CN114774171A - Energy-saving environment-friendly catalytic water-based synthetic diesel oil and preparation method thereof - Google Patents
Energy-saving environment-friendly catalytic water-based synthetic diesel oil and preparation method thereof Download PDFInfo
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- CN114774171A CN114774171A CN202111304877.6A CN202111304877A CN114774171A CN 114774171 A CN114774171 A CN 114774171A CN 202111304877 A CN202111304877 A CN 202111304877A CN 114774171 A CN114774171 A CN 114774171A
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- 239000002283 diesel fuel Substances 0.000 title claims abstract description 78
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 239000003350 kerosene Substances 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 15
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 15
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 15
- 239000003599 detergent Substances 0.000 claims abstract description 15
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 13
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 13
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 13
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000005642 Oleic acid Substances 0.000 claims abstract description 13
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 13
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims abstract description 13
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 13
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 13
- 235000019388 lanolin Nutrition 0.000 claims abstract description 12
- 239000004166 Lanolin Substances 0.000 claims abstract description 9
- 229940039717 lanolin Drugs 0.000 claims abstract description 9
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 235000021313 oleic acid Nutrition 0.000 claims abstract 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 abstract description 4
- 238000000926 separation method Methods 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 18
- 238000002485 combustion reaction Methods 0.000 description 15
- 239000007789 gas Substances 0.000 description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 229910002091 carbon monoxide Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000013067 intermediate product Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000003916 ethylene diamine group Chemical group 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000011900 installation process Methods 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
Abstract
The invention relates to the technical field of synthetic diesel oil, in particular to energy-saving and environment-friendly catalytic water-based synthetic diesel oil and a preparation method thereof, which are characterized in that the synthetic diesel oil comprises 15-20 parts by weight of diesel oil synthetic agent, 90-100 parts by weight of diesel oil and 30-34 parts by weight of water, the diesel oil synthetic agent comprises 30-70 parts by weight of kerosene, sbane, triethanolamine, ethylenediamine, oleic acid, lanolin, ammonia water, detergent, cetane number improver and ferrocene, the components comprise 30-70 parts by weight of kerosene, 5-15 parts by weight of sbane, 0.5-4 parts by weight of sbane, 1.2-2 parts by weight of triethanolamine, 1-3 parts by weight of ethylenediamine, 0.5-3 parts by weight of oleic acid, 0.5-6 parts by weight of lanolin, 1-3 parts by weight of ammonia water, and, 2-5 parts of detergent, 0.3-3 parts of cetane number improver and 1-2 parts of ferrocene, and the synthetic diesel oil is prepared by mixing the components, and has the advantages of simple proportioning, good stability, difficult separation of oil and water, low emulsifier consumption, low price, convenient industrial application and the like.
Description
Technical Field
The invention relates to the technical field of synthetic diesel oil, in particular to energy-saving environment-friendly catalytic water-based synthetic diesel oil which is simple in proportioning, good in stability, low in emulsifier dosage, low in price and convenient for industrial application and a preparation method thereof, and oil and water are not easy to separate.
Background
As is known, synthetic diesel oil is a new energy source, is used as substitute fuel for diesel motor vehicles to solve the problems of fuel deficiency and atmospheric pollution, and has the advantages of quick start, complete combustion, high thermal efficiency, strong explosive force, high power, low oil consumption, no detonation, stable operation and no black smoke in tail gas emission. Meanwhile, the effect of the synthetic diesel oil can be unchanged when the synthetic diesel oil is mixed with national standard diesel oil. The synthetic diesel oil is prepared by physical method from common raw materials in petrochemical, coking and chemical products in daily life, and has wide raw material sources.
However, at present, the existing W/O type emulsified diesel oil has poor stability, oil and water are easy to separate, the dosage of emulsifier is large, the price is high, the industrial application is inconvenient, the water addition is more important than the oil saving rate, the purpose of water addition is to save oil and reduce the pollution to the environment, the water addition amount can be as high as about 35 percent by introducing some technical data, however, the water has no heat, so the emulsified diesel oil is not fuel and can not become fuel or alternative fuel, excessive water addition during oil injection does not have good effect but brings certain difficulty to practical application, if the viscosity of the emulsified diesel oil is increased without taking measures, the atomization and combustion are influenced, an internal combustion engine is difficult to start in winter, and the emulsified synthetic diesel oil has the disadvantages as follows: firstly, the problem of synthetic agent, secondly, relevant with the production method, the production technology of synthetic diesel oil generally adds water in the diesel oil and adds emulsification synthetic agent and stirs together and form, but some technologies are final through the magnetizer, but the intensity of magnetization is than lower and the velocity of flow is fast, does not play due shearing action, all equipment also has obvious not enough, conveying equipment generally adopts the gear pump, destroys the looks form that the synthesis formed easily, but quiet mixing apparatus makes emulsification synthetic particle fineness difference great, makes the quality of oil difficult to guarantee.
