CN114804669A - 一种电解锰渣的无害化处置方法 - Google Patents
一种电解锰渣的无害化处置方法 Download PDFInfo
- Publication number
- CN114804669A CN114804669A CN202210640780.0A CN202210640780A CN114804669A CN 114804669 A CN114804669 A CN 114804669A CN 202210640780 A CN202210640780 A CN 202210640780A CN 114804669 A CN114804669 A CN 114804669A
- Authority
- CN
- China
- Prior art keywords
- leaching
- electrolytic manganese
- manganese slag
- column
- microwave
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 81
- 239000011572 manganese Substances 0.000 title claims abstract description 81
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 69
- 239000002893 slag Substances 0.000 title claims abstract description 68
- 238000000034 method Methods 0.000 title claims abstract description 36
- 238000002386 leaching Methods 0.000 claims abstract description 157
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 238000005303 weighing Methods 0.000 claims abstract description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 27
- 238000007789 sealing Methods 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 11
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 2
- 230000007246 mechanism Effects 0.000 claims description 2
- 230000008901 benefit Effects 0.000 abstract description 10
- 239000003344 environmental pollutant Substances 0.000 abstract description 8
- 231100000719 pollutant Toxicity 0.000 abstract description 8
- 238000006243 chemical reaction Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- 238000003756 stirring Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000007791 liquid phase Substances 0.000 abstract description 3
- 238000004904 shortening Methods 0.000 abstract description 2
- 239000007790 solid phase Substances 0.000 abstract description 2
- 230000002572 peristaltic effect Effects 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 5
- 238000010828 elution Methods 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 4
- 238000011105 stabilization Methods 0.000 description 4
- 230000000087 stabilizing effect Effects 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- 235000012255 calcium oxide Nutrition 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 244000088401 Pyrus pyrifolia Species 0.000 description 1
- 235000001630 Pyrus pyrifolia var culta Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 238000009270 solid waste treatment Methods 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B5/00—Treatment of metallurgical slag ; Artificial stone from molten metallurgical slag
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/30—Destroying solid waste or transforming solid waste into something useful or harmless involving mechanical treatment
- B09B3/38—Stirring or kneading
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/70—Chemical treatment, e.g. pH adjustment or oxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B5/00—Operations not covered by a single other subclass or by a single other group in this subclass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Processing Of Solid Wastes (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN202210640780.0A CN114804669B (zh) | 2022-06-07 | 2022-06-07 | 一种电解锰渣的无害化处置方法 |
Applications Claiming Priority (1)
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CN202210640780.0A CN114804669B (zh) | 2022-06-07 | 2022-06-07 | 一种电解锰渣的无害化处置方法 |
Publications (2)
Publication Number | Publication Date |
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CN114804669A true CN114804669A (zh) | 2022-07-29 |
CN114804669B CN114804669B (zh) | 2023-07-07 |
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CN202210640780.0A Active CN114804669B (zh) | 2022-06-07 | 2022-06-07 | 一种电解锰渣的无害化处置方法 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116082011A (zh) * | 2022-12-27 | 2023-05-09 | 贵州大学 | 一种电解锰渣生产加气混凝土砌块及其制备方法 |
CN116375383A (zh) * | 2022-12-27 | 2023-07-04 | 贵州大学 | 一种电解锰渣制备水泥外加剂及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011129336A (ja) * | 2009-12-17 | 2011-06-30 | Tosoh Corp | 電池からのマンガンの回収方法 |
CN103817132A (zh) * | 2013-12-13 | 2014-05-28 | 中国环境科学研究院 | 一种电解锰渣处理系统 |
CN107838188A (zh) * | 2017-11-24 | 2018-03-27 | 云南民族大学 | 一种植入式微波土壤淋洗柱制作方法 |
CN108262336A (zh) * | 2018-02-24 | 2018-07-10 | 昆明理工大学 | 一种电解锰渣的固化处理方法 |
CN109622566A (zh) * | 2018-12-24 | 2019-04-16 | 长沙湘朴科技有限公司 | 一种电解锰渣无害化处理方法 |
-
2022
- 2022-06-07 CN CN202210640780.0A patent/CN114804669B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011129336A (ja) * | 2009-12-17 | 2011-06-30 | Tosoh Corp | 電池からのマンガンの回収方法 |
CN103817132A (zh) * | 2013-12-13 | 2014-05-28 | 中国环境科学研究院 | 一种电解锰渣处理系统 |
CN107838188A (zh) * | 2017-11-24 | 2018-03-27 | 云南民族大学 | 一种植入式微波土壤淋洗柱制作方法 |
CN108262336A (zh) * | 2018-02-24 | 2018-07-10 | 昆明理工大学 | 一种电解锰渣的固化处理方法 |
CN109622566A (zh) * | 2018-12-24 | 2019-04-16 | 长沙湘朴科技有限公司 | 一种电解锰渣无害化处理方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116082011A (zh) * | 2022-12-27 | 2023-05-09 | 贵州大学 | 一种电解锰渣生产加气混凝土砌块及其制备方法 |
CN116375383A (zh) * | 2022-12-27 | 2023-07-04 | 贵州大学 | 一种电解锰渣制备水泥外加剂及其制备方法 |
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Publication number | Publication date |
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CN114804669B (zh) | 2023-07-07 |
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Inventor after: Yin Hao Inventor after: Qi Yutong Inventor after: Lou Wei Inventor after: Zhou Hua Inventor after: Lu Peng Inventor after: Huang Yuqing Inventor after: Cao Yafeng Inventor after: Wang Linling Inventor after: Chen Jing Inventor after: Liu Tianlun Inventor before: Yin Hao Inventor before: Lou Wei Inventor before: Qi Yutong Inventor before: Zhou Hua Inventor before: Cao Yafeng Inventor before: Liu Tianlun |
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