CN106833357A - A kind of ultraviolet light cured burnished paint and preparation method thereof - Google Patents
A kind of ultraviolet light cured burnished paint and preparation method thereof Download PDFInfo
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- CN106833357A CN106833357A CN201710028881.1A CN201710028881A CN106833357A CN 106833357 A CN106833357 A CN 106833357A CN 201710028881 A CN201710028881 A CN 201710028881A CN 106833357 A CN106833357 A CN 106833357A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention discloses a kind of ultraviolet light cured burnished paint, the low luster coating is made up of the component B of the component A and 75~55wt% of 25~45wt%, wherein, component A is the urethane acrylate obtained by the reaction of polyethylene glycol adipate, IPDI and hydroxy-ethyl acrylate；Component B includes nine degree of functionality urethane acrylates, three-functionality-degree urethane acrylate, double pentaerythritol methacrylate, three（2 ethoxys）Isocyanuric acid triacrylate, 1,6 hexanediyl esters, double pentaerythritol C5 methacrylate and crack type photoinitiator.The coating that the coating is formed has good pliability, also has excellent hardness concurrently, and is added without delustring filler and can just reach matte effect, and curing rate is fast, energy-conserving and environment-protective, the advantages of storage stability is good.
Description
Technical field
The present invention relates to a kind of ultraviolet light cured burnished paint and preparation method thereof.
Background technology
Recently as the continuous improvement of people's living standard, requirement of the people to quality of life also more and more higher.For
Articles for daily use, no matter in outward appearance or sense of touch, constantly pursue brand-new, comfortable experience.Therefore many height of current era
Shelves articles for use, start, with attractive in appearance, comfortable profile and sense of touch, to attract popular attention.The application of dumb light coating is also just arisen at the historic moment.
It with appearance attractive in appearance, comfortable Human physiology sense of touch, gradually in industries such as automotive trim, electronic products, account for a seat it
Ground, and increasingly obtain more favors.
But the technology of production low luster coating is mainly using inorganic filler is added now, i.e., to adding one in the system of coating
Quantitative delustring auxiliary agent, silica or alundum (Al2O3) of predominantly various particle diameters etc..Because the introducing of this auxiliary agent cannot
System is dissolved each other with filler, coating is in a kind of unsure state, storage and when using, sinking due to filler in the later stage
Drop may cause, and inorganic filler is located at container bottom, influence the Painting effect in later stage, and production is had undesirable effect.
The content of the invention
The technical problem to be solved in the present invention is to overcome existing defect, there is provided a kind of ultraviolet light without inorganic filler
Light cured burnished paint and preparation method thereof.
In order to solve the above-mentioned technical problem, the invention provides following technical scheme：
A kind of ultraviolet light cured burnished paint, is made up of the component B of the component A and 75~55wt% of 25~45wt%,
Wherein, component A is obtained by the reaction of polyethylene glycol adipate, IPDI and hydroxy-ethyl acrylate
Urethane acrylate；
Component B includes nine degree of functionality urethane acrylates, three-functionality-degree urethane acrylate, the acrylic acid of bipentaerythrite six
Ester, three（2- ethoxys）Isocyanuric acid triacrylate, 1,6 hexanediol diacrylate, double pentaerythritol C5 methacrylate and
Crack type photoinitiator.
Preferably, count by weight, component A is by polyethylene glycol adipate 30-50 parts, IPDI
35-45 parts and hydroxy-ethyl acrylate 10-20 parts should obtain.
Preferably, added in the reaction of polyethylene glycol adipate, toluene di-isocyanate(TDI) and hydroxy-ethyl acrylate anti-
Oxidant, polymerization inhibitor and catalyst.Preferably, the antioxidant is 2,6- di-tert-butyl-4-methy phenols, and consumption is 2~5
Weight portion, the polymerization inhibitor is MEHQ, and consumption is 2~5 weight portions, and the catalyst is di lauric dibutyl
Tin, consumption is 2~5 weight portions.
Preferably, in component B, the parts by weight of each raw material are as follows：Nine 5~30 parts of degree of functionality urethane acrylates, three
5~25 parts of degree of functionality urethane acrylate, 5~20 parts of double pentaerythritol methacrylate, three（2- ethoxys）Isocyanide urea
10~40 parts of sour triacrylate, 30~50 parts of 1,6 hexanediol diacrylate, double pentaerythritol C5 methacrylate 5~15
Part, 3~9 parts of crack type photoinitiator.
