CN105454242B - A kind of composition pesticide and application thereof containing nitrile pyrrole mite ester - Google Patents

A kind of composition pesticide and application thereof containing nitrile pyrrole mite ester Download PDF

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CN105454242B
CN105454242B CN201510873430.9A CN201510873430A CN105454242B CN 105454242 B CN105454242 B CN 105454242B CN 201510873430 A CN201510873430 A CN 201510873430A CN 105454242 B CN105454242 B CN 105454242B
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mite ester
nitrile pyrrole
pyrrole mite
fluacrypyrim
composition pesticide
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CN105454242A (en
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孙鹏
赵萍
杜文博
张美翠
罗水凌
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SHAANXI BIAOZHENG CROPS SCIENCE CO Ltd
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SHAANXI BIAOZHENG CROPS SCIENCE CO Ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of composition pesticides and application thereof containing nitrile pyrrole mite ester, comprising: A) the first active constituent nitrile pyrrole mite ester；B) the second active constituent fluacrypyrim；Wherein, it is calculated according to weight ratio, the ratio of the first active constituent and the second active constituent is 20:1 ~ 1:20.This composition can be configured to the wettable powder agriculturally allowed, aqueous emulsion, suspending agent, water dispersible granules, microemulsion.The present composition is preferable to the red spider control efficiency on the crops such as citrus, apple, cotton.Instant component is reasonable, and good disinsection effect, drug cost is low, and active constituent nitrile pyrrole mite ester and fluacrypyrim have significant synergies, quick-acting is high, lasting effect is long, slows down the generation of resistance, preparation less residue, pollution-free to crop, safety is good, meets the security requirement of pesticidal preparations.

Description

A kind of composition pesticide and application thereof containing nitrile pyrrole mite ester
Technical field
The present invention relates to one kind containing nitrile pyrrole mite ester composition pesticide and application thereof, and the composition is with the first active constituent nitrile Allow in pyrrole mite ester and the second active constituent fluacrypyrim and pesticide using auxiliary agent form, for preventing and treating harmful mite agriculturally, It is especially suitable for preventing and treating red spider.
Background technique
Nitrile pyrrole mite ester, the general entitled cyenopyrafen of English.It is a kind of novel pyrazoles acaricide.By being metabolized to OH- form activation, generates activity.By upsetting complexⅱ, (succinic acid is de- on respiratory electron transport chain for this OH- form Hydrogen enzyme) reach the efficiency for inhibiting mitochondria.Higher inhibition is shown to mitochondrial protein complexⅱ after tert-butyl ester hydrolysis Effect hinders electron transmission, destroys oxidative phosphorylation process.It belongs to contact killing type acaricide, anti-with existing acaricide no interactions Property.However, nitrile pyrrole mite ester action site is single, action spectrum relative narrower inevitably generates anti-if long-term single use Property.Can not only drug resistance be delayed to generate by being compounded with other effective insecticidal/acaricidal agents, moreover it is possible to action spectrum is widened, it can Prevention and treatment mite class can prevent and treat part pest again.
Fluacrypyrim, the general entitled fluacrypyrim of English.It is thin that fluacrypyrim is that a kind of mitochondrial inhibitors pass through inhibition Electron transmission between born of the same parents' pigment b and c1 prevents mitochondria from generating ATP, causes cell dead to inhibit the breathing of mitochondria It dies.The medicament is first methoxy acrylic acaricide.With tagging and stomach poison function well, to each of harmful mite Developmental stage, including ovum, deutonymph, adult mite are effective, and quick-acting is good, and the lasting period is up to 30 days or more.
Red spider (Panonychus citriIt Mcg.) is a kind of common pest, main harm Solanaceae, Curcurbitaceae, beans A variety of fruit trees such as the various vegetables such as section, Liliaceae crop and jujube tree, citrus, mainly survive at the leaf back side, pass through pierce-suck type Mouthpart is pierced into blade and sucks juice, destroys chlorophyll, and sallow point or patch is presented in blade, seriously affects the photosynthetic of blade Effect, finally makes leaf abscission, often results in crushing disaster.The method of prevention and treatment red spider is mainly controlled by chemical pesticides at present, Used medicament mainly includes avermectin, pyridaben, flolimat, propargite etc., but mite class fertility is very strong, and long Phase is easy to produce resistance using single medicament.
