CN114994422A - Hydrogen natural emptying and electrostatic safety monitoring mutual feedback reaction protection system - Google Patents

Hydrogen natural emptying and electrostatic safety monitoring mutual feedback reaction protection system Download PDF

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CN114994422A
CN114994422A CN202210609041.5A CN202210609041A CN114994422A CN 114994422 A CN114994422 A CN 114994422A CN 202210609041 A CN202210609041 A CN 202210609041A CN 114994422 A CN114994422 A CN 114994422A
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venting
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hydrogen
pipe
nitrogen
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CN114994422B (en
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蒲亮
何永琛
代明昊
严童童
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Xian Jiaotong University
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R29/00Arrangements for measuring or indicating electric quantities not covered by groups G01R19/00 - G01R27/00
    • G01R29/24Arrangements for measuring quantities of charge
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J5/00Radiation pyrometry, e.g. infrared or optical thermometry
    • G01J5/48Thermography; Techniques using wholly visual means
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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    • Y02P90/45Hydrogen technologies in production processes

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Abstract

The invention relates to the technical field of hydrogen natural emptying safety processing, in particular to a hydrogen natural emptying and static safety monitoring mutual feedback reaction protection system which comprises a hydrogen storage and transportation device, a nitrogen containing grid, an emptying system air inlet pipe, a hydrogen emptying pipe main body, a static measurement system, an infrared camera, a computer and a signal acquisition system. According to the invention, by monitoring the state parameters and the static accumulation behavior of the emptying pipe during irregular emptying operation and combining a computer and a signal acquisition system, a safety mutual feedback protection system is formed, so that the aims of ensuring the normal operation of the emptying system and providing hazard early warning information are fulfilled, and powerful reference is provided for the safety mutual feedback protection of various hydrogen emptying implementation scenes.

Description

一种氢气自然放空与静电安全监测互馈反应防护系统A mutual feedback reaction protection system for hydrogen natural venting and electrostatic safety monitoring

技术领域technical field

本发明涉及氢气自然放空安全处理技术领域,特别涉及一种氢气自然放空与静电安全监测互馈反应防护系统。The invention relates to the technical field of hydrogen natural venting safety treatment, in particular to a mutual feedback reaction protection system for hydrogen natural venting and electrostatic safety monitoring.

背景技术Background technique

氢能以其能量转化率高、使用过程环境友好、无碳排放等特点在交通运输、分布式发电等诸多领域广泛应用,对于实现“碳达峰”、“碳中和”目标有着至关重要的作用。随着我国氢应用技术领域的快速发展,氢气储运量及储运压力越来越高,氢气自然放空系统作为氢能储运链安全设施的重要组成部分,其安全性需重点考虑。在进行氢气自然放空作业时,会经常出现摩擦、碰撞、剥离等行为,导致静电电荷不断产生并积累甚至放电,容易发生氢气意外自燃并造成放空装置火焰入侵,对自然放空系统及上游制氢、储氢设施装置构成潜在危险。Hydrogen energy is widely used in many fields such as transportation and distributed power generation due to its high energy conversion rate, environmentally friendly use process, and no carbon emissions. effect. With the rapid development of my country's hydrogen application technology, the hydrogen storage and transportation volume and storage and transportation pressure are getting higher and higher. During the natural venting of hydrogen, behaviors such as friction, collision and peeling will often occur, resulting in the continuous generation, accumulation and even discharge of electrostatic charges, which is prone to accidental spontaneous combustion of hydrogen and flame intrusion of the venting device. Hydrogen storage facilities pose a potential hazard.

目前,氢气放空作业通常具有间歇性、不稳定、非连续等特点,使得氢气自然放空系统无法精确监测放空设施在放空作业过程中的工作状态,不能及时的处理放空系统失效问题。另外,传统的放空设备一般只设置了基本的安全设施,没有将各种复杂放空条件下的状态参数及静电累积行为联系起来,无法从根本上高效解决放空系统静电累积行为造成的氢气自燃甚至爆炸事故。At present, hydrogen venting operations are usually intermittent, unstable, and discontinuous, so that the natural hydrogen venting system cannot accurately monitor the working status of venting facilities during the venting operation, and cannot deal with the failure of the venting system in time. In addition, the traditional venting equipment is generally only equipped with basic safety facilities, and does not link the state parameters and electrostatic accumulation behavior under various complex venting conditions, and cannot fundamentally and efficiently solve the hydrogen spontaneous combustion or even explosion caused by the electrostatic accumulation behavior of the venting system. ACCIDENT.

发明内容SUMMARY OF THE INVENTION

针对上述存在问题,本发明旨在提供一种氢气自然放空与静电安全监测互馈反应防护系统,能够根据氢气自然放空状态调整系统防护措施并在线监测静电累积行为,以解决放空作业过程中的静电及意外燃爆安全问题。In view of the above problems, the present invention aims to provide a mutual feedback reaction protection system for hydrogen natural venting and electrostatic safety monitoring, which can adjust system protection measures according to the natural hydrogen venting state and monitor static electricity accumulation behavior online, so as to solve the static electricity in the venting process. and accidental explosion safety issues.