Disclosure of Invention
The invention aims to solve the defects of the prior art and provide the energy-saving environment-friendly catalytic water-based synthetic diesel oil and the preparation method thereof, wherein the energy-saving environment-friendly catalytic water-based synthetic diesel oil has the advantages of simple proportioning, good stability, difficult oil-water separation, low emulsifier consumption, low price and convenient industrial application.
The technical scheme adopted by the invention for solving the technical problems is as follows:
the energy-saving environment-friendly catalytic water-based synthetic diesel oil is characterized in that the synthetic diesel oil comprises 15-20 parts by weight of diesel oil synthetic agent, 90-100 parts by weight of diesel oil and 30-34 parts by weight of water.
The diesel oil synthetic agent comprises, by weight, 30-70 parts of kerosene, 5-15 parts of benzine, 0.5-4 parts of a span, 1.2-2 parts of triethanolamine, 1-3 parts of ethylamine, 0.5-3 parts of oleic acid, 0.5-6 parts of lanolin, 1-3 parts of ammonia water, 2-5 parts of a detergent, 0.3-3 parts of a cetane number improver and 1-2 parts of ferrocene.
The diesel oil synthetic agent comprises, by weight, 30-70 parts of kerosene, 10 parts of span, 1 part of span, 1.5 parts of triethanolamine, 1.5 parts of ethylenediamine, 1 part of oleic acid, 1 part of lanolin, 1 part of ammonia water, 3.5 parts of a detergent, 1 part of a cetane number improver and 1.5 parts of ferrocene.
The model of the sbane is sbane S-80, the model of the sbane is sbane 80, the model of the cleaning agent is T1804, and the kerosene is aviation kerosene.
The weight portion of the kerosene is 30-50 portions in summer, and the weight portion of the kerosene is 50-100 portions in winter, so that the density of the oil is adjusted, and the oil is prevented from being dense in winter.
The concentration of the ammonia water is 25%.
A method for preparing energy-saving and environment-friendly catalytic water-based synthetic diesel oil is characterized by comprising the following steps: firstly, mixing water and diesel oil, and then adding a diesel oil synthetic agent, wherein the diesel oil synthetic agent is added in the sequence of adding the span, the detergent, the wool grease, the oleic acid, the triethanolamine, the ethylamine, the ammonia water, the kerosene, the ferrocene and the cetane number improver in turn, the components are added into a reaction kettle, the rotating speed of the reaction kettle is 2800 revolutions per minute, and the mixture is stirred for 15 minutes to obtain a finished product.
The diesel oil and the performance in the patent can improve the combustion condition of the diesel oil, dispersed water particles are instantaneously heated during combustion, and water particles are vaporized to generate a micro-explosion effect, so that the diesel oil is further atomized, the combustion area of the diesel oil is increased, the combustion efficiency is improved, part of water is decomposed into hydrogen and oxygen at high temperature in the presence of the catalyst, wherein the hydrogen is combustible gas with high heat value, the oxygen is indispensable combustion-supporting gas, so that the diesel oil is fully combusted, water can generate water gas reaction with carbon at high temperature to generate carbon monoxide and hydrogen with high heat value, the generation of carbon deposition is reduced, in the actual combustion process, the water is not further decomposed into the oxygen, high-activity intermediate product oxygen atoms are generated in Twenty-year, and the active oxygen can react with the carbon to generate water gas, The hydrocarbon and the carbon monoxide have rapid oxidation reaction, the combustion process is accelerated, the complete combustion can be realized, the discharge amount of harmful components such as carbon monoxide, sulfur dioxide, hydrocarbon and smoke dust in the waste gas is greatly reduced, and the energy-saving and environment-friendly dual benefits are achieved.
Drawings
FIG. 1 is a table of the inspection indexes of the product quality supervision and inspection institute of Shandong province in synthetic diesel oil of the present invention.
FIG. 2 is a graph showing the comparison of performance between commercial diesel and synthetic diesel of the present invention.
Detailed Description
The invention is further described below with reference to the accompanying drawings:
the use or installation process, the principle of operation, as shown in the figures.
The energy-saving environment-friendly catalytic water-based synthetic diesel oil is characterized in that the synthetic diesel oil comprises 15-20 parts by weight of diesel oil synthetic agent, 90-100 parts by weight of diesel oil and 30-34 parts by weight of water.
