CN1148075A - 化学紧固用封堵化合物 - Google Patents
化学紧固用封堵化合物 Download PDFInfo
- Publication number
- CN1148075A CN1148075A CN96111688A CN96111688A CN1148075A CN 1148075 A CN1148075 A CN 1148075A CN 96111688 A CN96111688 A CN 96111688A CN 96111688 A CN96111688 A CN 96111688A CN 1148075 A CN1148075 A CN 1148075A
- Authority
- CN
- China
- Prior art keywords
- resin
- plugging compound
- compound
- solidifying agent
- plugging
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 31
- 239000000126 substance Substances 0.000 title claims description 7
- 229920005989 resin Polymers 0.000 claims abstract description 64
- 239000011347 resin Substances 0.000 claims abstract description 64
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 239000003112 inhibitor Substances 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 13
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 12
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 12
- 229920001567 vinyl ester resin Polymers 0.000 claims description 11
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 9
- 239000002775 capsule Substances 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 5
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 4
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 claims description 4
- 125000005936 piperidyl group Chemical group 0.000 claims description 4
- 238000006068 polycondensation reaction Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims 2
- -1 tetrahydropyrrolyl nitroxide Chemical class 0.000 abstract description 15
- 125000003386 piperidinyl group Chemical group 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 150000004982 aromatic amines Chemical class 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000004568 cement Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000001879 gelation Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000004567 concrete Substances 0.000 description 3
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- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 230000000171 quenching effect Effects 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 2
- JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000002152 alkylating effect Effects 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
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- 230000002028 premature Effects 0.000 description 2