为实现上述目的,本发明采取如下技术方案:To achieve the above object, the present invention adopts the following technical solutions:

一种氢气自然放空与静电安全监测互馈反应防护系统,包括氢储运装置、氮气集装格、氢气放空管主体、静电测量系统、所述红外摄像仪以及计算机及信号采集系统;A hydrogen natural venting and electrostatic safety monitoring mutual feedback reaction protection system, comprising a hydrogen storage and transportation device, a nitrogen container, a hydrogen venting pipe main body, an electrostatic measurement system, the infrared camera, a computer and a signal acquisition system;

所述氢储运装置和所述氮气集装格分别通过所述氢气流路管道和所述氮气流路管道与所述放空系统进气管连接,所述放空系统进气管上设有缓冲罐和阻火器;所述放空系统进气管末端连接放空管主体底部;The hydrogen storage and transportation device and the nitrogen container are respectively connected to the air intake pipe of the venting system through the hydrogen flow channel pipeline and the nitrogen gas flow channel pipeline, and a buffer tank and a damper are arranged on the air intake pipe of the venting system. Firearm; the end of the air intake pipe of the venting system is connected to the bottom of the main body of the venting pipe;

放空管主体包括分子密封器、放空管排放口和检测单元一,所述检测单元一用于监测放空作业过程中的放空状态,经数据传输导线将放空状态反馈给计算机及数据采集系统,当氢气放空作业存在间歇性、不连续放空时,由计算机及信号采集系统立即发出指令,控制氮气流路管道上的流量调节阀和电磁阀,经氮气流路支路注入分子密封器,所述分子密封器用氮气分子作为密封填料,起到密封和防止空气进入放空系统的作用;The main body of the venting tube includes a molecular sealer, a venting tube discharge port and a detection unit 1. The detection unit 1 is used to monitor the venting state during the venting operation, and the venting state is fed back to the computer and the data acquisition system through the data transmission wire. When there is intermittent and discontinuous venting in the hydrogen venting operation, the computer and the signal acquisition system will immediately issue instructions to control the flow regulating valve and solenoid valve on the nitrogen flow path, and inject the molecular sealer through the nitrogen flow path branch. Molecular sealers use nitrogen molecules as sealing fillers to seal and prevent air from entering the venting system;

所述静电测量系统包括管内静电传感器、静电传输导线、静电信号调理板和管外静电传感器,所述三个管内静电传感器均设置在氢气排放管主体中,分别由下至上布置于放空系统进气管与氢气排放管主体连接处、分子密封器下端、分子密封器上端与放空管排气口连接处,所述管外静电传感器设置在放空管排气口出口上方,用于监测放空管排气口出口处静电累积行为,所述管内静电传感器和管外静电传感器均通过静电传输导线分别与静电信号调理板连接,以便于静电测量及后续安全处理;静电信号调理板通过数据传输导线与计算机及信号采集系统连接,对静电感应信号进行实时采集并存储、处理,同时结合氢气放空状态,分析放空管不规律放空作业时的静电累积行为;The electrostatic measurement system includes an electrostatic sensor in the tube, an electrostatic transmission wire, an electrostatic signal conditioning board and an electrostatic sensor outside the tube. The three electrostatic sensors in the tube are all arranged in the main body of the hydrogen discharge pipe, and are respectively arranged in the air intake pipe of the venting system from bottom to top. The connection with the main body of the hydrogen discharge pipe, the lower end of the molecular sealer, and the connection between the upper end of the molecular sealer and the exhaust port of the venting pipe, the electrostatic sensor outside the pipe is arranged above the exhaust port of the venting pipe, and is used for monitoring the venting pipe. The electrostatic accumulation behavior at the outlet of the exhaust port, the electrostatic sensor in the pipe and the electrostatic sensor outside the pipe are connected to the electrostatic signal conditioning board respectively through the electrostatic transmission wire, so as to facilitate electrostatic measurement and subsequent safe processing; the electrostatic signal conditioning board is connected to the electrostatic signal conditioning board through the data transmission wire. The computer is connected with the signal acquisition system to collect, store, and process the electrostatic induction signal in real time. At the same time, combined with the hydrogen venting state, analyze the electrostatic accumulation behavior of the venting pipe during irregular venting operations;

所述红外摄像仪布置在放空管排气口一侧,并与所述计算机集信号采集系统连接,用于监测放空系统外异常点火情况。The infrared camera is arranged on one side of the exhaust port of the venting pipe, and is connected to the computer collecting signal collection system for monitoring abnormal ignition conditions outside the venting system.

本发明进一步的改进在于,所述氢气流路管道设有减压阀和调节阀。A further improvement of the present invention is that the hydrogen flow pipeline is provided with a pressure reducing valve and a regulating valve.

本发明进一步的改进在于,所述缓冲罐末端设有超压泄放管并布置了爆破片,防止因压力失衡造成的系统损害。A further improvement of the present invention is that an overpressure relief pipe and a bursting disc are arranged at the end of the buffer tank to prevent system damage caused by pressure imbalance.

本发明进一步的改进在于,所述阻火器用于防止由于火焰入侵对自然放空系统及上游氢储运设施装置构成潜在危险。A further improvement of the present invention is that the flame arrester is used to prevent potential danger to the natural venting system and the upstream hydrogen storage and transportation facility due to flame intrusion.

本发明进一步的改进在于,所述氮气集装格由多个商业氮气钢瓶组成,高压氮气瓶压力为12.5MPa,采用立式或卧式组装,用于提供惰性保护气体。A further improvement of the present invention is that the nitrogen container is composed of a plurality of commercial nitrogen cylinders, and the pressure of the high-pressure nitrogen cylinder is 12.5MPa, which is assembled vertically or horizontally to provide inert protective gas.

本发明进一步的改进在于,管内静电传感器为环形非接触式静电传感器,镶嵌于放空管主体内侧并保证管道内壁光滑。A further improvement of the present invention is that the electrostatic sensor in the tube is a ring-shaped non-contact electrostatic sensor, which is embedded in the inner side of the main body of the venting tube and ensures the smooth inner wall of the pipeline.

本发明进一步的改进在于,所述静电信号调理板下端与支撑架杆及静电接地装置连接,能够及时将经过转化、滤波、放大后的静电感应电荷通过静电接地装置安全释放。A further improvement of the present invention is that the lower end of the electrostatic signal conditioning plate is connected to the support frame rod and the electrostatic grounding device, which can safely release the electrostatically induced charges after conversion, filtering and amplification through the electrostatic grounding device in time.

