CN114644509A - 一种高掺量钢渣废料的轻质硅晶石墙板及制备方法 - Google Patents
一种高掺量钢渣废料的轻质硅晶石墙板及制备方法 Download PDFInfo
- Publication number
- CN114644509A CN114644509A CN202210275768.4A CN202210275768A CN114644509A CN 114644509 A CN114644509 A CN 114644509A CN 202210275768 A CN202210275768 A CN 202210275768A CN 114644509 A CN114644509 A CN 114644509A
- Authority
- CN
- China
- Prior art keywords
- steel slag
- wallboard
- spar
- temperature
- pug
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002893 slag Substances 0.000 title claims abstract description 72
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 71
- 239000010959 steel Substances 0.000 title claims abstract description 71
- 239000002699 waste material Substances 0.000 title claims abstract description 21
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 17
- 239000010703 silicon Substances 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000005245 sintering Methods 0.000 claims abstract description 20
- 230000008569 process Effects 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 13
- 239000011707 mineral Substances 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000011343 solid material Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 34
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 21
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 8
- 238000010521 absorption reaction Methods 0.000 claims description 7
- 239000004927 clay Substances 0.000 claims description 7
- 238000005303 weighing Methods 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 239000010433 feldspar Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 4
- 238000000137 annealing Methods 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910052656 albite Inorganic materials 0.000 claims description 3
- 239000010459 dolomite Substances 0.000 claims description 3
- 229910000514 dolomite Inorganic materials 0.000 claims description 3
- 238000010304 firing Methods 0.000 claims description 3
- -1 shale Substances 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 2
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 2
- 239000010436 fluorite Substances 0.000 claims description 2
- 230000004907 flux Effects 0.000 claims description 2
- 238000010791 quenching Methods 0.000 claims description 2
- 230000000171 quenching effect Effects 0.000 claims description 2
