CN114644509A - 一种高掺量钢渣废料的轻质硅晶石墙板及制备方法 - Google Patents

一种高掺量钢渣废料的轻质硅晶石墙板及制备方法 Download PDF

Info

Publication number
CN114644509A
CN114644509A CN202210275768.4A CN202210275768A CN114644509A CN 114644509 A CN114644509 A CN 114644509A CN 202210275768 A CN202210275768 A CN 202210275768A CN 114644509 A CN114644509 A CN 114644509A
Authority
CN
China
Prior art keywords
steel slag
wallboard
spar
temperature
pug
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210275768.4A
Other languages
English (en)
Inventor
谢贵全
白冰
马明龙
田密
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhubang Construction Technology Investment Shenzhen Co ltd
Original Assignee
Zhubang Construction Technology Investment Shenzhen Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhubang Construction Technology Investment Shenzhen Co ltd filed Critical Zhubang Construction Technology Investment Shenzhen Co ltd
Priority to CN202210275768.4A priority Critical patent/CN114644509A/zh
Publication of CN114644509A publication Critical patent/CN114644509A/zh
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/138Waste materials; Refuse; Residues from metallurgical processes, e.g. slag, furnace dust, galvanic waste
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201Alkali metal oxides or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C04B2235/321Dolomites, i.e. mixed calcium magnesium carbonates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/36Glass starting materials for making ceramics, e.g. silica glass
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602Making the green bodies or pre-forms by moulding
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6562Heating rate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6565Cooling rate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567Treatment time
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74Physical characteristics
    • C04B2235/77Density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

本发明涉及绿色建筑材料技术领域,具体涉及一种高掺量钢渣废料的轻质硅晶石墙板及制备方法,墙板由固体物料与水按照1:0.15~0.2的重量比例混合烧制而成;按重量百分含量计,固体物料由60%~80%钢渣、15%~40%矿物、1%~5%助熔剂组成。与现有技术相比,本发明以不同颗粒级配钢渣为主要原料,掺加一定质量的矿物原料和化工原料,经混料、成型、干燥、1000~1200℃高温烧结后制得轻质硅晶石墙板,解决钢渣在应用时的安定性问题,避免墙板在干燥和烧成过程中的收缩和开裂,提高了大宗固废的资源化利用效率,制得的产品满足新型装配式墙体材料的要求,且成品率高达98%以上,具有极高的经济价值和环保价值。