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- 239000012763 reinforcing filler Substances 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003351 stiffener Substances 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- CBWZKGWYEBXDMQ-UHFFFAOYSA-N 1-butylperoxybutane;2-ethylhexanoic acid Chemical group CCCCOOCCCC.CCCCC(CC)C(O)=O CBWZKGWYEBXDMQ-UHFFFAOYSA-N 0.000 description 1
- ZMARGGQEAJXRFP-UHFFFAOYSA-N 1-hydroxypropan-2-yl 2-methylprop-2-enoate Chemical compound OCC(C)OC(=O)C(C)=C ZMARGGQEAJXRFP-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- MMEDJBFVJUFIDD-UHFFFAOYSA-N 2-[2-(carboxymethyl)phenyl]acetic acid Chemical compound OC(=O)CC1=CC=CC=C1CC(O)=O MMEDJBFVJUFIDD-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- DHOQDAVVCQNTEY-UHFFFAOYSA-N C(OC1=CC=CC=C1)(=O)Cl.CC(C(=O)O)=C Chemical compound C(OC1=CC=CC=C1)(=O)Cl.CC(C(=O)O)=C DHOQDAVVCQNTEY-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 150000000703 Cerium Chemical class 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- CMEWLCATCRTSGF-UHFFFAOYSA-N N,N-dimethyl-4-nitrosoaniline Chemical compound CN(C)C1=CC=C(N=O)C=C1 CMEWLCATCRTSGF-UHFFFAOYSA-N 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- LCXXNKZQVOXMEH-UHFFFAOYSA-N Tetrahydrofurfuryl methacrylate Chemical compound CC(=C)C(=O)OCC1CCCO1 LCXXNKZQVOXMEH-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical compound CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000005466 alkylenyl group Chemical group 0.000 description 1
- 125000000746 allylic group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 239000010428 baryte Substances 0.000 description 1
- 229910052601 baryte Inorganic materials 0.000 description 1
- 150000004054 benzoquinones Chemical class 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate group Chemical group [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011381 foam concrete Substances 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000011796 hollow space material Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052806 inorganic carbonate Inorganic materials 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229950007687 macrogol ester Drugs 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 125000005245 nitryl group Chemical group [N+](=O)([O-])* 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-dimethylbenzene Natural products CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 238000009527 percussion Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/06—Inhibiting the setting, e.g. mortars of the deferred action type containing water in breakable containers ; Inhibiting the action of active ingredients