Preferably, the crack type photoinitiator by 1~5 weight portion 1- hydroxycyclohexyl phenyl ketones and 1~5 weight
2- hydroxy-2-methyl -1- phenyl -1- acetone the composition of part.
The preparation method of above-mentioned ultraviolet light polymerization flexibility low luster coating, including：
（1）First under antioxidant, polymerization inhibitor effect, ethylene glycol adipate is reacted with toluene di-isocyanate(TDI), and reaction is completed
Afterwards, hydroxy-ethyl acrylate and catalyst, the component A that reaction is obtained are added；
（2）By nine degree of functionality urethane acrylates, three-functionality-degree urethane acrylate, double pentaerythritol methacrylate,
Three（2- ethoxys）Isocyanuric acid triacrylate, 1,6 hexanediol diacrylate, double pentaerythritol C5 methacrylate and split
Solution type light trigger is mixed, and obtains component B.
Preferably, step（1）Reaction temperature be 60~80 DEG C.
A kind of ultraviolet light cured burnished coating, mixes, ultraviolet light polymerization is obtained by by above-mentioned group A with component B.
The coating that coating of the present invention is formed has good pliability, also has excellent hardness concurrently, and be added without delustring
Filler can just reach matte effect, and curing rate is fast, the advantages of energy-conserving and environment-protective.It is main present invention, avoiding existing low luster coating
Matte effect is obtained by adding inorganic filler simultaneously again because filling settlement, dispersion inequality cause the unstable problem of storage.
Can be widely applied to gradually in decoration industries such as automotive trim, electronic products.
Specific embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
" part " of following presentation consumption is parts by weight.
1st, by 47 parts of polyethylene glycol adipates（The chemical industry of Jining 101, molecular weight is 500）It is different with 44 parts of isophorones two
Cyanate diisocyanate adds the 250ml four-necked bottles equipped with reflux condensing tube, thermometer, agitator and nitrogen inlet, adds 4
The antioxidant of part（2,6 di tert butyl 4 methyl phenol）With 5 parts of polymerization inhibitors（MEHQ）, under the protection of nitrogen
Heat up, after 80 DEG C of reaction 4h, cool to 60 DEG C, the hydroxy-ethyl acrylate and 4 parts of dibutyl tin laurate for adding 12 parts exist
60 DEG C of reaction 2h, obtain component A.
2nd, by 10 part of nine degree of functionality urethane acrylate（CN9013NS, Sartomer）, 25 parts of three-functionality-degree polyurethane three
Acrylate（CN989NS, Sartomer）, 5 parts of double pentaerythritol methacrylate, 10 parts of double pentaerythritol C5 methacrylates, 10
Part three（2- ethoxys）Isocyanuric acid triacrylate, 40 parts of 1,6 hexanediol diacrylates, cracking type light of 7 parts of compoundings draw
Hair agent mixes 10min in mixer with the speed of 1000r/min, obtains component B, wherein, the cracking type initiator of compounding is
Mixed with 5 parts of 2- hydroxy-2-methyl -1- phenyl -1- acetone by 2 parts of 1- hydroxycyclohexyl phenyl ketones.
3rd, the component B by 25 parts of component A with 75 parts mixes 15min in mixer with the speed of 1000r/min, will apply
Material is uniformly coated on by the BOPET film of sided corona treatment（400 μm of thickness）Surface, coating thickness is 3 μm, is then with power
The uv cure machine solidification 20s of 1000W, i.e., obtain ultraviolet light cured burnished coating in BOPET film.
Embodiment 2
" part " of following presentation consumption is parts by weight.
1st, by 47 parts of polyethylene glycol adipates（The chemical industry of Jining 101, molecular weight is 500）It is different with 44 parts of isophorones two
Cyanate diisocyanate adds the 250ml four-necked bottles equipped with reflux condensing tube, thermometer, agitator and nitrogen inlet, adds 4
The antioxidant of part（2,6 di tert butyl 4 methyl phenol）With 5 parts of polymerization inhibitors（MEHQ）, under the protection of nitrogen
Heat up, after 80 DEG C of reaction 4h, cool to 60 DEG C, add 12 parts of hydroxy-ethyl acrylate and tin dilaurate that mass fraction is 4 parts
Dibutyl tin reacts 2h at 60 DEG C, obtains component A.
