CN101050393A - High environmental protective diesel oil by using water and regenerative vegetable oil as raw material - Google Patents
High environmental protective diesel oil by using water and regenerative vegetable oil as raw material Download PDFInfo
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- CN101050393A CN101050393A CNA2007100089528A CN200710008952A CN101050393A CN 101050393 A CN101050393 A CN 101050393A CN A2007100089528 A CNA2007100089528 A CN A2007100089528A CN 200710008952 A CN200710008952 A CN 200710008952A CN 101050393 A CN101050393 A CN 101050393A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Abstract
This invention relates to highly clean and environmentally friendly diesel oil, which is composed of: water 12-30 parts, plant oil 18-38 parts, diesel oil 18-36 parts, kerosene 7-15 parts, ethanol amine 1.0-3 parts, n-butylamine 1.0-2.0 parts, ammonium solution 1-3 parts, 200# solvent 6-15 parts, C9 10-20 parts, cleaning agent 0.00001-0.04 part, multifunctional diesel oil additive 0.00000001-0.008 part, cetane value improver 0.00000001-0.002 part, antioxidant 0.00000002-0.001 part, and antifreeze 0.00000001-0.015 part. The multifunctional diesel oil additive is composed of: cyclopentadienyl manganese tricarbonyl 6-20 parts, plant oil 60-80 parts, and toluene diamine 6-20 parts. The diesel oil has such advantages as simple formula, abundant raw materials, low cost, good appearance and wide applications.
Description
Technical field
The present invention relates to a kind of high clean environmental protection diesel oil of making raw material with water and aftergrowth oil.
Background technology
In July, 1981, the international association of burning classifies the Emulsification of Fuel Oil emulsifying combustion one of as three big conservation measuress, and China comes from the fifties, also carries out active research in this field, and obtains certain achievement; Also spell out in " the saving and the Tenth Five-year plan of alternative fuel oil " of State Economic and Trade Commission's promulgation in October calendar year 2001: " give priority to ..., fuel-saving techniques such as fuel emulsification, fuel oil additive ".
Background context data in the prior art:
1, the Chinese patent notification number 1060506, denomination of invention is " preparation method of diesel oil emulsifier and diesel oil emulsification thereof ", this method is with water, sodium hydroxide, kerosene, rosin, Tween-60, Span-80, rust-preventive agent are raw material, heat with the certain proportion mixing, be cooled to room temperature and be the emulsifying agent finished product, again this emulsifying agent and diesel oil, water are mixed in proportion stirring, promptly make emulsified water-in-oil diesel oil.
2, the Chinese patent notification number 1144867, denomination of invention is " a kind of colloidal diesel oil and preparation method thereof ", with low-molecular-weight poly-carbon four, carbon pentaene hydrocarbon is the basic raw material of emulsifying agent, can form the colloidal diesel oil of stabilizer pole, simultaneously can also add some nitrogen sulphur trapping agents, auxiliary agents such as cetane number improving agent.
More than two kinds add water diesel oil diesel fuel characteristics all got the effect of improvement, but all can't thoroughly change the outward appearance that oil in water emulsion is milk shape or glue etc. and ordinary diesel oil difference, in addition, on stability, versatility, also exist not enough.
3, the Chinese patent notification number 1632065, denomination of invention is " purification of diesel and preparation technology thereof ", by amyl nitrate, rare hydrocarbon, demulsifying compound, tetraethyl lead, extreme pressure saponified oil, Italian chilli oil, white mineral oil, naphthenic hydrocarbon, methylnaphthalene, aromatic hydrocarbon etc. is basic raw material, auxiliary diesel, by technologies such as synthetic, atomizing, mixing, water is disperseed uniformly and stably with nano level, form water-in-oil.But this water-diesel blend density height, the easy carbon deposit of oil nozzle, and the ratio of 0# diesel oil is on the high side in producing, and does not reach optimum energy-saving effect.
At present, most diesel oil emulsification poor stability of having researched and developed, profit is easily separated, the emulsifying agent consumption is big, the price height, be not easy to industrialization utilization, and the technical information that has introduce amount of water can be up to about 30%, pay attention to adding water and do not pay attention to rate of economizing gasoline, the purpose that adds water in fact is in order to save oil plant, reduction is to the pollution of environment, and well-known, water does not have heat, thereby it is not a fuel, can not become fuel or alternative fuel,, not only not play good effect toward the too much water mixing of oil plant, bring certain difficulty to practical application on the contrary, diesel oil after the emulsification will make its viscosity increase as not taking measures, influence atomizing and burning, winter, oil engine was difficult to start, there is above-mentioned drawback in water-diesel blend just, and existing water-diesel blend technical scheme can not be satisfactory, so the water-diesel blend difficulty is given the all-round popularization use.
