CN115094387A - 一种抗菌型镀膜剂及其镀膜工艺 - Google Patents
一种抗菌型镀膜剂及其镀膜工艺 Download PDFInfo
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- 239000007888 film coating Substances 0.000 title claims abstract description 12
- 238000009501 film coating Methods 0.000 title claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 6
- 238000000034 method Methods 0.000 title claims description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 metal oxide zirconium dioxide Chemical class 0.000 claims abstract description 8
- 229910003437 indium oxide Inorganic materials 0.000 claims abstract description 7
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052709 silver Inorganic materials 0.000 claims abstract description 7
- 239000004332 silver Substances 0.000 claims abstract description 7
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001887 tin oxide Inorganic materials 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000002484 inorganic compounds Chemical class 0.000 claims abstract description 4
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 4
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims description 12
- 238000005498 polishing Methods 0.000 claims description 7
- 238000007747 plating Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000004321 preservation Methods 0.000 claims description 3
- 238000005086 pumping Methods 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 3
- 230000001580 bacterial effect Effects 0.000 abstract description 5
- 108091005804 Peptidases Proteins 0.000 abstract description 4
- 239000004365 Protease Substances 0.000 abstract description 4
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 abstract description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract description 3
- 241000894006 Bacteria Species 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 2
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
- 238000001755 magnetron sputter deposition Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical compound [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000005329 float glass Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
- C23C14/28—Vacuum evaporation by wave energy or particle radiation
- C23C14/30—Vacuum evaporation by wave energy or particle radiation by electron bombardment
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P1/00—Disinfectants; Antimicrobial compounds or mixtures thereof
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
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Abstract
本发明公开了一种抗菌型镀膜剂，包括以下成分无机化合物二氧化硅、金属氧化物二氧化锆、氧化物铟锡、氧化铝和银离子，其中氧化物铟锡是通过氧化铟和氧化锡混合，且氧化铟和氧化锡的比例为9比1。本发明本发明通过在镀膜剂的原料中添加银离子，银离子可以强烈地吸引细菌体中蛋白酶上的巯基，迅速与其结合在一起，使蛋白酶丧失活性，导致细菌死亡。
Description
技术领域
本发明涉及抗菌型镀膜剂技术领域，尤其涉及一种抗菌型镀膜剂及其镀膜工艺。
背景技术
镀膜工艺是用不同的材料在基片表面形成新表面的方法，镀膜方法有真空蒸发、真空溅射、化学还原、溶胶凝胶等。我公司采用的是阴极真空磁控溅射法，通过磁控溅射，在优质浮法玻璃的表面镀一层或多层金属、或金属化合物薄膜。通过镀膜可以改变基片的某些属性，如光学性能、电学性能、机械性能、化学性能、装饰性能等。现有的镀膜机抗菌性能较差，所以提出一种抗菌型镀膜剂。
发明内容
基于背景技术存在的技术问题，本发明提出了一种抗菌型镀膜剂及其镀膜工艺。
本发明提出的一种抗菌型镀膜剂，包括以下成分无机化合物二氧化硅、金属氧化物二氧化锆、氧化物铟锡、氧化铝和银离子，其中氧化物铟锡是通过氧化铟和氧化锡混合，且氧化铟和氧化锡的比例为9比1。
一种抗菌型镀膜剂的镀膜工艺，包括以下步骤：
S1：镜片装好镀膜盘后进保温，通过烘箱70摄氏度保温；
S2：将保温好的镜片进入镀膜机的真空腔体内进行抽真空，当真空值达到工作要求时，开始进行镀膜前的准备；
S3：准备1进行镜片表面打磨处理打磨处理时间，打磨的时间范围为120-200秒；
S4：准备2进行真空电子枪烧药阶段，各成分原料如下：
S5：整个过程完成后镀膜腔体进入大气，开门后进行下一盘镜片生产。
本发明中的有益效果为：
1.本发明通过在镀膜剂的原料中添加银离子，银离子可以强烈地吸引细菌体中蛋白酶上的巯基(-SH)，迅速与其结合在一起，使蛋白酶丧失活性，导致细菌死亡。当细菌被Ag杀后，Ag又由细菌尸体中游离出来，再与其它菌落接触，周而复始地进行上述过程，银杀菌持久性的原因。
附图说明
图1为本发明提出的一种抗菌型镀膜剂及其镀膜工艺的流程图。
具体实施方式
下面将结合本发明实施例中的附图，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。
参照图1，一种抗菌型镀膜剂，包括以下成分无机化合物二氧化硅、金属氧化物二氧化锆、氧化物铟锡、氧化铝和银离子，其中氧化物铟锡是通过氧化铟和氧化锡混合，且氧化铟和氧化锡的比例为9比1。
一种抗菌型镀膜剂的镀膜工艺，包括以下步骤：
S1：镜片装好镀膜盘后进保温，通过烘箱70摄氏度保温；
S2：将保温好的镜片进入镀膜机的真空腔体内进行抽真空，当真空值达到工作要求时，开始进行镀膜前的准备；
S3：准备1进行镜片表面打磨处理打磨处理时间，打磨的时间范围为120-200秒；
S4：准备2进行真空电子枪烧药阶段，各成分原料如下：
S5：整个过程完成后镀膜腔体进入大气，开门后进行下一盘镜片生产。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。
Claims (2)
1.一种抗菌型镀膜剂，包括以下成分无机化合物二氧化硅、金属氧化物二氧化锆、氧化物铟锡、氧化铝和银离子，其中氧化物铟锡是通过氧化铟和氧化锡混合，且氧化铟和氧化锡的比例为9比1。
2.根据权利要求1所述的一种抗菌型镀膜剂的镀膜工艺，其特征在于，包括以下步骤：
S1：镜片装好镀膜盘后进保温，通过烘箱70摄氏度保温；
S2：将保温好的镜片进入镀膜机的真空腔体内进行抽真空，当真空值达到工作要求时，开始进行镀膜前的准备；
S3：准备1进行镜片表面打磨处理打磨处理时间，打磨的时间范围为120-200秒；
S4：准备2进行真空电子枪烧药阶段，各成分原料如下：
S5：整个过程完成后镀膜腔体进入大气，开门后进行下一盘镜片生产。
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102660730A (zh) * | 2012-05-02 | 2012-09-12 | 江苏格林视通光学有限公司 | 用于镀制眼镜镜片超加硬发水膜的方法 |
| CN106772713A (zh) * | 2016-12-27 | 2017-05-31 | 上海康耐特光学股份有限公司 | 一种抗菌镀膜树脂镜片及其制造方法 |
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- 2022-07-01 CN CN202210773743.7A patent/CN115094387A/zh active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102660730A (zh) * | 2012-05-02 | 2012-09-12 | 江苏格林视通光学有限公司 | 用于镀制眼镜镜片超加硬发水膜的方法 |
| CN106772713A (zh) * | 2016-12-27 | 2017-05-31 | 上海康耐特光学股份有限公司 | 一种抗菌镀膜树脂镜片及其制造方法 |
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