CN115005227A - Insecticidal composition containing albizim alcohol - Google Patents
Insecticidal composition containing albizim alcohol Download PDFInfo
- Publication number
- CN115005227A CN115005227A CN202210867209.2A CN202210867209A CN115005227A CN 115005227 A CN115005227 A CN 115005227A CN 202210867209 A CN202210867209 A CN 202210867209A CN 115005227 A CN115005227 A CN 115005227A
- Authority
- CN
- China
- Prior art keywords
- farnesol
- insecticidal composition
- alcohol
- active ingredients
- composition containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 32
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 16
- CRDAMVZIKSXKFV-FBXUGWQNSA-N (2-cis,6-cis)-farnesol Chemical compound CC(C)=CCC\C(C)=C/CC\C(C)=C/CO CRDAMVZIKSXKFV-FBXUGWQNSA-N 0.000 claims abstract description 35
- 239000000260 (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol Substances 0.000 claims abstract description 34
- 229930002886 farnesol Natural products 0.000 claims abstract description 34
- 229940043259 farnesol Drugs 0.000 claims abstract description 34
- CRDAMVZIKSXKFV-UHFFFAOYSA-N trans-Farnesol Natural products CC(C)=CCCC(C)=CCCC(C)=CCO CRDAMVZIKSXKFV-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000004480 active ingredient Substances 0.000 claims abstract description 13
- HVQHXBNMBZJPLK-UHFFFAOYSA-N 1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-[(2-methylprop-2-en-1-yl)amino]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound CC(=C)CNC1=C([S+]([O-])C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl HVQHXBNMBZJPLK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000005660 Abamectin Substances 0.000 claims abstract description 10
- 241000220433 Albizia Species 0.000 claims abstract description 10
- 239000005925 Pymetrozine Substances 0.000 claims abstract description 10
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 claims abstract description 10
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 claims abstract description 8
- 229950008167 abamectin Drugs 0.000 claims abstract description 8
- 238000013329 compounding Methods 0.000 claims abstract description 8
- 239000002917 insecticide Substances 0.000 claims description 14
- 239000003337 fertilizer Substances 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 4
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 2
- 235000010333 potassium nitrate Nutrition 0.000 claims description 2
- 239000004323 potassium nitrate Substances 0.000 claims description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
- 235000011151 potassium sulphates Nutrition 0.000 claims description 2
- LEZAYTDLNNEFJT-UHFFFAOYSA-N tetracosasodium octaborate tetrahydrate Chemical compound O.O.O.O.[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] LEZAYTDLNNEFJT-UHFFFAOYSA-N 0.000 claims description 2
- 239000004562 water dispersible granule Substances 0.000 claims description 2
- 239000004563 wettable powder Substances 0.000 claims description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 2
- 239000007900 aqueous suspension Substances 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 239000001120 potassium sulphate Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 235000009529 zinc sulphate Nutrition 0.000 claims 1
- 239000011686 zinc sulphate Substances 0.000 claims 1
- 241001124076 Aphididae Species 0.000 abstract description 31
- 239000000575 pesticide Substances 0.000 abstract description 11
- 230000002195 synergetic effect Effects 0.000 abstract description 9
- 241000607479 Yersinia pestis Species 0.000 abstract description 7
- 238000011161 development Methods 0.000 abstract description 6
- 239000013043 chemical agent Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 5
- 230000007246 mechanism Effects 0.000 abstract description 4
- 230000002829 reductive effect Effects 0.000 abstract description 4
- 206010059866 Drug resistance Diseases 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 241000238631 Hexapoda Species 0.000 description 21
- 238000012360 testing method Methods 0.000 description 9
- 241000196324 Embryophyta Species 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 5
- 230000006378 damage Effects 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 231100000820 toxicity test Toxicity 0.000 description 4
- 230000001018 virulence Effects 0.000 description 4
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 3
- 241000238421 Arthropoda Species 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 229960002715 nicotine Drugs 0.000 description 3
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- OGNSCSPNOLGXSM-UHFFFAOYSA-N (+/-)-DABA Natural products NCCC(N)C(O)=O OGNSCSPNOLGXSM-UHFFFAOYSA-N 0.000 description 2
- 241000273311 Aphis spiraecola Species 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000003042 antagnostic effect Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 229930014550 juvenile hormone Natural products 0.000 description 2
