CN111253819A - High-wear-resistance matte low-release transfer photo-curing coating composition and preparation method thereof - Google Patents
High-wear-resistance matte low-release transfer photo-curing coating composition and preparation method thereof Download PDFInfo
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- CN111253819A CN111253819A CN202010264698.3A CN202010264698A CN111253819A CN 111253819 A CN111253819 A CN 111253819A CN 202010264698 A CN202010264698 A CN 202010264698A CN 111253819 A CN111253819 A CN 111253819A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Abstract
The invention discloses a high-wear-resistance matte low-release transfer photocureable coating composition and a preparation method thereof, wherein the coating composition comprises the following components in parts by weight: 65-80 parts of self-extinction acrylic resin, 5-15 parts of silicon-fluorine modified polyester acrylic resin, 5-10 parts of monomer, 5-10 parts of photoinitiator, 0.5-1 part of auxiliary agent and 30-80 parts of solvent. The invention provides high wear resistance and can effectively reduce phase splitting caused by adding matting powder and improve storage stability through high wear-resistant acrylic acid with self-matting groups, and simultaneously, a coating with low release force can be obtained after ultraviolet curing of the coating composition by introducing the silicon-fluorine modified polyester acrylic acid with low release effect, so that the coating composition can be better used in a transfer printing technology.
Description
Technical Field
The invention relates to the technical field of photocureable coating, in particular to a high-wear-resistance matte low-release transfer photocureable coating composition and a preparation method thereof.
Background
The artificial leather such as PVC, PU and the like is widely applied to the fields of bags, furniture and the like due to the advantages of high glossiness, rich colors, air permeability and the like. With the increasing demand of people on decorative aesthetic feeling, the requirements on the glossiness and the apparent texture of leather are different, such as bright leather, matte leather and the like. The carrier film of the prior matte leather is mainly transfer release paper, which has the advantage of high temperature resistance, but has the defects of tearing resistance, less transfer reuse times and the like.
Disclosure of Invention
In view of the above, the present invention is directed to the defects of the prior art, and the main object of the present invention is to provide a high abrasion-resistant matte low-release transfer photo-curable coating composition and a preparation method thereof, which can improve the tear resistance and transfer repetition times of a transfer carrier film, improve the abrasion resistance of a matte transfer coating, and provide a lower release force performance.
In order to achieve the purpose, the invention adopts the following technical scheme:
a high-wear-resistance matte low-release transfer printing photocureable coating composition comprises the following components in parts by weight: 65-80 parts of self-extinction acrylic resin, 5-15 parts of silicon-fluorine modified polyester acrylic resin, 5-10 parts of monomer, 5-10 parts of photoinitiator, 0.5-1 part of auxiliary agent and 30-80 parts of solvent.
As a preferable scheme, the self-extinction acrylic resin is obtained by in-situ polymerization of extinction powder.
Preferably, the silicon-fluorine polyester acrylic resin is one or more of nine-reaction-functionality silicon-fluorine modified polyester acrylic acid, ten-reaction-functionality silicon-fluorine modified polyester acrylic acid and twelve-reaction-functionality silicon-fluorine modified polyester acrylic acid.
Preferably, the monomer is one or more of a tri-reaction functional monomer and a tetra-reaction functional monomer.
Preferably, the photoinitiator is one or more of cracking type photoinitiator and hydrogen abstraction type photoinitiator.
As a preferable scheme, the auxiliary agent is one or more of a leveling agent, a defoaming agent and a wetting agent.
Preferably, the solvent is one or more of ethyl acetate, butyl acetate, methyl isobutyl ketone and propylene glycol monomethyl ether.
A preparation method of the high-wear-resistance matte low-release transfer printing photocureable coating composition comprises the steps of adding self-extinction acrylic resin, silicon-fluorine modified polyester acrylic resin, a monomer, a photoinitiator, an auxiliary agent and a solvent into a container, mixing and uniformly stirring.
Compared with the prior art, the invention has obvious advantages and beneficial effects, and specifically, the technical scheme includes that:
the invention provides high wear resistance and can effectively reduce phase splitting caused by adding matting powder and improve storage stability through high wear-resistant acrylic acid with self-matting groups, and simultaneously, a coating with low release force can be obtained after ultraviolet curing of the coating composition by introducing the silicon-fluorine modified polyester acrylic acid with low release effect, so that the coating composition can be better used in a transfer printing technology.