Description

一种高掺量钢渣废料的轻质硅晶石墙板及制备方法
技术领域
本发明涉及绿色建筑材料技术领域,具体涉及一种高掺量钢渣废料的轻质硅晶石墙板及制备方法。
背景技术
钢渣是炼钢过程中产生的一种副产品,其产率为粗钢产量的8%~15%,据统计2020年我国钢渣产量约为1.60亿吨。迄今为止,钢渣的回收利用主要集中在本厂回收、道路铺填、农业肥料等方面,但由于受到钢渣安定性问题限制难以深度开发,高效利用科技投入不足,产需双方标准不统一,所以钢渣的总体利用率仍不达30%。因此开发一种更高效、高附加值的钢渣利用方法对冶金行业的可持续发展具有重要意义。
轻质硅晶石墙板是一种以钢渣、页岩、石英砂尾矿、河道淤泥、陶瓷抛光渣、煤矸石、高锰酸钾尾渣等固体废物为主要原料,引入适量粘土、长石、青石等无机物,采用高温烧成工艺制备出的一种轻质墙板,具有保温隔热、隔音降噪、防水防潮的功能。在国家大力推进装配式墙体材料,烧结墙体材料部品化的形势下,轻质硅晶石墙板的开发适应市场发展,有着十分积极的意义。本发明利用大掺量钢渣制备轻质硅晶石墙板,主要通过控制钢渣的颗粒级配然后进行烧成,来解决钢渣在使用过程中的安定性问题,避免墙板在干燥和烧成过程中的收缩和开裂。制备该墙板的原料中钢渣含量大于70%,所以使得产品成本也大大降低。
发明内容
针对背景技术中提到的问题,本发明提供一种高掺量钢渣废料的轻质硅晶石墙板及制备方法,解决钢渣在应用时的安定性,提高钢渣利用效率问题。
一方面,本发明提供一种高掺量钢渣废料的轻质硅晶石墙板,关键在于:由固体物料与水按照1:0.15~0.2的重量比例混合烧制而成;按重量百分含量计,所述固体物料的组成如下:
钢渣60%~80%;
矿物15%~40%;
助熔剂1%~5%;
其中,按重量百分含量计,所述钢渣的颗粒级配组成如下:
20~40目钢渣20%~50%
40~100目钢渣30%~70%
>100目钢渣10%~30%。
优选的,矿物是黏土、长石、页岩、萤石、钾长石、钠长石、白云石中的一种或多种。
优选的,所述助熔剂为腐植酸钠、碳酸钠、氧化铝、偏硅酸钠、玻璃熔块中的一种或多种。
另一方面,本发明提供一种高掺量钢渣废料的轻质硅晶石墙板的制备方法,关键在于:
S1.按照配方准确称量钢渣、矿物和助熔剂,并一次性投入进入混料机,混合均匀后,再向混料机里面加水,然后搅拌混匀得到可塑性指数为7-15的泥料;
S2.先将模具中均匀铺设一层泥料,压实,然后再继续铺设一层泥料,压实,如此重复多次,直至泥料均匀地填满整个模具后,脱模,得到胚体;
S3.将胚体送入干燥器内进行干燥成型,控制干燥失水率为15.2%~18%之间,控制坯体收缩率为0~1.0%;
S4.将干燥的坯体放入电炉中,在室温--1200℃下按照烧成工艺曲线进行烧结,在在1000~1200℃,保温30~60min,烧结后产品经急冷、缓冷两段退火工艺,得到成品。
优选的,S1中矿物粒度<40目,助熔剂粒度<40目。
优选的,S2具体为:模具尺寸为40×40×160mm,先在模具壁上均匀的涂刷脱模剂,然后将泥料均匀铺入模具中,厚度约为10mm,用手压实然后用橡皮锤捶打,确保模具中的泥料均匀密实;重复4~5次,使泥料均匀地填满整个模具,然后继续捶打,使得泥料之间结合紧密不存在空隙,成型面光滑,随后进行脱模,得到胚体。
优选的,S3中的干燥条件为:干燥温度为70℃~100℃,干燥时间为8h~10h。
优选的,S4中烧成工艺曲线为:从室温到120℃,采用8~15℃/min的升温速率;从120℃到400℃,采用4~8℃/min的升温速率;从400℃到800℃,采用3~7℃/min的升温速率;从800℃到1000℃,采用2~6℃/min的升温速率;从1000℃到1000~1200℃,采用2~4℃/min的升温速率。
优选的,S4中退火工艺为:采用6-8℃/min的降温速率从烧成温度降至800℃,然后采用3℃/min的降温速率降至室温。
优选的,所述成品的容重在1000~2000kg/m3之间,抗压强度为10.0~45.0MPa,抗折强度为4.5~20.0MPa,吸水率≤10.0%。
与现有技术相比,本发明提供的一种高掺量钢渣废料的轻质硅晶石墙板及制备方法,具有如下有益效果:
