CN115160662A - Strippable glazing cloth and process thereof - Google Patents

Strippable glazing cloth and process thereof Download PDF

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Publication number
CN115160662A
CN115160662A CN202210680082.3A CN202210680082A CN115160662A CN 115160662 A CN115160662 A CN 115160662A CN 202210680082 A CN202210680082 A CN 202210680082A CN 115160662 A CN115160662 A CN 115160662A
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Prior art keywords
cloth
glue
rubber
black
glazing
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CN202210680082.3A
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Chinese (zh)
Inventor
徐毛清
陈士强
高杰亮
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Jiangsu Commscope Printing Technology Co ltd
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Jiangsu Commscope Printing Technology Co ltd
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Priority to CN202210680082.3A priority Critical patent/CN115160662A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/14Layered products comprising a layer of natural or synthetic rubber comprising synthetic rubber copolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/10Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284Application of adhesive
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/04Polysulfides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02Copolymers with acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2309/02Copolymers with acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00Characterised by the use of unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2391/00Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C08J2391/02Vulcanised oils, e.g. factice
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • C08K7/26Silicon- containing compounds

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a strippable glazing cloth and a process thereof, and the technical scheme is as follows: including cloth group and gluey group, cloth group includes surface cloth, well cloth and backer, gluey group includes surface glue, black glue and white glue, the white glue coating bonds in the backer top, well cloth is located the white glue top, backer and well cloth are connected through the white glue veneer, the black glue coating bonds in well cloth top, surface cloth is located the black glue top, surface cloth and well cloth are connected and are fixed through the black glue veneer, the surface glue coating bonds in surface cloth top, a strippable glazing cloth and technology beneficial effect are: the manufacturing process of the strippable glazing cloth is clear in order and convenient to operate, the surface cloth and the surface adhesive of the strippable glazing cloth can be torn by hands, places which do not need to be glazed can be stripped by using the strippable glazing cloth, and only the places which need to be glazed are used, so that partial glazing is facilitated, and the problems that the existing glazing cloth cannot be stripped, all glazing is needed during glazing, the cost is wasted and the cost is wasted are solved.

Description

Strippable glazing cloth and process thereof
Technical Field
The invention relates to the technical field of glazing cloth, in particular to strippable glazing cloth and a process thereof.
Background
The light-feeding function is to coat a layer of colorless transparent coating on the surface of the printed matter, and the colorless transparent coating plays a role in protecting and increasing the luster of the printed matter after being dried. A layer of colorless transparent coating is coated on the surface of the cloth, a thin and uniform transparent bright layer is formed on the surface of the cloth after leveling, drying, calendaring and curing, and the process has the functions of enhancing the surface smoothness of a carrier and protecting the finish processing of printed pictures and texts, so that the glazing cloth is obtained.
The existing glazing cloth on the market can not be peeled, the whole glazing is needed during the glazing, the waste is high, the peelable glazing cloth can be used for peeling the place which does not need to be glazed, only the place which needs to be glazed is used, the glazing part is formed by combining three layers of cloth and three layers of sizing materials, and the surface cloth and the foaming adhesive can be peeled manually, so that the place which only needs to be glazed can be conveniently touched.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides a strippable glazing cloth and a process thereof, wherein three layers of cloth and three types of rubber materials are sequentially overlapped and bonded together, surface rubber is adhered to the upper surface of the surface cloth, vulcanization processing and polishing are required after the surface rubber is coated, black rubber is adhered to the lower surface of the surface cloth, and the black rubber is foamed by a foaming technology, so that the problems that the existing glazing cloth cannot be stripped, all glazing is required during glazing, the cost is wasted and the cost is wasted are solved.
In order to achieve the above purpose, the invention provides the following technical scheme: a strippable glazing cloth and a process thereof comprise a cloth group and a rubber mixing group, wherein the cloth group comprises a surface cloth, a middle cloth and a base cloth, the rubber mixing group comprises surface glue, black glue and white glue, the white glue is coated and bonded on the top of the base cloth, the middle cloth is positioned on the top of the white glue, the base cloth and the middle cloth are connected through the white glue in a gluing mode, the black glue is coated and bonded on the top of the middle cloth, the surface cloth is positioned on the top of the black glue, the surface cloth and the middle cloth are fixedly connected through the black glue in a gluing mode, and the surface glue is coated and bonded on the top of the surface cloth.