本发明进一步的改进在于,支撑架杆及静电接地装置上端设有检测单元二,用于氢气放空后放空环境安全监测,经数据传输导线将放空状态反馈给计算机及数据采集系统,当氢气放空至系统外部环境出现氢气异常聚集现象时,由计算机及信号采集系统立即发出指令,控制氮气吹扫系统保护放空系统及上游设备装置,并根据实际情况暂停放空作业,避免危险状态进一步扩大。A further improvement of the present invention is that the upper end of the support frame rod and the electrostatic grounding device is provided with a detection unit 2, which is used for the safety monitoring of the venting environment after the hydrogen is vented, and the venting state is fed back to the computer and the data acquisition system through the data transmission wire. When abnormal accumulation of hydrogen occurs in the external environment of the system, the computer and the signal acquisition system will immediately issue instructions to control the nitrogen purging system to protect the venting system and upstream equipment, and suspend the venting operation according to the actual situation to avoid further expansion of the dangerous state.

本发明进一步的改进在于,所述计算机及信号采集系统负责采集检测单元一、检测单元二相关检测元件的数据监测信息,进一步控制氮气吹扫系统保护放空系统及上游设备装置;在不同放空条件下采集静电测量系统的静电累积行为。A further improvement of the present invention is that the computer and the signal acquisition system are responsible for collecting the data monitoring information of the relevant detection elements of the detection unit 1 and the detection unit 2, and further control the nitrogen purging system to protect the venting system and upstream equipment; under different venting conditions Collect the electrostatic accumulation behavior of the electrostatic measurement system.

本发明至少具有如下有益的技术效果:The present invention at least has the following beneficial technical effects:

本发明利用检测单元和拍摄装置实时监测放空管状态参数,通过静电测量系统对放空管静电感应电荷进行捕集并测量。将上述关键信息及时反馈至计算机及信号采集系统并有效控制氮气吹扫保护气注入放空系统,有效解决了放空系统因浓度异常、意外点火、间歇放空、空气回流导致系统失效的难题。The invention utilizes the detection unit and the photographing device to monitor the state parameters of the venting tube in real time, and captures and measures the electrostatically induced charge of the venting tube through an electrostatic measurement system. Feedback the above key information to the computer and signal acquisition system in time and effectively control the injection of nitrogen purging and protective gas into the venting system, effectively solving the problem of system failure caused by abnormal concentration, accidental ignition, intermittent venting, and air backflow in the venting system.

本发明静电检测装置能够及时将捕集到的静电电荷传导至静电信号调理板,以电子信号的方式反馈至计算机及信号采集系统,并通过支撑架杆及静电接地装置将静电电荷安全释放。The electrostatic detection device of the invention can conduct the captured electrostatic charge to the electrostatic signal conditioning board in time, feed it back to the computer and the signal acquisition system in the form of an electronic signal, and safely release the electrostatic charge through the support rod and the electrostatic grounding device.

本发明计算机系信号采集系统可对放空状态参数以及静电感应信号进行存储、处理,结合不同条件下的氢气放空状态,分析放空管不规律作业时的放空状态参数以及静电累积行为,为各类可燃气体放空实施场景的安全互馈防护提供有力参考。The signal acquisition system of the computer system of the present invention can store and process the venting state parameters and electrostatic induction signals, and analyze the venting state parameters and electrostatic accumulation behavior of the venting pipe during irregular operation in combination with the hydrogen venting state under different conditions. Provides a strong reference for the safety mutual feed protection of gas venting implementation scenarios.

附图说明Description of drawings

图1为本发明公开的氢气放空与静电安全监测互馈反应防护系统示意图。FIG. 1 is a schematic diagram of a mutual feedback reaction protection system for hydrogen venting and electrostatic safety monitoring disclosed in the present invention.

附图标记说明:Description of reference numbers:

1-氢储运装置;11-氢气流路管道;12-减压阀;13-调节阀;1-Hydrogen storage and transportation device; 11-Hydrogen flow pipeline; 12-Reducing valve; 13-Regulating valve;

2-氮气集装格;21-氮气流路管道;22-止回阀;23-流量调节阀;24-电磁阀;25-氮气流路支路一;26-氮气流路支路二;2-nitrogen container; 21-nitrogen flow pipeline; 22-check valve; 23-flow regulating valve; 24-solenoid valve; 25-nitrogen flow branch 1; 26-nitrogen flow branch 2;

3-放空系统进气管;31-阻火器;3- Vent system intake pipe; 31- Flame arrester;

4-缓冲罐;41-超压泄放管;42-爆破片;4-buffer tank; 41-overpressure relief pipe; 42-bursting disc;

5-氢气放空管主体;51-放空管基座;52-分子密封器;53-放空管排气口;54-检测单元一;55-检测单元二;5-Hydrogen venting tube main body; 51-Venting tube base; 52-Molecular sealer; 53-Venting tube exhaust port; 54-Detection unit 1; 55-Detection unit 2;

6-静电测量系统;61-管内静电传感器;62-静电传输导线;63-静电信号调理板;64-管外静电传感器;65-支撑架杆及静电接地装置;6-Electrostatic measurement system; 61-Electrostatic sensor inside the pipe; 62-Electrostatic transmission wire; 63-Electrostatic signal conditioning board; 64-Electrostatic sensor outside the pipe; 65-Support frame rod and electrostatic grounding device;

7-红外摄像仪;7- Infrared camera;

8-计算机及信号采集系统;81-报警单元一;82-报警单元二。8-computer and signal acquisition system; 81-alarm unit one; 82-alarm unit two.

具体实施方式Detailed ways

下面结合附图和具体实施例对本发明的技术方案做进一步描述。The technical solutions of the present invention will be further described below with reference to the accompanying drawings and specific embodiments.