Detailed Description
The invention discloses a high-wear-resistance matte low-release transfer printing photocureable coating composition which comprises the following components in parts by weight: 65-80 parts of self-extinction acrylic resin, 5-15 parts of silicon-fluorine modified polyester acrylic resin, 5-10 parts of monomer, 5-10 parts of photoinitiator, 0.5-1 part of auxiliary agent and 30-80 parts of solvent. The self-extinction acrylic resin is obtained by in-situ polymerization of extinction powder on acrylic resin. The silicon-fluorine polyester acrylic resin is one or more of nine-reaction-functionality silicon-fluorine modified polyester acrylic acid, ten-reaction-functionality silicon-fluorine modified polyester acrylic acid and twelve-reaction-functionality silicon-fluorine modified polyester acrylic acid. The monomer is one or more of a tri-reaction functional monomer and a tetra-reaction functional monomer. The photoinitiator is one or more of cracking type photoinitiators and hydrogen abstraction type photoinitiators. The auxiliary agent is one or more of a flatting agent, a defoaming agent and a wetting agent. The solvent is one or more of ethyl acetate, butyl acetate, methyl isobutyl ketone and propylene glycol monomethyl ether.
The invention also discloses a preparation method of the high-wear-resistance matte low-release transfer printing photocureable coating composition, which comprises the steps of adding self-extinction acrylic resin, silicon-fluorine modified polyester acrylic resin, a monomer, a photoinitiator, an auxiliary agent and a solvent into a container, mixing and uniformly stirring.
The invention is illustrated in more detail below in the following examples:
example 1:
a high-wear-resistance matte low-release transfer printing photocureable coating composition comprises the following components in parts by weight: 70 parts of self-extinction acrylic resin (three 5208), 15 parts of nine-reaction-functionality-degree silicon-fluorine-modified polyester acrylic resin, 10 parts of monomer (pentaerythritol tetraacrylate), 2.8 parts of photoinitiator (1-hydroxy-cyclohexyl acetone), 2.4 parts of photoinitiator (2-isopropyl thioxanthone), 0.5 part of auxiliary agent (BYK 111), 10 parts of ethyl acetate and 20 parts of butyl acetate.
The preparation method comprises the following steps: 70 parts by mass of self-extinction acrylic resin (three 5208), 15 parts by mass of nine-reaction-functionality-degree silicon-fluorine-modified polyester acrylic resin, 10 parts by mass of monomer (pentaerythritol tetraacrylate), 2.8 parts by mass of photoinitiator (1-hydroxy-cyclohexyl acetone), 2.4 parts by mass of photoinitiator (2-isopropyl thioxanthone), 0.5 part by mass of auxiliary agent (BYK 111), 10 parts by mass of ethyl acetate and 20 parts by mass of butyl acetate are mixed and uniformly stirred to prepare the high-wear-resistant matte low-release transfer-printing photocuring coating composition.
Example 2:
a high-wear-resistance matte low-release transfer printing photocureable coating composition comprises the following components in parts by weight: 75 parts by mass of self-extinction acrylic resin (three 5203 products), 10 parts by mass of ten-reaction-functionality-degree silicon-fluorine-modified polyester acrylic resin, 8 parts by mass of monomer (ethoxylated pentaerythritol tetraacrylate), 1.2 parts by mass of photoinitiator (benzophenone), 2.4 parts by mass of photoinitiator (2-isopropyl thioxanthone), 0.5 part by mass of auxiliary agent (BYK 333), 10 parts by mass of ethyl acetate, 20 parts by mass of butyl acetate and 12 parts by mass of methyl isobutyl ketone
The preparation method comprises the following steps: 75 parts by mass of self-extinction acrylic resin (three 5203), 10 parts by mass of ten-reaction-functionality-degree silicon-fluorine-modified polyester acrylic resin, 8 parts by mass of monomer (ethoxylated pentaerythritol tetraacrylate), 1.2 parts by mass of photoinitiator (benzophenone), 2.4 parts by mass of photoinitiator (2-isopropyl thioxanthone), 0.5 part by mass of auxiliary agent (BYK 333), 10 parts by mass of ethyl acetate, 20 parts by mass of butyl acetate and 12 parts by mass of methyl isobutyl ketone are mixed and uniformly stirred to prepare the high-abrasion-resistant matte low-release transfer-printing photocuring coating composition.
