CN106833357B - A kind of ultraviolet light cured burnished paint and preparation method thereof - Google Patents
A kind of ultraviolet light cured burnished paint and preparation method thereof Download PDFInfo
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- CN106833357B CN106833357B CN201710028881.1A CN201710028881A CN106833357B CN 106833357 B CN106833357 B CN 106833357B CN 201710028881 A CN201710028881 A CN 201710028881A CN 106833357 B CN106833357 B CN 106833357B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention discloses a kind of ultraviolet light cured burnished paint, the low luster coating is made of the component B of the component A and 75~55wt% of 25~45wt%, wherein, component A is the urethane acrylate reacted by polyethylene glycol adipate, isophorone diisocyanate and hydroxy-ethyl acrylate；Component B includes nine degree of functionality urethane acrylates, three-functionality-degree urethane acrylate, double pentaerythritol methacrylate, three (2- ethoxy) isocyanuric acid triacrylate, 1,6 hexanediol diacrylate, double pentaerythritol C5 methacrylate and crack type photoinitiators.The advantages that coating that the coating is formed has good flexibility, also has both excellent hardness, and be added without delustring filler to reach matte effect, and curing rate is fast, and energy conservation and environmental protection, storage stability are good.
Description
Technical field
The present invention relates to a kind of ultraviolet light cured burnished paints and preparation method thereof.
Background technique
Recently as continuous improvement of people's living standards, requirement of the people to quality of life is also higher and higher.For
Articles for daily use constantly pursue completely new, comfortable experience no matter in appearance or sense of touch.Therefore many height of current era
Shelves articles start to attract public attention with beautiful, comfortable shape and sense of touch.The application of dumb light coating is also just come into being.
It is with beautiful appearance, comfortable Human physiology sense of touch, gradually in industries such as automobile interior decoration, electronic products, Zhan get Yi seat it
Ground, and increasingly obtain more favors.
But now the technology of production low luster coating is added one into the system of coating mainly using inorganic filler is added
Quantitative delustring auxiliary agent, silica or aluminum oxide of predominantly various partial sizes etc..Since the introducing of this auxiliary agent can not
So that system is dissolved each other with filler, coating is made to be in a kind of unstable state, storage and in use, sinking due to filler in the later period
Drop may cause, and inorganic filler is located at container bottom, influences the Painting effect in later period, cause adverse effect to production.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the existing defects, provides a kind of ultraviolet light without inorganic filler
Light cured burnished paint and preparation method thereof.
In order to solve the above-mentioned technical problems, the present invention provides the following technical solutions:
A kind of ultraviolet light cured burnished paint is made of the component B of the component A and 75~55wt% of 25~45wt%,
Wherein, component A is to be reacted by polyethylene glycol adipate, isophorone diisocyanate and hydroxy-ethyl acrylate
The urethane acrylate arrived；
Component B includes nine degree of functionality urethane acrylates, three-functionality-degree urethane acrylate, dipentaerythritol 6 third
Olefin(e) acid ester, three (2- ethoxy) isocyanuric acid triacrylates, 1,6 hexanediol diacrylate, five acrylic acid of dipentaerythritol
Ester and crack type photoinitiator.
Preferably, according to parts by weight, component A is by 30-50 parts of polyethylene glycol adipate, isophorone diisocyanate
35-45 parts and hydroxy-ethyl acrylate 10-20 parts should obtain.
Preferably, it is added in the reaction of polyethylene glycol adipate, toluene di-isocyanate(TDI) and hydroxy-ethyl acrylate anti-
Oxidant, polymerization inhibitor and catalyst.Preferably, the antioxidant is 2,6- di-tert-butyl-4-methy phenol, and dosage is 2~5
Parts by weight, the polymerization inhibitor are p-hydroxyanisole, and dosage is 2~5 parts by weight, and the catalyst is di lauric dibutyl
Tin, dosage are 2~5 parts by weight.