Summary of the invention
The object of the present invention is to provide a kind of high clean environmental protection diesel oil, to solve present w/o type diesel oil emulsification poor stability, profit is easily separated, and the emulsifying agent consumption is big, price is high, is not easy to the drawback of industrialization utilization.
The present invention is achieved in that described high clean environmental protection diesel oil is synthetic by the component of the weight part of following scope: 12～30 parts in water, 18～38 parts of vegetables oil, 18～36 parts of diesel oil, 7～15 parts of kerosene, 1.0～3 parts of thanomins, 1.0～2.0 parts of dobutamines, 1～3 part of ammoniacal liquor, 6～15 parts of 200# solvents, 9 10～20 parts in carbon, 0.00001～0.04 part of purification agent, 0.00000001～0.008 part of multifunctional diesel oil additive, 0.00000001～0.002 part of cetane number improver, 0.00000002～0.001 part in oxidation inhibitor, 0.00000001～0.015 part of freezing agent; Above-mentioned diesel oil can be GB No. zero diesel oil, and described vegetables oil can be regenerated fuel or the aftergrowth oil that refines from useless plant slag charge; Above-mentioned raw materials at normal temperatures and pressures, order adds in the reactor in proportion, stir 10～20 minutes with pneumatic power or machinery after, be described high clean environmental protection diesel oil after synthetic.
Described multifunctional diesel oil additive is synthetic by the component of the weight part of following scope: encircle 6～20 parts of penta 2 rare manganese tricarbonyls, 60～80 parts of vegetables oil, 6～20 parts of xylidene(s)s.This multifunctional diesel oil additive contains multiple catalytically active material, and metal ion not has multiple usefulness: the one, play stabilization; The 2nd, not stratified, the not degreasing of protection oil product, emulsifying effect not; The 3rd, by optimizing the oil plant carbon-chain structure, make combustion flame obviously brighten, shorten, realize fully burning; The 4th, efficient decarbonizing is guaranteed the original normal compressionization of power, reduces oil consumption; The 5th, effectively reduce condensation point, improve liquidity, realize fully atomizing, make burning more abundant; The 6th, decompose combustion aid function, described high clean environmental protection diesel oil contains certain hydroxide material, under the combustion high temperature condition, especially in the combustion chamber of power through high temperature and catalysis, they are to participate in active atom of incendiary and free radical for energy decomposing H .O (hydrogen and oxygen), can promote burning and make fuel discharge bigger heat energy, for example, in producing one ton of high clean environmental protection diesel oil, add 0.02% multifunctional diesel oil additive, can play stable, anti-breast is combustion-supporting, fuel-economizing reduces blowdown, improve the energetic synergistic effect of power, this formula material belongs to regenerative raw materials, easily does buying and production, cost is lower.
The inventor is through concentrating on studies for many years, and it is on probation to carry out various tests and small serial production, thus this high clean environmental protection diesel oil of innovation and creation, this high clean environmental protection diesel oil be a kind of high in technological content, versatility good, safe and reliable power fuel oil.Described high clean environmental protection diesel oil contains water, aftergrowth oil, 200# solvent, carbon nine, and its mutual solvent makes profit realize dissolving each other.Because above-mentioned high clean environmental protection diesel oil contains ammoniacal liquor, dobutamine, after profit is mixed, in emulsion process moisture content group by broken be the subset state after, molecule by oil surrounds, realize real water-in-oil, make the same as clear as crystal complete oil body state of outward appearance of described high clean environmental protection diesel oil with ordinary diesel oil.Described high clean environmental protection diesel oil contains the multiple additives of purification agent, cetane number improver, multifunctional diesel oil additive, oxidation inhibitor, freezing agent, make that oil property is stable, dynamic performance is good, sufficient combustion, ignition characteristic be good, reaches the effect of fuel-economizing, environmental protection, cleaning, smoke elimination.