Preferably, the materials of the surface rubber comprise nitrile rubber E3380, mixed rubber 3360, subimage 7375, polysulfide and phthalocyanine blue.
Preferably, the black rubber comprises 3380 of nitrile rubber, 7030N of mixed rubber, carbon black, white carbon black, rubber scraps, black factice and zinc oxide.
Preferably, the white glue material comprises butyronitrile glue 6250, white carbon black, a coupling agent SI-69, zinc oxide, an antioxidant 2246 and stearic acid.
A process for stripping glazing cloth comprises the following steps:
s1: uniformly pressing a layer of black glue on the upper surface of the middle cloth, coating the black glue on the upper surface of the middle cloth to form a cloth-to-glue layer, and splicing the upper surface of the black glue layer with a surface cloth through a vulcanizing machine to form two cloth-to-glue layers;
s2: then, foaming the black glue between the medium cloth and the surface cloth by a foaming technology to form foaming glue by the black glue;
s3: then uniformly coating a layer of white glue on the lower surface of the middle cloth, and coating the white glue on the lower surface of the middle cloth to form two pieces of cloth and two pieces of glue;
s4: then the base fabric is spliced on the lower surface of the white glue through a vulcanizing machine to form three-cloth two-glue, and then the upper surface of the surface cloth is coated with uniform surface glue so as to press the upper surface of the surface cloth with surface glue to form three-cloth three-glue;
s5: then the surface glue on the upper surface of the fabric is vulcanized, and then the surface of the surface glue is polished by a polisher.
Preferably, the vulcanizer is a machine for vulcanizing various rubber and plastic products, the vulcanizer vulcanizes the black rubber coated on the surface of the middle cloth, and the vulcanized black rubber forms a spatial three-dimensional structure and has high elasticity, heat resistance and tensile strength.
Preferably, the foaming technology is that a honeycomb or porous structure is formed by the black rubber layer through the addition and reaction of a chemical foaming agent, and the shell fabric can be easily peeled off when the foaming rubber enters the fabric seam depth in the foaming process.
Preferably, the surface glue is vulcanized by adding sulfur powder into the surface glue to convert linear macromolecules of the surface glue into a three-dimensional network structure.
Preferably, the temperature of the surface rubber during vulcanization is 130-170 ℃, the time of vulcanization is 1-0.4h, and the pressure during vulcanization is 16-8Mpa.
The embodiment of the invention has the following advantages:
1. the three layers of cloth and the three rubber materials are sequentially overlapped and bonded together, the black adhesive is adhered to the lower surface of the face cloth, the black adhesive is foamed through a foaming technology, the manufacturing process of the strippable glazing cloth is clear in order and convenient to operate, the face cloth and the face adhesive of the strippable glazing cloth can be torn by hands, places which do not need to be glazed can be stripped only by using the place which needs to be glazed so as to be partially glazed, and the problems that the existing glazing cloth cannot be stripped, all glazing is needed during glazing, the cost is wasted and the cost is wasted are solved.
2. According to the invention, the surface adhesive is adhered to the upper surface of the surface cloth, the surface adhesive needs to be vulcanized after being coated and then polished, and the vulcanized surface adhesive changes the inherent defects of low strength, small elasticity, cold hardness, hot adhesion, easy aging and the like, obviously improves the wear resistance, swelling resistance, heat resistance and the like, and prolongs the service life of the strippable glazing cloth.
Detailed Description
The present invention is described in terms of specific embodiments, and other advantages and benefits of the present invention will become apparent to those skilled in the art from the following disclosure. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
Example 1:
the invention provides a strippable glazing cloth and a process thereof, wherein the strippable glazing cloth comprises a cloth group and a rubber mixing group, the cloth group comprises a surface cloth, a middle cloth and a base cloth, the rubber mixing group comprises a surface rubber, a black rubber and a white rubber, the white rubber is coated and adhered on the top of the base cloth, the middle cloth is positioned on the top of the white rubber, the base cloth and the middle cloth are connected through the white rubber in a gluing way, the black rubber is coated and adhered on the top of the middle cloth, the surface cloth is positioned on the top of the black rubber, the surface cloth and the middle cloth are fixedly connected through the black rubber in a gluing way, the surface rubber is coated and adhered on the top of the surface cloth, the surface rubber comprises butyronitrile rubber E3380, mixed rubber 3360, sub-image 7375, polysulfide and phthalocyanine blue, the black rubber comprises butyronitrile rubber 3380, mixed rubber 7030N, carbon black, white carbon black, rubber, crumb, black factice and zinc oxide, and the white rubber comprises butyronitrile rubber 6250, white carbon black, coupling agents SI-69, zinc oxide, antioxidant 2246 and stearic acid.
