CN107372554A - Formula of novel high-efficiency cockroach killing bait - Google Patents

Formula of novel high-efficiency cockroach killing bait Download PDF

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Publication number
CN107372554A
CN107372554A CN201710612151.6A CN201710612151A CN107372554A CN 107372554 A CN107372554 A CN 107372554A CN 201710612151 A CN201710612151 A CN 201710612151A CN 107372554 A CN107372554 A CN 107372554A
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CN
China
Prior art keywords
cockroach
sulfluramid
killing bait
arprocarb
cockroach killing
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710612151.6A
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Chinese (zh)
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CN107372554B (en
Inventor
邹继勇
吴智福
谢金兴
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Xiamen Shengweida Industry And Trade Co ltd
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Xiamen Shengweida Industry And Trade Co ltd
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Priority to CN201710612151.6A priority Critical patent/CN107372554B/en
Publication of CN107372554A publication Critical patent/CN107372554A/en
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Publication of CN107372554B publication Critical patent/CN107372554B/en
Expired - Fee Related legal-status Critical Current
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/22O-Aryl or S-Aryl esters thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/002Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
    • A01N25/006Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04Sulfonic acids; Derivatives thereof
    • A01N41/06Sulfonic acid amides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/14Boron; Compounds thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Insects & Arthropods (AREA)
  • Food Science & Technology (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention provides a high-efficiency cockroach killer composition which comprises active ingredients and auxiliary ingredients, wherein the active ingredients comprise propoxur and sulfluramid, and the weight ratio of the propoxur to the sulfluramid is 1:10-10: 1; the percentage content of the active ingredients in the composition is 0.5-1.5%; the balance of auxiliary components.