- 238000010583 slow cooling Methods 0.000 claims description 2
- 239000000047 product Substances 0.000 abstract description 8
- 239000002994 raw material Substances 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 4
- 238000005336 cracking Methods 0.000 abstract description 3
- 239000002910 solid waste Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 239000004566 building material Substances 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000009740 moulding (composite fabrication) Methods 0.000 abstract description 2
- 239000000843 powder Substances 0.000 description 8
- 235000010755 mineral Nutrition 0.000 description 6
- 230000009467 reduction Effects 0.000 description 5
- 238000010009 beating Methods 0.000 description 4
- 238000007664 blowing Methods 0.000 description 4
- 230000001680 brushing effect Effects 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 229910001341 Crude steel Inorganic materials 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/138—Waste materials; Refuse; Residues from metallurgical processes, e.g. slag, furnace dust, galvanic waste
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
- C04B2235/321—Dolomites, i.e. mixed calcium magnesium carbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/36—Glass starting materials for making ceramics, e.g. silica glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/602—Making the green bodies or pre-forms by moulding
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6562—Heating rate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6565—Cooling rate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/77—Density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
本发明涉及绿色建筑材料技术领域,具体涉及一种高掺量钢渣废料的轻质硅晶石墙板及制备方法,墙板由固体物料与水按照1:0.15~0.2的重量比例混合烧制而成;按重量百分含量计,固体物料由60%~80%钢渣、15%~40%矿物、1%~5%助熔剂组成。与现有技术相比,本发明以不同颗粒级配钢渣为主要原料,掺加一定质量的矿物原料和化工原料,经混料、成型、干燥、1000~1200℃高温烧结后制得轻质硅晶石墙板,解决钢渣在应用时的安定性问题,避免墙板在干燥和烧成过程中的收缩和开裂,提高了大宗固废的资源化利用效率,制得的产品满足新型装配式墙体材料的要求,且成品率高达98%以上,具有极高的经济价值和环保价值。
Description
技术领域
本发明涉及绿色建筑材料技术领域,具体涉及一种高掺量钢渣废料的轻质硅晶石墙板及制备方法。
背景技术
钢渣是炼钢过程中产生的一种副产品,其产率为粗钢产量的8%~15%,据统计2020年我国钢渣产量约为1.60亿吨。迄今为止,钢渣的回收利用主要集中在本厂回收、道路铺填、农业肥料等方面,但由于受到钢渣安定性问题限制难以深度开发,高效利用科技投入不足,产需双方标准不统一,所以钢渣的总体利用率仍不达30%。因此开发一种更高效、高附加值的钢渣利用方法对冶金行业的可持续发展具有重要意义。