The present invention successfully provides a kind of profit and mixes, and makes its thorough mixing, and water is all encased, and realizes real water in oil environmental protection diesel oil, and it both can use separately, also can mix with other oil products and use and do additive; The same as clear as crystal complete oil body state of the outward appearance of described high clean environmental protection diesel oil with ordinary diesel oil, and can mix arbitrarily and good stability with ordinary diesel oil.Described high clean environmental protection diesel oil does not have waste gas, waste water, waste residue " three wastes " discharging in process of production again, and is minimum to surrounding environment influence, belongs to the environment-friendly and energy-efficient high-new technology products.
The preparation of high clean environmental protection diesel oil of the present invention is to select the starting material of easily purchasing on several markets for use, can adjust the prescription of compound agent according to the starting material of different areal distribution and locality.The invention solves present w/o type diesel oil emulsification poor stability, profit is easily separated, the emulsifying agent consumption is big, price is high, is not easy to the drawback of industrialization utilization, and it has prescription and lacks, raw material is easily purchased, price is low, the good advantage of the general property of light is gathered materials on the spot thereby reach, and adapts to wide, be convenient to promote, have the vast market requirement.
Embodiment
Below further specify the present invention for example.(but not being limitation of the present invention).
Embodiment 1
Described high clean environmental protection diesel oil is synthetic by the component of the weight part of following scope: 12～30 parts in water, 18～38 parts of vegetables oil, 18～36 parts of diesel oil, 7～15 parts of kerosene, 1.0～3 parts of thanomins, 1.0～2.0 parts of dobutamines, 1～3 part of ammoniacal liquor, 6～15 parts of 20# solvents, 9 10～20 parts in carbon, 0.00001～0.04 part of purification agent, 0.00000001～0.008 part of multifunctional diesel oil additive, 0.00000001～0.002 part of cetane number improver, 0.00000002～0.001 part in oxidation inhibitor, 0.00000001～0.015 part of freezing agent; Above-mentioned diesel oil can be GB No. zero diesel oil, and described vegetables oil can be regenerated fuel or the aftergrowth oil that refines from useless plant slag charge; Above-mentioned raw materials at normal temperatures and pressures, order adds in the reactor in proportion, stir 10～20 minutes with pneumatic power or machinery after, be described high clean environmental protection diesel oil after synthetic.
Described multifunctional diesel oil additive is synthetic by the component of the weight part of following scope: encircle 6～20 parts of penta 2 rare manganese tricarbonyls, 60～80 parts of vegetables oil, 6～20 parts of xylidene(s)s.
Embodiment 2:
The component that can press the row weight part according to embodiment 1 described high clean environmental protection diesel oil is synthetic:
17.04 parts in water, 21.58 parts of vegetables oil, 28.4 parts of diesel oil, 1.7 parts of thanomins, 1.42 parts of dobutamines, 1.42 parts of ammoniacal liquor, 8.52 parts of 200# solvent oils, 8.52 parts of kerosene, 9 11.36 parts in carbon, 0.02 part of purification agent, 0.0000005 part in oxidation inhibitor, 0.0000003 part of multifunctional diesel oil additive, 0.0000001 part of cetane number improver, 0.0000008 part of freezing agent.
Embodiment 3:
The component that can press the row weight part according to embodiment 1 described high clean environmental protection diesel oil is synthetic:
13.46 parts in water, 18.84 parts of vegetables oil, 33.66 parts of diesel oil, 1.34 parts of ammoniacal liquor, 1.34 parts of dobutamines, 1.0 parts of thanomins, 6.73 parts of 200# solvent oils, 10.09 parts of kerosene, 9 13.46 parts in carbon, 0.00025 part of purification agent, 0.00000006 part in oxidation inhibitor, 0.00000002 part of multifunctional diesel oil additive, 0.00000001 part of cetane number improver, 0.00000001 part of freezing agent.