如附图1所示,本发明提供的一种氢气自然放空与静电安全监测互馈反应防护系统,包括氢储运装置1、氮气集装格2、放空系统进气管3、超压泄放管41、氢气放空管主体5、检测单元一54和检测单元二55、静电测量系统6、红外摄像仪7、计算机及数据采集系统8以及报警单元,所述氢储运装置1和所述氮气集装格2分别通过所述氢气流路管道11和所述氮气流路管道21与所述放空系统进气管3连接,实施氢气放空前需进行氮气吹扫作业。所述放空系统进气管3上设有缓冲罐4和阻火器31。所述氢气流路管道11上设有减压阀12和调节阀13。氮气流路管道21上设有减压阀12、止回阀22、流量调节阀23和电磁阀24,之后氮气流路管道21分设氮气流路支路一25和氮气流路支路二26,所述氮气流路支路一25连接所述分子密封器52,所述氮气流路支路二26连接放空系统进气管3,并设有调节阀.As shown in accompanying drawing 1, a kind of hydrogen natural venting and electrostatic safety monitoring mutual feedback reaction protection system provided by the present invention includes hydrogen storage and transportation device 1, nitrogen container compartment 2, venting system intake pipe 3, overpressure relief pipe 41. The main body of the hydrogen venting pipe 5, the first detection unit 54 and the second detection unit 55, the electrostatic measurement system 6, the infrared camera 7, the computer and the data acquisition system 8 and the alarm unit, the hydrogen storage and transportation device 1 and the nitrogen gas The container 2 is connected to the air inlet pipe 3 of the venting system through the hydrogen flow pipeline 11 and the nitrogen flow pipeline 21, respectively, and nitrogen purging operation is required before carrying out hydrogen venting. The air intake pipe 3 of the venting system is provided with a buffer tank 4 and a flame arrester 31 . The hydrogen flow pipeline 11 is provided with a pressure reducing valve 12 and a regulating valve 13 . The nitrogen flow pipeline 21 is provided with a pressure reducing valve 12, a check valve 22, a flow regulating valve 23 and a solenoid valve 24, and then the nitrogen flow pipeline 21 is divided into a nitrogen flow branch one 25 and a nitrogen flow branch two 26, The nitrogen flow path branch one 25 is connected to the molecular sealer 52, and the nitrogen flow path branch two 26 is connected to the air inlet pipe 3 of the venting system, and is provided with a regulating valve.

所述缓冲罐4末端设有超压泄放管41并布置了爆破片42,防止因压力失衡造成的系统损害。An overpressure relief pipe 41 and a bursting disc 42 are arranged at the end of the buffer tank 4 to prevent system damage caused by pressure imbalance.

所述阻火器31用于防止由于火焰入侵对自然放空系统及上游氢储运设施装置构成潜在危险。The flame arrester 31 is used to prevent potential danger to the natural venting system and upstream hydrogen storage and transportation facilities due to flame intrusion.

所述氢储运装置1涉及的放空作业可以为多个实施场景,例如:加氢站储氢罐维护、制氢场所放空、氢运输管道维护、氢储运装置预冷后放空等场景。The venting operations involved in the hydrogen storage and transportation device 1 can be implemented in multiple scenarios, such as: maintenance of hydrogen storage tanks at hydrogen refueling stations, venting of hydrogen production sites, maintenance of hydrogen transportation pipelines, and venting of hydrogen storage and transportation devices after pre-cooling.

所述氮气集装格2由多个商业氮气钢瓶组成,高压氮气瓶压力为12.5MPa,采用立式或卧式组装,提供惰性保护气体。The nitrogen container 2 is composed of a plurality of commercial nitrogen cylinders, and the pressure of the high-pressure nitrogen cylinder is 12.5MPa, which is assembled vertically or horizontally, and provides inert protective gas.

所述放空系统进气管3末端连接放空管主体5底部,所述放空管主体5包括分子密封器52、放空管排放口53和检测单元一54,所述检测单元一54由温度传感器、压力传感器和流量传感器等元器件构成,用于监测放空作业过程中的放空状态,经数据传输导线将放空状态反馈给计算机及数据采集系统8,当氢气放空作业存在间歇性、不连续放空时,报警单元一81闪烁并发出警报声,由计算机及信号采集系统8立即发出指令,控制氮气流路管道21上的流量调节阀23和电磁阀24,经氮气流路支路25注入分子密封器52,所述分子密封器52用氮气分子作为密封填料,起到密封和防止空气进入放空系统的作用。The end of the air inlet pipe 3 of the venting system is connected to the bottom of the venting pipe main body 5, and the venting pipe main body 5 includes a molecular sealer 52, a venting pipe discharge port 53 and a detection unit 1 54, and the detection unit 1 54 is composed of a temperature sensor. It is composed of components such as pressure sensor and flow sensor, which are used to monitor the venting state during the venting operation. The venting state is fed back to the computer and data acquisition system through the data transmission wire. When the hydrogen venting operation has intermittent and discontinuous venting , the alarm unit 1 81 flashes and an alarm sound is issued, and the computer and the signal acquisition system 8 immediately issue instructions to control the flow regulating valve 23 and the solenoid valve 24 on the nitrogen flow path pipeline 21, and inject the molecular sealer through the nitrogen flow path branch 25. 52. The molecular sealer 52 uses nitrogen molecules as a sealing filler to seal and prevent air from entering the venting system.

所述静电测量系统6包括管内静电传感器61、静电传输导线62、静电信号调理板63、管外静电传感器64和支撑架杆及静电接地装置65,所述三个管内静电传感器61均设置在氢气排放管主体5中,分别由下至上布置于放空系统进气管3与氢气排放管主体5连接处、分子密封器52下端、分子密封器52上端与放空管排气口53连接处,管内静电传感器61为环形非接触式静电传感器,镶嵌于放空管主体5内侧并保证管道内壁光滑,所述管外静电传感器64设置在放空管排气口53出口上方,用于监测放空管排气口53出口处静电累积行为,所述管内静电传感器61和管外静电传感器64均通过静电传输导线62分别与静电信号调理板63连接,以便于静电测量及后续安全处理。The electrostatic measurement system 6 includes an electrostatic sensor 61 in the tube, an electrostatic transmission wire 62, an electrostatic signal conditioning board 63, an electrostatic sensor 64 outside the tube, a support frame rod and an electrostatic grounding device 65. In the main body 5 of the discharge pipe, they are arranged from bottom to top at the connection between the intake pipe 3 of the venting system and the main body 5 of the hydrogen discharge pipe, the lower end of the molecular sealer 52, and the connection between the upper end of the molecular sealer 52 and the exhaust port 53 of the venting pipe. The sensor 61 is an annular non-contact electrostatic sensor, which is embedded in the inner side of the venting pipe body 5 and ensures that the inner wall of the pipe is smooth. The electrostatic accumulation behavior at the outlet of the air port 53, the electrostatic sensor 61 in the tube and the electrostatic sensor 64 outside the tube are connected to the electrostatic signal conditioning board 63 through the electrostatic transmission wire 62 respectively, so as to facilitate electrostatic measurement and subsequent safe processing.