- 239000002949 juvenile hormone Substances 0.000 description 2
- 150000003633 juvenile hormone derivatives Chemical class 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 102000012440 Acetylcholinesterase Human genes 0.000 description 1
- 108010022752 Acetylcholinesterase Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241001414720 Cicadellidae Species 0.000 description 1
- 241001442053 Cinnamomum tenuipile Species 0.000 description 1
- 239000005891 Cyromazine Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 241001466042 Fulgoromorpha Species 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 241000500891 Insecta Species 0.000 description 1
- 241001579180 Matthiola longipetala Species 0.000 description 1
- 235000006029 Prunus persica var nucipersica Nutrition 0.000 description 1
- 244000017714 Prunus persica var. nucipersica Species 0.000 description 1
- 241000180219 Sitobion avenae Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 229940022698 acetylcholinesterase Drugs 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 229940124277 aminobutyric acid Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- LVQDKIWDGQRHTE-UHFFFAOYSA-N cyromazine Chemical compound NC1=NC(N)=NC(NC2CC2)=N1 LVQDKIWDGQRHTE-UHFFFAOYSA-N 0.000 description 1
- 229950000775 cyromazine Drugs 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000004634 feeding behavior Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 230000007830 nerve conduction Effects 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 230000001537 neural effect Effects 0.000 description 1
- 239000000447 pesticide residue Substances 0.000 description 1
- 244000000003 plant pathogen Species 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000000611 regression analysis Methods 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 239000013598 vector Substances 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N49/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds containing the group, wherein m+n>=1, both X together may also mean —Y— or a direct carbon-to-carbon bond, and the carbon atoms marked with an asterisk are not part of any ring system other than that which may be formed by the atoms X, the carbon atoms in square brackets being part of any acyclic or cyclic structure, or the group, wherein A means a carbon atom or Y, n>=0, and not more than one of these carbon atoms being a member of the same ring system, e.g. juvenile insect hormones or mimics thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/04—Insecticides
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The invention relates to the technical field of pesticides, and particularly relates to an insecticidal composition containing albizim alcohol. An insecticidal composition containing farnesol is characterized in that the active ingredients of the insecticidal composition are prepared by binary compounding of abamectin, butene-fipronil, cycolxylidin or pymetrozine and farnesol. The insecticidal mechanisms of the albizzia alcohol and other active ingredients in the insecticidal composition are different, and the albizzia alcohol and other active ingredients can effectively delay the generation of drug resistance of pests and prolong the service life of the insecticidal composition when the albizzia alcohol and other active ingredients are compounded for use. In addition, when the active ingredients in the insecticidal composition are compounded, the synergistic effect on aphid control is shown, the aphid control effect can be improved, the use amount of the active ingredients is reduced, and the pest control cost is reduced; meanwhile, the method can provide support for the comprehensive control of aphids and the development of novel chemical agents for controlling the aphids.
Description
Technical Field
The invention relates to the technical field of pesticides, and particularly relates to an insecticidal composition containing albizim alcohol.
Background
Farnesol, english name Farnesol, CAS number: 4602-84-0, molecular formula: c 15 H 26 O, structural formula as follows:
farnesol is the main component of perfume plant farnesol type cinnamomum tenuipilum Kosterm essential oil, has more complex bioactivity on various arthropods, and can influence the development of insects as one of the components of insect juvenile hormone. The combined poisoning effect of farnesol and nicotine on Aphis citricola (Leyss et al, China biological control, 2.2019, 35(1), 37-43) is characterized in that Aphis citricola is used as a test insect, and the combined aphid killing activity of the farnesol and the nicotine is measured, so that the combined aphid killing effect of the farnesol and the nicotine is obvious.