Claims (3)
1, a kind of high clean environmental protection diesel oil, it is characterized in that described high clean environmental protection diesel oil is synthetic by the component of the weight part of following scope: 12～30 parts in water, 18～38 parts of vegetables oil, 18～36 parts of diesel oil, 7～15 parts of kerosene, 1.0～3 parts of thanomins, 1.0～2.0 parts of dobutamines, 1～3 part of ammoniacal liquor, 6～15 parts of 200# solvents, 9 10～20 parts in carbon, 0.00001～0.04 part of purification agent, 0.00000001～0.008 part of multifunctional diesel oil additive, 0.00000001～0.002 part of cetane number improver, 0.00000002～0.001 part in oxidation inhibitor, 0.00000001～0.015 part of freezing agent; Described diesel oil is GB No. zero diesel oil, and described vegetables oil is regenerated fuel or the aftergrowth oil that refines from useless plant slag charge; Above-mentioned raw materials at normal temperatures and pressures, order adds in the reactor in proportion, stir 10～20 minutes with pneumatic power or machinery after, be described high clean environmental protection diesel oil after synthetic;
Described multifunctional diesel oil additive is synthetic by the component of the weight part of following scope: encircle 6～20 parts of penta 2 rare manganese tricarbonyls, 60～80 parts of vegetables oil, 6～20 parts of xylidene(s)s.
2, high clean environmental protection diesel oil according to claim 1, it is synthetic to it is characterized in that described high clean environmental protection diesel oil is pressed the component of row weight part: 17.04 parts in water, 21.58 parts of vegetables oil, 28.4 parts of diesel oil, 1.7 parts of thanomins, 1.42 parts of dobutamines, 1.42 parts of ammoniacal liquor, 8.52 parts of 200# solvent oils, 8.52 parts of kerosene, 9 11.36 parts in carbon, 0.02 part of purification agent, 0.0000005 part in oxidation inhibitor, 0.0000003 part of multifunctional diesel oil additive, 0.0000001 part of cetane number improver, 0.0000008 part of freezing agent.
3, high clean environmental protection diesel oil according to claim 1, it is synthetic to it is characterized in that described high clean environmental protection diesel oil is pressed the component of row weight part: 13.46 parts in water, 18.84 parts of vegetables oil, 33.66 parts of diesel oil, 1.34 parts of ammoniacal liquor, 1.34 parts of dobutamines, 1.0 parts of thanomins, 6.73 parts of 200# solvent oils, 10.09 parts of kerosene, 9 13.46 parts in carbon, 0.00025 part of purification agent, 0.00000006 part in oxidation inhibitor, 0.00000002 part of multifunctional diesel oil additive, 0.00000001 part of cetane number improver, 0.00000001 part of freezing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100089528A CN101050393A (en) | 2007-05-11 | 2007-05-11 | High environmental protective diesel oil by using water and regenerative vegetable oil as raw material |
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| Application Number | Priority Date | Filing Date | Title |
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| CNA2007100089528A CN101050393A (en) | 2007-05-11 | 2007-05-11 | High environmental protective diesel oil by using water and regenerative vegetable oil as raw material |
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| CN101050393A true CN101050393A (en) | 2007-10-10 |
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| CNA2007100089528A Pending CN101050393A (en) | 2007-05-11 | 2007-05-11 | High environmental protective diesel oil by using water and regenerative vegetable oil as raw material |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102676247A (en) * | 2012-05-29 | 2012-09-19 | 赵春德 | Environment-friendly diesel oil synergist and production method thereof |
| CN101633859B (en) * | 2009-08-20 | 2013-01-16 | 漳州泽涛新能源科技有限公司 | High-cleanness diesel oil |
| CN103289766A (en) * | 2013-06-19 | 2013-09-11 | 朱觉锦 | Efficient energy-saving emulsified fuel oil |
| CN105132116A (en) * | 2015-07-21 | 2015-12-09 | 朱明� | High thermal-energy fuel or diesel additive and preparation method thereof |
-
2007
- 2007-05-11 CN CNA2007100089528A patent/CN101050393A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101633859B (en) * | 2009-08-20 | 2013-01-16 | 漳州泽涛新能源科技有限公司 | High-cleanness diesel oil |
| CN102676247A (en) * | 2012-05-29 | 2012-09-19 | 赵春德 | Environment-friendly diesel oil synergist and production method thereof |
| CN102676247B (en) * | 2012-05-29 | 2014-11-12 | 赵春德 | Environment-friendly diesel oil synergist and production method thereof |
| CN103289766A (en) * | 2013-06-19 | 2013-09-11 | 朱觉锦 | Efficient energy-saving emulsified fuel oil |
| CN105132116A (en) * | 2015-07-21 | 2015-12-09 | 朱明� | High thermal-energy fuel or diesel additive and preparation method thereof |
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Open date: 20071010 |