CN1150271C - 高乙烯基含量的氢化苯乙烯-丁二烯-苯乙烯嵌段共聚物的油凝胶配料 - Google Patents
高乙烯基含量的氢化苯乙烯-丁二烯-苯乙烯嵌段共聚物的油凝胶配料 Download PDFInfo
- Publication number
- CN1150271C CN1150271C CNB971179697A CN97117969A CN1150271C CN 1150271 C CN1150271 C CN 1150271C CN B971179697 A CNB971179697 A CN B971179697A CN 97117969 A CN97117969 A CN 97117969A CN 1150271 C CN1150271 C CN 1150271C
- Authority
- CN
- China
- Prior art keywords
- weight
- oil
- butadiene
- polymer
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract description 29
- 229920002554 vinyl polymer Polymers 0.000 title abstract description 27
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title abstract description 17
- 238000009472 formulation Methods 0.000 title description 11
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical class C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 title 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 title 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract description 17
- 239000007788 liquid Substances 0.000 abstract description 12
- 229920001400 block copolymer Polymers 0.000 abstract description 11
- 239000004606 Fillers/Extenders Substances 0.000 abstract description 8
- 229920000098 polyolefin Polymers 0.000 abstract description 7
- 229920000642 polymer Polymers 0.000 description 71
- 239000003921 oil Substances 0.000 description 42
- 239000000499 gel Substances 0.000 description 27
- -1 vinyl aromatic hydrocarbon Chemical class 0.000 description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 13
- 238000011925 1,2-addition Methods 0.000 description 10
- 239000001993 wax Substances 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- 239000000945 filler Substances 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 7
- 238000005984 hydrogenation reaction Methods 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 229920002633 Kraton (polymer) Polymers 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 150000001993 dienes Chemical class 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 239000003999 initiator Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 4
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 229920006158 high molecular weight polymer Polymers 0.000 description 3
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 229920013639 polyalphaolefin Polymers 0.000 description 3
- 150000003440 styrenes Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VPBZZPOGZPKYKX-UHFFFAOYSA-N 1,2-diethoxypropane Chemical compound CCOCC(C)OCC VPBZZPOGZPKYKX-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N cycloheptane Chemical compound C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
- SMBQBQBNOXIFSF-UHFFFAOYSA-N dilithium Chemical compound [Li][Li] SMBQBQBNOXIFSF-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 description 1
- IBVPVTPPYGGAEL-UHFFFAOYSA-N 1,3-bis(prop-1-en-2-yl)benzene Chemical compound CC(=C)C1=CC=CC(C(C)=C)=C1 IBVPVTPPYGGAEL-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical class C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000007868 Raney catalyst Substances 0.000 description 1
- 229910000564 Raney nickel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 150000002900 organolithium compounds Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/075—Macromolecular gels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/10—Copolymers of styrene with conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2283496P | 1996-07-31 | 1996-07-31 | |
| US022,834 | 1996-07-31 | ||
| US022834 | 1996-07-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1180081A CN1180081A (zh) | 1998-04-29 |
| CN1150271C true CN1150271C (zh) | 2004-05-19 |
Family
ID=21811674
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB971179697A Expired - Lifetime CN1150271C (zh) | 1996-07-31 | 1997-07-29 | 高乙烯基含量的氢化苯乙烯-丁二烯-苯乙烯嵌段共聚物的油凝胶配料 |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0822227B1 (enExample) |
| JP (1) | JPH1077382A (enExample) |
| KR (1) | KR980009376A (enExample) |
| CN (1) | CN1150271C (enExample) |
| BR (1) | BR9705233A (enExample) |
| CA (1) | CA2211944A1 (enExample) |
| DE (1) | DE69732273T2 (enExample) |
| MX (1) | MX9705763A (enExample) |
| TR (1) | TR199700720A3 (enExample) |
| TW (1) | TW416971B (enExample) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5777043A (en) * | 1997-03-05 | 1998-07-07 | Shell Oil Company | Sealant formulations containing high vinyl content hydrogenated styrene-butadiene-styrene block copolymers |
| US6465557B1 (en) * | 1999-06-25 | 2002-10-15 | Kraton Polymers U.S. Llc | Hot melt pressure sensitive positioning adhesive |
| US6657000B1 (en) * | 1999-06-25 | 2003-12-02 | Kraton Polymers U.S. Llc | Hot melt pressure sensitive positioning adhesive (III) |
| JP2001151980A (ja) * | 1999-11-24 | 2001-06-05 | Aron Kasei Co Ltd | ゲル状組成物 |
| JP2001151979A (ja) * | 1999-11-24 | 2001-06-05 | Aron Kasei Co Ltd | ゲル状組成物 |
| JP2001335640A (ja) * | 2000-03-24 | 2001-12-04 | Asahi Kagaku Gosei Kk | スチレン系熱可塑性エラストマー組成物の製造方法 |
| AU2002224347A1 (en) * | 2000-10-04 | 2002-04-15 | Kraton Polymers Research B.V. | An elastomeric film and fiber grade thermoplastic elastomer composition |
| ES2207478T3 (es) * | 2000-10-10 | 2004-06-01 | Dynasol Elastomeros, S.A. | Composiciones para relleno de cables. |
| EP1472316B1 (en) * | 2002-01-31 | 2018-11-28 | Kraton Polymers U.S. LLC | Blockcopolymer compositions having improved mechanical properties and processablility |
| JP4090998B2 (ja) | 2002-01-31 | 2008-05-28 | クレイトン・ポリマーズ・リサーチ・ベー・ベー | 機械的特性と加工性が改善されたブロック共重合体組成物 |
| EP1333058A1 (en) * | 2002-01-31 | 2003-08-06 | KRATON Polymers Research B.V. | Modified styrenic block copolymer and compounds thereof having improved mechanical properties and processability |
| US6987142B2 (en) | 2002-02-07 | 2006-01-17 | Kraton Polymers U.S. Llc | Adhesives and sealants from controlled distribution block copolymers |
| US7012118B2 (en) | 2002-02-07 | 2006-03-14 | Kraton Polymers U.S. Llc | Photopolymerizable compositions and flexographic plates prepared from controlled distribution block copolymers |
| US20030181584A1 (en) * | 2002-02-07 | 2003-09-25 | Kraton Polymers U.S. Llc | Elastomeric articles prepared from controlled distribution block copolymers |
| US7517932B2 (en) * | 2003-03-24 | 2009-04-14 | Kraton Polymers U.S. Llc | Poly(styrene-butadiene-styrene)polymers having a high vinyl content in the butadiene block and hot melt adhesive composition comprising said polymers |
| KR100959327B1 (ko) * | 2005-03-11 | 2010-05-26 | 크레이튼 폴리머즈 리서치 비.브이. | 분포 제어된 블록 공중합체와 에스터 오일로 된 오일 겔 |
| US20060205904A1 (en) | 2005-03-11 | 2006-09-14 | St Clair David J | Oil gels of controlled distribution block copolymers and ester oils |
| US9304231B2 (en) * | 2014-02-04 | 2016-04-05 | Kraton Polymers U.S. Llc | Heat fusible oil gels |
| TWI604027B (zh) * | 2015-06-12 | 2017-11-01 | 科騰聚合物美國有限責任公司 | 用於纜線填充應用之熱活化膠 |
| TWI644988B (zh) * | 2016-07-13 | 2018-12-21 | 科騰聚合物美國有限責任公司 | 用於凝膠組合物之嵌段共聚物 |
| JP7110118B2 (ja) | 2016-09-09 | 2022-08-01 | ダイナソル エラストマーラ エス エー デ シー ブイ | 高度なビニルブロック共重合のための極性改質剤系 |
| CN107384272A (zh) * | 2017-06-07 | 2017-11-24 | 吴秀兰 | 胶状组合物及其制造方法和钢化玻璃保护膜、电子设备 |
| CN109535624A (zh) * | 2017-09-22 | 2019-03-29 | 湖州赛德新材料科技有限公司 | 一种电力电子绝缘密封防潮材料及其制造方法 |
| JP7486429B2 (ja) * | 2018-03-23 | 2024-05-17 | クレイトン・ポリマーズ・エル・エル・シー | 超高メルトフロースチレンブロックコポリマー |
| US11542355B2 (en) * | 2018-10-18 | 2023-01-03 | Dynasol Elastómeros, S.A. De C.V. | Polar modifier systems for high vinyl block copolymerization |
| KR102428479B1 (ko) | 2021-11-12 | 2022-08-03 | 우진라페 주식회사 | 캐스타블 거푸집 시공용 분체 이송시스템 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3830767A (en) * | 1973-05-02 | 1974-08-20 | Shell Oil Co | Block copolymer compositions |
| CA1156450A (en) * | 1981-01-30 | 1983-11-08 | John M. R. Hagger | Electric cables and compositions for use in them |
| GB8922445D0 (en) * | 1989-10-05 | 1989-11-22 | Raychem Ltd | Gels |
-
1997
- 1997-07-23 TW TW086110503A patent/TW416971B/zh not_active IP Right Cessation
- 1997-07-28 KR KR1019970035574A patent/KR980009376A/ko not_active Withdrawn
- 1997-07-29 CN CNB971179697A patent/CN1150271C/zh not_active Expired - Lifetime
- 1997-07-29 CA CA002211944A patent/CA2211944A1/en not_active Abandoned
- 1997-07-29 BR BR9705233A patent/BR9705233A/pt not_active IP Right Cessation
- 1997-07-29 JP JP9203457A patent/JPH1077382A/ja active Pending
- 1997-07-29 DE DE69732273T patent/DE69732273T2/de not_active Expired - Lifetime
- 1997-07-29 EP EP97202332A patent/EP0822227B1/en not_active Expired - Lifetime
- 1997-07-30 MX MX9705763A patent/MX9705763A/es unknown
- 1997-07-31 TR TR97/00720A patent/TR199700720A3/tr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2211944A1 (en) | 1998-01-31 |
| EP0822227A1 (en) | 1998-02-04 |
| CN1180081A (zh) | 1998-04-29 |
| TW416971B (en) | 2001-01-01 |
| KR980009376A (ko) | 1998-04-30 |
| MX9705763A (es) | 1998-02-28 |
| BR9705233A (pt) | 1999-06-29 |
| DE69732273T2 (de) | 2005-06-23 |
| EP0822227B1 (en) | 2005-01-19 |
| DE69732273D1 (de) | 2005-02-24 |
| TR199700720A2 (xx) | 1998-02-21 |
| JPH1077382A (ja) | 1998-03-24 |
| TR199700720A3 (tr) | 1998-02-21 |
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