Preferably, in component B, the parts by weight of each raw material are as follows: nine 5~30 parts of degree of functionality urethane acrylates, three
5~25 parts of degree of functionality urethane acrylate, 5~20 parts of double pentaerythritol methacrylate, three (2- ethoxy) isocyanide ureas
10~40 parts of sour triacrylate, 30~50 parts of 1,6 hexanediol diacrylate, double pentaerythritol C5 methacrylate 5~15
Part, 3~9 parts of crack type photoinitiator.
Preferably, the crack type photoinitiator by 1~5 parts by weight 1- hydroxycyclohexyl phenyl ketone and 1~5 weight
2- hydroxy-2-methyl -1- phenyl -1- acetone the composition of part.
Above-mentioned ultraviolet light solidifies the preparation method of flexible low luster coating, comprising:
(1) first under antioxidant, polymerization inhibitor effect, ethylene glycol adipate is reacted with toluene di-isocyanate(TDI), reaction
After the completion, hydroxy-ethyl acrylate and catalyst are added, the component A reacted；
(2) by nine degree of functionality urethane acrylates, three-functionality-degree urethane acrylate, six acrylic acid of dipentaerythritol
Ester, three (2- ethoxy) isocyanuric acid triacrylates, 1,6 hexanediol diacrylate, double pentaerythritol C5 methacrylate and
Crack type photoinitiator mixes, and obtains component B.
Preferably, the reaction temperature of step (1) is 60~80 DEG C.
A kind of ultraviolet light cured burnished coating, by mixing above-mentioned group A with component B, ultraviolet light solidifies to obtain.
The coating that coating of the present invention is formed has good flexibility, also has both excellent hardness, and be added without delustring
The advantages that filler can reach matte effect, and curing rate is fast, energy conservation and environmental protection.The invention avoids existing low luster coating is main
Matte effect is obtained by the way that inorganic filler is added simultaneously again because filling settlement, dispersion unevenness cause to store unstable problem.
It can be widely applied to gradually in decoration industries such as automobile interior decoration, electronic products.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
" part " of following presentation dosage is parts by weight.
1,47 parts of polyethylene glycol adipates (101 chemical industry of Jining, molecular weight 500) and 44 parts of isophorones two are different
The 250ml four-necked bottle that reflux condensing tube, thermometer, blender and nitrogen inlet are housed is added in cyanate diisocyanate, is added 4
The antioxidant (2,6- di-tert-butyl-4-methy phenol) of part and 5 parts of polymerization inhibitors (p-hydroxyanisole), under the protection of nitrogen
It heats up, after 80 DEG C of reaction 4h, cools to 60 DEG C, 12 parts of hydroxy-ethyl acrylate is added and 4 parts of dibutyl tin dilaurate exists
60 DEG C of reaction 2h, obtain component A.
2, by 10 part of nine degree of functionality urethane acrylate (CN9013NS, Sartomer), 25 parts of three-functionality-degree polyurethane three
Acrylate (CN989NS, Sartomer), 5 parts of double pentaerythritol methacrylates, 10 parts of double pentaerythritol C5 methacrylates, 10
Three (2- ethoxy) isocyanuric acid triacrylates of part, 40 parts of 1,6 hexanediol diacrylates, 7 parts of cracking type light compounded draw
It sends out agent and 10min is mixed with the speed of 1000r/min in mixing machine, obtain component B, wherein the cracking type initiator of compounding is
It is mixed by 2 parts of 1- hydroxycyclohexyl phenyl ketones and 5 parts of 2- hydroxy-2-methyl -1- phenyl -1- acetone.
3,25 parts of component A is mixed into 15min in mixing machine with 75 parts of component B with the speed of 1000r/min, will applied
Material is uniformly coated on BOPET film (400 μm of thickness) surface by sided corona treatment, and coating thickness is 3 μm, is then with power
The uv cure machine of 1000W solidifies 20s, i.e., ultraviolet light cured burnished coating is obtained in BOPET film.
Embodiment 2
" part " of following presentation dosage is parts by weight.