The pest of resistance is agriculturally generated for preventing and treating, a kind of method is research and development new component.But the exploitation of such method at This height, the period is long, and resistance once occurs, often results in chemical control failure, is forced deactivated or superseded.And exploitation medicament is usual The speed of resistance is all generated less than pest.Other methods such as crop structure adjustment, different pesticide rotations etc., in practical operation During, it is difficult really to play apparent effect.Another effective method is that heterogeneity medicament is compounded.This It is to prevent and treat resistant insect or the very common method of harmful mite.Heterogeneity is compounded, according to the effect of practical application, to judge certain Kind compounding is synergy, adduction or antagonism.Compound synergic is formulated well, due to significantly improving practical control efficiency, is reduced The usage amount of pesticide is the important means of integrated control pest to greatly delay the generation of pest resistance to insecticide.Mesh Before, the combination and application of nitrile pyrrole mite ester and fluacrypyrim has not been reported.
Summary of the invention
The purpose of the present invention is to provide a kind of good disinsection effects, and drug cost is low, are not likely to produce the pesticide group of drug resistance Close object.
Another object of the present invention is to provide purposes of the above-mentioned composition in prevention and treatment red spider.
In order to overcome the defect of existing single component formulations, above-mentioned purpose is realized, the technical scheme is that solving in this way :
A kind of composition pesticide containing nitrile pyrrole mite ester, comprising:
A) the first active constituent nitrile pyrrole mite ester；
B) the second active constituent fluacrypyrim；
Wherein, it is calculated according to weight ratio, the ratio of the first active constituent and the second active constituent is 20:1 ~ 1:20.
Further, it is preferred that the form of the composition pesticide is wettable powder, aqueous emulsion, suspending agent, moisture Shot agent, microemulsion.
Further, it is preferred that calculated according to weight ratio, nitrile pyrrole mite ester 5%, fluacrypyrim 15%, sodium lignin sulfonate 8%, Alkylphenol-polyethenoxy base ether formaldehyde condensation products phosphate 3%, surplus is the mixture of precipitated calcium carbonate, through airslide disintegrating mill It is configured to wettable powder.
Further, it is preferred that being calculated according to weight ratio, nitrile pyrrole mite ester 15%, fluacrypyrim 10%, K12(dodecyl Sodium sulphate) 1.5%, NNO(naphthalene sulfonate) 4%, sodium lignin sulfonate 6%, surplus is kaolin, is configured to through airslide disintegrating mill Wettable powder.
Further, it is preferred that being calculated according to weight ratio, nitrile pyrrole mite ester 10%, fluacrypyrim 10%, dodecyl benzene sulfonic acid Sodium 3%, styrene 1%, sodium carboxymethyl starch 1% are configured to aqueous emulsion after being sufficiently stirred.
Further, it is preferred that being calculated according to weight ratio, nitrile pyrrole mite ester 15%, fluacrypyrim 5%, poly- naphthalene formaldehyde sulfonate Salt 4%, alkylaryl polyoxyethylene polyoxypropylene ether again 2%, xanthan gum 0.2%, sodium benzoate 0.1%, surplus are water, are matched through being sanded Suspending agent is made.
Further, it is preferred that being calculated according to weight ratio, nitrile pyrrole mite ester 12%, fluacrypyrim 28%, the poly- naphthaldehyde sulphur of MF( Acid sodium-salt) 5%, white carbon black 2%, TX-10(nonylphenol polyoxyethylene ether (10EO)) 2%, 20% aqueous emulsion of dimethyl polysiloxane fluid 2%, second Glycol 4%, xanthan gum 0.4%, sodium benzoate 0.1%, surplus are water, are configured to suspending agent through frosted.