轻质硅晶石墙板是一种以钢渣、页岩、石英砂尾矿、河道淤泥、陶瓷抛光渣、煤矸石、高锰酸钾尾渣等固体废物为主要原料,引入适量粘土、长石、青石等无机物,采用高温烧成工艺制备出的一种轻质墙板,具有保温隔热、隔音降噪、防水防潮的功能。在国家大力推进装配式墙体材料,烧结墙体材料部品化的形势下,轻质硅晶石墙板的开发适应市场发展,有着十分积极的意义。本发明利用大掺量钢渣制备轻质硅晶石墙板,主要通过控制钢渣的颗粒级配然后进行烧成,来解决钢渣在使用过程中的安定性问题,避免墙板在干燥和烧成过程中的收缩和开裂。制备该墙板的原料中钢渣含量大于70%,所以使得产品成本也大大降低。
发明内容
针对背景技术中提到的问题,本发明提供一种高掺量钢渣废料的轻质硅晶石墙板及制备方法,解决钢渣在应用时的安定性,提高钢渣利用效率问题。
一方面,本发明提供一种高掺量钢渣废料的轻质硅晶石墙板,关键在于:由固体物料与水按照1:0.15~0.2的重量比例混合烧制而成;按重量百分含量计,所述固体物料的组成如下:
钢渣60%~80%;
矿物15%~40%;
助熔剂1%~5%;
其中,按重量百分含量计,所述钢渣的颗粒级配组成如下:
20~40目钢渣20%~50%
40~100目钢渣30%~70%
>100目钢渣10%~30%。
优选的,矿物是黏土、长石、页岩、萤石、钾长石、钠长石、白云石中的一种或多种。
优选的,所述助熔剂为腐植酸钠、碳酸钠、氧化铝、偏硅酸钠、玻璃熔块中的一种或多种。
另一方面,本发明提供一种高掺量钢渣废料的轻质硅晶石墙板的制备方法,关键在于:
S1.按照配方准确称量钢渣、矿物和助熔剂,并一次性投入进入混料机,混合均匀后,再向混料机里面加水,然后搅拌混匀得到可塑性指数为7-15的泥料;
S2.先将模具中均匀铺设一层泥料,压实,然后再继续铺设一层泥料,压实,如此重复多次,直至泥料均匀地填满整个模具后,脱模,得到胚体;
S3.将胚体送入干燥器内进行干燥成型,控制干燥失水率为15.2%~18%之间,控制坯体收缩率为0~1.0%;
S4.将干燥的坯体放入电炉中,在室温--1200℃下按照烧成工艺曲线进行烧结,在在1000~1200℃,保温30~60min,烧结后产品经急冷、缓冷两段退火工艺,得到成品。
优选的,S1中矿物粒度<40目,助熔剂粒度<40目。
优选的,S2具体为:模具尺寸为40×40×160mm,先在模具壁上均匀的涂刷脱模剂,然后将泥料均匀铺入模具中,厚度约为10mm,用手压实然后用橡皮锤捶打,确保模具中的泥料均匀密实;重复4~5次,使泥料均匀地填满整个模具,然后继续捶打,使得泥料之间结合紧密不存在空隙,成型面光滑,随后进行脱模,得到胚体。
优选的,S3中的干燥条件为:干燥温度为70℃~100℃,干燥时间为8h~10h。
优选的,S4中烧成工艺曲线为:从室温到120℃,采用8~15℃/min的升温速率;从120℃到400℃,采用4~8℃/min的升温速率;从400℃到800℃,采用3~7℃/min的升温速率;从800℃到1000℃,采用2~6℃/min的升温速率;从1000℃到1000~1200℃,采用2~4℃/min的升温速率。
优选的,S4中退火工艺为:采用6-8℃/min的降温速率从烧成温度降至800℃,然后采用3℃/min的降温速率降至室温。
优选的,所述成品的容重在1000~2000kg/m3之间,抗压强度为10.0~45.0MPa,抗折强度为4.5~20.0MPa,吸水率≤10.0%。
与现有技术相比,本发明提供的一种高掺量钢渣废料的轻质硅晶石墙板及制备方法,具有如下有益效果:
(1)本发明以不同颗粒级配钢渣为主要原料,掺加一定质量的矿物原料和化工原料,经混料、成型、干燥、1000~1200℃高温烧结后制得轻质硅晶石墙板,解决钢渣在应用时的安定性问题,避免墙板在干燥和烧成过程中的收缩和开裂,提高了大宗固废的资源化利用效率,改善了生态环境,具有极高的经济价值和环保价值;
(2)本发明制得的轻质硅晶石墙板具有容重小、抗压强度高、抗折强度高、吸水率低、成本低等优势,同时产品的强度性能指标稳定可控,进而保证了产品的成品率高,可达98%以上,能够满足新型装配式墙体材料的要求,引领烧结材料部品化新市场。
具体实施方式
为了使本发明的目的、技术方案和优点更加清楚,下面结合具体实施例对本发明进行详细描述。在此,还需要说明的是,为了避免因不必要的细节而模糊了本发明,在具体实施例中仅仅示出了与本发明的方案密切相关的结构和/或处理步骤,而省略了与本发明关系不大的其他细节。
另外,还需要说明的是,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。
实施例1
称取钢渣共450.0g,其中:粒度>100目的钢渣55.0g;粒度在40~100目之间的钢渣260.0g;粒度在20~40目之间的钢渣135.0g;称取页岩50.0g,黏土50.0g,长石38.0g,碳酸钠12.0g。将上述称取好的粉料一次性置入行星搅拌锅中进行搅拌,搅拌锅转速为140r/min,搅拌时间为5min;固体粉料搅拌均匀后关闭搅拌锅,加入90.0g水后继续搅拌,搅拌锅转速为140r/min,搅拌时间为 8min,在三联模中均匀地刷入脱模剂,然后将混合好的可塑性指数为7的泥料分散成小块均匀放入模具中。先均匀铺入一层泥料,厚度约为10mm,用手压实然后用橡皮锤捶打,确保模具中的泥料均匀密实。重复4次,使泥料均匀地填满整个模具,然后继续捶打,使得泥料之间结合紧密不存在空隙,成型面光滑。随后进行脱模,脱模过程中保证已成型的坯体不发生变形,将脱模后的坯体置于托盘中,记录此时的坯体质量和尺寸。随后将坯体和托盘一同放入鼓风恒温干燥箱进行干燥,干燥温度为70℃,干燥时间为10h,此时的干燥收缩率为0.6%,失水率为16.3%。将干坯放入电炉中烧结:从室温到120℃,采用8℃/min的升温速率;从120℃到400℃,采用6℃/min的升温速率;从400℃到800℃,采用4℃/min的升温速率;从800℃到1000℃,采用3℃/min的升温速率;从1000℃到1200℃,采用2℃/min的升温速率。在1200℃温度范围内的保温时间为45min。随后采用8℃/min的降温速率从烧成温度降至800℃,然后采用3℃/min的降温速率降至室温。