A process for stripping glazing cloth comprises the following steps:
s1: uniformly pressing a layer of black glue on the upper surface of the middle cloth, coating the black glue on the upper surface of the middle cloth to form a cloth-to-glue layer, and splicing the upper surface of the black glue layer with a surface cloth through a vulcanizing machine to form two cloth-to-glue layers;
s2: then, foaming the black glue between the medium cloth and the surface cloth by a foaming technology to form foaming glue by the black glue;
s3: then uniformly coating a layer of white glue on the lower surface of the middle cloth, and coating the white glue on the lower surface of the middle cloth to form two cloths and two glues;
s4: then the base fabric is spliced on the lower surface of the white glue through a vulcanizing machine to form three-cloth two-glue, and then the upper surface of the surface cloth is coated with uniform surface glue so as to press the upper surface of the surface cloth with surface glue to form three-cloth three-glue;
s5: then the surface glue on the upper surface of the fabric is vulcanized, and then the surface of the surface glue is polished by a polisher.
In the embodiment, the vulcanizer is a machine for vulcanizing various rubber and plastic products, the vulcanizer vulcanizes the black adhesive coated on the surface of the middle cloth, a spatial three-dimensional structure is formed in the vulcanized black adhesive, and the black adhesive has high elasticity, heat resistance and tensile strength, the foaming technology is characterized in that a honeycomb or porous structure is formed by the addition and reaction of a chemical foaming agent, the foaming adhesive enters the cloth seam depth in the foaming process and can easily peel off the surface cloth, sulfur powder is added into the surface adhesive in the surface adhesive vulcanizing process to convert linear macromolecules of the surface adhesive into a three-dimensional network structure, the temperature of the surface adhesive in the vulcanizing process is 130 ℃, the time of the vulcanizing process is 1h, and the pressure of the vulcanizing process is 16Mpa.
Example 2:
the invention provides strippable glazing cloth and a process thereof, wherein the strippable glazing cloth comprises a cloth group and a rubber compound group, the cloth group comprises surface cloth, middle cloth and base cloth, the rubber compound group comprises surface rubber, black rubber and white rubber, the white rubber is coated and adhered to the top of the base cloth, the middle cloth is positioned at the top of the white rubber, the base cloth and the middle cloth are connected through the white rubber in a gluing manner, the black rubber is coated and adhered to the top of the middle cloth, the surface cloth is positioned at the top of the black rubber, the surface cloth and the middle cloth are fixed through the black rubber in a gluing manner, the surface rubber is coated and adhered to the top of the surface cloth, the surface rubber comprises butyronitrile rubber E3380, mixed rubber 3360, sub-elephant 7375, polysulfide and phthalocyanine blue, the black rubber comprises butyronitrile rubber 3380, mixed rubber 7030N, carbon black, white carbon black, rubber crumbs, black factice and zinc oxide, and the white rubber comprises butyronitrile rubber 6250, white carbon black, coupling agents SI-69, zinc oxide, antioxidant 2246 and stearic acid.
A process for stripping glazing cloth comprises the following steps:
s1: uniformly pressing a layer of black glue on the upper surface of the middle cloth, coating the black glue on the upper surface of the middle cloth to form a cloth-to-glue layer, and splicing the upper surface of the black glue layer with a surface cloth through a vulcanizing machine to form two cloth-to-glue layers;
s2: then, foaming the black glue between the medium cloth and the surface cloth by a foaming technology to form foaming glue by the black glue;
s3: then uniformly coating a layer of white glue on the lower surface of the middle cloth, and coating the white glue on the lower surface of the middle cloth to form two pieces of cloth and two pieces of glue;
s4: then the base fabric is spliced on the lower surface of the white glue through a vulcanizing machine to form three-cloth two-glue, and then the upper surface of the surface cloth is coated with uniform surface glue so as to press the upper surface of the surface cloth with surface glue to form three-cloth three-glue;
s5: then the surface glue on the upper surface of the fabric is vulcanized, and then the surface of the surface glue is polished by a polisher.