The diesel oil synthetic agent comprises, by weight, 30-70 parts of kerosene, 5-15 parts of benzine, 0.5-4 parts of a span, 1.2-2 parts of triethanolamine, 1-3 parts of ethylamine, 0.5-3 parts of oleic acid, 0.5-6 parts of lanolin, 1-3 parts of ammonia water, 2-5 parts of a detergent, 0.3-3 parts of a cetane number improver and 1-2 parts of ferrocene.
The diesel oil synthetic agent comprises 30-70 parts of kerosene, 10 parts of span, 1 part of span, 1.5 parts of triethanolamine, 1.5 parts of ethylamine, 1 part of oleic acid, 1 part of lanolin, 1 part of ammonia water, 3.5 parts of detergent, 1 part of cetane number improver and 1.5 parts of ferrocene.
Further, the model of the span is span S-80, the model of the span is span 80, the model of the detergent is T1804, and the kerosene is aviation kerosene.
The weight portion of the kerosene is 30-50 portions in summer, and the weight portion of the kerosene is 50-100 portions in winter, so that the density of the oil is adjusted, and the oil is prevented from being dense in winter.
The concentration of the ammonia water is 25%.
A method for preparing energy-saving and environment-friendly catalytic water-based synthetic diesel oil is characterized by comprising the following steps: firstly, mixing water and diesel oil, and then adding a diesel oil synthetic agent, wherein the diesel oil synthetic agent is added in the sequence of adding the span, the detergent, the wool grease, the oleic acid, the triethanolamine, the ethylamine, the ammonia water, the kerosene, the ferrocene and the cetane number improver in turn, the components are added into a reaction kettle, the rotating speed of the reaction kettle is 2800 revolutions per minute, and the mixture is stirred for 15 minutes to obtain a finished product.
The cetane number improver and the ferrocene can ensure quick start for increasing the power of oil products, the catalyst is span and span, the span is oleophylic nonionic surfactant, the span is hydrophilic nonionic surfactant interstellar, the stabilizer is ethylenediamine, triethanolamine and oleic acid, and the T1804 is flow modifier and detergent dispersing additive.
The synthetic diesel oil prepared by the method has the following advantages:
1. the stability is high, the grain size of the oil is between 10 and 100nm, layering, coalescence, flocculation, emulsion breaking, sedimentation and deformation do not occur when the oil is normally stored for more than one year in an oil depot, and no sewage or any harmful gas polluting the environment is discharged;
2. the combustibility is good: the determination of long ignition delay time of the catalytic dye is solved, and the concentration content of the light dye is 30-33.5%;
3. the oil saving property is high: the water mixing rate reaches 30-34%, and the mineral oil is saved by more than 30% per ton;
4. the environmental protection property is good: the discharge amount of tail gas is reduced by more than 50 percent compared with mineral oil, in particular the harmful gas NO contained in the tail gasxThe discharge capacity of carbon monoxide is reduced by 30 percent, and the discharge capacity of carbon monoxide is reduced by more than 35 percent;
5. because the diameter of the liquid bead of the synthetic diesel oil is smaller than the half wavelength of the visible light wavelength, the optical fiber can bypass the liquid bead particles and is transparent.
According to the detection of the Shandong province product quality supervision and inspection research institute, the fuel oil of the patent has the following indexes: cetane number 45, density (20 ℃ C.) kg/m384-86, kinematic viscosity (50 ℃) 5.812mm2The condensation point is minus 10 ℃, the flash point (closed) is 55 ℃, the cold filter plugging point is minus 4 ℃, copper sheet corrosion is 50 ℃, 3 h) 1a, the heat value of a bench test is 41.6Mj/kg, the national light diesel oil standard is met, figure 2 is a performance comparison curve made by a commercial diesel oil and a commercial synthetic diesel oil detection center of the patent, and the comparison curve shows that the power of the synthetic diesel oil of the patent has little difference under the same rotation speed, the specific oil consumption of the synthetic diesel oil of the patent is gradually close to the specific oil consumption of the commercial diesel oil along with the increase of the rotation speed, but the cost of the synthetic diesel oil is low, so the economic efficiency of the synthetic diesel oil is also good on the whole.
The diesel oil and water can be atomized, the combustion area of the diesel oil is increased, the combustion efficiency is improved, partial water is decomposed into hydrogen and oxygen at high temperature and in the presence of the catalyst, wherein the hydrogen is combustible gas with high heat value, the oxygen is indispensable combustion-supporting gas, the diesel oil is fully combusted, water energy and carbon can generate water gas reaction at high temperature to generate carbon monoxide and hydrogen with high heat value, the generation of carbon deposit is reduced, in the actual combustion process, the water does not further decompose the oxygen, and twenty-first high-activity intermediate product oxygen atoms are generated, and the active oxygen can react with the carbon to generate water gas, The hydrocarbon and the carbon monoxide have rapid oxidation reaction, the combustion process is accelerated, the complete combustion can be realized, the discharge amount of harmful components of the carbon monoxide, sulfur dioxide, hydrocarbon and smoke dust in the waste gas is greatly reduced, and the energy-saving and environment-friendly dual benefits are achieved.