2nd, by 15 part of nine degree of functionality urethane acrylate（CN9013NS, Sartomer）, 10 parts of three-functionality-degree polyurethane three
Acrylate（CN989NS, Sartomer）, 20 parts of double pentaerythritol methacrylate, 5 parts of Dipentaerythritol Pentaacrylates, 20
Part three（2- ethoxys）Isocyanuric acid triacrylate, 30 parts of 1,6 hexanediol diacrylates, cracking type light of 6 parts of compoundings draw
Hair agent mixes 10min in mixer with the speed of 1000r/min, obtains component B, wherein, the cracking type initiator of compounding is
Mixed with 1 part of 2- hydroxy-2-methyl -1- phenyl -1- acetone by 5 parts of 1- hydroxycyclohexyl phenyl ketones.
3rd, the component B by 30 parts of component A with 70 parts mixes 15min in mixer with the speed of 1000r/min, then
Coating is uniformly coated on by the BOPET film of sided corona treatment（400 μm of thickness）Surface, coating thickness is 5 μm, then hard
Rate is the uv cure machine solidification 10s of 1000W, i.e., ultraviolet light cured burnished coating is obtained in BOPET film.
Embodiment 3
" part " of following presentation consumption is parts by weight.
1st, by 47 parts of polyethylene glycol adipates（The chemical industry of Jining 101, molecular weight is 500）It is different with 44 parts of isophorones two
Cyanate diisocyanate adds the 250ml four-necked bottles equipped with reflux condensing tube, thermometer, agitator and nitrogen inlet, adds 4
The antioxidant of part（2,6 di tert butyl 4 methyl phenol）With 5 parts of polymerization inhibitors（MEHQ）, under the protection of nitrogen
Heat up, after 80 DEG C of reaction 4h, cool to 60 DEG C, add 12 parts of hydroxy-ethyl acrylate and tin dilaurate that mass fraction is 4 parts
Dibutyl tin reacts 2h at 60 DEG C, obtains component A.
2nd, by 12 part of nine degree of functionality urethane acrylate（CN9013NS, Sartomer）, 13 parts of three-functionality-degree polyurethane three
Acrylate（CN989NS, Sartomer）, 13 parts of double pentaerythritol methacrylate, 12 parts of Dipentaerythritol Pentaacrylates, 20
Part three（2- ethoxys）Isocyanuric acid triacrylate, 30 parts of 1,6 hexanediol diacrylates, cracking type light of 6 parts of compoundings draw
Hair agent mixes 30min in mixer with the speed of 500r/min, obtains component B, wherein, the cracking type initiator of compounding be by
3 parts of 1- hydroxycyclohexyl phenyl ketones are mixed with 3 parts of 2- hydroxy-2-methyl -1- phenyl -1- acetone.
3rd, the component B by 35 parts of component A with 65 parts mixes 15min in mixer with the speed of 1000r/min, then
Coating is uniformly coated on by the BOPET film of sided corona treatment（400 μm of thickness）Surface, coating thickness is 7 μm, then hard
Rate is the uv cure machine solidification 15s of 1000W, i.e., ultraviolet light cured burnished coating is obtained in BOPET film.
Embodiment 4
" part " of following presentation consumption is parts by weight.
1st, by 47 parts of polyethylene glycol adipates（The chemical industry of Jining 101, molecular weight is 500）It is different with 44 parts of isophorones two
Cyanate diisocyanate adds the 250ml four-necked bottles equipped with reflux condensing tube, thermometer, agitator and nitrogen inlet, adds 4
The antioxidant of part（2,6 di tert butyl 4 methyl phenol）With 5 parts of polymerization inhibitors（MEHQ）, under the protection of nitrogen
Heat up, after 80 DEG C of reaction 4h, cool to 60 DEG C, add 12 parts of hydroxy-ethyl acrylate and tin dilaurate that mass fraction is 4 parts
Dibutyl tin reacts 2h at 60 DEG C, obtains component A.