Aphids, otherwise known as greates or nectarines, belong to the class hemiptera of the class insecta of the arthropoda, nearly 5000 species of aphids are known in the world at present, and more than 1000 species are found in China. The aphids have serious harm to plants, and on one hand, the aphids directly harm the plants by sucking plant juice or releasing toxic substances, and influence the normal physiological metabolic activity and growth and development of the plants; on the other hand, aphids are the transmission vectors of plant pathogens, and most of the extremely common viral diseases of plants are transmitted by the aphids, so that the damage of the aphids to the plants is increased.
At present, chemical pesticides still take the main role in aphid control, but long-term application of a single chemical agent can easily cause drug resistance of pests, and can cause a plurality of problems of pesticide residue, environmental pollution and the like. A plurality of aphids, such as the sitobion avenae, have developed resistance to a plurality of chemical pesticides to different degrees.
Compounding the effective components of the pesticide with different action mechanisms is an effective and rapid way for developing new products of the pesticide and preventing and treating resistant plant diseases and insect pests at present. After different pesticide active ingredients are compounded, three action types can be shown: additive, synergistic and antagonistic. The inventor discovers through a large number of indoor tests that the compound of abamectin, butene-fipronil, cyromazine or pymetrozine and farnesol shows synergistic effect on aphid control, and can provide support for comprehensive control of aphid and development of novel chemical agents for controlling aphid.
At present, no relevant reports of relevant compounding exist.
Disclosure of Invention
The invention aims to provide an insecticide composition containing albizim alcohol, which solves the problems existing in the case of using a single chemical agent.
In order to achieve the purpose, the invention provides the following technical scheme:
the first purpose of the invention is to provide an insecticide composition containing albizim alcohol, wherein the active ingredients of the insecticide composition are prepared by binary compounding of abamectin, butene-fipronil, epoxyimidacloprid or pymetrozine and farnesol.
Preferably, the mass ratio of the abamectin to the farnesol is 1-9: 10-1.
Preferably, the mass ratio of the butene-fipronil to the farnesol is 1-25: 5-1.
Preferably, the mass ratio of the cycolazofamid to the farnesol is 1-7: 30-1.
Preferably, the mass ratio of the pymetrozine to the farnesol is 1-15: 3-1.
The second purpose of the invention is to provide an insecticide, which consists of the insecticide composition containing the albizzia alcohol and auxiliary components which are allowable to be added in the aspect of agricultural pharmacy.
Preferably, the mass of the insecticidal composition containing the albizzia alcohol accounts for 0.75-80% of the total mass of the insecticide.
Preferably, the pesticide is in the form of wettable powder, water dispersible granules or suspending agents.
The invention also provides a foliar fertilizer which consists of the pesticide and a water-soluble fertilizer, wherein the water-soluble fertilizer is one or more selected from potassium sulfate, ammonium chloride, potassium nitrate, zinc sulfate and sodium octaborate tetrahydrate.
Compared with the prior art, the invention has the following beneficial effects:
(1) the abamectin in the insecticidal composition interferes with the neurophysiological activity and stimulates the release of gamma-aminobutyric acid, and the aminobutyric acid has an inhibiting effect on the nerve conduction of arthropods;
the action mechanism of the butene-fipronil is to obstruct the chloride metabolism controlled by the gamma-aminobutyric acid of the insect, and the butene-fipronil has high insecticidal activity on pests such as aphids, leafhoppers, plant hoppers and the like;
the epoxy imidacloprid has the function of selectively inhibiting a nicotinic acetylcholinesterase receptor of an insect nervous system, and is a high-efficiency neonicotinoid insecticide;
pymetrozine can specifically block the feeding behavior of insects, so that the insects suffering from pesticide injury stop feeding immediately, and even though the insects can still do exercise, the insects die of hunger due to the irreversible food refusal effect;
farnesol, one of the components of insect juvenile hormone, affects insect development.
As can be seen from the above, the insecticidal mechanisms of the albizzia alcohol and other active ingredients in the insecticidal composition are different, and when the albizzia alcohol and the other active ingredients are compounded for use, the generation of drug resistance of pests can be effectively delayed, and the service life of the insecticidal composition is prolonged.