所述静电传输导线62采用铜导线,两端连接静电传感器与静电信号调理板63,保证静电信号调理板63接收到的感应电荷是与静电传感器测量到的感应电荷数据是一致的。The electrostatic transmission wire 62 is a copper wire, and the two ends are connected to the electrostatic sensor and the electrostatic signal conditioning board 63 to ensure that the induced charge received by the electrostatic signal conditioning board 63 is consistent with the induced charge data measured by the electrostatic sensor.

所述静电信号调理板63为圆盘状面板,可对静电信号进行滤波、放大处理,通过数据传输导线与计算机及信号采集系统8连接,对静电感应信号进行实时采集并存储、处理,可以结合氢气放空状态,分析放空管不规律放空作业时的静电累积行为。The electrostatic signal conditioning plate 63 is a disc-shaped panel, which can filter and amplify the electrostatic signal, and is connected to the computer and the signal acquisition system 8 through a data transmission wire to collect, store and process the electrostatic induction signal in real time, which can be combined with hydrogen gas. In the emptying state, the electrostatic accumulation behavior of the emptying pipe during irregular emptying operation is analyzed.

所述支撑架杆及静电接地装置65主要有支撑固定静电信号调理板63的作用,并设置了静电接地保护装置。The supporting frame rod and the electrostatic grounding device 65 mainly have the function of supporting and fixing the electrostatic signal conditioning plate 63, and are provided with an electrostatic grounding protection device.

所述静电信号调理板63下端与支撑架杆及静电接地装置65连接,可及时将经过转化、滤波、放大后的静电感应电荷通过静电接地装置安全释放。The lower end of the electrostatic signal conditioning plate 63 is connected with the support frame rod and the electrostatic grounding device 65 , and the electrostatically induced charge after conversion, filtering and amplification can be safely released through the electrostatic grounding device in time.

所述支撑架杆及静电接地装置65上端设有检测单元二55,所述检测单元二由氢气浓度传感器、温度传感器、火焰探测器等元器件构成,用于氢气放空后放空环境安全监测,经数据传输导线将放空状态反馈给计算机及数据采集系统8,当氢气放空至系统外部环境出现氢气异常聚集等现象时,报警单元二82闪烁并发出警报声,由计算机及信号采集系统8立即发出指令,控制氮气吹扫系统2保护放空系统及上游设备装置,并根据实际情况暂停放空作业,避免危险状态进一步扩大。The upper end of the support frame rod and the electrostatic grounding device 65 is provided with a detection unit 2 55. The detection unit 2 is composed of a hydrogen concentration sensor, a temperature sensor, a flame detector and other components, and is used for the safety monitoring of the venting environment after the hydrogen is vented. The data transmission wire feeds back the venting state to the computer and the data acquisition system 8. When the hydrogen gas is vented to the external environment of the system and abnormal accumulation of hydrogen occurs, the alarm unit 2 82 flashes and an alarm sound is issued, and the computer and the signal acquisition system 8 immediately issue an instruction , Control the nitrogen purging system 2 to protect the venting system and upstream equipment, and suspend the venting operation according to the actual situation to avoid the further expansion of the dangerous state.

所述红外摄像仪7布置在放空管排气口53一侧,并与所述计算机集信号采集系统8连接,用于监测放空系统外异常点火情况。The infrared camera 7 is arranged on one side of the exhaust port 53 of the venting pipe, and is connected to the computer signal collection system 8 for monitoring abnormal ignition conditions outside the venting system.

所述计算机及信号采集系统8负责采集检测单元一54、检测单元二55相关检测元件的数据监测信息并反馈至相应的报警单元一81、报警单元二82,进一步控制氮气吹扫系统2保护放空系统及上游设备装置;在不同放空条件下采集静电测量系统6的静电累积行为。The computer and the signal acquisition system 8 are responsible for collecting the data monitoring information of the relevant detection elements of the detection unit 1 54 and the detection unit 2 55 and feed them back to the corresponding alarm unit 1 81 and alarm unit 2 82, and further control the nitrogen purging system 2 to protect and vent. System and upstream equipment; the electrostatic accumulation behavior of the electrostatic measurement system 6 is collected under different venting conditions.

本发明提供的一种氢气自然放空与静电安全监测互馈反应防护系统,其工作过程为:A kind of hydrogen gas natural venting and electrostatic safety monitoring mutual feedback reaction protection system provided by the invention, its working process is as follows:

本发明所涉及的放空作业安全防护系统适用于多个实施场景,例如:加氢站储氢罐维护放空、化工制氢场所作业放空、氢运输管道检修放空、大型氢储运设备预冷放空等场景。The venting safety protection system involved in the present invention is suitable for multiple implementation scenarios, such as: maintenance venting of hydrogen storage tanks in hydrogen refueling stations, venting for operations in chemical hydrogen production sites, venting for maintenance of hydrogen transportation pipelines, pre-cooling venting for large-scale hydrogen storage and transportation equipment, etc. Scenes.

根据监测及防护目的,需要定期检修并测试系统所述各关键环节工作状态,保证放空管路无超压漏气等现象发生。According to the purpose of monitoring and protection, it is necessary to regularly overhaul and test the working status of each key link of the system to ensure that there is no overpressure and air leakage in the venting pipeline.