In the embodiment, the vulcanizer is a machine for vulcanizing various rubber and plastic products, the vulcanizer vulcanizes the black adhesive coated on the surface of the middle cloth, a spatial three-dimensional structure is formed in the vulcanized black adhesive, and the black adhesive has high elasticity, heat resistance and tensile strength, the foaming technology is characterized in that a honeycomb or porous structure is formed by the black adhesive layer through the addition and reaction of a chemical foaming agent, the foaming adhesive enters the cloth seam depth in the foaming process and can be easily peeled off from the surface cloth, sulfur powder is added into the surface adhesive in the vulcanization processing process of the surface adhesive, linear macromolecules of the surface adhesive are converted into a three-dimensional network structure, the temperature of the surface adhesive in the vulcanization processing is 150 ℃, the time of the vulcanization processing is 0.8h, and the pressure of the vulcanization processing is 14Mpa.
Example 3:
the invention provides a strippable glazing cloth and a process thereof, wherein the strippable glazing cloth comprises a cloth group and a rubber mixing group, the cloth group comprises a surface cloth, a middle cloth and a base cloth, the rubber mixing group comprises a surface rubber, a black rubber and a white rubber, the white rubber is coated and adhered on the top of the base cloth, the middle cloth is positioned on the top of the white rubber, the base cloth and the middle cloth are connected through the white rubber in a gluing way, the black rubber is coated and adhered on the top of the middle cloth, the surface cloth is positioned on the top of the black rubber, the surface cloth and the middle cloth are fixedly connected through the black rubber in a gluing way, the surface rubber is coated and adhered on the top of the surface cloth, the surface rubber comprises butyronitrile rubber E3380, mixed rubber 3360, sub-image 7375, polysulfide and phthalocyanine blue, the black rubber comprises butyronitrile rubber 3380, mixed rubber 7030N, carbon black, white carbon black, rubber, crumb, black factice and zinc oxide, and the white rubber comprises butyronitrile rubber 6250, white carbon black, coupling agents SI-69, zinc oxide, antioxidant 2246 and stearic acid.
A process for stripping glazing cloth comprises the following steps:
s1: uniformly pressing a layer of black glue on the upper surface of the middle cloth, coating the black glue on the upper surface of the middle cloth to form a cloth-to-glue layer, and splicing the upper surface of the black glue layer with a surface cloth through a vulcanizing machine to form two cloth-to-glue layers;
s2: then, foaming the black glue between the medium cloth and the surface cloth by a foaming technology to form foaming glue by the black glue;
s3: then uniformly coating a layer of white glue on the lower surface of the middle cloth, and coating the white glue on the lower surface of the middle cloth to form two pieces of cloth and two pieces of glue;
s4: then the base fabric is spliced on the lower surface of the white glue through a vulcanizing machine to form three-cloth two-glue, and then the upper surface of the surface cloth is coated with uniform surface glue so as to press the upper surface of the surface cloth with surface glue to form three-cloth three-glue;
s5: then the surface glue on the upper surface of the fabric is vulcanized, and then the surface of the surface glue is polished by a polisher.
In the embodiment, the vulcanizing machine is a machine for vulcanizing various rubber and plastic products, the vulcanizing machine vulcanizes the black adhesive coated on the surface of the middle cloth, a spatial three-dimensional structure is formed in the vulcanized black adhesive, the vulcanized black adhesive has high elasticity, heat resistance and tensile strength, the foaming technology is characterized in that a honeycomb or porous structure is formed by the black adhesive through the addition and reaction of a chemical foaming agent, the foaming adhesive enters the cloth seam depth in the foaming process and can be easily peeled off the surface cloth, sulfur powder is added into the surface adhesive in the vulcanizing processing process of the surface adhesive, linear macromolecules of the surface adhesive are converted into a three-dimensional net structure, the vulcanizing processing temperature of the surface adhesive is 160 ℃, the vulcanizing processing time is 0.6h, and the vulcanizing processing pressure is 10Mpa.