检测结果:高掺量钢渣废料的轻质硅晶石墙板抗压强度为18.4MPa,抗折强度为5.8MPa,容重为1742.2kg/m3,吸水率为7.2%。
实施例2
称取钢渣共468.0g,其中:粒度>100目的钢渣130.0g;粒度在40~100目之间的钢渣280.0g;粒度在20~40目之间的钢渣58.0g,称取页岩30.0g,黏土 25.0g,长石25.0g,白云石28.0g,玻璃熔块16.0g,偏硅酸钠8.0g。将上述称取好的粉料一次性置入行星搅拌锅中进行搅拌,搅拌锅转速为140r/min,搅拌时间为5min;固体粉料搅拌均匀后关闭搅拌锅,加入115.0g水后继续搅拌,搅拌锅转速为140r/min,搅拌时间为8min。在三联模中均匀地刷入脱模剂,然后将混合好的可塑性指数为9的泥料分散成小块均匀放入模具中。先均匀铺入一层泥料,厚度约为10mm,用手压实然后用橡皮锤捶打,确保模具中的泥料均匀密实。重复5次,使泥料均匀地填满整个模具,然后继续捶打,使得泥料之间结合紧密不存在空隙,成型面光滑。随后进行脱模,脱模过程中保证已成型的坯体不发生变形,将脱模后的坯体置于托盘中,记录此时的坯体质量和尺寸。随后将坯体和托盘一同放入放入鼓风恒温干燥箱进行干燥,干燥温度为85℃,干燥时间为7h,此时的干燥收缩率为0.8%,失水率为15.2%。将干坯放入电炉中烧结:从室温到120℃,采用8℃/min的升温速率;从120℃到400℃,采用7℃/min 的升温速率;从400℃到800℃,采用5℃/min的升温速率;从800℃到1000℃,采用3℃/min的升温速率;从1000℃到1150℃,采用2℃/min的升温速率。在 1150℃温度范围内的保温时间为30min。随后采用6℃/min的降温速率从烧成温度降至800℃,然后采用3℃/min的降温速率降至室温。
检测结果:高掺量钢渣废料的轻质硅晶石墙板抗压强度为40.7MPa,抗折强度为18.9MPa,容重为1830.8kg/m3,吸水率为6.3%。
实施例3
称取钢渣共360.0g,其中:粒度>100目的钢渣72.0g;粒度在40~100目之间的钢渣252.0g;粒度在20~40目之间的钢渣36.0g,称取页岩50.0g,黏土75.0g,钾长石55.0g,钠长石30.0g,玻璃熔块30.0g。将上述称取好的粉料一次性置入行星搅拌锅中进行搅拌,搅拌锅转速为140r/min,搅拌时间为5min;固体粉料搅拌均匀后关闭搅拌锅,加入108.0g水后继续搅拌,搅拌锅转速为 280r/min,搅拌时间为8min。在三联模中均匀地刷入脱模剂,然后将混合好的可塑性指数为12的泥料分散成小块均匀放入模具中。先均匀铺入一层泥料,厚度约为10mm,用手压实然后用橡皮锤捶打,确保模具中的泥料均匀密实。重复 4次,使泥料均匀地填满整个模具,然后继续捶打,使得泥料之间结合紧密不存在空隙,成型面光滑。随后进行脱模,脱模过程中保证已成型的坯体不发生变形,将脱模后的坯体置于托盘中,记录此时的坯体质量和尺寸。随后将坯体和托盘一同放入放入鼓风恒温干燥箱进行干燥,干燥温度为90℃,干燥时间为8h,此时的干燥收缩率为1.0%,失水率为18%。将干坯放入电炉中烧结:从室温到 120℃,采用10℃/min的升温速率;从120℃到400℃,采用8℃/min的升温速率;从400℃到800℃,采用7℃/min的升温速率;从800℃到1000℃,采用6℃/min 的升温速率;从1000℃到1200℃,采用4℃/min的升温速率。在1200℃温度范围内的保温时间为60min。随后采用7℃/min的降温速率从烧成温度降至800℃,然后采用3℃/min的降温速率降至室温。
检测结果:高掺量钢渣废料的轻质硅晶石墙板抗压强度为21.5MPa,抗折强度为10.6MPa,容重为1630.8kg/m3,吸水率为7.3%。
实施例4
称取钢渣共480.0g,其中:粒度>100目的钢渣240.0g;粒度在40~100目之间的钢渣144.0g;粒度在20~40目之间的钢渣96.0g,称取页岩40.0g,黏土 50.0g,腐植酸钠20.0g,偏硅酸钠10.0g。将上述称取好的粉料一次性置入行星搅拌锅中进行搅拌,搅拌锅转速为140r/min,搅拌时间为5min;固体粉料搅拌均匀后关闭搅拌锅,加入102.0g水后继续搅拌,搅拌锅转速为280r/min,搅拌时间为8min。在三联模中均匀地刷入脱模剂,然后将混合好的可塑性指数为15 的泥料分散成小块均匀放入模具中。先均匀铺入一层泥料,厚度约为10mm,用手压实然后用橡皮锤捶打,确保模具中的泥料均匀密实。重复5次,使泥料均匀地填满整个模具,然后继续捶打,使得泥料之间结合紧密不存在空隙,成型面光滑。随后进行脱模,脱模过程中保证已成型的坯体不发生变形,将脱模后的坯体置于托盘中,记录此时的坯体质量和尺寸。随后将坯体和托盘一同放入放入鼓风恒温干燥箱进行干燥,干燥温度为100℃,干燥时间为7h,此时的干燥收缩率为0.3%,失水率为16.9%。将干坯放入电炉中烧结:从室温到120℃,采用15℃/min的升温速率;从120℃到400℃,采用4℃/min的升温速率;从400℃到800℃,采用7℃/min的升温速率;从800℃到1000℃,采用2℃/min 的升温速率;从1000℃到1150℃,采用2℃/min的升温速率。在1150℃温度范围内的保温时间为40min。随后采用7℃/min的降温速率从烧成温度降至800℃,然后采用3℃/min的降温速率降至室温。