Further, it is preferred that being calculated according to weight ratio, 20% nitrile pyrrole mite ester, 10% fluacrypyrim, dodecyl sulphate Sodium 4%, sodium lignin sulfonate 12%, naphthalene sulfonate 8%, urea 15%, kaolin surplus are configured to water dispersible granules.
Further, it is preferred that being calculated according to weight ratio, nitrile pyrrole mite ester 5%, fluacrypyrim 15%, lauryl sodium sulfate (K12) 4%, sodium lignin sulfonate 10%, polycarboxylate 4%, urea 10%, surplus is kaolin, is configured to water dispersible granules.
Further, it is preferred that being calculated according to weight ratio, nitrile pyrrole mite ester 15%, fluacrypyrim 20%, cyclohexanone 6%, isopropyl Alcohol 8%, phenethyl phenol polyoxyethylene poly-oxygen propylene aether 15%, fatty alcohol polyoxyethylene ether 5%, surplus are water, are configured to homogeneous Transparent liquid, is made microemulsion.
Composition pesticide and application thereof above containing nitrile pyrrole mite ester.
Wherein, the preparation formulation that the present composition can be prepared according to method well known to those skilled in the art of the present technique It is wettable powder, aqueous emulsion, suspending agent, water dispersible granules, microemulsion.In addition its purposes, refer mainly to prevention and treatment citrus, apple, Purposes in cotton red spider.
Instant component is reasonable, and good disinsection effect, drug cost is low, and active constituent nitrile pyrrole mite ester and fluacrypyrim have significantly Synergistic effect, quick-acting is high, lasting effect is long, slows down the generation of resistance, preparation less residue, safety pollution-free to crop It is good, meet the security requirement of pesticidal preparations.
Specific embodiment
The content of present invention is described further below with reference to embodiment.
In order to avoid agriculturally generating the red spider of resistance, inventor has carried out phase with ingredients such as nitrile pyrrole mite ester, fluacrypyrims The synergistic effect research mutually compounded.It tests using red spider as test object, method particularly includes:
1) red spider (Panonychus citriMcg.) test medicine nitrile pyrrole mite ester raw medicine uses SUMITOMO CHEMICAL company The raw medicine of production, fluacrypyrim raw medicine use the raw medicine of Tso Tat Co., Ltd., Japan's production.The limited public affairs of positive crop science are marked by Shaanxi Raw medicine is configured to the test medicine needed by research department, department.Test method is referring to " People's Republic of China's agricultural industry criteria NY/T1154.13-2008 farm-chemical indoor determination test rule ".Test worm is that field acquires red spider, (temperature 25 in greenhouse ± 1 DEG C, photoperiod L:D=16:8) it is raised with Citrus leaf, Apple Leaves, cotton leaf to three generations, select growth uniformity Red spider, access put citrus tender leaf, apple tender leaf, cotton tender leaf (with cotton ball moisturizing handle) culture dish (diameter 12 Centimetre) in, every ware connects 20 red spiders, and 5 repetitions are arranged, and it is spraying under 50PSI pressure with potter spray tower, one is sprayed every time A ware, 1 milliliter of every ware spraying liquid are transferred under rearing conditions and raise after medical fluid sedimentation.General each processing setting 6 dense Spend gradient.It checks within 48 hours dead borer population, calculates the death rate.Equivalent clear water is sprayed in blank control.It is united with DPS statistical analysis software Meter analysis, calculates the EC of each medicament50, reagent agent is evaluated to the activity of test worm with this.Co-toxicity coefficient is calculated according to Sun Yunpei's Method (CTC).
The co-toxicity coefficient (CTC value) of mixture is calculated according to the following formula:
In formula:
ATI--- mixture surveys toxicity index；
The EC of S--- standard pesticide agent50, unit is milligrams per liter (mg/L);
The EC of M--- mixture50, unit is milligrams per liter (mg/L)；
TTI=TIA×PA+TIB×PB
In formula:
TTI--- mixtures theoretical toxicity index；
TIA----A medicament toxicity index；
Percentage composition of the PA-----A medicament in mixture, unit are percentage；
TIB----B medicament toxicity index；
Percentage composition of the PB-----B medicament in mixture, unit are percentage.