2nd, by 5 part of nine degree of functionality urethane acrylate（CN9013NS, Sartomer）, 15 parts of three-functionality-degree polyurethane 3 third
Olefin(e) acid ester（CN989NS, Sartomer）, 5 parts of double pentaerythritol methacrylates, 15 parts of Dipentaerythritol Pentaacrylates, 10 parts
Three（2- ethoxys）Isocyanuric acid triacrylate, 50 parts of 1,6 hexanediol diacrylates, 8 parts of cracking types for compounding are light-initiated
Agent mixes 50min in mixer with the speed of 200r/min, obtains component B, wherein, the cracking type initiator of compounding is by 1
Part 1- hydroxycyclohexyl phenyl ketones are mixed with 5 parts of 2- hydroxy-2-methyl -1- phenyl -1- acetone.
3rd, the component B by 35 parts of component A with 65 parts mixes 15min in mixer with the speed of 1000r/min, then
Coating is uniformly coated on by the BOPET film of sided corona treatment（400 μm of thickness）Surface, coating thickness is 3 μm, then hard
Rate is the uv cure machine solidification 15s of 1000W, i.e., ultraviolet light cured burnished coating is obtained in BOPET film.
Ultraviolet light cured burnished coating obtained in above-described embodiment is carried out into performance test, it is as a result as follows.
1st, the glossiness of dumb light coating can reach the requirement of dumb light below 60.
2nd, after by natural exposure 7d and ultraviolet light 10min, the phenomenons such as xanthochromia in coating, it was demonstrated that coating there is no
There is no big destruction in structure, it was demonstrated that coating has a good weatherability.
2nd, more than pencil hardness 3H, O grades of rub resistance, the wear-resistant scratch-resistant of coating can be good.
3rd, bending resistance is good, and only in the cylinder using a diameter of 2mm, coating just occurs a little rupture, it was demonstrated that coating has
There is good bending performance, also further illustrating coating has good pliability and adhesive force.Applied after 180 ° of doublings are carried out
Layer does not ftracture, and illustrates that processing characteristics and pliability are excellent.
Finally it should be noted that：The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention,
Although being described in detail to the present invention with reference to the foregoing embodiments, for a person skilled in the art, it still may be used
Modified with to the technical scheme described in foregoing embodiments, or equivalent is carried out to which part technical characteristic.
All any modification, equivalent substitution and improvements within the spirit and principles in the present invention, made etc., should be included in of the invention
Within protection domain.
Claims (9)
1. a kind of ultraviolet light cured burnished paint, is made up of the component B of the component A and 75~55wt% of 25~45wt%,
Wherein, component A is obtained by the reaction of polyethylene glycol adipate, IPDI and hydroxy-ethyl acrylate
Urethane acrylate；
Component B includes nine degree of functionality urethane acrylates, three-functionality-degree urethane acrylate, the acrylic acid of bipentaerythrite six
Ester, three（2- ethoxys）Isocyanuric acid triacrylate, 1,6 hexanediol diacrylate, double pentaerythritol C5 methacrylate and
Crack type photoinitiator.
2. ultraviolet light cured burnished paint according to claim 1, it is characterised in that：Count by weight, component A is by gathering
Ethylene glycol adipate 30-50 parts, IPDI 35-45 parts and hydroxy-ethyl acrylate 10-20 parts should obtain.
3. ultraviolet light cured burnished paint according to claim 1, it is characterised in that：In polyethylene glycol adipate, first
Antioxidant, polymerization inhibitor and catalyst are added in the reaction of phenylene diisocyanate and hydroxy-ethyl acrylate.
4. ultraviolet light cured burnished paint according to claim 3, it is characterised in that：The antioxidant is the uncles of 2,6- bis-
Butyl -4- methylphenols, the polymerization inhibitor is MEHQ, and the catalyst is dibutyl tin laurate.
5. ultraviolet light cured burnished paint according to claim 1, it is characterised in that：In component B, the weight portion of each raw material
Number is as follows：Nine 5~30 parts of degree of functionality urethane acrylates, 5~25 parts of three-functionality-degree urethane acrylate, double Ji Wusi
5~20 parts of six acrylate of alcohol, three（2- ethoxys）10~40 parts of isocyanuric acid triacrylate, the propylene of 1,6-HD two
30~50 parts of acid esters, 5~15 parts of double pentaerythritol C5 methacrylate, 3~9 parts of crack type photoinitiator.
6. ultraviolet light cured burnished paint according to claim 1 or 5, it is characterised in that：The crack type photoinitiator
By the 1- hydroxycyclohexyl phenyl ketones and the 2- hydroxy-2-methyl -1- phenyl -1- acetone groups of 1~5 weight portion of 1~5 weight portion
Into.