- C04B40/0666—Chemical plugs based on hydraulic hardening materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00715—Uses not provided for elsewhere in C04B2111/00 for fixing bolts or the like
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Abstract
一种用于化学紧固钻孔中的锚定螺栓、拧螺丝的套管和螺杆的封堵化合物，它含反应性树脂和与树脂空间分开的树脂用固化剂，在反应性树脂中含有0.0005～2％(重)哌啶基或四氢吡咯基硝基氧作为抑制剂。
Description
反应性树脂组合物作为粘合剂用于化学紧固技术是大家熟悉的。所述的反应性树脂组合物是两组分体系，其中一组分为反应性树脂，而另一组分为固化剂。这些组分中的一个或两个可含有其他常用的成分如填充剂、促进剂、稳定剂以及包括反应性溶剂(共聚单体)在內的溶剂。将两组分混合反产生自由基并引发使树脂固化的反应。
为了将锚定螺栓固定在混凝土或坚石的钻孔中，通常使用有两个小室的封囊使各组分分开(如参见EP-A150555)。封囊本身优选由吹制玻璃制成，但也可使用由UV稳定的薄膜制成的封囊，如聚乙烯、聚对苯二甲酸乙二醇酯或相应的复合材料。将封囊插入钻孔，在送入紧固元件以前，通过旋转撞击使封囊和小室破坏。将两种组分混合，引发反应。固化的树脂组合物可在没有横向膨胀压力的条件下强制进入基层。已证明这样的锚定物对于重型卡具特别有用。
两室料管特别是可用于多孔基层或空心基层的锚定物情况中，例如发泡混凝土块或空心砖，也可用于坚岩、砖和混凝土(如参见DE-A3617702)。封堵化合物的两组分同时从料管中挤出，用适合的方法混合(如螺杆)，并强制送入钻孔。然后可将任何所需截面的锚定紧固元件直接放入钻孔，当树脂固化后，元件就固定在钻孔中；或者先将內部套丝了的套筒插入孔中，并通过树脂固化固定在适当位置，然后可拧紧螺杆或螺栓。在空心砖的情况下，钻孔先衬塑料或金属制成的网型圆柱套筒。然后从两室料管强制送入树脂。內部拧螺丝的套筒插入后，通过多孔套管的开孔强制压入封堵化合物，以致当封堵化合物固化时形成紧固的锚定物。
在Rigips座下的锚定物情况下，或在空心砖中，所用的料管装有可发泡的粘合剂组合物，如在EP-A338983中描述的。封堵化合物中的一种组分含无机碳酸盐，如白垩，而另一种组分含酸，如聚丙烯酸或磷酸。钻孔衬有内部套丝了的套管或多孔套管，而可发泡封堵化合物被强制送入。当各组分混合时，释放出CO2，使封堵化合物发泡并填满空心空间，或者在座下方形成蘑菇形锚定物，当封堵化合物固化时，卡具被锚定。
适合化学紧固技术用的反应性树脂是乙烯基酯树脂和乙烯基酯尿烷树脂，如在EP-A150555、EP-A199671、EP-A 5081183和EP-A534201中公开的。这些树脂通常含有使树脂对早期聚合稳定的抑制剂，如氢醌、取代氢醌、苯醌、叔丁基邻苯二酚或吩噻嗪。这些抑制剂使树脂有数月的贮存稳定性，虽然仅在溶解在树脂中的氧存在下。如果树脂在没有空气的条件下贮存，取合会在几天内出现。由于这一原因，封堵化合物迄今必须按这样的方式包装：树脂要与空气接触。但是，气密包装制作应更坚固和简单。
本发明的一个目的是提供一种在气密包装的情况下以及在光存在下使封堵化合物有足够长的贮存稳定性的抑制剂。
化学紧固技术的一具体实施例方案在DE-A 4231161中公开。在这一背景技术中，反应性树脂组分还包括水力固化的无机化合物或可缩聚的无机化合物，如水泥，固化剂组分还包括水。现已发现，碱性水泥会破坏常用的酚类抑制剂的作用。树脂会过早固化，以致当各组分混合时，实际的固化不均匀，在锚定中产生差的固化区。因此，螺栓的抗挤出性受到损失。本发明的另一目的是提供一种甚至在特定的水泥实施方案的情况下对其作用无不良影响的抑制剂。
我们已发现，根据本发明当哌啶基氮氧化物或四氢吡咯基氮氧化物用作抑制剂时，这些目的可以实现。
因此，本发明提供了一种用于锚定钻孔中的螺栓套丝了的套管和螺杆，它含有
I可自由基固化的反应性树脂，含0.0005～2％(重)哌啶基氮氧化物或四氢吡咯基氮氧化物抑制剂，以及
II与树脂空间上分开的树脂用固化剂。
适合的反应性树脂包括乙烯基酯树脂和乙烯基酯尿烷树脂。
1.不饱和乙烯基酯树脂(环氧-丙烯酸酯)是聚环氧化物与不饱和一元羧酸(优选甲基丙烯酸)的加成产物。这些树脂例如在US 3066112和3179623中公开，优选使用基于双酚A的乙烯基酯树脂。它们具有高的韧性和良好的耐化学品性，以及有限的耐热性。相反，由环氧/可溶酚醛树脂和(甲基)丙烯酸制得的乙烯基酯树脂有更高的耐热性，但韧性较差，如在US 3256226中公开的。
这类乙烯基酯树脂的特征是以下基团
式中，R为H或CH3。
另一类乙烯基酯树脂是任选烷基化的双酚A与(甲基)丙烯酸的酯化产物，如在EP-A 534 201中公开的。
2.不饱和乙烯基酯尿烷树脂(尿烷丙烯酸酯)通常有以下基团：
式中，R为H或CH3。
式中，R2为有4～40个碳原子的两价脂族、芳族或环脂族基团，优选有6～20个碳原子的芳族基团，任选
c)-O-R3-O-
式中，R3为有2～100个碳原子的脂族、环脂族或芳族基团。
优选的是，乙烯基酯尿烷树脂是以下组分的反应产物
-多官能性的异氰酸酯，
-任选的多元醇，
-任选的多元胺，
-(甲基)丙烯酸羟烷基酯，
异氰酸酯与(醇＋胺)的重量比为100∶0～100∶300，(甲基)丙烯酸羟烷基酯与反应产物中游离异氰酸酯基团的当量比为3∶1～1∶2。
反应性树脂含10～80、优选30～60％(重)共聚单体。