1,47 parts of polyethylene glycol adipates (101 chemical industry of Jining, molecular weight 500) and 44 parts of isophorones two are different
The 250ml four-necked bottle that reflux condensing tube, thermometer, blender and nitrogen inlet are housed is added in cyanate diisocyanate, is added 4
The antioxidant (2,6- di-tert-butyl-4-methy phenol) of part and 5 parts of polymerization inhibitors (p-hydroxyanisole), under the protection of nitrogen
It heats up, after 80 DEG C of reaction 4h, cools to 60 DEG C, 12 parts of hydroxy-ethyl acrylate and mass fraction is added as 4 parts of tin dilaurate
Dibutyl tin obtains component A in 60 DEG C of reaction 2h.
2, by 15 part of nine degree of functionality urethane acrylate (CN9013NS, Sartomer), 10 parts of three-functionality-degree polyurethane three
Acrylate (CN989NS, Sartomer), 20 parts of double pentaerythritol methacrylates, 5 parts of Dipentaerythritol Pentaacrylates, 20
Three (2- ethoxy) isocyanuric acid triacrylates of part, 30 parts of 1,6 hexanediol diacrylates, 6 parts of cracking type light compounded draw
It sends out agent and 10min is mixed with the speed of 1000r/min in mixing machine, obtain component B, wherein the cracking type initiator of compounding is
It is mixed by 5 parts of 1- hydroxycyclohexyl phenyl ketones and 1 part of 2- hydroxy-2-methyl -1- phenyl -1- acetone.
3,30 parts of component A is mixed into 15min with speed of 70 parts of the component B in mixing machine with 1000r/min, then
Coating is uniformly coated on BOPET film (400 μm of thickness) surface by sided corona treatment, coating thickness is 5 μm, then hard
The uv cure machine that rate is 1000W solidifies 10s, i.e., ultraviolet light cured burnished coating is obtained in BOPET film.
Embodiment 3
" part " of following presentation dosage is parts by weight.
1,47 parts of polyethylene glycol adipates (101 chemical industry of Jining, molecular weight 500) and 44 parts of isophorones two are different
The 250ml four-necked bottle that reflux condensing tube, thermometer, blender and nitrogen inlet are housed is added in cyanate diisocyanate, is added 4
The antioxidant (2,6- di-tert-butyl-4-methy phenol) of part and 5 parts of polymerization inhibitors (p-hydroxyanisole), under the protection of nitrogen
It heats up, after 80 DEG C of reaction 4h, cools to 60 DEG C, 12 parts of hydroxy-ethyl acrylate and mass fraction is added as 4 parts of tin dilaurate
Dibutyl tin obtains component A in 60 DEG C of reaction 2h.
2, by 12 part of nine degree of functionality urethane acrylate (CN9013NS, Sartomer), 13 parts of three-functionality-degree polyurethane three
Acrylate (CN989NS, Sartomer), 13 parts of double pentaerythritol methacrylates, 12 parts of Dipentaerythritol Pentaacrylates, 20
Three (2- ethoxy) isocyanuric acid triacrylates of part, 30 parts of 1,6 hexanediol diacrylates, 6 parts of cracking type light compounded draw
Send out agent and 30min mixed with the speed of 500r/min in mixing machine, obtain component B, wherein the cracking type initiator of compounding be by
3 parts of 1- hydroxycyclohexyl phenyl ketones are mixed with 3 parts of 2- hydroxy-2-methyl -1- phenyl -1- acetone.
3,35 parts of component A is mixed into 15min with speed of 65 parts of the component B in mixing machine with 1000r/min, then
Coating is uniformly coated on BOPET film (400 μm of thickness) surface by sided corona treatment, coating thickness is 7 μm, then hard
The uv cure machine that rate is 1000W solidifies 15s, i.e., ultraviolet light cured burnished coating is obtained in BOPET film.
Embodiment 4
" part " of following presentation dosage is parts by weight.