(1)本发明以不同颗粒级配钢渣为主要原料,掺加一定质量的矿物原料和化工原料,经混料、成型、干燥、1000~1200℃高温烧结后制得轻质硅晶石墙板,解决钢渣在应用时的安定性问题,避免墙板在干燥和烧成过程中的收缩和开裂,提高了大宗固废的资源化利用效率,改善了生态环境,具有极高的经济价值和环保价值;
(2)本发明制得的轻质硅晶石墙板具有容重小、抗压强度高、抗折强度高、吸水率低、成本低等优势,同时产品的强度性能指标稳定可控,进而保证了产品的成品率高,可达98%以上,能够满足新型装配式墙体材料的要求,引领烧结材料部品化新市场。
具体实施方式
为了使本发明的目的、技术方案和优点更加清楚,下面结合具体实施例对本发明进行详细描述。在此,还需要说明的是,为了避免因不必要的细节而模糊了本发明,在具体实施例中仅仅示出了与本发明的方案密切相关的结构和/或处理步骤,而省略了与本发明关系不大的其他细节。
另外,还需要说明的是,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。
实施例1
称取钢渣共450.0g,其中:粒度>100目的钢渣55.0g;粒度在40~100目之间的钢渣260.0g;粒度在20~40目之间的钢渣135.0g;称取页岩50.0g,黏土50.0g,长石38.0g,碳酸钠12.0g。将上述称取好的粉料一次性置入行星搅拌锅中进行搅拌,搅拌锅转速为140r/min,搅拌时间为5min;固体粉料搅拌均匀后关闭搅拌锅,加入90.0g水后继续搅拌,搅拌锅转速为140r/min,搅拌时间为 8min,在三联模中均匀地刷入脱模剂,然后将混合好的可塑性指数为7的泥料分散成小块均匀放入模具中。先均匀铺入一层泥料,厚度约为10mm,用手压实然后用橡皮锤捶打,确保模具中的泥料均匀密实。重复4次,使泥料均匀地填满整个模具,然后继续捶打,使得泥料之间结合紧密不存在空隙,成型面光滑。随后进行脱模,脱模过程中保证已成型的坯体不发生变形,将脱模后的坯体置于托盘中,记录此时的坯体质量和尺寸。随后将坯体和托盘一同放入鼓风恒温干燥箱进行干燥,干燥温度为70℃,干燥时间为10h,此时的干燥收缩率为0.6%,失水率为16.3%。将干坯放入电炉中烧结:从室温到120℃,采用8℃/min的升温速率;从120℃到400℃,采用6℃/min的升温速率;从400℃到800℃,采用4℃/min的升温速率;从800℃到1000℃,采用3℃/min的升温速率;从1000℃到1200℃,采用2℃/min的升温速率。在1200℃温度范围内的保温时间为45min。随后采用8℃/min的降温速率从烧成温度降至800℃,然后采用3℃/min的降温速率降至室温。
检测结果:高掺量钢渣废料的轻质硅晶石墙板抗压强度为18.4MPa,抗折强度为5.8MPa,容重为1742.2kg/m3,吸水率为7.2%。
实施例2
称取钢渣共468.0g,其中:粒度>100目的钢渣130.0g;粒度在40~100目之间的钢渣280.0g;粒度在20~40目之间的钢渣58.0g,称取页岩30.0g,黏土 25.0g,长石25.0g,白云石28.0g,玻璃熔块16.0g,偏硅酸钠8.0g。将上述称取好的粉料一次性置入行星搅拌锅中进行搅拌,搅拌锅转速为140r/min,搅拌时间为5min;固体粉料搅拌均匀后关闭搅拌锅,加入115.0g水后继续搅拌,搅拌锅转速为140r/min,搅拌时间为8min。在三联模中均匀地刷入脱模剂,然后将混合好的可塑性指数为9的泥料分散成小块均匀放入模具中。先均匀铺入一层泥料,厚度约为10mm,用手压实然后用橡皮锤捶打,确保模具中的泥料均匀密实。重复5次,使泥料均匀地填满整个模具,然后继续捶打,使得泥料之间结合紧密不存在空隙,成型面光滑。随后进行脱模,脱模过程中保证已成型的坯体不发生变形,将脱模后的坯体置于托盘中,记录此时的坯体质量和尺寸。随后将坯体和托盘一同放入放入鼓风恒温干燥箱进行干燥,干燥温度为85℃,干燥时间为7h,此时的干燥收缩率为0.8%,失水率为15.2%。将干坯放入电炉中烧结:从室温到120℃,采用8℃/min的升温速率;从120℃到400℃,采用7℃/min 的升温速率;从400℃到800℃,采用5℃/min的升温速率;从800℃到1000℃,采用3℃/min的升温速率;从1000℃到1150℃,采用2℃/min的升温速率。在 1150℃温度范围内的保温时间为30min。随后采用6℃/min的降温速率从烧成温度降至800℃,然后采用3℃/min的降温速率降至室温。