In formula:
CTC---- co-toxicity coefficient；
ATI--- mixture surveys toxicity index；
TTI--- mixtures theoretical toxicity index.
The co-toxicity coefficient (CTC) >=120 of compounding agent shows as synergistic effect；CTC≤80 show as antagonism；80 < CTC < 120 shows as summation action.
2) measurement result of red spider is shown in Table 1, table 2, table 3 respectively.
Toxicity test result of 1 different disposal of table to citrus red mite
Toxicity test result of 2 different disposal of table to European red mite
Toxicity test result of 3 different disposal of table to cotton red spider
Find out from table 1,2,3, to red spider (apple when nitrile pyrrole mite ester and fluacrypyrim are compounded in the ratio of 20:1 ~ 1:20 Red spider, cotton red spider, citrus red mite) have a higher virulence, and co-toxicity coefficient is all larger than 120, i.e., nitrile pyrrole mite ester with Fluacrypyrim, which compounds (20:1 ~ 1:20), has synergistic effect, wherein matching co-toxicity coefficient highest, synergistic effect in 10:1 ~ 1:10 It is most significant.
For this purpose, the present invention provides a kind of composition pesticides containing nitrile pyrrole mite ester according to the above test, comprising:
A) the first active constituent nitrile pyrrole mite ester；
B) the second active constituent fluacrypyrim；
Wherein, it is calculated according to weight ratio, the ratio of the first active constituent and the second active constituent is 20:1 ~ 1:20.
In order to further appreciate that the invention, it is illustrated below with reference to formulation examples.
Example of formulations 1: 20% nitrile pyrrole mite ester fluacrypyrim wettable powder (weight ratio) of cotton red spider is prevented and treated
It is calculated according to weight ratio, nitrile pyrrole mite ester 5%, fluacrypyrim 15%, sodium lignin sulfonate 8%, SOPA(alkyl phenol polyoxy second Alkene ether formaldehyde condensation products phosphate) 3%, surplus is the mixture of precipitated calcium carbonate, is configured to wettable through airslide disintegrating mill Pulvis.Said preparation prevents and treats cotton red spider by 4000 times of dilutions by spraying, and 72 hours control efficiency are 92.6% after medicine, 10% nitrile pyrrole mite Ester suspending agent (2000 times of liquid of dilution) and 30% fluacrypyrim suspending agent (5000 times of liquid of dilution) are used according to same method, 72 after medicine Hour preventive effect is respectively 82.5% and 83.8%.Within the range of experimental dose, 20% nitrile pyrrole mite ester fluacrypyrim wettable powder is anti- Effect is apparently higher than control single dose medicament.
Formulation examples 2: 25% nitrile pyrrole mite ester fluacrypyrim wettable powder of cotton red spider is prevented and treated
Calculated according to weight ratio, nitrile pyrrole mite ester 15%, fluacrypyrim 10%, K12(lauryl sodium sulfate) 1.5%, NNO(naphthalene Sulfonate) 4%, sodium lignin sulfonate 6%, surplus is kaolin, is configured to wettable powder through airslide disintegrating mill.Said preparation is dilute It releases 5000 times of liquid and prevents and treats cotton red spider by spraying, comparison medicament is 10% nitrile pyrrole mite ester suspending agent (2000 times of liquid of dilution) and 30% Fluacrypyrim suspending agent (dilutes 5000 times of liquid), 72 hours after medicine, the control efficiency of 25% nitrile pyrrole mite ester fluacrypyrim wettable powder Reach 93.6%, is far longer than preventive effect (10% nitrile pyrrole mite ester suspending agent 82.9%, the 30% fluacrypyrim suspending agent of comparison medicament 84.6%).