放空作业前,由计算机及信号采集系统8发出命令,控制氮气流路从氮气集装格2经氮气流路支路二26进入放空系统进气管3,将整个系统管路中的空气等杂质气体置换出来。Before the venting operation, the computer and the signal acquisition system 8 issue a command to control the nitrogen flow path from the nitrogen container 2 through the nitrogen flow path branch 26 to enter the air inlet pipe 3 of the venting system, and the air and other impurity gases in the entire system pipeline are removed. replace it.

放空作业时,氢气介质由氢储运装置1经氢气流管道11进入放空系统进气管3,放空系统进气管3上设置了阻火器31和缓冲罐4,可以有效阻止外部火焰窜入氢气排放管以及防止因压力失衡造成的系统损害。During the venting operation, the hydrogen medium enters the venting system intake pipe 3 from the hydrogen storage and transportation device 1 through the hydrogen flow pipe 11. The venting system intake pipe 3 is provided with a flame arrester 31 and a buffer tank 4, which can effectively prevent the external flame from entering the hydrogen discharge pipe. As well as preventing system damage due to pressure imbalances.

本发明提供的一种氢气自然放空与静电安全监测互馈反应防护系统,主要有以下几种安全监测互馈反应防护工况:The invention provides a hydrogen gas natural venting and electrostatic safety monitoring mutual feedback reaction protection system, which mainly includes the following safety monitoring mutual feedback reaction protection working conditions:

情况1:氢气介质从放空系统进气管3进入氢气放空管主体5正常放空时,由检测单元一54监测放空作业过程中的放空状态并采集管路流量、压力、温度等数据经数据传输导线反馈给计算机及数据采集系统8,发出指令并控制氮气流路管道21上的流量调节阀23和电磁阀24,经氮气流路支路一25以小流量氮气吹扫气注入分子密封器52,保持管路内气体形成微正压,防止气体回流。Situation 1: When the hydrogen medium enters the main body 5 of the hydrogen venting pipe from the intake pipe 3 of the venting system, when the venting is normally vented, the detection unit 1 54 monitors the venting state during the venting operation and collects data such as pipeline flow, pressure, and temperature through the data transmission wire. Feedback to the computer and the data acquisition system 8, issue instructions and control the flow regulating valve 23 and the solenoid valve 24 on the nitrogen flow path pipeline 21, and inject the molecular sealer 52 with a small flow of nitrogen purge gas through the nitrogen flow path branch-25, Keep the gas in the pipeline to form a slight positive pressure to prevent the gas from backflow.

情况2:当氢气放空作业存在间歇性、不连续放空时,检测单元一54迅速反应,将放空管流量、压力、温度等数据经数据传输导线反馈给计算机及数据采集系统8,报警单元一81闪烁并发出警报声,由计算机及信号采集系统8立即发出指令,控制氮气流路管道21上的流量调节阀23和电磁阀24,经氮气流路支路一25以大流量氮气吹扫气注入分子密封器52,充分保护和防止外界杂质气体侵入放空管。Situation 2: When there is intermittent and discontinuous venting in the hydrogen venting operation, the detection unit 1 54 responds quickly, and feeds back the data such as the flow rate, pressure, and temperature of the venting pipe to the computer and the data acquisition system 8 through the data transmission wire. The alarm unit 1 81 flashes and an alarm sounds, the computer and the signal acquisition system 8 immediately issue instructions to control the flow regulating valve 23 and the solenoid valve 24 on the nitrogen flow pipeline 21, and the nitrogen flow branch 1 25 is purged with a large flow of nitrogen gas. Inject the molecular sealer 52 to fully protect and prevent the foreign impurity gas from invading the venting tube.

情况3:无论氢气正常或间歇性放空时,氢气放空至系统外部环境都可能会出现氢气浓度、环境温度异常的现象,容易发生静电意外点火等危险状况,此时检测单元二55迅速反应,将监测状态参数经数据传输导线反馈给计算机及数据采集系统8,报警单元二82闪烁并发出警报声,由计算机及信号采集系统8立即发出指令,氮气流路管道21上的流量调节阀23和电磁阀24完全打开,大流量氮气喷入排放管,消除火焰危害,保证放空系统在各种条件下均能正常进行放空作业。Situation 3: No matter when the hydrogen is vented normally or intermittently, the hydrogen concentration and ambient temperature may be abnormal when the hydrogen is vented to the external environment of the system, and dangerous situations such as static electricity accidental ignition are likely to occur. The monitoring state parameters are fed back to the computer and the data acquisition system 8 through the data transmission wire, the alarm unit 2 82 flashes and an alarm sound is issued, and the computer and the signal acquisition system 8 issue an instruction immediately. The valve 24 is fully opened, and a large flow of nitrogen is sprayed into the discharge pipe to eliminate the flame hazard and ensure that the venting system can perform the venting operation normally under various conditions.

情况4:在进行氢气自然放空的整个作业过程中,会经常因摩擦、碰撞等行为致使静电电荷异常积累甚至放电,容易发生氢气意外自燃并造成放空装置火焰入侵,对自然放空系统及上游制氢、储氢设施装置构成潜在危险。Situation 4: During the whole process of natural venting of hydrogen, there will often be abnormal accumulation or even discharge of electrostatic charge due to friction, collision and other behaviors, which is prone to accidental spontaneous combustion of hydrogen and intrusion of the flame of the venting device, which will affect the natural venting system and upstream hydrogen production , hydrogen storage facilities constitute potential hazards.