优选的共聚单体包括甲基丙烯酸酯类，如甲基丙烯酸2-乙基己酯、甲基丙烯酸苯基乙酯、甲基丙烯酸四氢化糠基酯、甲基丙烯酸乙基三甘醇酯、甲基丙烯酸N，N-二甲基氨乙基酯、甲基丙烯酸N，N-二甲基氨甲基酯、二甲基丙烯酸1，4-丁二醇酯、甲基丙烯酸乙酰基羧烷基酯、甲基丙烯酸乙酰基乙酰氧乙基酯、二甲基丙烯酸1，2-乙二醇酯、甲基丙烯酸异冰片基酯、二甲基丙烯酸二乙二醇酯、甲基丙烯酸甲氧基聚乙二醇酯、甲基丙烯酸三甲基环己基酯、三甲基丙烯酸三羟甲基丙烷酯、甲基丙烯酸2-羟基乙酯、甲基丙烯酸羟丙酯和甲基丙烯酸二环戊氧基乙酯。二甲基丙烯酸丁二醇酯是特别优选的。
丙烯酸酯不太优选，因为它们通常是皮肤刺激剂，其水解性差。
原则上，也可使用其他常用的共聚单体，单独使用或与甲基丙烯酸酯混合使用，如苯乙烯、α-甲基苯乙烯、烷基化的苯乙烯(如叔丁基苯乙烯)、二乙烯基苯和烯丙基化合物。
根据本发明，封堵化合物含有0.0005～2、优选0.1～1％(重)哌啶基氮氧化物或四氢吡咯基氮氧化物作为抑制剂。它们是下式的硝酰基类(氮氧化自由基)。
式中，E1和E3各自独立为C1～C5烷基，或苯基，E2和E4各自独立为C1～C5烷基，或E1或E2一起或E3和E4一起为四亚甲基或五亚甲基，T为两价基团，与氮原子和两个叔碳原子一起构成5或6元环，T可被取代或未取代。
优选4-羟基-2，2，6，6-四甲基哌啶-1-基氧
在优选的实施方案中，封堵化合物还含有0.005～2、优选0.05～1％(重)的传统的抑制剂，特别是苯酚、醌或吩噻嗪，如2，6-二叔丁基对甲酚。
反应性树脂用增强填充剂的例子包括石英、玻璃、刚玉、瓷、陶土、重晶石、lightspar、石膏、滑石和白垩。填充剂以砂粒、粉末或特定的形状(圆柱形、球形等)混合在树脂溶液中和/或硬化剂(引发剂)中。
填充剂可使用纤维(原纤维填充剂)。优选的和更增强的是圆形惰性材料(球形)。
过氧化物固化剂通常与促进剂一起作用，它们最好与树脂放在一起，也就是与硬化剂分开。适合的促进剂包括芳族胺类，如N，N-二甲基苯胺、N，N-二乙基苯胺；甲苯胺类和二甲苯胺类，如N，N-二异丙醇-对-甲苯胺、N，N-二甲基-对-甲苯胺、N，N-双(2-羟基乙基)二甲苯胺和N，N-双(2-羟基乙基)甲苯胺；也有钴、锰、锡和铈盐，如辛酸钴或环烷酸钴。
反应性树脂的粘度优选为30～5000mPa.s(23℃下)。
在本发明的封堵化合物中，固化剂与树脂分装。优选的固化剂包括贮存稳定的有机过氧化物。特别适合的是二苯甲酰过氧化物和甲乙酮过氧化物，还有过氧化苯甲酸叔丁酯、环己酮过氧化物、月桂酰过氧化物和异丙苯过氧化物以及叔丁基-过氧-2-乙基己酸酯。
按反应性树脂计，过氧化物的用量优选为0.5～10％(重)，更优选3～7％(重)。
使用固化剂是有利的，用惰性填料，石英砂钝化的是优选的。
在本发明特别优选的实施方案中，组分I除反应性树脂外还包括水硬固化的或可缩聚的无机化合物，特别是水泥，组分II除固化剂外还包括水。这样的封堵化合物在DE-A 4231161中详细描述。
通常，所述的包装形式是两室封管形式。一种被证实的封管形式是玻璃管，因为玻璃在混合过程中可细粉碎，然后作为增强填充剂组合在粘合剂基质中。使用陶瓷材料制成的多室料管也是可能的，如在DE-A3939 603.2中描述的，也有薄膜制成的料管，如用聚乙烯、聚对苯二甲酸乙二醇酯或层压材料。
所用的料管优选为两室料管，其中较大的室装有树脂，而较小的室装有固化剂，在每一情况下都与填充料装在一起。在可发泡粘合剂组合物的情况下，优选将碳酸盐加到树脂中，而酸组分可与固化剂一起放在一个室內，或单独放在一个室內。
含有本发明抑制剂的树脂可在没有任何特殊措施的情况下用于化学紧固。这类锚定有良好的豁裂蔓延特性、低的体积收缩、良好的耐水解性和良好的耐热性，以及对矿物接收材料(如混凝土、天然矿石)以及发泡和空心块有良好的粘合性。封堵化合物有特别好的贮存稳定性，甚至在无大气氧的情况下也如此。含有本发明抑制剂的水泥封堵化合物可均匀地固化。
在实施例中，百分数按重量计。
实施例
1a将300g二苯基甲烷二异氰酸酯的异构体混合物与1ml二月桂酸二丁基锡混合。在40℃下滴加37g二丙二醇、随后将混合物搅拌1小时。然后滴加280g甲基丙烯酸羟丙基酯，将反应温度升至80℃。随后在90℃下搅拌混合物，一直到残留的异氰酸酯含量降到0.01％以下(100℃下的熔体粘度为750mPa.s)。用6.7g 2-羟基-2，2，6，6-四甲基哌啶-1-基氧和2.7g2，6-二叔丁基对甲酚抑制该树脂。535g二甲基丙烯酸1，4-丁二醇酯和133g甲基丙烯酸乙酰基乙酰氧基乙酯作为反应性稀释剂加入。加入芳族胺使胶凝时间调节到约3.5分钟。树脂的粘度为约250mPa.s。在无空气的条件下，在80℃下在日光中贮存，3周后树脂仍稳定。在Heraeus生产的Suntest CPS Plus中，在光下贮存，样品在3周內是稳定的。
1b.用5.1g叔丁基邻苯二酚和0.13g吩噻嗪的混合物作为抑制剂重复1a。在无空气的条件下，在80℃下贮存，该树脂在5小时內胶凝。在Suntest中光照下贮存，样品在3小时內胶凝。
2.将1475g以1286g 4，4′-二苯基甲烷二异氰酸酯为基础的预聚的二异氰酸酯在40℃下溶于1320g苯乙烯中。加入1.3ml二月桂酸二丁基锡，随后滴加125g二丙二醇和74g聚丙二醇(羟基数250)。放热反应结束后，将混合物搅拌1小时，然后滴加入1195g甲基丙烯酸羟丙基酯。加完后再加入1.3ml二月桂酸二丁基锡，在后在80℃下将物料搅拌到残留异氰酸酯的含量降到0.01％以下。用16.8g 4-羟基-2，2，6，6-四甲基哌啶-1-基氧抑制该树脂。加入芳族胺使树脂的胶凝时间调节到约3.5分钟。树脂的粘度为约460mPa.s
3.将1.3g2，6-二叔丁基对甲酚和0.36g二甲基苄基胺加到300g双酚A二环氧甘油醚(由Shell公司生产的Epikote 828)中。然后在85℃下滴加入136g甲基丙烯酸，同时使內部温度升到110℃。将物料在空气下搅拌到酸值达到切换值≤15单位。然后用3.4g 4-羟基-2，2，6，6-四甲基哌啶-1-基氧抑制该树脂。将170g二甲基丙烯酸1，4-丁二醇酯和68g甲基丙烯酸乙酰基乙酰氧基乙酯加入作为反应性稀释剂。用芳族胺调节树脂的胶凝时间到约3.5分钟。