检测结果:高掺量钢渣废料的轻质硅晶石墙板抗压强度为42.7MPa,抗折强度为17.6MPa,容重为1910.8kg/m3,吸水率为7.1%。
最后说明的是,以上实施例仅用以说明本发明的技术方案而非限制,尽管参照较佳实施例对本发明进行了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的宗旨和范围,其均应涵盖在本发明的权利要求范围当中。
Claims (10)
1.一种高掺量钢渣废料的轻质硅晶石墙板,其特征在于由固体物料与水按照1:0.15~0.2的重量比例混合烧制而成;按重量百分含量计,所述固体物料的组成如下:
钢渣60%~80%;
矿物15%~40%;
助熔剂1%~5%;
其中,按重量百分含量计,所述钢渣的组成如下:
20~40目钢渣20%~50%
40~100目钢渣30%~70%
>100目钢渣10%~30%。
2.根据权利要求1所述的一种高掺量钢渣废料的轻质硅晶石墙板,其特征在于:矿物是黏土、长石、页岩、萤石、钾长石、钠长石、白云石中的一种或多种。
3.根据权利要求1所述的一种高掺量钢渣废料的轻质硅晶石墙板,其特征在于:所述助熔剂为腐植酸钠、碳酸钠、氧化铝、偏硅酸钠、玻璃熔块中的一种或多种。
4.一种如权利要求1-3所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于:
S1.按照配方准确称量钢渣、矿物和助熔剂,并一次性投入进入混料机,混合均匀后,再向混料机里面加水,然后搅拌混匀得到可塑性指数为7-15的泥料;
S2.先将模具中均匀铺设一层泥料,压实,然后再继续铺设一层泥料,压实,如此重复多次,直至泥料均匀地填满整个模具后,脱模,得到胚体;
S3.将胚体送入干燥器内进行干燥成型,控制干燥失水率为15.2%~18%之间,控制坯体收缩率为0~1.0%;
S4.将干燥的坯体放入电炉中,在室温--1200℃下按照烧成工艺曲线进行烧结,在1000~1200℃,保温30~60min,烧结后产品经急冷、缓冷两段退火工艺,得到成品。
5.根据权利要求4所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于S1中矿物粒度<40目,助熔剂粒度<40目。
6.根据权利要求4所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于S2具体为:模具尺寸为40×40×160mm,先在模具壁上均匀的涂刷脱模剂,然后将泥料均匀铺入模具中,厚度约为10mm,用手压实然后用橡皮锤捶打,确保模具中的泥料均匀密实;重复4~5次,使泥料均匀地填满整个模具,然后继续捶打,使得泥料之间结合紧密不存在空隙,成型面光滑,随后进行脱模,得到胚体。
7.根据权利要求4所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于S3中的干燥条件为:干燥温度为70℃~100℃,干燥时间为8h~10h。
8.根据权利要求4所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于S4中烧成工艺曲线为:从室温到120℃,采用8~15℃/min的升温速率;从120℃到400℃,采用4~8℃/min的升温速率;从400℃到800℃,采用3~7℃/min的升温速率;从800℃到1000℃,采用2~6℃/min的升温速率;从1000℃到1000~1200℃,采用2~4℃/min的升温速率。
9.根据权利要求4所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于S4中退火工艺为:采用6-8℃/min的降温速率从烧成温度降至800℃,然后采用3℃/min的降温速率降至室温。
10.根据权利要求4所述的高掺量钢渣废料的轻质硅晶石墙板的制备方法,其特征在于:所述成品的容重在1000~2000kg/m3之间,抗压强度为10.0~45.0MPa,抗折强度为4.5~20.0MPa,吸水率≤10.0%。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210275768.4A CN114644509A (zh) | 2022-03-21 | 2022-03-21 | 一种高掺量钢渣废料的轻质硅晶石墙板及制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210275768.4A CN114644509A (zh) | 2022-03-21 | 2022-03-21 | 一种高掺量钢渣废料的轻质硅晶石墙板及制备方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN114644509A true CN114644509A (zh) | 2022-06-21 |
Family
ID=81995505
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202210275768.4A Pending CN114644509A (zh) | 2022-03-21 | 2022-03-21 | 一种高掺量钢渣废料的轻质硅晶石墙板及制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN114644509A (zh) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108395211A (zh) * | 2018-03-24 | 2018-08-14 | 广州城建职业学院 | 一种新型的建筑用吸声材料及其制备方法 |