Example of formulations 3: the 20% nitrile pyrrole mite ester fluacrypyrim aqueous emulsion of citrus red mite is prevented and treated
It is calculated according to weight ratio, nitrile pyrrole mite ester 10%, fluacrypyrim 10%, neopelex 3%, styrene 1%, carboxylic first Base sodium starch 1% is configured to aqueous emulsion after being sufficiently stirred.Said preparation prevents and treats citrus red mite, comparison medicine by 4000 times of dilutions by spraying Agent is 10% nitrile pyrrole mite ester suspending agent (dilution 2000 times of liquid) and 30% fluacrypyrim suspending agent (diluting 5000 times of liquid), and 72 is small after medicine When, the control efficiency of 20% nitrile pyrrole mite ester fluacrypyrim aqueous emulsion reaches 90.12%, 10% nitrile pyrrole mite ester suspending agent of comparison medicament, 30% Fluacrypyrim suspending agent drug effect is respectively 80.2% and 81.3%.
Example of formulations 4: the 20% nitrile pyrrole mite ester fluacrypyrim suspending agent of citrus red mite is prevented and treated
It is calculated according to weight ratio, nitrile pyrrole mite ester 15%, fluacrypyrim 5%, poly- naphthalene formaldehyde sulfonate salt 4%, alkylaryl polyoxy third Alkene polyoxyethylene ether 2%, xanthan gum 0.2%, sodium benzoate 0.1%, surplus are water, are configured to suspending agent through being sanded.Said preparation is pressed 4000 times of dilutions prevent and treat citrus red mite by spraying, and comparison medicament is that 10% nitrile pyrrole mite ester suspending agent (2000 times of liquid of dilution) and 30% are phonetic Mite ester suspending agent (dilutes 5000 times of liquid), and 72 hours after medicine, the control efficiency of 20% nitrile pyrrole mite ester fluacrypyrim suspending agent reaches 92.12%, 10% nitrile pyrrole mite ester suspending agent of comparison medicament, 30% fluacrypyrim suspending agent drug effect are respectively 82.3% and 82.6%.
Formulation examples 5: the 40% nitrile pyrrole mite ester fluacrypyrim suspending agent of citrus red mite is prevented and treated
Calculated according to weight ratio, nitrile pyrrole mite ester 12%, fluacrypyrim 28%, the poly- naphthalene formaldehyde sulfonate salt of MF() 5%, white carbon black 2%, TX-10(nonylphenol polyoxyethylene ether (10EO)) 2%, 20% aqueous emulsion of dimethyl polysiloxane fluid 2%, ethylene glycol 4%, xanthan gum 0.4%, Sodium benzoate 0.1%, surplus are water, are configured to suspending agent through frosted.Said preparation prevents and treats the red spider of citrus by 7000 times of dilutions by spraying Spider, comparison medicament are 10% nitrile pyrrole mite ester suspending agent (dilution 2000 times of liquid) and 30% fluacrypyrim suspending agent (diluting 5000 times of liquid), 72 hours after medicine, the control efficiency of 40% nitrile pyrrole mite ester fluacrypyrim suspending agent reaches 93.6%, and 10% nitrile pyrrole mite ester of comparison medicament is outstanding Floating agent, 30% fluacrypyrim suspending agent drug effect are respectively 82.4% and 83.1%.
Formulation examples 6: the 30% nitrile pyrrole mite ester fluacrypyrim water dispersible granules of European red mite are prevented and treated
It is calculated according to weight ratio, nitrile pyrrole mite ester 20%, fluacrypyrim 10%, lauryl sodium sulfate (K12) 4%, sulfomethylated lignin Sour sodium 12%, naphthalene sulfonate (NNO) 8%, urea 15%, kaolin surplus are configured to water dispersible granules.Said preparation is dilute by 6000 times Spraying prevention and treatment European red mite is released, comparison medicament is that 10% nitrile pyrrole mite ester suspending agent (2000 times of liquid of dilution) and 30% fluacrypyrim suspend Agent (dilutes 5000 times of liquid), and 72 hours after medicine, the control efficiency of 30% nitrile pyrrole mite ester fluacrypyrim water dispersible granules reaches 94.2%, 10% nitrile pyrrole mite ester suspending agent of comparison medicament, 30% fluacrypyrim suspending agent drug effect are respectively 82.6% and 83.4%.