1,47 parts of polyethylene glycol adipates (101 chemical industry of Jining, molecular weight 500) and 44 parts of isophorones two are different
The 250ml four-necked bottle that reflux condensing tube, thermometer, blender and nitrogen inlet are housed is added in cyanate diisocyanate, is added 4
The antioxidant (2,6- di-tert-butyl-4-methy phenol) of part and 5 parts of polymerization inhibitors (p-hydroxyanisole), under the protection of nitrogen
It heats up, after 80 DEG C of reaction 4h, cools to 60 DEG C, 12 parts of hydroxy-ethyl acrylate and mass fraction is added as 4 parts of tin dilaurate
Dibutyl tin obtains component A in 60 DEG C of reaction 2h.
2, by 5 part of nine degree of functionality urethane acrylate (CN9013NS, Sartomer), 15 parts of three-functionality-degree polyurethane 3 third
Olefin(e) acid ester (CN989NS, Sartomer), 5 parts of double pentaerythritol methacrylates, 15 parts of Dipentaerythritol Pentaacrylates, 10 parts
Three (2- ethoxy) isocyanuric acid triacrylates, 50 parts of 1,6 hexanediol diacrylates, the cracking type of 8 parts of compoundings are light-initiated
Agent mixes 50min in mixing machine with the speed of 200r/min, obtains component B, wherein the cracking type initiator of compounding is by 1
Part 1- hydroxycyclohexyl phenyl ketone is mixed with 5 parts of 2- hydroxy-2-methyl -1- phenyl -1- acetone.
3,35 parts of component A is mixed into 15min with speed of 65 parts of the component B in mixing machine with 1000r/min, then
Coating is uniformly coated on BOPET film (400 μm of thickness) surface by sided corona treatment, coating thickness is 3 μm, then hard
The uv cure machine that rate is 1000W solidifies 15s, i.e., ultraviolet light cured burnished coating is obtained in BOPET film.
Ultraviolet light cured burnished coating made from above-described embodiment is tested for the property, as a result as follows.
1, the glossiness of dumb light coating is 60 hereinafter, can achieve the requirement of dumb light.
2, after natural exposure 7d and ultraviolet light 10min, phenomena such as xanthochromia does not occur for coating, it was demonstrated that coating
Big destruction does not occur for structure, it was demonstrated that coating has good weatherability.
2, pencil hardness 3H or more, O grades of rub resistance, the wear-resistant scratch-resistant of coating can be good.
3, bending resistance is good, and only coating just occurs to rupture a little when using the cylindrical body that diameter is 2mm, it was demonstrated that coating tool
There is good bending performance, also further illustrates that coating has good flexibility and adhesive force.It is applied after carrying out 180 ° of doublings
Layer does not crack, and illustrates that processing performance and flexibility are excellent.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features.
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention
Within protection scope.
Claims (7)
1. a kind of ultraviolet light cured burnished paint is made of the component B of the component A and 75~55wt% of 25~45wt%,
Wherein, component A is to react to obtain by polyethylene glycol adipate, isophorone diisocyanate and hydroxy-ethyl acrylate
Urethane acrylate；
Component B includes nine degree of functionality urethane acrylates, three-functionality-degree urethane acrylate, six propylene of dipentaerythritol
Acid esters, three (2- ethoxy) isocyanuric acid triacrylates, 1,6 hexanediol diacrylate, double pentaerythritol C5 methacrylate
And crack type photoinitiator；
According to parts by weight, component A is by 30-50 parts of polyethylene glycol adipate, 35-45 parts of isophorone diisocyanate
It is obtained with 10-20 parts of reactions of hydroxy-ethyl acrylate；
In component B, the parts by weight of each raw material are as follows: nine 5~30 parts of degree of functionality urethane acrylates, three-functionality-degree are poly-
5~25 parts of urethane acrylate, 5~20 parts of double pentaerythritol methacrylate, three (2- ethoxy) isocyanuric acids 3 third
10~40 parts of olefin(e) acid ester, 30~50 parts of 1,6 hexanediol diacrylate, double pentaerythritol C5 methacrylate 5~15
Part, 3~9 parts of crack type photoinitiator.