Claims (6)
1. The energy-saving environment-friendly catalytic water-based synthetic diesel oil is characterized in that the synthetic diesel oil comprises 15-20 parts by weight of diesel oil synthetic agent, 90-100 parts by weight of diesel oil and 30-34 parts by weight of water, wherein the diesel oil synthetic agent comprises kerosene, sbane, span, triethanolamine, ethylenediamine, oleic acid, lanolin, ammonia water, a detergent, a cetane number improver and ferrocene, and the diesel oil synthetic agent comprises 30-70 parts by weight of kerosene, 5-15 parts by weight of span, 0.5-4 parts by weight of span, 1.2-2 parts by weight of triethanolamine, 1-3 parts by weight of ethylenediamine, 0.5-3 parts by weight of oleic acid, 0.5-6 parts by weight of lanolin detergent, 1-3 parts by weight of ammonia water, 2-5 parts by weight of cetane number improver and 0.3-3 parts by weight of cetane number improver, 1-2 parts of ferrocene.
2. The energy-saving environment-friendly catalytic water-based synthetic diesel oil as claimed in claim 1, wherein the diesel oil synthetic agent comprises 30-70 parts by weight of kerosene, 10 parts by weight of span, 1 part by weight of span, 1.5 parts by weight of triethanolamine, 1.5 parts by weight of ethylenediamine, 1 part by weight of oleic acid, 1 part by weight of lanolin, 1 part by weight of ammonia water, 3.5 parts by weight of detergent, 1 part by weight of cetane number improver and 1.5 parts by weight of ferrocene.
3. The energy-saving environment-friendly catalytic water-based synthetic diesel oil as claimed in claim 1, wherein the model of the sbane is sbane S-80, the model of the sbane is sbane 80, the model of the detergent is T1804, and the kerosene is aviation kerosene.
4. The energy-saving environment-friendly catalytic water-based synthetic diesel oil as claimed in claim 1, wherein the weight portion of kerosene is 30-50 parts in summer, the weight portion of kerosene is 50-70 parts in winter, and the density of oil is adjusted to avoid the density of oil in winter.
5. The energy-saving environment-friendly catalytic water-based synthetic diesel oil as claimed in claim 1, wherein the concentration of the ammonia water is 25%.
6. A method for preparing energy-saving and environment-friendly catalytic water-based synthetic diesel oil is characterized by comprising the following steps: firstly, mixing water and diesel oil, and then adding a diesel oil synthetic agent, wherein the diesel oil synthetic agent is added in the sequence of adding the span, the detergent, the wool grease, the oleic acid, the triethanolamine, the ethylamine, the ammonia water, the kerosene, the ferrocene and the cetane number improver in turn, the components are added into a reaction kettle, the rotating speed of the reaction kettle is 2800 revolutions per minute, and the mixture is stirred for 15 minutes to obtain a finished product.
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| CN202111304877.6A CN114774171A (en) | 2021-11-05 | 2021-11-05 | Energy-saving environment-friendly catalytic water-based synthetic diesel oil and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1405278A (en) * | 2001-08-17 | 2003-03-26 | 马宗臣 | Energy-saving environmental-protection (water-based) synthetic diesel |
| CN102690695A (en) * | 2012-06-08 | 2012-09-26 | 袁自远 | Methanol diesel additive |
| CN102952593A (en) * | 2011-08-20 | 2013-03-06 | 张朝斌 | Novel composite diesel oil |
| CN108080024A (en) * | 2017-11-15 | 2018-05-29 | 绵阳双甘科技有限公司 | Environment-protection energy-saving anthracene oil catalyst |
-
2021
- 2021-11-05 CN CN202111304877.6A patent/CN114774171A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1405278A (en) * | 2001-08-17 | 2003-03-26 | 马宗臣 | Energy-saving environmental-protection (water-based) synthetic diesel |
| CN102952593A (en) * | 2011-08-20 | 2013-03-06 | 张朝斌 | Novel composite diesel oil |
| CN102690695A (en) * | 2012-06-08 | 2012-09-26 | 袁自远 | Methanol diesel additive |
| CN108080024A (en) * | 2017-11-15 | 2018-05-29 | 绵阳双甘科技有限公司 | Environment-protection energy-saving anthracene oil catalyst |
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