4.将1000g双乙氧基化的双酚A与甲基丙烯酸的酯化产物加热到50℃。然后用5g4-羟基-2，2，6，6-四甲基哌啶-1-基氧抑制该树脂。用芳族胺调节胶凝时间到约3.5分钟。树脂的粘度为约1600mPa.s。
Claims (9)
1.一种用于化学紧固钻孔中的锚定螺栓、套丝了的套管和螺杆的封堵化合物，它含有
I.可自由基固化的反应性树脂，含0.0005～2％(重)抑制剂，以及
II.与树脂空间上分开的树脂用固化剂，
其中抑制剂是哌啶基氮氧化物或四氢吡咯基氮氧化物。
2.根据权利要求1的封堵化合物，其中反应性树脂含有至少20％(重)乙烯基酯树脂或乙烯基酯尿烷树脂。
3.根据权利要求1的封堵化合物，其中树脂包括甲基丙烯酸作为共聚单体。
4.根据权利要求1的封堵化合物，其中树脂中含有用于固化剂的促进剂，优选有机叔胺。
5.根据权利要求1的封堵化合物，其中树脂还含有传统抑制剂。
6.根据权利要求5的封堵化合物，其中还含有酚、醌或吩噻嗪。
7.根据权利要求1的封堵化合物，其中固化剂是有机过氧化物，按树脂计，其用量为0.5～10％(重)。
8.根据权利要求1的封堵化合物，其中组分I除树脂外还包括水硬固化的或可缩聚的无机化合物，而组分III除固化剂外还包括水。
9.一种装有权利要求1的封堵化合物的封囊、料管或薄膜袋，它有两个或两个以上分别装树脂和固化剂的相互分开的小室。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19531649.5 | 1995-08-29 | ||
| DE19531649A DE19531649A1 (de) | 1995-08-29 | 1995-08-29 | Dübelmasse für die chemische Befestigungstechnik |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1148075A true CN1148075A (zh) | 1997-04-23 |
| CN1140602C CN1140602C (zh) | 2004-03-03 |
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ID=7770608
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB961116889A Expired - Lifetime CN1140602C (zh) | 1995-08-29 | 1996-08-29 | 化学紧固用封堵化合物及其制品 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5854305A (zh) |
| EP (1) | EP0761792B1 (zh) |
| JP (2) | JPH09143380A (zh) |
| CN (1) | CN1140602C (zh) |
| AT (1) | ATE190993T1 (zh) |
| DE (2) | DE19531649A1 (zh) |
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Families Citing this family (88)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE287901T1 (de) * | 1999-12-09 | 2005-02-15 | Ciba Sc Holding Ag | Verwendung von einer zusatzzusammensetzung zur erhöhung der lagerstabilität von äthylenischen ungesättigten harzen |
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Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6028478A (ja) * | 1983-07-27 | 1985-02-13 | Asahi Chem Ind Co Ltd | 耐食性に優れたボルト固定用固着材 |
| DE3569514D1 (en) * | 1984-03-22 | 1989-05-24 | Ciba Geigy Ag | Process for the preparation of nitroxyls of sterically hindered amines |
| JPS62187710A (ja) * | 1986-02-14 | 1987-08-17 | Kohjin Co Ltd | アクリルモノマ−用重合禁止剤 |
| US5256723A (en) * | 1989-12-05 | 1993-10-26 | Hilti Aktiengesellschaft | Cartridge having hardenable cycloaliphatic derivatives for bore hole-filling masses |
| US5290888A (en) * | 1990-07-20 | 1994-03-01 | Ciba-Geigy Corporation | Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions |
| DE4111828A1 (de) * | 1991-04-11 | 1992-10-15 | Basf Ag | Patrone fuer die chemische befestigungstechnik |