Formulation examples 7: the 20% nitrile pyrrole mite ester fluacrypyrim water dispersible granules of European red mite are prevented and treated
It is calculated according to weight ratio, nitrile pyrrole mite ester 5%, fluacrypyrim 15%, lauryl sodium sulfate (K12) 4%, lignin sulfonic acid Sodium 10%, polycarboxylate 4%, urea 10%, surplus are kaolin, are configured to water dispersible granules.Said preparation is spraying by 4000 times of dilutions European red mite is prevented and treated, comparison medicament is that 10% nitrile pyrrole mite ester suspending agent (2000 times of liquid of dilution) and 30% fluacrypyrim suspending agent are (dilute Release 5000 times of liquid), 72 hours after medicine, the control efficiency of 20% nitrile pyrrole mite ester fluacrypyrim water dispersible granules reaches 93.2%, comparison medicine 10% nitrile pyrrole mite ester suspending agent of agent, 30% fluacrypyrim suspending agent drug effect are respectively 82.6% and 83.4%.
Formulation examples 8: the 35% nitrile pyrrole mite ester fluacrypyrim microemulsion of European red mite is prevented and treated
By weight calculating, nitrile pyrrole mite ester 15%, fluacrypyrim 20%, cyclohexanone 6%, isopropanol 8%, 1601#(phenethyl phenol Polyoxyethylene poly-oxygen propylene aether) 15%, JFC (fatty alcohol polyoxyethylene ether) 5%, surplus is water, is configured to the liquid of homogeneous phase transparent. The formula prevents and treats European red mite by 7000 times of dilutions by spraying, and comparison medicament is (2000 times of the dilution of 10% nitrile pyrrole mite ester suspending agent Liquid) and 30% fluacrypyrim suspending agent (dilution 5000 times of liquid), 72 hours after medicine, the prevention and treatment of 35% nitrile pyrrole mite ester fluacrypyrim microemulsion Effect reaches 94.5%, and 10% nitrile pyrrole mite ester suspending agent of comparison medicament, 30% fluacrypyrim suspending agent drug effect are respectively 81.6% and 82.4%。
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features. All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (12)

1. a kind of composition pesticide containing nitrile pyrrole mite ester characterized by comprising
First active constituent nitrile pyrrole mite ester；
Second active constituent fluacrypyrim；
Wherein, it is calculated according to weight ratio, the ratio of the first active constituent and the second active constituent is 20:1-1:20；
The composition pesticide containing nitrile pyrrole mite ester further includes sodium lignin sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation Object phosphate, precipitated calcium carbonate, lauryl sodium sulfate, NNO, kaolin, neopelex, styrene, carboxymethyl Sodium starch, alkylaryl polyoxyethylene polyoxypropylene ether again, xanthan gum, sodium benzoate, water, poly- naphthalene formaldehyde sulfonate salt, white carbon black, TX-10,20% aqueous emulsion of dimethyl polysiloxane fluid, ethylene glycol, naphthalene sulfonate, urea, polycarboxylate, cyclohexanone, isopropanol, benzene second One of base phenol polyethenoxy polyethenoxy ether and fatty alcohol polyoxyethylene ether or a variety of combinations.
2. the composition pesticide according to claim 1 containing nitrile pyrrole mite ester, which is characterized in that the composition pesticide Form is wettable powder, aqueous emulsion, suspending agent, water dispersible granules, microemulsion.
3. the composition pesticide according to claim 1 or 2 containing nitrile pyrrole mite ester, which is characterized in that according to weight ratio meter It calculates, nitrile pyrrole mite ester 5%, fluacrypyrim 15%, sodium lignin sulfonate 8%, alkylphenol-polyethenoxy base ether formaldehyde condensation products phosphate 3%, surplus is the mixture of precipitated calcium carbonate, is configured to wettable powder through airslide disintegrating mill.