检测结果:高掺量钢渣废料的轻质硅晶石墙板抗压强度为40.7MPa,抗折强度为18.9MPa,容重为1830.8kg/m3,吸水率为6.3%。
实施例3
称取钢渣共360.0g,其中:粒度>100目的钢渣72.0g;粒度在40~100目之间的钢渣252.0g;粒度在20~40目之间的钢渣36.0g,称取页岩50.0g,黏土75.0g,钾长石55.0g,钠长石30.0g,玻璃熔块30.0g。将上述称取好的粉料一次性置入行星搅拌锅中进行搅拌,搅拌锅转速为140r/min,搅拌时间为5min;固体粉料搅拌均匀后关闭搅拌锅,加入108.0g水后继续搅拌,搅拌锅转速为 280r/min,搅拌时间为8min。在三联模中均匀地刷入脱模剂,然后将混合好的可塑性指数为12的泥料分散成小块均匀放入模具中。先均匀铺入一层泥料,厚度约为10mm,用手压实然后用橡皮锤捶打,确保模具中的泥料均匀密实。重复 4次,使泥料均匀地填满整个模具,然后继续捶打,使得泥料之间结合紧密不存在空隙,成型面光滑。随后进行脱模,脱模过程中保证已成型的坯体不发生变形,将脱模后的坯体置于托盘中,记录此时的坯体质量和尺寸。随后将坯体和托盘一同放入放入鼓风恒温干燥箱进行干燥,干燥温度为90℃,干燥时间为8h,此时的干燥收缩率为1.0%,失水率为18%。将干坯放入电炉中烧结:从室温到 120℃,采用10℃/min的升温速率;从120℃到400℃,采用8℃/min的升温速率;从400℃到800℃,采用7℃/min的升温速率;从800℃到1000℃,采用6℃/min 的升温速率;从1000℃到1200℃,采用4℃/min的升温速率。在1200℃温度范围内的保温时间为60min。随后采用7℃/min的降温速率从烧成温度降至800℃,然后采用3℃/min的降温速率降至室温。
检测结果:高掺量钢渣废料的轻质硅晶石墙板抗压强度为21.5MPa,抗折强度为10.6MPa,容重为1630.8kg/m3,吸水率为7.3%。
实施例4
称取钢渣共480.0g,其中:粒度>100目的钢渣240.0g;粒度在40~100目之间的钢渣144.0g;粒度在20~40目之间的钢渣96.0g,称取页岩40.0g,黏土 50.0g,腐植酸钠20.0g,偏硅酸钠10.0g。将上述称取好的粉料一次性置入行星搅拌锅中进行搅拌,搅拌锅转速为140r/min,搅拌时间为5min;固体粉料搅拌均匀后关闭搅拌锅,加入102.0g水后继续搅拌,搅拌锅转速为280r/min,搅拌时间为8min。在三联模中均匀地刷入脱模剂,然后将混合好的可塑性指数为15 的泥料分散成小块均匀放入模具中。先均匀铺入一层泥料,厚度约为10mm,用手压实然后用橡皮锤捶打,确保模具中的泥料均匀密实。重复5次,使泥料均匀地填满整个模具,然后继续捶打,使得泥料之间结合紧密不存在空隙,成型面光滑。随后进行脱模,脱模过程中保证已成型的坯体不发生变形,将脱模后的坯体置于托盘中,记录此时的坯体质量和尺寸。随后将坯体和托盘一同放入放入鼓风恒温干燥箱进行干燥,干燥温度为100℃,干燥时间为7h,此时的干燥收缩率为0.3%,失水率为16.9%。将干坯放入电炉中烧结:从室温到120℃,采用15℃/min的升温速率;从120℃到400℃,采用4℃/min的升温速率;从400℃到800℃,采用7℃/min的升温速率;从800℃到1000℃,采用2℃/min 的升温速率;从1000℃到1150℃,采用2℃/min的升温速率。在1150℃温度范围内的保温时间为40min。随后采用7℃/min的降温速率从烧成温度降至800℃,然后采用3℃/min的降温速率降至室温。
检测结果:高掺量钢渣废料的轻质硅晶石墙板抗压强度为42.7MPa,抗折强度为17.6MPa,容重为1910.8kg/m3,吸水率为7.1%。
最后说明的是,以上实施例仅用以说明本发明的技术方案而非限制,尽管参照较佳实施例对本发明进行了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的宗旨和范围,其均应涵盖在本发明的权利要求范围当中。