Description

New and effective cockroach killing bait formula
Technical field
The invention belongs to health pest control field, and in particular to a kind of efficiently cockroach killing bait composition.
Background technology
Health hazard of the blattaria (being commonly called as cockroach) to the mankind is serious, and at present, cockroach has become the city insect of maximum, it By feeding everywhere, creeping spreads disease.Cockroach is the generation of a variety of diseases and propagates root, and it carries yersinia pestis, dysentery 40 multiple pathogens such as bacillus, Escherichia coli, vertebra grey matter fire virus and aspergillus flavus poison, and also contain in its secretion and excrement There are a variety of carcinogens.A kind of grease for having special stench is additionally secreted, is creeped on food and tableware and daily apparatus When leave peculiar smell and multiple pathogens.
Arprocarb(propoxur)It is mainly used in industrial crops control of insect (snout moth's larva, cotten aphid such as on rice, vegetable aphid, tea Orange goitre mite, dendrolimus punctatus etc.) and various sanitary insect pests (such as cockroach, light culex, the blattaria of elimination family and public place Deng), have the characteristics that insecticidal spectrum is wide, residual effect is long, kill rate is high.Arprocarb is also that the World Health Organization (WHO) ratifies and recommended One of domestic hygiene control of insect medicament, but because it is long-term use of, pest resistance to insecticide is than more serious.
Sulfluramid (sulfluramid) is organic fluoride class insecticide, and its mechanism of action is that the breathing for suppressing harmful insect is made With prevention APP produces the ATP with high-energy by oxidative phosphorylation process, so as to cause insect death.Sulfluramid has slow Property virulence property, to social insect such as blattaria, termite or ant, can cause in colony it is secondary, be poisoned three times, so as to Reach the purpose for eliminating whole colony.
It was verified that resistance problem easily occurs in the long-term use of chemical hygiene desinsection single dose, dosage is caused to continue to increase, Risk increase, is unfavorable for Environment Ecological Safe.The active ingredient of different types of structure is compounded, is that the current single dose that solves should Cost and a kind of effective means the problems such as resistance during.At home and abroad also compounded at present without arprocarb and sulfluramid Relevant report.
The content of the invention
To solve technical problem of the prior art, the present invention provides a kind of efficiently cockroach killing bait composition.The skill of offer Art scheme is as follows:
A kind of efficiently cockroach killing bait composition, comprising active component and auxiliary element, active component is by arprocarb and sulfluramid group Into, and the weight proportion of arprocarb and sulfluramid is 1:10-10:1.
Efficiently cockroach killing bait composition of the present invention, the preferably weight proportion of arprocarb and sulfluramid are 2:1-1:5.
The percentage composition of active component in the composition is 0.5- in efficiently cockroach killing bait composition of the present invention 1.5%;Surplus is auxiliary element.
Auxiliary element of the present invention includes:Cockroach attractant 0.01-0.02%, milk powder 25-40%, white sugar 10-25%, glycerine 5- 10%th, sodium carboxymethylcellulose 0.6-0.8%, Tea Saponin 0.2-1%, boric acid 0.1-1%, preservative 0.8-1.2%, water 20-30%, jade Rice starch surplus.
The preparation method of efficiently cockroach killing bait composition of the present invention, it is characterised in that:(1)By carboxymethyl cellulose Sodium and white sugar are added to the water, and stirring is to being completely dissolved;(2)It is equal that stirring is added after glycerine and arprocarb, sulfluramid are well mixed It is even;(3)Surplus stock is added and stirred.
Efficiently cockroach killing bait composition of the present invention is used for the preventing and treating of sanitary insect pest.It is preferred for Groton bug, U.S. The big Lian in continent preventing and treating.
Compared with prior art, the present invention has the advantages that:
Arprocarb and sulfluramid are applied in combination first by the present invention, and composition of the invention has significant synergies, can be with Lower active component usage amount, reduce environmental pollution.Secondly auxiliary element sodium carboxymethylcellulose pyce, Tea Saponin and boric acid are applied in combination Composition can be effectively improved kills cockroach effect.
Embodiment
The embodiment of the present invention is described in detail with reference to embodiment, it is to be understood that the guarantor of the present invention Shield scope is not limited by embodiment.
Assays Example:Arprocarb sulfluramid is compounded to Groton bug indoor biological determination of activity
Subjects:Groton bug adult;Test medicine:Arprocarb single dose, sulfluramid single dose and arprocarb sulfluramid are answered With composition.
Test method:Using topical application method:Active component is diluted with acetone solution, is arranged to according to method of ratio is waited 6 series mass concentration.With carbon dioxide by after Groton bug stunning, the adult that neat and consistent is chosen with writing brush is placed in culture dish In, drop processing is carried out by head by set drug dose concentration, drop is on polypide pronotary, every μ of drop medicament 1.0 L.Groton bug after drop is transferred into raising sight in bio-incubator respectively to look into.Each 15 test worms of processing, 3 repetitions, And the acetone solvent processing without medicament is set as control.Groton bug death condition is investigated after processing after 1d, it is soft by analyzing Part calculates the LC50 of each medicament.The toxicity index and co-toxicity coefficient (CTC) of medicament are calculated according to the abundant methods of Sun Yun.As CTC < 80, then Composition shows as antagonism, and as 80 < CTC < 120, then composition shows as summation action, as CTC > 120, then composition Show as synergistic effect.
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent LC50) × 100
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture in A percentage composition+B medicament toxicity index × mixture B percentage composition
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100.Virulence is surveyed Surely it the results are shown in Table 1.
As shown in Table 1, arprocarb and sulfluramid compounding are 1:20-20:Do not occur antagonism in the range of 1, when residual Prestige and sulfluramid compounding are killed 1:10-10:Synergistic function is shown as in the range of 1.When arprocarb and sulfluramid compounding exist 1:5-2:Notable synergistic effect is shown as in the range of 1.
Example of formulations
Embodiment 1:1% efficient cockroach killing bait composition
Arprocarb 0.5%, sulfluramid 0.5%, cockroach attractant 0.01%, milk powder 25%, white sugar 20%, glycerine 6%, carboxymethyl cellulose Plain sodium 0.6%, Tea Saponin 0.4%, boric acid 1%, preservative 1%, water 20%, cornstarch surplus.
Embodiment 2:0.6% efficient cockroach killing bait composition
Arprocarb 0.2%, sulfluramid 0.4%, cockroach attractant 0.02%, milk powder 30%, white sugar 15%, glycerine 8%, carboxymethyl cellulose Plain sodium 0.7%, Tea Saponin 0.6%, boric acid 0.7%, preservative 1.2%, water 23%, cornstarch surplus.
Embodiment 3:1.5% efficient cockroach killing bait composition
Arprocarb 0.4%, sulfluramid 1.1%, cockroach attractant 0.02%, milk powder 35%, white sugar 12%, glycerine 7%, carboxymethyl cellulose Sodium 0.8%, Tea Saponin 0.8%, boric acid 0.4%, preservative 0.8%, water 25%, cornstarch surplus.
The arprocarb cockroach killing bait composition of comparative example 10.5%
Arprocarb 0.5%, cockroach attractant 0.01%, milk powder 25%, white sugar 20%, glycerine 6%, sodium carboxymethylcellulose 0.6%, tea Saponin 0.4%, boric acid 1%, preservative 1%, water 20%, cornstarch surplus.
The sulfluramid cockroach killing bait composition of comparative example 2 0.5%
Sulfluramid 0.5%, cockroach attractant 0.01%, milk powder 25%, white sugar 20%, glycerine 6%, sodium carboxymethylcellulose 0.6%, tea soap Element 0.4%, boric acid 1%, preservative 1%, water 20%, cornstarch surplus.
Comparative example 3
Arprocarb 0.5%, sulfluramid 0.5%, cockroach attractant 0.01%, milk powder 25%, white sugar 20%, glycerine 6%, carboxymethyl cellulose Plain sodium 1%, boric acid 1%, preservative 1%, water 20%, cornstarch surplus.
Comparative example 4
Arprocarb 0.5%, sulfluramid 0.5%, cockroach attractant 0.01%, milk powder 25%, white sugar 20%, glycerine 6%, Tea Saponin 1%, boron Acid 1%, preservative 1%, water 20%, cornstarch surplus.
Comparative example 5
Arprocarb 0.5%, sulfluramid 0.5%, cockroach attractant 0.01%, milk powder 25%, white sugar 20%, glycerine 6%, carboxymethyl cellulose Plain sodium 1%, Tea Saponin 1%, preservative 1%, water 20%, cornstarch surplus.
Indoor harmacological effect determines
Subjects:Adult bombay canary;Test medicine:Referring to table 2.
Test method:30 adult bombay canaries are respectively put into square chest, several reports to knead are put into square chest Paper (for inhabiting), shuts up the door carefully, stoppers and put worm channel.After test worm recovers normal activity, bait formulation to be measured is placed for one jiao in case, Diagonal to place cockroach feed, center, which is placed, fills immersion cotton balls culture dish.Day by day test worm death condition is observed, experiment repeats 3 It is secondary, and set blank control group
As shown in Table 2, arprocarb is used alone or sulfluramid preventive effect is relatively low, 96 hours America of bait formulation composition prepared by the present invention The big Lian death rates 100%, i.e., with obvious synergistic effect.In addition found by comparative example 1 and comparative example 3-5, methyl is fine Tie up plain sodium, Tea Saponin and boric acid and be applied in combination to improve and kill cockroach effect.
Further narration has been done to the present invention above in conjunction with embodiment, but the present invention is not limited to above-mentioned embodiment, In one skilled in the relevant art's possessed knowledge, it can also be made on the premise of present inventive concept is not departed from Various change.

