CN114789129A - UV-super matte skin-feel surface coating method and surface coating paint applied to woodware coating - Google Patents
UV-super matte skin-feel surface coating method and surface coating paint applied to woodware coating Download PDFInfo
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- CN114789129A CN114789129A CN202210579109.XA CN202210579109A CN114789129A CN 114789129 A CN114789129 A CN 114789129A CN 202210579109 A CN202210579109 A CN 202210579109A CN 114789129 A CN114789129 A CN 114789129A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
- B05D5/061—Special surface effect
- B05D5/062—Wrinkled, cracked or ancient-looking effect
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
- B05D3/065—After-treatment
- B05D3/067—Curing or cross-linking the coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/06—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2502/00—Acrylic polymers
- B05D2502/005—Acrylic polymers modified
Abstract
The invention discloses a UV-ultra matte skin-feel top coating method and a top coating paint applied to woodware coating. The UV-ultra matte skin-feel paint is prepared by adopting special raw materials and compatibility of the materials, and then the effects of eliminating light and having skin feel are achieved by matching special excimer equipment and technology. The UV-super-matte skin-feel paint selects the resin with good elasticity, moderate crosslinking density and good surface curing from the selection of the UV resin, the resin can provide a soft framework, the surface curing is good, the special excimer curing equipment is matched, the paint film forms wrinkle textures on the surface after the excimer lamp curing to obtain super-matte, the addition amount of matte powder is reduced, the hand feeling of the paint film is greatly improved, and the leveling property of the paint surface is excellent.
Description
Technical Field
The invention relates to a coating method and a coating, in particular to a UV-ultra matte skin-feel surface coating method and a surface coating applied to woodware coating.
Background
As a new material which rises from the beginning of the 20 th century in the 70 th, the UV curing coating is increasingly widely applied due to the characteristics of high curing speed, excellent coating performance, energy conservation, no solvent emission and the like. The matt coating film can give elegant and comfortable feeling to people, and the soft gloss gives beautiful enjoyment to people. 95% of furniture floor coatings abroad are matt coatings, and woodware coatings are also moving from bright to matt in china.
The UV curing coating has fast curing speed and high efficiency, and generally, the curing film forming is completed within a few seconds. As known from the film forming mechanism of the coating, as long as double bonds are crosslinked to form a film, the crosslinking density is large, the distance between bonds is shortened, the gloss is higher, and the photocuring volume is reduced, not shrinkage and wrinkling, but the distance between molecules is reduced, so that the surface is more rigid, firmer and higher in gloss.
According to a conventional extinction mechanism, a certain roughness is given to the surface, namely, the crosslinking density is reduced, and some crosslinking structures are changed; and secondly, the matting powder is added to scatter and matting the paint film. At present, because the matte finish paint on the market has large powder quantity, the finish paint has poor transparency and touch and soft visual effect.
Disclosure of Invention
The invention aims to: in order to solve the problems in the prior art, the invention provides a UV-super matte skin-feel surface coating method and a surface coating paint which have super matte, exquisite and soft hand feeling and good visual effect and are applied to woodware coating.
The technical scheme is as follows: in order to achieve the above purpose, the invention adopts the following technical scheme:
a UV-ultra matte skin-feel top coating method applied to woodware coating is characterized in that a conventional UV roller coating process is adopted as a bottom coating, a UV-ultra matte skin-feel top coating process is adopted as a top coating, and a special excimer device laser roller device is adopted to perform roller coating by adopting a UV-ultra matte skin-feel top coating.
Furthermore, the coating amount of the UV-ultra matte surface-sensitive coating adopted by the roller coating process of the laser roller equipment is 25-40g/m 2 。
Furthermore, the surface coating process specifically comprises the following steps:
s1: coating with a laser roller to obtain a paint film with enough thickness and flatness;
s2: in the pre-curing stage, the UV-LED lamp with adjustable energy is pre-cured to provide a foundation for different skin-feel effects;
s3: curing by using an excimer lamp, wherein nitrogen is used for isolating oxygen on the surface of the coated substrate in the curing process of the excimer lamp to provide a wrinkled surface, so that ultra-matte gloss and different skin feeling effects are obtained;
s4: and (4) fully curing, curing by a conventional mercury lamp, and fully drying.
Further, the wavelength of the excimer lamp is 172 nm.