7. the method for preparing ultraviolet light cured burnished paint described in claim 1, including：
（1）First under antioxidant, polymerization inhibitor effect, polyethylene glycol adipate reacts with IPDI, instead
After the completion of answering, hydroxy-ethyl acrylate and catalyst, the component A that reaction is obtained are added；
（2）By nine degree of functionality urethane acrylates, three-functionality-degree urethane acrylate, double pentaerythritol methacrylate,
Three（2- ethoxys）Isocyanuric acid triacrylate, 1,6 hexanediol diacrylate, double pentaerythritol C5 methacrylate and split
Solution type light trigger is mixed, and obtains component B.
8. method according to claim 7, it is characterised in that step（1）Reaction temperature be 60~80 DEG C.
9. a kind of ultraviolet light cured burnished coating, mixes, ultraviolet light polymerization is obtained by by the group A described in claim 1 with component B
Arrive.
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| CN201710028881.1A CN106833357B (en) | 2017-01-16 | 2017-01-16 | A kind of ultraviolet light cured burnished paint and preparation method thereof |
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| CN201710028881.1A CN106833357B (en) | 2017-01-16 | 2017-01-16 | A kind of ultraviolet light cured burnished paint and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108997558A (en) * | 2018-08-07 | 2018-12-14 | 哈尔滨工业大学无锡新材料研究院 | A kind of more block UV-cured resins of aqueous three-arm star-shaped and preparation method thereof |
| CN111253819A (en) * | 2020-04-07 | 2020-06-09 | 广州四面体新材料科技有限公司 | High-wear-resistance matte low-release transfer photo-curing coating composition and preparation method thereof |
| CN112341599A (en) * | 2020-11-26 | 2021-02-09 | 广东立邦长润发科技材料有限公司 | Ultraviolet-curing matte resin and preparation method thereof |
| CN112680095A (en) * | 2020-12-18 | 2021-04-20 | 黎明化工研究设计院有限责任公司 | Ultraviolet-cured matte wear-resistant rubber floor paint |
| CN113603850A (en) * | 2021-08-31 | 2021-11-05 | 武汉中科先进技术研究院有限公司 | High-wear-resistance hydrophilic resin, high-wear-resistance solvent-free antifogging coating, and preparation method and application thereof |
| CN113698861A (en) * | 2021-02-04 | 2021-11-26 | 广东鼎立森新材料有限公司 | Dual-curing coating for curved surface and application thereof |
| WO2022133668A1 (en) * | 2020-12-21 | 2022-06-30 | 张佩嫦 | Uv curable matt resin and preparation method therefor |
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| CN111040102A (en) * | 2019-12-02 | 2020-04-21 | 中国科学院福建物质结构研究所 | Photosensitive resin and preparation method and application thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108997558A (en) * | 2018-08-07 | 2018-12-14 | 哈尔滨工业大学无锡新材料研究院 | A kind of more block UV-cured resins of aqueous three-arm star-shaped and preparation method thereof |
| CN111253819A (en) * | 2020-04-07 | 2020-06-09 | 广州四面体新材料科技有限公司 | High-wear-resistance matte low-release transfer photo-curing coating composition and preparation method thereof |
| CN112341599A (en) * | 2020-11-26 | 2021-02-09 | 广东立邦长润发科技材料有限公司 | Ultraviolet-curing matte resin and preparation method thereof |
| CN112680095A (en) * | 2020-12-18 | 2021-04-20 | 黎明化工研究设计院有限责任公司 | Ultraviolet-cured matte wear-resistant rubber floor paint |
| CN112680095B (en) * | 2020-12-18 | 2022-08-05 | 黎明化工研究设计院有限责任公司 | Ultraviolet-cured matte wear-resistant rubber floor paint |
| WO2022133668A1 (en) * | 2020-12-21 | 2022-06-30 | 张佩嫦 | Uv curable matt resin and preparation method therefor |
| CN113698861A (en) * | 2021-02-04 | 2021-11-26 | 广东鼎立森新材料有限公司 | Dual-curing coating for curved surface and application thereof |
| CN113603850A (en) * | 2021-08-31 | 2021-11-05 | 武汉中科先进技术研究院有限公司 | High-wear-resistance hydrophilic resin, high-wear-resistance solvent-free antifogging coating, and preparation method and application thereof |
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|---|---|
| CN106833357B (en) | 2019-06-28 |
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