Claims (7)

1. a kind of efficiently cockroach killing bait composition, it is characterised in that comprising active component and auxiliary element, active component is by massacreing Prestige and sulfluramid composition, and the weight proportion of arprocarb and sulfluramid is 1:10-10:1.
2. efficiently cockroach killing bait composition according to claim 2, it is characterised in that the weight of arprocarb and sulfluramid is matched somebody with somebody Than for 2:1-1:5.
3. efficiently cockroach killing bait composition according to claim 1 or 2, it is characterised in that active component is in the composition Percentage composition be 0.5-1.5%;Surplus is auxiliary element.
4. the efficient cockroach killing bait composition according to claim any one of 1-3, it is characterised in that auxiliary element includes: Cockroach attractant, milk powder, white sugar, glycerine, sodium carboxymethylcellulose, Tea Saponin, boric acid, preservative, cornstarch and water.
5. the preparation method of the efficient cockroach killing bait composition according to any one of claim 4, it is characterised in that:(1)Will Sodium carboxymethylcellulose and white sugar are added to the water, and stirring is to being completely dissolved;(2)Glycerine and arprocarb, sulfluramid are well mixed Add and stir afterwards;(3)Surplus stock is added and stirred.
6. the efficient cockroach killing bait composition according to claim any one of 1-4 is used for the preventing and treating of sanitary insect pest.
7. efficient cockroach killing bait composition according to claim any one of 1-4 be used for Groton bug, American cockroach it is anti- Control.
CN201710612151.6A 2017-07-25 2017-07-25 Formula of novel high-efficiency cockroach killing bait Expired - Fee Related CN107372554B (en)

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CN107372554B CN107372554B (en) 2019-12-13

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111296478A (en) * 2018-12-10 2020-06-19 江苏功成生物科技有限公司 Boric acid-containing insecticidal composition and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1947515A (en) * 2006-11-09 2007-04-18 广东省昆虫研究所 Poison bait for killing Groton bug
CN101507437A (en) * 2009-03-13 2009-08-19 林燕如 Cockroach killing bait
CN102657158A (en) * 2012-05-04 2012-09-12 柳州华力家庭品业股份有限公司 Boxed granular cockroach killing bait and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1947515A (en) * 2006-11-09 2007-04-18 广东省昆虫研究所 Poison bait for killing Groton bug
CN101507437A (en) * 2009-03-13 2009-08-19 林燕如 Cockroach killing bait
CN102657158A (en) * 2012-05-04 2012-09-12 柳州华力家庭品业股份有限公司 Boxed granular cockroach killing bait and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
顾宝根等主编: "《农药生物活性测试标准操作规范-杀虫卷》", 31 August 2016, 化学工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111296478A (en) * 2018-12-10 2020-06-19 江苏功成生物科技有限公司 Boric acid-containing insecticidal composition and application thereof

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Granted publication date: 20191213