Furthermore, the curing energy of the full curing of the conventional mercury lamp is 350-450mj/cm 2 。
Further, the UV-super matte skin-feel top coating comprises the following preparation raw materials in parts by weight: 100 percent of UV resin 60-70 percent, 0.1-0.5 percent of defoaming agent, 0.5-1 percent of dispersing agent, 1-5 percent of skin-feel powder, 1-3 percent of hand feeling agent, 2-4 percent of initiator, 0.5-1.5 percent of anti-settling agent and the balance of monomer.
Further, the 100% UV-resin is a 3 functional UV urethane acrylic resin.
Furthermore, the monomer is acrylate, modified acrylate or a mixture thereof; good flexibility and high surface curing speed.
The skin feeling powder is superfine modified extinction powder or wax powder with the particle size of less than 3 mu m; the hand feeling agent is a fluorine-containing compound or an organic silicon auxiliary agent.
The defoaming agent is polysiloxane solution, polyacrylic acid high polymer or a mixture thereof; the dispersant is a high molecular weight block copolymer solution, a modified acrylic acid block copolymer solution or a mixture thereof; the initiator is aromatic ketone, benzoin and derivatives thereof or a mixture thereof, such as 184, 1173, TPO or a mixture thereof produced by CIBA; the anti-settling agent is fumed silica, polycarboxylic acid salts of polyamine amide, modified urea solution or a mixture thereof, such as BYK204 produced by Byk.
Furthermore, the UV-ultra matte skin-feel top coating is prepared by dispersing 100% of UV-resin, monomer, defoamer, dispersant and initiator, adding the anti-settling agent and the skin-feel powder, and uniformly dispersing; the liquid temperature does not exceed 60 ℃ during stirring.
Has the advantages that:
(1) the UV-ultra matte skin-feel paint is prepared by adopting special raw materials and compatibility of the materials, and then the effects of eliminating light and having skin feel are achieved by matching special excimer equipment and technology. The UV-super-matte skin-feel paint is characterized in that the UV resin is selected from resins with good elasticity, moderate crosslinking density and good surface curing, the resins can provide a soft framework, the surface curing is good, the UV-super-matte skin-feel paint is matched with special excimer curing equipment, the paint film forms wrinkle textures on the surface after the excimer lamp is cured to obtain super-matte, the addition amount of the matte powder is reduced, the hand feeling of the paint film is greatly improved, and the leveling property of the paint surface is excellent;
(2) the skin-feel powder of the UV-super-matte skin-feel coating disclosed by the invention has a specific particle size (below 3 microns), and the modified matting powder and the wax have small particle sizes while matting, so that fine and soft handfeel is provided; and finally, adding a hand feeling agent, wherein the hand feeling agent migrates to the surface of the coating in the reaction process of the coating, so that the surface tension of the coating is reduced, the fine smoothness is provided, and the paint film has the functions of fingerprint resistance and pollution resistance.
(3) A paint film subjected to surface coating has the surface effects of ultra-matte and skin feel, and has both aesthetic feeling and performance. The traditional extinction mode is abandoned, and the ultra-matte effect and the skin touch feeling are obtained by using a small amount of the matte powder.
Detailed Description
Example 1:
a UV-ultra matte skin-feel top coating method applied to woodware coating is characterized in that a conventional UV roller coating process is adopted as bottom coating, a UV-ultra matte skin-feel top coating process is adopted as top coating, a special excimer device laser roller device is specifically used for carrying out roller coating by adopting UV-ultra matte skin-feel top coating, and the coating weight is 25g/m 2 。
The surface coating process comprises the following specific steps:
s1: coating with a laser roller to obtain a paint film with enough thickness and flatness;
s2: in the pre-curing stage, the UV-LED lamp with adjustable energy is used for pre-curing, and the curing energy is 20%; the UV-ultra matte skin feel effect coating with frosting effect can be obtained;
s3: curing by using an excimer lamp with the wavelength of 172nm, and isolating and coating oxygen on the surface of the substrate by using nitrogen in the curing process of the excimer lamp to provide a wrinkled surface, so that the ultra-matte luster and different skin feel effects are obtained;
s4: full curing, curing by a conventional mercury lamp and curing energy of 350mj/cm 2 And (4) drying comprehensively.
The UV-super matte skin-feel top coating comprises the following preparation raw materials in parts by weight: 100% of UV resin 70%, defoaming agent 0.3%, dispersing agent 0.5%, skin-feel powder 1%, hand feeling agent 2%, initiator 2%, anti-settling agent 0.5%, and the balance of monomer.