Claims (10)

1.一种高掺量钢渣废料的轻质硅晶石墙板,其特征在于由固体物料与水按照1:0.15~0.2的重量比例混合烧制而成;按重量百分含量计,所述固体物料的组成如下:
钢渣60%~80%;
矿物15%~40%;
助熔剂1%~5%;
其中,按重量百分含量计,所述钢渣的组成如下:
20~40目钢渣20%~50%
40~100目钢渣30%~70%
>100目钢渣10%~30%。
2.根据权利要求1所述的一种高掺量钢渣废料的轻质硅晶石墙板,其特征在于:矿物是黏土、长石、页岩、萤石、钾长石、钠长石、白云石中的一种或多种。
3.根据权利要求1所述的一种高掺量钢渣废料的轻质硅晶石墙板,其特征在于:所述助熔剂为腐植酸钠、碳酸钠、氧化铝、偏硅酸钠、玻璃熔块中的一种或多种。
4.一种如权利要求1-3所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于:
S1.按照配方准确称量钢渣、矿物和助熔剂,并一次性投入进入混料机,混合均匀后,再向混料机里面加水,然后搅拌混匀得到可塑性指数为7-15的泥料;
S2.先将模具中均匀铺设一层泥料,压实,然后再继续铺设一层泥料,压实,如此重复多次,直至泥料均匀地填满整个模具后,脱模,得到胚体;
S3.将胚体送入干燥器内进行干燥成型,控制干燥失水率为15.2%~18%之间,控制坯体收缩率为0~1.0%;
S4.将干燥的坯体放入电炉中,在室温--1200℃下按照烧成工艺曲线进行烧结,在1000~1200℃,保温30~60min,烧结后产品经急冷、缓冷两段退火工艺,得到成品。
5.根据权利要求4所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于S1中矿物粒度<40目,助熔剂粒度<40目。
6.根据权利要求4所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于S2具体为:模具尺寸为40×40×160mm,先在模具壁上均匀的涂刷脱模剂,然后将泥料均匀铺入模具中,厚度约为10mm,用手压实然后用橡皮锤捶打,确保模具中的泥料均匀密实;重复4~5次,使泥料均匀地填满整个模具,然后继续捶打,使得泥料之间结合紧密不存在空隙,成型面光滑,随后进行脱模,得到胚体。
7.根据权利要求4所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于S3中的干燥条件为:干燥温度为70℃~100℃,干燥时间为8h~10h。
8.根据权利要求4所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于S4中烧成工艺曲线为:从室温到120℃,采用8~15℃/min的升温速率;从120℃到400℃,采用4~8℃/min的升温速率;从400℃到800℃,采用3~7℃/min的升温速率;从800℃到1000℃,采用2~6℃/min的升温速率;从1000℃到1000~1200℃,采用2~4℃/min的升温速率。
9.根据权利要求4所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于S4中退火工艺为:采用6-8℃/min的降温速率从烧成温度降至800℃,然后采用3℃/min的降温速率降至室温。
10.根据权利要求4所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于:所述成品的容重在1000~2000kg/m3之间,抗压强度为10.0~45.0MPa,抗折强度为4.5~20.0MPa,吸水率≤10.0%。
CN202210275768.4A 2022-03-21 2022-03-21 一种高掺量钢渣废料的轻质硅晶石墙板及制备方法 Pending CN114644509A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210275768.4A CN114644509A (zh) 2022-03-21 2022-03-21 一种高掺量钢渣废料的轻质硅晶石墙板及制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210275768.4A CN114644509A (zh) 2022-03-21 2022-03-21 一种高掺量钢渣废料的轻质硅晶石墙板及制备方法

Publications (1)

Publication Number Publication Date
CN114644509A true CN114644509A (zh) 2022-06-21

Family

ID=81995505

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210275768.4A Pending CN114644509A (zh) 2022-03-21 2022-03-21 一种高掺量钢渣废料的轻质硅晶石墙板及制备方法