管内静电传感器61和管外静电传感器64用于监测氢气自然放空作业过程中的静电累积行为,当静电传感器捕集到静电电荷时,会迅速经静电传输导线62转移至静电信号调理板63,避免静电电荷在静电传感器处异常累积。然后静电信号调理板对接收到的静电信号进行滤波、放大处理,电子信号通过数据传输导线反馈至计算机及信号采集系统8,静电电荷则通过支撑架杆及静电接地装置65安全释放。若静电电荷未及时释放,出现意外点火事故,可根据情况3妥善处理。The electrostatic sensor 61 inside the tube and the electrostatic sensor 64 outside the tube are used to monitor the electrostatic accumulation behavior during the natural hydrogen venting operation. Electrostatic charge builds up abnormally at the electrostatic sensor. Then the electrostatic signal conditioning board filters and amplifies the received electrostatic signal, the electronic signal is fed back to the computer and the signal acquisition system 8 through the data transmission wire, and the electrostatic charge is safely released through the support rod and the electrostatic grounding device 65 . If the electrostatic charge is not released in time and an accidental ignition accident occurs, it can be properly handled according to Situation 3.

放空作业后,由计算机及信号采集系统8发出命令,控制氮气流路从氮气集装格2经氮气流路支路一25和氮气流路支路二26分别进入分子密封器52放空系统进气管3,将整个系统管路吹扫干净,对放空状态参数以及静电感应信号进行存储、处理,结合不同条件下的氢气放空状态,分析放空管不规律作业时的放空状态参数(包括流量、压力、温度等参数)以及静电累积行为,为各类氢放空实施场景的安全互馈防护提供有力参考。可以理解的是,以上关于本发明的具体描述,仅用于说明本发明而并非受限于本发明实施例所描述的技术方案,本领域的普通技术人员应当理解,仍然可对本发明进行修改或等同替换,以达到相同的技术效果,只要满足使用需要,都在本发明的保护范围之内。After the venting operation, the computer and the signal acquisition system 8 issue commands to control the nitrogen flow path from the nitrogen container 2 through the nitrogen flow path branch 1 25 and the nitrogen flow branch 26 to enter the molecular sealer 52 and the air inlet pipe of the venting system respectively. 3. Purge the entire system pipeline, store and process the venting state parameters and electrostatic induction signals, and analyze the venting state parameters (including flow, pressure, parameters such as temperature) and electrostatic accumulation behavior, providing a strong reference for the safety mutual feedback protection of various hydrogen venting implementation scenarios. It can be understood that the above specific description of the present invention is only used to illustrate the present invention and is not limited to the technical solutions described in the embodiments of the present invention. Those of ordinary skill in the art should understand that the present invention can still be modified or Equivalent replacement to achieve the same technical effect, as long as the needs of use are met, all fall within the protection scope of the present invention.

Claims (9)