(2) When the active ingredients in the insecticidal composition are compounded, the synergistic effect is shown on aphid prevention and control, the aphid prevention and control effect can be improved, the use amount of the active ingredients is reduced, and the pest prevention and control cost is reduced; meanwhile, the method can provide support for the comprehensive control of aphids and the development of novel chemical agents for controlling the aphids.
Detailed Description
The present invention will be better understood from the following examples, which are given for illustrative purposes only and should not be construed as limiting the invention as detailed in the claims.
Examples: farnesol-compounded indoor bioactivity test
1. Test subjects: after the sitophila avenae collected from the wheat field in the suburb of Zhengzhou is raised in a laboratory for 6 generations, the healthy wingless adult aphid with consistent insect bodies is selected as a test object.
2. Reagent for testing
92% avermectin active compound (Jiangsu Fengyuan bioengineering Co., Ltd.)
96% butene-fipronil raw material (Dalianjiuxin crop science Co., Ltd.)
95% Oxycycloimidan (Sichuan and Bang Biotech Co., Ltd.)
98% pymetrozine (Shandong province combined pesticide industry Co., Ltd.)
95% farnesol original drug (Shanghai Aladdin Biotechnology GmbH)
Dissolving the raw materials with dimethyl sulfoxide to obtain single-dose mother liquor, diluting with 0.1% Tween-80 aqueous solution, setting multiple groups of ratios, and setting 7 gradient mass concentrations for each single dose and each group of ratios according to equal ratio method.
3. The test method comprises the following steps: (refer to "NY/T1154.6-2006 indoor bioassay Standard for agricultural chemicals insecticide part 6: insect-soaking method for insecticidal Activity test")
Soaking the test insects in the medicinal liquid for 10s, sucking the excessive medicinal liquid with filter paper, transferring to normal condition, feeding, repeating each treatment for 4 times, soaking 20 insects, and setting the treatment containing only 0.1% Tween-80 as blank control. And observing the death condition of the test insects 24h after treatment, respectively recording the total number of the insects and the number of dead insects of each treatment, and calculating the corrected death rate of each treatment according to the total number of the insects and the number of the dead insects.
In the above formula: p- -mortality in%; k- -number of dead insects; n- -total number of treated worms.
In the above formula: p 1 Corrected mortality in%; p t Treatment mortality in%; p 0 Blank mortality in%.
4. And (3) data analysis: using DPS software to perform regression analysis on the log values of each treatment agent concentration and the corrected mortality probability value of each treatment, and calculating LC of each treatment agent 50 And calculating the co-toxicity coefficient (CTC value) of the mixture according to the Sun Yunpei method.
In the above formula: ATI- -the observed virulence index of the combination; s- -LC of Standard drug 50 In mg/L; LC of M-mixtures 50 The unit is mg/L.
TTI＝TI A ×P A +TI B ×P B
In the above formula: TTI- -theoretical toxicological index of the compound; TI A -the virulence index of the agent a; p A -the percentage of agent a in the mixture in units of percentage (%); TI B -virulence index of the B agent; p B The percentage of the agent B in the mixture is given in percentage (%).
In the above formula: CTC-co-toxicity coefficient; ATI- -measured virulence index of the mixture; TTI- -mixture theory virulence index.
5. Evaluation of drug efficacy
And evaluating the synergism of the medicament according to the calculated co-toxicity coefficient (CTC), wherein the CTC is not more than 80 as an antagonistic action, the CTC is more than 80 and less than 120 as an additive action, and the CTC is not less than 120 as a synergistic action, and the results are shown in tables 1-4.
TABLE 1 toxicity test results of compounding abamectin and farnesol on aphids
As can be seen from Table 1, in the range of 1-9: within the mass ratio of 10-1, the co-toxicity coefficient of the abamectin and the farnesol to aphid is more than 120, and the synergistic effect is shown.
TABLE 2 toxicity test results of combinations of butene-fipronil and farnesol on aphids
As can be seen from Table 2, in the range of 1-25: within the mass ratio of 5-1, the co-toxicity coefficient of the butene-fipronil and the farnesol after compounding is more than 120, and the synergistic effect is shown.