Country Status (1)

Country Link
CN (1) CN114644509A (zh)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108395211A (zh) * 2018-03-24 2018-08-14 广州城建职业学院 一种新型的建筑用吸声材料及其制备方法
CN111056820A (zh) * 2019-12-10 2020-04-24 谢贵全 利用工业全固废制备的scs亚纳米硅晶石及其制备方法
WO2021022589A1 (zh) * 2019-08-07 2021-02-11 东北大学 一种以金矿尾砂为原料的泡沫陶瓷及其制备方法
CN113387681A (zh) * 2021-07-02 2021-09-14 沈阳工业大学 一种利用工业固废制备装配式建筑用炻石条板的方法
CN113683397A (zh) * 2021-07-09 2021-11-23 新疆互力佳源环保科技有限公司 一种用于高温储热的钢渣蓄热砖配方及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108395211A (zh) * 2018-03-24 2018-08-14 广州城建职业学院 一种新型的建筑用吸声材料及其制备方法
WO2021022589A1 (zh) * 2019-08-07 2021-02-11 东北大学 一种以金矿尾砂为原料的泡沫陶瓷及其制备方法
CN111056820A (zh) * 2019-12-10 2020-04-24 谢贵全 利用工业全固废制备的scs亚纳米硅晶石及其制备方法
CN113387681A (zh) * 2021-07-02 2021-09-14 沈阳工业大学 一种利用工业固废制备装配式建筑用炻石条板的方法
CN113683397A (zh) * 2021-07-09 2021-11-23 新疆互力佳源环保科技有限公司 一种用于高温储热的钢渣蓄热砖配方及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
徐兵等: "钢渣混凝土配制及在护岸工程中的应用", 《混凝土》 *

Similar Documents

Publication Publication Date Title
CN101386528B (zh) 一种利用冶金钢渣生产陶瓷砖的方法
CN102875065B (zh) 一种原料含有萤石矿渣的加气砖的制备工艺
CN102875187B (zh) 一种高强度加气混凝土砌块
JPH0543666B2 (zh)
CN101654362B (zh) 一种氧氮化硅结合碳化硅高温陶瓷材料及其制备方法
CN111606612B (zh) 碱激发胶凝材料及其使用方法
CN1420097A (zh) 一种免挤压无粘土固体废渣烧结砖的生产技术
CN104003733A (zh) 氮化硅结合碳化硅耐火材料的制备方法
CN112897956A (zh) 环保型无机人造石及其制备方法
CN113213869A (zh) 一种利用地质聚合物制备蒸压加气混凝土砌块的方法
CN104844254B (zh) 一种利用辊道窑生产发泡赤泥装饰瓷砖的方法
CN108911726B (zh) 一种煤矸石-脱硫石膏-碳酸钙体系透水陶瓷砖及其制备方法
CN104016693A (zh) 氮化硅结合碳化硅耐火材料的制备方法
CN102344298A (zh) 一种泡沫混凝土保温承重砖及其生产方法
KR20110125913A (ko) 석분오니를 함유하는 내장용 벽돌 및 그 제조방법
CN104909800A (zh) 一种添加瓷砖废料并经辊道窑烧成发泡赤泥瓷砖的方法
CN105622055A (zh) 一种大规格超薄建筑陶瓷砖瓷坯的制备方法
CN114644509A (zh) 一种高掺量钢渣废料的轻质硅晶石墙板及制备方法
CN107879682B (zh) 一种以矿渣为基质的加气砖及其加工方法
CN102584260B (zh) 一种利用铁尾矿制备堇青石-莫来石复相耐热材料的方法
CN111116128A (zh) 一种仿石材制品及其制备方法和用途
CN107459342B (zh) 一种微波冶金窑车用方镁石-氧氮化硅复合耐火材料
CN113929425A (zh) 一种建筑砌块及其制备方法
CN107840641B (zh) 一种利用尾矿及废渣制作的文化石
CN110835259A (zh) 一种均匀发泡轻质隔热陶瓷及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20220621

RJ01 Rejection of invention patent application after publication