Example 4:
the invention provides strippable glazing cloth and a process thereof, wherein the strippable glazing cloth comprises a cloth group and a rubber compound group, the cloth group comprises surface cloth, middle cloth and base cloth, the rubber compound group comprises surface rubber, black rubber and white rubber, the white rubber is coated and adhered to the top of the base cloth, the middle cloth is positioned at the top of the white rubber, the base cloth and the middle cloth are connected through the white rubber in a gluing manner, the black rubber is coated and adhered to the top of the middle cloth, the surface cloth is positioned at the top of the black rubber, the surface cloth and the middle cloth are fixed through the black rubber in a gluing manner, the surface rubber is coated and adhered to the top of the surface cloth, the surface rubber comprises butyronitrile rubber E3380, mixed rubber 3360, sub-elephant 7375, polysulfide and phthalocyanine blue, the black rubber comprises butyronitrile rubber 3380, mixed rubber 7030N, carbon black, white carbon black, rubber crumbs, black factice and zinc oxide, and the white rubber comprises butyronitrile rubber 6250, white carbon black, coupling agents SI-69, zinc oxide, antioxidant 2246 and stearic acid.
A process for stripping glazing cloth comprises the following steps:
s1: uniformly pressing a layer of black glue on the upper surface of the middle cloth, coating the black glue on the upper surface of the middle cloth to form a cloth-to-glue layer, and splicing the upper surface of the black glue layer with a surface cloth through a vulcanizing machine to form two cloth-to-glue layers;
s2: then, foaming the black glue between the medium cloth and the surface cloth by a foaming technology to form foaming glue by the black glue;
s3: then uniformly coating a layer of white glue on the lower surface of the middle cloth, and coating the white glue on the lower surface of the middle cloth to form two cloths and two glues;
s4: then the base fabric is spliced on the lower surface of the white glue through a vulcanizing machine to form three-cloth two-glue, and then the upper surface of the surface cloth is coated with uniform surface glue so as to press the upper surface of the surface cloth with surface glue to form three-cloth three-glue;
s5: then the surface rubber on the upper surface of the face fabric is vulcanized, and then the surface of the surface rubber is polished by a polisher.
In the embodiment, the vulcanizer is a machine for vulcanizing various rubber and plastic products, the vulcanizer vulcanizes the black adhesive coated on the surface of the middle cloth, a spatial three-dimensional structure is formed in the vulcanized black adhesive, and the black adhesive has high elasticity, heat resistance and tensile strength, the foaming technology is characterized in that a honeycomb or porous structure is formed by the black adhesive layer through the addition and reaction of a chemical foaming agent, the foaming adhesive enters the cloth seam depth in the foaming process and can be easily peeled off from the surface cloth, sulfur powder is added into the surface adhesive in the vulcanization processing process of the surface adhesive, linear macromolecules of the surface adhesive are converted into a three-dimensional reticular structure, the temperature of the surface adhesive in the vulcanization processing is 170 ℃, the time of the vulcanization processing is 0.4h, and the pressure of the vulcanization processing is 8Mpa.
From the above embodiments it follows that:
Figure BDA0003697994700000081
Figure BDA0003697994700000091
according to the table, in the embodiment 3, under the conditions that the temperature is 160 ℃, the time is 0.6h and the pressure is 10Mpa, the torque of the surface adhesive vulcanization processing is larger, the service life of the surface adhesive is prolonged, the glazing cloth is more durable, the place which does not need to be glazed can be peeled, only the place which needs to be glazed is used, the glazing part is formed by combining three layers of cloth materials and three layers of rubber materials, the surface cloth and the foaming rubber can be peeled by hands, but cannot be easily layered, and only the place which needs to be glazed is conveniently covered.
The above description is only a preferred embodiment of the present invention, and any person skilled in the art may modify the present invention or modify it into an equivalent technical solution by using the technical solution described above. Therefore, any simple modifications or equivalent replacements made according to the technical solution of the present invention belong to the protection scope of the present invention.

Claims (9)

1. The strippable glazing cloth comprises a cloth group and a rubber mixing group, and is characterized in that: the rubber mixing group comprises surface cloth, middle cloth and base cloth, the white rubber is coated and bonded on the top of the base cloth, the middle cloth is positioned on the top of the white rubber, the base cloth and the middle cloth are connected through the white rubber in a gluing mode, the black rubber is coated and bonded on the top of the middle cloth, the surface cloth is positioned on the top of the black rubber, the surface cloth and the middle cloth are fixedly connected through the black rubber in a gluing mode, and the surface rubber is coated and bonded on the top of the surface cloth.