2. the ultraviolet light cured burnished paint according to claim 1, it is characterised in that: in polyethylene glycol adipate, different
Antioxidant, polymerization inhibitor and catalyst are added in the reaction of isophorone diisocyanate and hydroxy-ethyl acrylate.
3. ultraviolet light cured burnished paint according to claim 2, it is characterised in that: the antioxidant is 2,6-, bis- uncle
Butyl -4- methylphenol, the polymerization inhibitor are p-hydroxyanisole, and the catalyst is dibutyl tin dilaurate.
4. ultraviolet light cured burnished paint according to claim 1, it is characterised in that: the crack type photoinitiator is by 1
The 1- hydroxycyclohexyl phenyl ketone of~5 parts by weight and the 2- hydroxy-2-methyl -1- phenyl -1- acetone group of 1~5 parts by weight
At.
5. the method for preparing ultraviolet light cured burnished paint described in claim 1, comprising:
(1) according to parts by weight, first under antioxidant, polymerization inhibitor effect, 30-50 parts of polyethylene glycol adipates and 35-45
Part isophorone diisocyanate reaction, after the reaction was completed, adds 10-20 parts of hydroxy-ethyl acrylates and catalyst, reacts
The component A arrived；
(2) by 5~30 part of nine degree of functionality urethane acrylate, 5~25 parts of three-functionality-degree urethane acrylates, 5~20
Part double pentaerythritol methacrylate, 10~40 part of three (2- ethoxy) isocyanuric acid triacrylate, 30~50 parts of 1,6-
Hexanediyl ester, 5~15 parts of double pentaerythritol C5 methacrylates and 3~9 parts of crack type photoinitiators mix, and obtain
Component B.
6. the method according to claim 5, which is characterized in that the reaction temperature of step (1) is 60~80 DEG C.
7. a kind of ultraviolet light cured burnished coating, by the way that component A described in claim 1 is mixed with component B, ultraviolet light
Solidification obtains.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111040102A (en) * | 2019-12-02 | 2020-04-21 | 中国科学院福建物质结构研究所 | Photosensitive resin and preparation method and application thereof |
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| CN108997558A (en) * | 2018-08-07 | 2018-12-14 | 哈尔滨工业大学无锡新材料研究院 | A kind of more block UV-cured resins of aqueous three-arm star-shaped and preparation method thereof |
| CN111253819A (en) * | 2020-04-07 | 2020-06-09 | 广州四面体新材料科技有限公司 | High-wear-resistance matte low-release transfer photo-curing coating composition and preparation method thereof |
| CN112341599A (en) * | 2020-11-26 | 2021-02-09 | 广东立邦长润发科技材料有限公司 | Ultraviolet-curing matte resin and preparation method thereof |
| CN112680095B (en) * | 2020-12-18 | 2022-08-05 | 黎明化工研究设计院有限责任公司 | Ultraviolet-cured matte wear-resistant rubber floor paint |
| WO2022133668A1 (en) * | 2020-12-21 | 2022-06-30 | 张佩嫦 | Uv curable matt resin and preparation method therefor |
| CN113698861A (en) * | 2021-02-04 | 2021-11-26 | 广东鼎立森新材料有限公司 | Dual-curing coating for curved surface and application thereof |
| CN113603850B (en) * | 2021-08-31 | 2023-04-28 | 武汉中科先进材料科技有限公司 | High-wear-resistance hydrophilic resin, high-wear-resistance solvent-free anti-fog coating, and preparation method and application thereof |
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| CN106243899A (en) * | 2016-08-18 | 2016-12-21 | 哈尔滨工业大学无锡新材料研究院 | The preparation method of the bent scratch resistance coating of curtain coating type polyester film surface |
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| CN102190789A (en) * | 2011-03-23 | 2011-09-21 | 安庆飞凯高分子材料有限公司 | Preparation method of polyurethane acrylate resin |
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| CN111040102A (en) * | 2019-12-02 | 2020-04-21 | 中国科学院福建物质结构研究所 | Photosensitive resin and preparation method and application thereof |
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