1.一种氢气自然放空与静电安全监测互馈反应防护系统,其特征在于,包括氢储运装置、氮气集装格、氢气放空管主体、静电测量系统、所述红外摄像仪以及计算机及信号采集系统;1. a natural hydrogen gas venting and electrostatic safety monitoring mutual feedback reaction protection system, is characterized in that, comprises hydrogen storage and transportation device, nitrogen container, hydrogen venting pipe main body, electrostatic measurement system, described infrared camera and computer and signal acquisition system; 所述氢储运装置和所述氮气集装格分别通过所述氢气流路管道和所述氮气流路管道与所述放空系统进气管连接,所述放空系统进气管上设有缓冲罐和阻火器;所述放空系统进气管末端连接放空管主体底部;The hydrogen storage and transportation device and the nitrogen container are respectively connected to the air intake pipe of the venting system through the hydrogen flow channel pipeline and the nitrogen gas flow channel pipeline, and a buffer tank and a damper are arranged on the air intake pipe of the venting system. Firearm; the end of the air intake pipe of the venting system is connected to the bottom of the main body of the venting pipe; 放空管主体包括分子密封器、放空管排放口和检测单元一,所述检测单元一用于监测放空作业过程中的放空状态,经数据传输导线将放空状态反馈给计算机及数据采集系统,当氢气放空作业存在间歇性、不连续放空时,由计算机及信号采集系统立即发出指令,控制氮气流路管道上的流量调节阀和电磁阀,经氮气流路支路注入分子密封器,所述分子密封器用氮气分子作为密封填料,起到密封和防止空气进入放空系统的作用;The main body of the venting tube includes a molecular sealer, a venting tube discharge port and a detection unit 1. The detection unit 1 is used to monitor the venting state during the venting operation, and the venting state is fed back to the computer and the data acquisition system through the data transmission wire. When there is intermittent and discontinuous venting in the hydrogen venting operation, the computer and the signal acquisition system will immediately issue instructions to control the flow regulating valve and solenoid valve on the nitrogen flow path, and inject the molecular sealer through the nitrogen flow path branch. Molecular sealers use nitrogen molecules as sealing fillers to seal and prevent air from entering the venting system; 所述静电测量系统包括管内静电传感器、静电传输导线、静电信号调理板和管外静电传感器,所述三个管内静电传感器均设置在氢气排放管主体中,分别由下至上布置于放空系统进气管与氢气排放管主体连接处、分子密封器下端、分子密封器上端与放空管排气口连接处,所述管外静电传感器设置在放空管排气口出口上方,用于监测放空管排气口出口处静电累积行为,所述管内静电传感器和管外静电传感器均通过静电传输导线分别与静电信号调理板连接,以便于静电测量及后续安全处理;静电信号调理板通过数据传输导线与计算机及信号采集系统连接,对静电感应信号进行实时采集并存储、处理,同时结合氢气放空状态,分析放空管不规律放空作业时的静电累积行为;The electrostatic measurement system includes an electrostatic sensor in the tube, an electrostatic transmission wire, an electrostatic signal conditioning board and an electrostatic sensor outside the tube. The three electrostatic sensors in the tube are all arranged in the main body of the hydrogen discharge pipe, and are respectively arranged in the air intake pipe of the venting system from bottom to top. The connection with the main body of the hydrogen discharge pipe, the lower end of the molecular sealer, and the connection between the upper end of the molecular sealer and the exhaust port of the venting pipe, the electrostatic sensor outside the pipe is arranged above the exhaust port of the venting pipe, and is used for monitoring the venting pipe. The electrostatic accumulation behavior at the outlet of the exhaust port, the electrostatic sensor in the pipe and the electrostatic sensor outside the pipe are connected to the electrostatic signal conditioning board respectively through the electrostatic transmission wire, so as to facilitate electrostatic measurement and subsequent safe processing; the electrostatic signal conditioning board is connected to the electrostatic signal conditioning board through the data transmission wire. The computer is connected with the signal acquisition system to collect, store, and process the electrostatic induction signal in real time. At the same time, combined with the hydrogen venting state, the electrostatic accumulation behavior of the venting pipe during irregular venting operations is analyzed; 所述红外摄像仪布置在放空管排气口一侧,并与所述计算机集信号采集系统连接,用于监测放空系统外异常点火情况。The infrared camera is arranged on one side of the exhaust port of the venting pipe, and is connected to the computer collecting signal collection system for monitoring abnormal ignition conditions outside the venting system. 2.根据权利要求1所述的一种氢气自然放空与静电安全监测互馈反应防护系统,其特征在于,所述氢气流路管道设有减压阀和调节阀。2. A kind of hydrogen natural venting and electrostatic safety monitoring mutual feedback reaction protection system according to claim 1, is characterized in that, described hydrogen flow path pipeline is provided with pressure reducing valve and regulating valve. 3.根据权利要求1所述的一种氢气自然放空与静电安全监测互馈反应防护系统,其特征在于,所述缓冲罐末端设有超压泄放管并布置了爆破片,防止因压力失衡造成的系统损害。3. a kind of hydrogen natural venting and electrostatic safety monitoring mutual feedback reaction protection system according to claim 1, is characterized in that, described buffer tank end is provided with overpressure relief pipe and arranges bursting disc, prevents from pressure imbalance system damage. 4.根据权利要求1所述的一种氢气自然放空与静电安全监测互馈反应防护系统,其特征在于,所述阻火器用于防止由于火焰入侵对自然放空系统及上游氢储运设施装置构成潜在危险。4. a kind of hydrogen natural venting and electrostatic safety monitoring mutual feedback reaction protection system according to claim 1, it is characterized in that, described flame arrester is used to prevent the natural venting system and upstream hydrogen storage and transportation facilities from being formed due to flame intrusion Potentially dangerous. 5.根据权利要求1所述的一种氢气自然放空与静电安全监测互馈反应防护系统,其特征在于,所述氮气集装格由多个商业氮气钢瓶组成,高压氮气瓶压力为12.5MPa,采用立式或卧式组装,用于提供惰性保护气体。5. a kind of hydrogen natural venting and electrostatic safety monitoring mutual feedback reaction protection system according to claim 1, is characterized in that, described nitrogen container is made up of a plurality of commercial nitrogen cylinders, and the pressure of high-pressure nitrogen cylinder is 12.5MPa, Available in vertical or horizontal assembly for supplying inert protective gas. 6.根据权利要求1所述的一种氢气自然放空与静电安全监测互馈反应防护系统,其特征在于,管内静电传感器为环形非接触式静电传感器,镶嵌于放空管主体内侧并保证管道内壁光滑。6. a kind of hydrogen natural venting and electrostatic safety monitoring mutual feedback reaction protection system according to claim 1, it is characterized in that, the electrostatic sensor in the tube is a ring-shaped non-contact electrostatic sensor, inlaid on the inside of the venting tube main body and guarantees the inner wall of the pipeline smooth. 7.根据权利要求1所述的一种氢气自然放空与静电安全监测互馈反应防护系统,其特征在于,所述静电信号调理板下端与支撑架杆及静电接地装置连接,能够及时将经过转化、滤波、放大后的静电感应电荷通过静电接地装置安全释放。7. A kind of hydrogen gas natural venting and electrostatic safety monitoring mutual feedback reaction protection system according to claim 1, characterized in that, the lower end of the electrostatic signal conditioning plate is connected with the support frame rod and the electrostatic grounding device, and the converted , Filtered and amplified electrostatically induced charges are safely released through the electrostatic grounding device. 8.根据权利要求1所述的一种氢气自然放空与静电安全监测互馈反应防护系统,其特征在于,支撑架杆及静电接地装置上端设有检测单元二,用于氢气放空后放空环境安全监测,经数据传输导线将放空状态反馈给计算机及数据采集系统,当氢气放空至系统外部环境出现氢气异常聚集现象时,由计算机及信号采集系统立即发出指令,控制氮气吹扫系统保护放空系统及上游设备装置,并根据实际情况暂停放空作业,避免危险状态进一步扩大。8. a kind of hydrogen natural venting and electrostatic safety monitoring mutual feedback reaction protection system according to claim 1, it is characterized in that, the upper end of the support frame rod and the electrostatic grounding device is provided with the detection unit two, which is used for the safety of the venting environment after the hydrogen venting Monitoring, the venting state is fed back to the computer and data acquisition system through the data transmission wire. When the hydrogen gas is vented to the external environment of the system and abnormal accumulation of hydrogen occurs, the computer and the signal acquisition system will immediately issue instructions to control the nitrogen purging system to protect the venting system and Upstream equipment is installed, and the emptying operation is suspended according to the actual situation to avoid the further expansion of the dangerous state. 9.根据权利要求1所述的一种氢气自然放空与静电安全监测互馈反应防护系统,其特征在于,所述计算机及信号采集系统负责采集检测单元一、检测单元二相关检测元件的数据监测信息,进一步控制氮气吹扫系统保护放空系统及上游设备装置;在不同放空条件下采集静电测量系统的静电累积行为。9. A kind of hydrogen natural venting and electrostatic safety monitoring mutual feedback reaction protection system according to claim 1, it is characterized in that, described computer and signal acquisition system are responsible for collecting the data monitoring of detection unit 1 and detection unit 2 related detection elements information, and further control the nitrogen purging system to protect the venting system and upstream equipment; collect the electrostatic accumulation behavior of the electrostatic measurement system under different venting conditions.
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