Example 3:
a high-wear-resistance matte low-release transfer printing photocureable coating composition comprises the following components in parts by weight: 80 parts by mass of self-extinction acrylic resin (lithochol L-6902A), 5 parts by mass of dodeca-reaction-functionality-degree silicon-fluorine-modified polyester acrylic resin, 8 parts by mass of monomer (pentaerythritol triacrylate), 1.2 parts by mass of photoinitiator (benzophenone), 2.4 parts by mass of photoinitiator (2-isopropyl thioxanthone), 0.5 part by mass of flatting agent (BYK-333), 0.2 part by mass of defoaming agent (BYK-014), 15 parts by mass of ethyl acetate, 15 parts by mass of butyl acetate and 12 parts by mass of methyl isobutyl ketone.
The preparation method comprises the following steps: 80 parts by mass of self-extinction acrylic resin (lithochol L-6902A), 5 parts by mass of dodecareactive functionality silicon fluorine modified polyester acrylic resin, 8 parts by mass of monomer (pentaerythritol triacrylate), 1.2 parts by mass of photoinitiator (benzophenone), 2.4 parts by mass of photoinitiator (2-isopropyl thioxanthone), 0.5 part by mass of flatting agent (BYK-333), 0.2 part by mass of defoaming agent (BYK-014), 15 parts by mass of ethyl acetate, 15 parts by mass of butyl acetate and 12 parts by mass of methyl isobutyl ketone are mixed and stirred uniformly to prepare the high-wear-resistant matte low-release transfer photo-curing coating composition.
Comparative example:
a transfer printing photocureable coating composition comprises the following components in parts by weight: 80 parts of non-high wear-resistant acrylic resin, 10 parts of polyester acrylic resin, 6 parts of monomer, 3.6 parts of photoinitiator (benzophenone), 8 parts of matting powder, 2.4 parts of photoinitiator (1-hydroxy-cyclohexyl acetone), 0.5 part of auxiliary agent, 25 parts of butyl acetate and 16 parts of methyl isobutyl ketone.
The preparation method comprises the following steps: 80 parts by mass of non-self-extinction acrylic resin, 10 parts by mass of silicon-fluorine modified polyester acrylic resin, 6 parts by mass of monomer, 3.6 parts by mass of photoinitiator (benzophenone), 8 parts by mass of extinction powder, 2.4 parts by mass of photoinitiator (1-hydroxy-cyclohexyl acetone), 0.5 part by mass of auxiliary agent, 25 parts by mass of butyl acetate and 16 parts by mass of methyl isobutyl ketone are mixed and stirred uniformly to prepare the transfer printing photocuring coating composition.
The photo-curable coating compositions prepared in the above examples and comparative examples were coated on a plastic substrate (125 μm PE base film as a performance test standard) and placed about 80 timesoDrying in a C oven for 1-2min, and irradiating with 400mJ/cm of radiation energy2The film is formed by curing, and the thickness of the film is about 3-4 microns. The properties thereof were measured and shown in Table 1.
TABLE 1
Adhesion force: testing was performed according to ASTM D3359.
Wear resistance: japanese Bonstar 0000# Steel wool, bearing a load of 1000g, rubbing head 1cm x 1cm, was observed for the maximum number of round trips without scratching.
Release force: testing according to GB/T25256-.
Gloss: tested according to ASTM-D523 GB 9754.
The invention adopts a new formula of a new process, particularly effectively adjusts the internal chemical structure and the molecular structure of the coating, provides a new process technology for the transfer printing release film, improves the tearing resistance and the transfer printing repetition times, and simultaneously has the performances of high wear resistance and low release force.
The design of the invention is characterized in that: the invention provides high wear resistance and can effectively reduce phase splitting caused by adding matting powder and improve storage stability through high wear-resistant acrylic acid with self-matting groups, and simultaneously, a coating with low release force can be obtained after ultraviolet curing of the coating composition by introducing the silicon-fluorine modified polyester acrylic acid with low release effect, so that the coating composition can be better used in a transfer printing technology.