4. the composition pesticide according to claim 1 or 2 containing nitrile pyrrole mite ester, which is characterized in that according to weight ratio meter It calculates, nitrile pyrrole mite ester 15%, fluacrypyrim 10%, lauryl sodium sulfate 1.5%, NNO4%, sodium lignin sulfonate 6%, surplus is Kaolin is configured to wettable powder through airslide disintegrating mill.
5. the composition pesticide according to claim 1 or 2 containing nitrile pyrrole mite ester, which is characterized in that according to weight ratio meter It calculates, nitrile pyrrole mite ester 10%, fluacrypyrim 10%, neopelex 3%, styrene 1%, sodium carboxymethyl starch 1%, surplus For water, aqueous emulsion is configured to after being sufficiently stirred.
6. the composition pesticide according to claim 1 or 2 containing nitrile pyrrole mite ester, which is characterized in that according to weight ratio meter It calculates, nitrile pyrrole mite ester 15%, fluacrypyrim 5%, poly- naphthalene formaldehyde sulfonate salt 4%, alkylaryl polyoxyethylene polyoxypropylene ether again 2%, Xanthan gum 0.2%, sodium benzoate 0.1%, surplus are water, are configured to suspending agent through being sanded.
7. the composition pesticide according to claim 1 or 2 containing nitrile pyrrole mite ester, which is characterized in that according to weight ratio meter It calculates, nitrile pyrrole mite ester 12%, fluacrypyrim 28%, poly- naphthalene formaldehyde sulfonate salt 5%, the poly- diformazan of white carbon black 2%, TX-102%, 20% Radical siloxane lotion 2%, ethylene glycol 4%, xanthan gum 0.4%, sodium benzoate 0.1%, surplus are water, are configured to hang through frosted Floating agent.
8. the composition pesticide according to claim 1 or 2 containing nitrile pyrrole mite ester, which is characterized in that according to weight ratio meter It calculates, nitrile pyrrole mite ester 20%, fluacrypyrim 10%, lauryl sodium sulfate 4%, sodium lignin sulfonate 12%, naphthalene sulfonate 8%, urine Element 15%, kaolin surplus is configured to water dispersible granules.
9. the composition pesticide according to claim 1 or 2 containing nitrile pyrrole mite ester, which is characterized in that according to weight ratio meter It calculates, nitrile pyrrole mite ester 5%, fluacrypyrim 15%, lauryl sodium sulfate 4%, sodium lignin sulfonate 10%, polycarboxylate 4%, urea 10%, surplus is kaolin, is configured to water dispersible granules.
10. the composition pesticide according to claim 1 or 2 containing nitrile pyrrole mite ester, which is characterized in that according to weight ratio meter It calculates, nitrile pyrrole mite ester 15%, fluacrypyrim 20%, cyclohexanone 6%, isopropanol 8%, phenethyl phenol polyoxyethylene poly-oxygen propylene aether 15%, fatty alcohol polyoxyethylene ether 5%, surplus is water, is configured to the liquid of homogeneous phase transparent.
11. purposes of the composition pesticide in prevention and treatment red spider as claimed in claim 1 or 2 containing nitrile pyrrole mite ester.
12. a kind of composition pesticide containing nitrile pyrrole mite ester such as according to claim 10 is in prevention and treatment citrus, apple or cotton The purposes for the red spider taken.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008009379A2 (en) * 2006-07-18 2008-01-24 Bayer Cropscience Ag Active ingredient combinations having insecticide and acaricide properties
CN104663693A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Composition containing pyriminostrobin and application of composition
CN104663670A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Synergistic miticidal composition
CN105766925A (en) * 2014-12-25 2016-07-20 中化农化有限公司 Pesticide composition comprising cyenopyrafen, and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008009379A2 (en) * 2006-07-18 2008-01-24 Bayer Cropscience Ag Active ingredient combinations having insecticide and acaricide properties
CN104663693A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Composition containing pyriminostrobin and application of composition
CN104663670A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Synergistic miticidal composition
CN105766925A (en) * 2014-12-25 2016-07-20 中化农化有限公司 Pesticide composition comprising cyenopyrafen, and application thereof

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