The 100% UV-resin is 3-functional UV polyurethane acrylic resin, and the specific manufacturer is SARTOMER; the monomer is modified acrylate, and the manufacturer is SARTOMER; good flexibility and high surface curing speed. The skin-feel powder is superfine modified matting powder or wax powder with the particle size of less than 3 mu m; the hand feeling agent is a fluorine-containing compound or an organic silicon auxiliary agent. The defoaming agent is polyacrylic acid high polymer; the dispersant is a high molecular weight block copolymer solution; the initiator is 1173 produced by CIBA; the anti-settling agent is BYK204 produced by Pico corporation.
The preparation method of the UV-super matte skin-feel top coating paint comprises the following steps: dispersing 100% of UV-resin, monomer, defoamer, dispersant and initiator, adding anti-settling agent and skin-feel powder, and dispersing uniformly, and finally adding hand-feel agent; the liquid temperature does not exceed 60 ℃ during stirring.
Example 2:
a UV-ultra matte skin-feel top coating method applied to woodware coating is characterized in that a conventional UV roller coating process is adopted as bottom coating, a UV-ultra matte skin-feel top coating process is adopted as top coating, a special excimer device laser roller device is specifically used for carrying out roller coating by adopting UV-ultra matte skin-feel top coating, and the coating weight is 40g/m 2 . The top coating process was the same as in example 1, except that the formulation of the UV-super matte skin-feel top coating was different. The method comprises the following specific steps:
the UV-super matte skin-feel top coating comprises the following preparation raw materials in parts by weight: 100% of UV resin 60%, defoaming agent 0.5%, dispersing agent 1.0%, skin-feel powder 5%, hand feeling agent 2%, initiator 4%, anti-settling agent 1.5%, and the balance monomer.
The 100% UV-resin is 3-functional UV polyurethane acrylic resin, and the specific manufacturer is CYTEC; the monomer is acrylate, and the manufacturer is CYTEC; good flexibility and high surface curing speed. The skin feeling powder is superfine modified extinction powder or wax powder with the particle size of less than 3 mu m; the hand feeling agent is a fluorine-containing compound or an organic silicon auxiliary agent. The defoaming agent is polysiloxane solution; the dispersant is a high molecular weight block copolymer solution; the initiator is 184 produced by CIBA; the anti-settling agent is BYK204 produced by Pico.
The preparation method of the UV-super matte skin-feel top coating comprises the following steps: dispersing 100% of UV-resin, monomer, defoamer, dispersant and initiator, adding anti-settling agent and skin feeling powder, and uniformly dispersing, and finally adding hand feeling agent, wherein the liquid temperature is not more than 60 ℃ during stirring.
Example 3:
a UV-super matte skin-feel top coating method applied to woodware coating is characterized in that a first coating is a conventional UV roller coating process, a top coating is a UV-super matte skin-feel top coating process, a special excimer device laser roller device is used for carrying out roller coating by adopting UV-super matte skin-feel top coating, and the coating amount is 25g/m 2 。
The surface coating process comprises the following steps:
s1: coating with a laser roller to obtain a paint film with enough thickness and flatness;
s2: in the pre-curing stage, pre-curing is carried out by an energy-adjustable UV-LED lamp, and the curing energy is 35%; the UV-ultra matte skin feel effect coating with micro-sanding effect can be obtained;
s3: curing by using an excimer lamp with the wavelength of 172nm, wherein nitrogen is used for isolating oxygen on the surface of the coated substrate in the curing process of the excimer lamp to provide a wrinkled surface, so that ultra-matte gloss and different skin feeling effects are obtained;
s4: full curing, curing by a conventional mercury lamp and curing energy of 350mj/cm 2 And (4) drying comprehensively.
The proportion and the preparation method of the UV-ultra matte skin-feel top coating are the same as those of the example 1, except that the curing energy of an LED lamp is adjusted.
The UV conventional matte top-coat paint is characterized in that the proportion is different from that of the UV conventional matte top-coat paint in examples 1-3, and the specific proportion is as follows: 100% of UV resin 20%, defoaming agent 0.4%, dispersing agent 3%, matting powder 18%, initiator 8%, anti-settling agent 0.5%, and the balance of monomers.