2. A peelable glazing cloth according to claim 1 in which: the surface glue comprises nitrile rubber E3380, mixed rubber 3360, a subimage 7375, polysulfide, white carbon black and phthalocyanine blue.
3. A peelable glazing cloth according to claim 1 in which: the black rubber comprises 3380 parts of nitrile rubber, 7030N parts of mixed rubber, carbon black, white carbon black, rubber scraps, black factice and zinc oxide.
4. A peelable glazing cloth according to claim 1 in which: the white glue material comprises butyronitrile glue 6250, white carbon black, a coupling agent SI-69, zinc oxide, an antioxidant 2246 and stearic acid.
5. A process of stripping a glazing cloth according to claim 1, comprising the steps of:
s1: uniformly pressing a layer of black glue on the upper surface of the middle cloth, coating the black glue on the upper surface of the middle cloth to form a cloth-to-glue layer, and splicing the upper surface of the black glue layer with a surface cloth through a vulcanizing machine to form two cloth-to-glue layers;
s2: then, foaming the black glue between the medium cloth and the surface cloth by a foaming technology to form foaming glue by the black glue;
s3: then uniformly coating a layer of white glue on the lower surface of the middle cloth, and coating the white glue on the lower surface of the middle cloth to form two pieces of cloth and two pieces of glue;
s4: then the base fabric is spliced on the lower surface of the white glue through a vulcanizing machine to form three-cloth two-glue, and then the upper surface of the surface cloth is coated with uniform surface glue so as to press the upper surface of the surface cloth with surface glue to form three-cloth three-glue;
s5: then the surface rubber on the upper surface of the face fabric is vulcanized, and then the surface of the surface rubber is polished by a polisher.
6. A process of stripping a glazing cloth as claimed in claim 5, wherein: the vulcanizing machine is a machine for vulcanizing various rubber and plastic products, the vulcanizing machine vulcanizes the black rubber coated on the surface of the middle cloth, and a space three-dimensional structure is formed in the vulcanized black rubber, so that the vulcanized black rubber has high elasticity, heat resistance and tensile strength.
7. A process of releasing a glazing cloth as claimed in claim 5, wherein: according to the foaming technology, a honeycomb or porous structure is formed by the black adhesive layer through the addition and reaction of a chemical foaming agent, and the foaming adhesive enters the cloth seam depth in the foaming process, so that the shell fabric can be easily peeled.
8. A process of releasing a glazing cloth as claimed in claim 5, wherein: the process of vulcanizing the surface glue is to add sulfur powder into the surface glue to convert linear macromolecules of the surface glue into a three-dimensional reticular structure.
9. A process of stripping a glazing cloth as claimed in claim 5, wherein: the temperature of the surface rubber during vulcanization processing is 130-170 ℃, the time of vulcanization processing is 1-0.4h, and the pressure during vulcanization processing is 16-8Mpa.
CN202210680082.3A 2022-06-16 2022-06-16 Strippable glazing cloth and process thereof Pending CN115160662A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103360982A (en) * 2013-07-16 2013-10-23 山西新华化工有限责任公司 Production method of multi-layer composite adhesive fabric
CN103702829A (en) * 2011-07-20 2014-04-02 横滨橡胶株式会社 Rubber laminate
CN111055519A (en) * 2019-12-27 2020-04-24 顾志坤 Production process of rubber blanket for industrial printing
CN114250040A (en) * 2021-12-16 2022-03-29 江苏康普印刷科技有限公司 Back rubber blanket and process thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103702829A (en) * 2011-07-20 2014-04-02 横滨橡胶株式会社 Rubber laminate
US20140150946A1 (en) * 2011-07-20 2014-06-05 The Yokohama Rubber Co., Ltd. Laminated body of rubber layers
CN103360982A (en) * 2013-07-16 2013-10-23 山西新华化工有限责任公司 Production method of multi-layer composite adhesive fabric
CN111055519A (en) * 2019-12-27 2020-04-24 顾志坤 Production process of rubber blanket for industrial printing
CN114250040A (en) * 2021-12-16 2022-03-29 江苏康普印刷科技有限公司 Back rubber blanket and process thereof

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