The above description is only a preferred embodiment of the present invention, and is not intended to limit the technical scope of the present invention, so that any minor modifications, equivalent changes and modifications made to the above embodiment according to the technical spirit of the present invention are within the technical scope of the present invention.
Claims (8)
1. A high-wear-resistance matte low-release transfer printing photocureable coating composition is characterized in that: comprises the following components in parts by weight: 65-80 parts of self-extinction acrylic resin, 5-15 parts of silicon-fluorine modified polyester acrylic resin, 5-10 parts of monomer, 5-10 parts of photoinitiator, 0.5-1 part of auxiliary agent and 30-80 parts of solvent.
2. The high abrasion matte low release transfer photocuring coating composition according to claim 1, characterized in that: the self-extinction acrylic resin is obtained by in-situ polymerization of extinction powder on acrylic resin.
3. The high abrasion matte low release transfer photocuring coating composition according to claim 1, characterized in that: the silicon-fluorine polyester acrylic resin is one or more of nine-reaction-functionality silicon-fluorine modified polyester acrylic acid, ten-reaction-functionality silicon-fluorine modified polyester acrylic acid and twelve-reaction-functionality silicon-fluorine modified polyester acrylic acid.
4. The high abrasion matte low release transfer photocuring coating composition according to claim 1, characterized in that: the monomer is one or more of a tri-reaction functional monomer and a tetra-reaction functional monomer.
5. The high abrasion matte low release transfer photocuring coating composition according to claim 1, characterized in that: the photoinitiator is one or more of cracking type photoinitiators and hydrogen abstraction type photoinitiators.
6. The high abrasion matte low release transfer photocuring coating composition according to claim 1, characterized in that: the auxiliary agent is one or more of a flatting agent, a defoaming agent and a wetting agent.
7. The high abrasion matte low release transfer photocuring coating composition according to claim 1, characterized in that: the solvent is one or more of ethyl acetate, butyl acetate, methyl isobutyl ketone and propylene glycol monomethyl ether.
8. A method for preparing the high abrasion resistant matte low release transfer photo-curing coating composition according to any one of claims 1 to 7, which is characterized in that: adding self-extinction acrylic resin, silicon-fluorine modified polyester acrylic resin, a monomer, a photoinitiator, an auxiliary agent and a solvent into a container, mixing and uniformly stirring.
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| CN202010264698.3A CN111253819A (en) | 2020-04-07 | 2020-04-07 | High-wear-resistance matte low-release transfer photo-curing coating composition and preparation method thereof |
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| CN202010264698.3A CN111253819A (en) | 2020-04-07 | 2020-04-07 | High-wear-resistance matte low-release transfer photo-curing coating composition and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112521856A (en) * | 2020-09-24 | 2021-03-19 | 湖南松井新材料股份有限公司 | UV (ultraviolet) silicon touch matte coating and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060282960A1 (en) * | 2003-08-25 | 2006-12-21 | Pearson Jason C | Ethylenically-unsaturated blue anthraquinone dyes |
| CN106833357A (en) * | 2017-01-16 | 2017-06-13 | 哈尔滨工业大学无锡新材料研究院 | A kind of ultraviolet light cured burnished paint and preparation method thereof |
| CN110802976A (en) * | 2019-10-16 | 2020-02-18 | 武汉华工图像技术开发有限公司 | Holographic thermoprinting film and preparation method thereof, holographic water transfer printing paper and preparation method thereof |
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2020
- 2020-04-07 CN CN202010264698.3A patent/CN111253819A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060282960A1 (en) * | 2003-08-25 | 2006-12-21 | Pearson Jason C | Ethylenically-unsaturated blue anthraquinone dyes |
| CN106833357A (en) * | 2017-01-16 | 2017-06-13 | 哈尔滨工业大学无锡新材料研究院 | A kind of ultraviolet light cured burnished paint and preparation method thereof |
| CN110802976A (en) * | 2019-10-16 | 2020-02-18 | 武汉华工图像技术开发有限公司 | Holographic thermoprinting film and preparation method thereof, holographic water transfer printing paper and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112521856A (en) * | 2020-09-24 | 2021-03-19 | 湖南松井新材料股份有限公司 | UV (ultraviolet) silicon touch matte coating and preparation method and application thereof |
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