CN111056820A (zh) * | 2019-12-10 | 2020-04-24 | 谢贵全 | 利用工业全固废制备的scs亚纳米硅晶石及其制备方法 |
WO2021022589A1 (zh) * | 2019-08-07 | 2021-02-11 | 东北大学 | 一种以金矿尾砂为原料的泡沫陶瓷及其制备方法 |
CN113387681A (zh) * | 2021-07-02 | 2021-09-14 | 沈阳工业大学 | 一种利用工业固废制备装配式建筑用炻石条板的方法 |
CN113683397A (zh) * | 2021-07-09 | 2021-11-23 | 新疆互力佳源环保科技有限公司 | 一种用于高温储热的钢渣蓄热砖配方及其制备方法 |
-
2022
- 2022-03-21 CN CN202210275768.4A patent/CN114644509A/zh active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108395211A (zh) * | 2018-03-24 | 2018-08-14 | 广州城建职业学院 | 一种新型的建筑用吸声材料及其制备方法 |
WO2021022589A1 (zh) * | 2019-08-07 | 2021-02-11 | 东北大学 | 一种以金矿尾砂为原料的泡沫陶瓷及其制备方法 |
CN111056820A (zh) * | 2019-12-10 | 2020-04-24 | 谢贵全 | 利用工业全固废制备的scs亚纳米硅晶石及其制备方法 |
CN113387681A (zh) * | 2021-07-02 | 2021-09-14 | 沈阳工业大学 | 一种利用工业固废制备装配式建筑用炻石条板的方法 |
CN113683397A (zh) * | 2021-07-09 | 2021-11-23 | 新疆互力佳源环保科技有限公司 | 一种用于高温储热的钢渣蓄热砖配方及其制备方法 |
Non-Patent Citations (1)
Title |
---|
徐兵等: "钢渣混凝土配制及在护岸工程中的应用", 《混凝土》 * |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101386528B (zh) | 一种利用冶金钢渣生产陶瓷砖的方法 | |
CN102875065B (zh) | 一种原料含有萤石矿渣的加气砖的制备工艺 | |
CN102875187B (zh) | 一种高强度加气混凝土砌块 | |
JPH0543666B2 (zh) | ||
CN101654362B (zh) | 一种氧氮化硅结合碳化硅高温陶瓷材料及其制备方法 | |
CN111606612B (zh) | 碱激发胶凝材料及其使用方法 | |
CN1420097A (zh) | 一种免挤压无粘土固体废渣烧结砖的生产技术 | |
CN104003733A (zh) | 氮化硅结合碳化硅耐火材料的制备方法 | |
CN112897956A (zh) | 环保型无机人造石及其制备方法 | |
CN113213869A (zh) | 一种利用地质聚合物制备蒸压加气混凝土砌块的方法 | |
CN104844254B (zh) | 一种利用辊道窑生产发泡赤泥装饰瓷砖的方法 | |
CN108911726B (zh) | 一种煤矸石-脱硫石膏-碳酸钙体系透水陶瓷砖及其制备方法 | |
CN104016693A (zh) | 氮化硅结合碳化硅耐火材料的制备方法 | |
CN102344298A (zh) | 一种泡沫混凝土保温承重砖及其生产方法 | |
KR20110125913A (ko) | 석분오니를 함유하는 내장용 벽돌 및 그 제조방법 | |
CN104909800A (zh) | 一种添加瓷砖废料并经辊道窑烧成发泡赤泥瓷砖的方法 | |
CN105622055A (zh) | 一种大规格超薄建筑陶瓷砖瓷坯的制备方法 | |
CN114644509A (zh) | 一种高掺量钢渣废料的轻质硅晶石墙板及制备方法 | |
CN107879682B (zh) | 一种以矿渣为基质的加气砖及其加工方法 | |
CN102584260B (zh) | 一种利用铁尾矿制备堇青石-莫来石复相耐热材料的方法 | |
CN111116128A (zh) | 一种仿石材制品及其制备方法和用途 | |
CN107459342B (zh) | 一种微波冶金窑车用方镁石-氧氮化硅复合耐火材料 | |
CN113929425A (zh) | 一种建筑砌块及其制备方法 | |
CN107840641B (zh) | 一种利用尾矿及废渣制作的文化石 | |
CN110835259A (zh) | 一种均匀发泡轻质隔热陶瓷及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220621 |
|
RJ01 | Rejection of invention patent application after publication |