A coating for finishing a fiber fabric according to claim 1, characterized in that:
the particle size of the nano titanium dioxide is 10-12 nanometers.
5. A coating for finishing a fibrous textile according to claim 1, characterized in that:
firstly, adding a waterproofing agent into a silicon rubber emulsion, mixing and stirring, gradually adding nano titanium dioxide into a stirrer with the rotating speed of not less than 300 revolutions per minute, dispersing and stirring for 30 minutes, then adding a titanate coupling agent, dispersing and stirring for not less than 60 minutes, and finally adding water for dispersing and stirring for 30 minutes.
6. Use of a coating for finishing a fibrous web according to any of claims 1 to 5, comprising the steps of:
step 1: fully washing the fiber fabric to be treated, and drying the washed fiber;
step 2: immersing a fiber fabric into the fiber fabric finishing coating according to any one of claims 1 to 5, and continuously overturning to fully impregnate the fiber fabric;
and step 3: throwing off redundant paint on the fully soaked fiber fabric on a centrifuge with low rotating speed to keep the liquid carrying capacity of the fabric at 70-75%;
and 4, step 4: putting the liquid-removed fiber fabric into a drying box, gradually heating, opening a fan to enable the temperature of the drying box to be uniform, and then cooling along with a furnace;
and 5: and (4) ironing and shaping the dried fiber fabric according to different materials and shapes.
7. Use according to claim 6, characterized in that: in step 1, the drying temperature is more than 100 ℃ and not less than 2 hours.
8. Use according to claim 6, characterized in that: in step 4, the drying temperature and time are as follows:
1. normal temperature → 60 ℃,50min;
2.60℃→110℃ 80min;
3.110℃→160℃20min。
CN202211113798.1A 2022-09-14 2022-09-14 Coating for finishing fiber fabric and using method thereof Pending CN115233456A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202211113798.1A CN115233456A (en) 2022-09-14 2022-09-14 Coating for finishing fiber fabric and using method thereof
PCT/CN2022/119833 WO2024055341A1 (en) 2022-09-14 2022-09-20 Coating for finishing fiber fabric, as well as use method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202211113798.1A CN115233456A (en) 2022-09-14 2022-09-14 Coating for finishing fiber fabric and using method thereof

Publications (1)

Publication Number Publication Date
CN115233456A true CN115233456A (en) 2022-10-25

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WO (1) WO2024055341A1 (en)

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CN107722318A (en) * 2017-09-20 2018-02-23 安徽锦翔纺织服饰有限公司 A kind of waterproof air previous polyurethane fabric and preparation method thereof
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CN107722318A (en) * 2017-09-20 2018-02-23 安徽锦翔纺织服饰有限公司 A kind of waterproof air previous polyurethane fabric and preparation method thereof
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