In addition, a comparative example 2 is set, which is a UV conventional matte top-coat, and the specific difference is that the top-coat process is different from that of examples 1-3, and the specific process is as follows:
the surface coating process comprises the following steps:
s1: coating with a flat rubber roller, wherein the coating weight is 4-6g/m 2 ；
S2: curing with a conventional mercury lamp at a curing energy of 60-70mj/cm 2
S3: coating with a flat rubber roller, wherein the coating weight is 4-6g/m 2 ；
S4: full curing, conventional mercury lamp curing, curing energy of 350- 2 。
The woodware coating surface coatings obtained by the surface coating application of examples 1 to 3 and comparative examples 1 to 2 were tested, and the specific performance indexes and the test methods are shown in table 1:
TABLE 1 results of performance testing of examples 1-3 and comparative examples 1-2
As can be seen from the data in Table 1, the UV-super matte skin feel effect coatings prepared in examples 1-3 of the present invention are slightly matte skin feel coatings with moderate gloss, and have significant advantages in gloss, stain resistance rating, fingerprint resistance, and surface feel compared to the coatings obtained in the UV conventional matte top coatings of comparative examples 1-2.
Claims (10)
1. A UV-super matte skin-feel top coating method applied to woodware coating is characterized in that a bottom coating is a conventional UV roller coating process, a top coating is a UV-super matte skin-feel top coating process, and a special excimer device laser roller device is specifically used for roller coating by adopting UV-super matte skin-feel top coating paint.
2. The UV-ultra matte skin-feel topcoat method applied to woodware coating according to claim 1, characterized in that: the coating weight of the UV-ultra matte skin-feel surface coating adopted by the roller coating process of the laser roller equipment is 25-40g/m 2 。
3. The UV-super matte skin-feel surface coating method applied to woodware coating according to claim 2, characterized in that the surface coating process specifically comprises:
s1: coating with a laser roller to obtain a paint film with enough thickness and flatness;
s2: in the pre-curing stage, the UV-LED lamp with adjustable energy is pre-cured to provide a foundation for different skin-feel effects;
s3: curing by using an excimer lamp, wherein nitrogen is used for isolating oxygen on the surface of the coated substrate in the curing process of the excimer lamp to provide a wrinkled surface, so that ultra-matte gloss and different skin feeling effects are obtained;
s4: full curing, curing by a conventional mercury lamp and full drying.
4. The UV-super matte skin-feel topcoat method applied to woodware coating according to claim 3, characterized in that: the wavelength of the excimer lamp is 172 nm.
5. The UV-super matte skin-feel top-coating method applied to woodware coating according to claim 3, characterized in that: the curing energy of the full curing of the conventional mercury lamp is 350-450mj/cm 2 。
6. A UV-ultra matte skin-feel topcoat paint for use in the topcoat method of any one of claims 1 to 5, characterized by comprising as preparation raw materials by weight: 100 percent of UV resin 60-70 percent, 0.1-0.5 percent of defoaming agent, 0.5-1 percent of dispersing agent, 1-5 percent of skin-feel powder, 1-3 percent of hand feeling agent, 2-4 percent of initiator, 0.5-1.5 percent of anti-settling agent and the balance of monomer.
7. The UV-ultra matte skin-feel topcoat paint of claim 6, characterized in that: the 100% UV-resin is a 3 functional UV polyurethane acrylic resin.
8. The UV-ultra matte skin-feel topcoat paint of claim 6, characterized in that: the monomer is acrylate, modified acrylate or their mixture.
9. The UV-ultra matte-feel topcoat coating of claim 6, wherein: the skin-feel powder is superfine modified matting powder or wax powder with the particle size of less than 3 mu m; the hand feeling agent is a fluorine-containing compound or an organic silicon auxiliary agent.
10. A method of making a UV-ultra matte-feel top-coat paint according to claim 6, characterized by comprising the steps of: dispersing 100% of UV-resin, monomer, defoamer, dispersant and initiator, adding anti-settling agent and skin feeling powder, and dispersing uniformly; the liquid temperature does not exceed 60 ℃ during stirring.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115651527A (en) * | 2022-09-13 | 2023-01-31 | 华容县恒兴建材有限公司 | Ultra-matte skin-feel ultraviolet curing coating and preparation method and curing method thereof |
| CN115780216A (en) * | 2022-12-23 | 2023-03-14 | 惠州市摩彩装饰材料有限公司 | Preparation method of antibacterial and aldehyde-removing UV excimer skin-feel coating plate |
| CN115926232A (en) * | 2022-11-21 | 2023-04-07 | 台州市纸巴鹿建材有限公司 | Antibacterial matte skin-feel decorative material and preparation method thereof |
| CN116063920A (en) * | 2023-02-02 | 2023-05-05 | 广东立邦长润发科技材料有限公司 | Excimer nitrogen protection curing UV coating and curing process thereof |
| CN116285634A (en) * | 2022-12-30 | 2023-06-23 | 常州市贝美家居科技有限公司 | Wallboard coating, skin-feel stain-resistant wallboard and processing method thereof |
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