| JP3197947B2 (ja) * | 1992-05-21 | 2001-08-13 | 株式会社クラレ | （メタ）アクリル酸の重合防止法 |
| US5254760A (en) * | 1992-07-29 | 1993-10-19 | Ciba-Geigy Corporation | Inhibiting polymerization of vinyl aromatic monomers |
| DE4231161A1 (de) * | 1992-09-17 | 1994-03-24 | Hilti Ag | Mörtel und Vorrichtung zur Befestigung von Verankerungsmitteln in Bohrlöchern |
| JP2725593B2 (ja) * | 1993-04-15 | 1998-03-11 | 株式会社日本触媒 | （メタ）アクリル酸およびそのエステルの重合防止方法 |
-
1995
- 1995-08-29 DE DE19531649A patent/DE19531649A1/de not_active Withdrawn
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1996
- 1996-08-19 DE DE59604743T patent/DE59604743D1/de not_active Expired - Lifetime
- 1996-08-19 EP EP96113239A patent/EP0761792B1/de not_active Expired - Lifetime
- 1996-08-19 AT AT96113239T patent/ATE190993T1/de active
- 1996-08-22 US US08/701,389 patent/US5854305A/en not_active Expired - Lifetime
- 1996-08-28 JP JP8226536A patent/JPH09143380A/ja active Pending
- 1996-08-29 CN CNB961116889A patent/CN1140602C/zh not_active Expired - Lifetime
-
2007
- 2007-02-02 JP JP2007024535A patent/JP2007197730A/ja not_active Withdrawn
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105408278A (zh) * | 2013-07-24 | 2016-03-16 | 喜利得股份公司 | 反应树脂灰浆、多组分灰浆体系和它们的用途 |
| CN106147731A (zh) * | 2015-04-10 | 2016-11-23 | 中国石油化工股份有限公司 | 一种用作堵漏剂的可自固化组合物及其应用 |
| CN106147731B (zh) * | 2015-04-10 | 2019-10-08 | 中国石油化工股份有限公司 | 一种用作堵漏剂的可自固化组合物及其应用 |
| CN110869404A (zh) * | 2017-07-10 | 2020-03-06 | 喜利得股份公司 | 用于生产具有改进的储存稳定性的含有tempol的氨基甲酸酯树脂组合物的方法 |
| CN110869404B (zh) * | 2017-07-10 | 2022-03-04 | 喜利得股份公司 | 用于生产具有改进的储存稳定性的含有tempol的氨基甲酸酯树脂组合物的方法 |
| CN112638984A (zh) * | 2018-09-14 | 2021-04-09 | 喜利得股份公司 | 反应性胺促进剂、含有所述促进剂的反应性树脂及其使用 |
| CN112638984B (zh) * | 2018-09-14 | 2023-05-16 | 喜利得股份公司 | 反应性胺促进剂、含有所述促进剂的反应性树脂及其使用 |
| US11859069B2 (en) | 2018-09-14 | 2024-01-02 | Hilti Aktiengesellschaft | Reactive amine accelerator, a reactive resin containing said accelerator, and the use thereof |
| CN115698117A (zh) * | 2020-06-25 | 2023-02-03 | Dic株式会社 | 自由基固化性树脂组合物、纤维强化成形材料及使用其的成形品 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0761792A3 (de) | 1998-07-01 |
| EP0761792A2 (de) | 1997-03-12 |
| US5854305A (en) | 1998-12-29 |
| CN1140602C (zh) | 2004-03-03 |
| JPH09143380A (ja) | 1997-06-03 |
| DE59604743D1 (de) | 2000-04-27 |
| ATE190993T1 (de) | 2000-04-15 |
| EP0761792B1 (de) | 2000-03-22 |
| JP2007197730A (ja) | 2007-08-09 |
| DE19531649A1 (de) | 1997-03-06 |
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