TABLE 3 toxicity test results of compounding of Epoxicoline and farnesol on aphid
As can be seen from Table 3, in the range of 1-7: 30-1, the co-toxicity coefficient of the compounded epoxycholine and farnesol to aphid is more than 120, and the synergistic effect is shown.
TABLE 4 toxicity test results of pymetrozine and farnesol compounded on aphids
As can be seen from Table 4, the ratio between 1-15: 3-1, the co-toxicity coefficient of the compounded pymetrozine and farnesol to aphids is more than 120, and the synergistic effect is shown.
The foregoing is only a preferred embodiment of the present invention and modifications, which are within the scope of the invention, will be apparent to those skilled in the art without departing from the principles of the invention.
Claims (9)
1. An insecticidal composition containing farnesol is characterized in that the active ingredients of the insecticidal composition are prepared by binary compounding of abamectin, butene-fipronil, cycolxylidin or pymetrozine and farnesol.
2. The insecticidal composition containing farnesol according to claim 1, wherein the mass ratio of the avermectin to the farnesol is 1-9: 10-1.
3. The insecticidal composition containing farnesol according to claim 1, wherein the mass ratio of butene-fipronil to farnesol is 1-25: 5-1.
4. The insecticidal composition containing farnesol according to claim 1, wherein the mass ratio of cycolcotine to farnesol is 1-7: 30-1.
5. The albizzia alcohol-containing insecticidal composition according to claim 1, wherein the mass ratio of pymetrozine to farnesol is 1-15: 3-1.
6. An insecticide comprising the insecticidal composition containing albizzia alcohol according to claim 1 and an agriculturally pharmaceutically acceptable auxiliary ingredient.
7. The insecticide according to claim 6, wherein the weight of the albizzia alcohol-containing insecticidal composition accounts for 0.75-80% of the total weight of the insecticide.
8. The insecticide according to claim 6, wherein the insecticide is in the form of wettable powder, water dispersible granules or suspension.
9. A foliar fertiliser comprising the insecticide as claimed in claim 6 and a water soluble fertiliser selected from one or more of potassium sulphate, ammonium chloride, potassium nitrate, zinc sulphate and sodium octaborate tetrahydrate.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310942312.3A CN116869016A (en) | 2022-07-21 | 2022-07-21 | Active foliar fertilizer with insecticidal effect |
| CN202210867209.2A CN115005227B (en) | 2022-07-21 | 2022-07-21 | Insecticidal composition containing farnesol |
| CN202310942313.8A CN116918824A (en) | 2022-07-21 | 2022-07-21 | Low-residue high-activity pesticide and foliar fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210867209.2A CN115005227B (en) | 2022-07-21 | 2022-07-21 | Insecticidal composition containing farnesol |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310942313.8A Division CN116918824A (en) | 2022-07-21 | 2022-07-21 | Low-residue high-activity pesticide and foliar fertilizer |
| CN202310942312.3A Division CN116869016A (en) | 2022-07-21 | 2022-07-21 | Active foliar fertilizer with insecticidal effect |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115005227A true CN115005227A (en) | 2022-09-06 |
| CN115005227B CN115005227B (en) | 2023-08-18 |
Family
ID=83079939
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310942313.8A Pending CN116918824A (en) | 2022-07-21 | 2022-07-21 | Low-residue high-activity pesticide and foliar fertilizer |
| CN202310942312.3A Pending CN116869016A (en) | 2022-07-21 | 2022-07-21 | Active foliar fertilizer with insecticidal effect |
| CN202210867209.2A Active CN115005227B (en) | 2022-07-21 | 2022-07-21 | Insecticidal composition containing farnesol |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310942313.8A Pending CN116918824A (en) | 2022-07-21 | 2022-07-21 | Low-residue high-activity pesticide and foliar fertilizer |
| CN202310942312.3A Pending CN116869016A (en) | 2022-07-21 | 2022-07-21 | Active foliar fertilizer with insecticidal effect |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN116918824A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87101769A (en) * | 1986-02-05 | 1987-09-16 | 弗蒙化学品公司 | Acaricidal composition and method for controlling mites |
| CN1125382A (en) * | 1993-04-30 | 1996-06-26 | 特洛伊生物科学公司 | Miticidal composition and method for controlling spider mite populations |
| TW201726662A (en) * | 2015-10-02 | 2017-08-01 | 先正達合夥公司 | Pesticidally active pyrazole derivatives |
| CN108013038A (en) * | 2017-12-28 | 2018-05-11 | 新疆绿洲兴源农业科技有限责任公司 | A kind of nicotine and fanesol complex insecticidal composition, preparation and its application |
-
2022
- 2022-07-21 CN CN202310942313.8A patent/CN116918824A/en active Pending
- 2022-07-21 CN CN202310942312.3A patent/CN116869016A/en active Pending
- 2022-07-21 CN CN202210867209.2A patent/CN115005227B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87101769A (en) * | 1986-02-05 | 1987-09-16 | 弗蒙化学品公司 | Acaricidal composition and method for controlling mites |
| CN1125382A (en) * | 1993-04-30 | 1996-06-26 | 特洛伊生物科学公司 | Miticidal composition and method for controlling spider mite populations |
| TW201726662A (en) * | 2015-10-02 | 2017-08-01 | 先正達合夥公司 | Pesticidally active pyrazole derivatives |
| CN108013038A (en) * | 2017-12-28 | 2018-05-11 | 新疆绿洲兴源农业科技有限责任公司 | A kind of nicotine and fanesol complex insecticidal composition, preparation and its application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN116869016A (en) | 2023-10-13 |
| CN116918824A (en) | 2023-10-24 |
| CN115005227B (en) | 2023-08-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101305723A (en) | Insecticidal composition containing spinosad and its use | |
| CN113068698B (en) | Insecticidal composition for preventing and treating macadimia nut aphids | |
| CN114287450B (en) | Pesticide composition for preventing and treating sugarcane thrips | |
| CN115005227A (en) | Insecticidal composition containing albizim alcohol | |
| CN111084190A (en) | Insecticidal composition containing emamectin benzoate B2a and application thereof | |
| CN113812407B (en) | Insecticidal composition containing bromofenoxaprop-p-fluorobenzene bisamide and tebuconazole and application thereof | |
| CN111226973B (en) | Pesticide synergistic composition for preventing and controlling armyworm | |
| CN113545346B (en) | Synergistic composition for preventing and treating papaya aphids | |
| CN113767923A (en) | Novel chemical agent for preventing and treating tea yellow mites | |
| CN114557354B (en) | Wheat cultivation method | |
| CN101584343B (en) | Metaflumizone and chlorpyrifos mixture insecticide | |
| CN115769821B (en) | Pesticide composition for preventing and controlling wormwood aphids | |
| CN111264545A (en) | Composition for preventing and treating aphids, insecticide and application | |
| CN115005221B (en) | Pesticide composition for preventing and controlling wheat aphids | |
| CN117562057A (en) | Biological-chemical synergistic insecticidal composition | |
| CN107372554A (en) | New and effective cockroach killing bait formula | |
| CN115005226A (en) | Insecticidal composition for preventing and treating corn armyworm | |
| CN117898301A (en) | Pesticide composition for preventing and controlling wormwood aphids | |
| CN106070294B (en) | A kind of composition pesticide of clothianidin-containing and triaguron | |
| CN114342941A (en) | Composition for preventing and treating diseases and insect pests of Chinese herbaceous peony | |
| CN116267954A (en) | Insecticidal and acaricidal composition for preventing and controlling cassava red spiders | |
| CN116982629A (en) | Insecticidal composition, insecticide and application thereof | |
| CN113519536A (en) | Binary compound insecticidal composition | |
| CN116616285A (en) | Pesticide composition for preventing and controlling wheat aphids | |
| CN116548448A (en) | Insecticidal composition and application thereof in prevention and control of green Chinese onion thrips |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |