CN114635278B - 一种环保型防腐蚀箱包布面料及其制造方法 - Google Patents

一种环保型防腐蚀箱包布面料及其制造方法 Download PDF

Info

Publication number
CN114635278B
CN114635278B CN202210197553.5A CN202210197553A CN114635278B CN 114635278 B CN114635278 B CN 114635278B CN 202210197553 A CN202210197553 A CN 202210197553A CN 114635278 B CN114635278 B CN 114635278B
Authority
CN
China
Prior art keywords
fabric
parts
environment
drying
friendly anti
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202210197553.5A
Other languages
English (en)
Other versions
CN114635278A (zh
Inventor
朱燕峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hangzhou Xiaoshan Zhengda Textile Co ltd
Original Assignee
Hangzhou Xiaoshan Zhengda Textile Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hangzhou Xiaoshan Zhengda Textile Co ltd filed Critical Hangzhou Xiaoshan Zhengda Textile Co ltd
Priority to CN202210197553.5A priority Critical patent/CN114635278B/zh
Publication of CN114635278A publication Critical patent/CN114635278A/zh
Application granted granted Critical
Publication of CN114635278B publication Critical patent/CN114635278B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/001—Treatment with visible light, infrared or ultraviolet, X-rays
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic System
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/08—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin
    • D06M14/12—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M14/14—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0036—Polyester fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1692—Weather resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/20—Packaging

Abstract

本发明公开了一种环保型防腐蚀箱包布面料的制造方法，包括以下步骤：（1）将涤纶纱线依次用无水乙醇、去离子水进行洗涤并烘干，随后浸入KMnO4和盐酸混合液中浸泡，随后在进行紫外辐照处理，得到预处理涤纶纱线；（2）将预处理涤纶纱线加入到N,N‑二甲基甲酰胺中，随后再加入丙烯酰胺、引发剂α‑溴代异丁酸乙酯，进行搅拌反应，得到表面接枝改性涤纶纱线；（3）将改性涤纶纱线织造为面料；（4）将面料放入复合整理剂中，浸渍后烘干，得到后整理面料；（5）将后整理面料表面涂覆改性水性聚氨酯，即得所述环保型防腐蚀箱包布面料。本发明提供的环保型防腐蚀箱包布面料，避免了聚氯乙烯中增塑剂DOP的残留，对环境友好。

Description

一种环保型防腐蚀箱包布面料及其制造方法
技术领域
本发明属于箱包布面料制造技术领域，具体涉及一种环保型防腐蚀箱包布面料及其制造方法。
背景技术
箱包是日常生活中的必备装备，用于存储容纳日常衣物等。随着时代的发展，用于制作箱包的面料从传统的真皮发展到聚酯、聚酰胺、PU、PVC等多种材质。
面料是箱包产品的主体材料，它不但直接影响产品的外观形象，还关系到产品的市场销售价格。能够用于箱包产品面料的原材料也有很多种，根据消费者的品位改变以及合成纤维的发展，箱包材质也更加多样化。在真皮、帆布、棉麻等质地箱包引领时尚潮流的同时，合成纤维也更多参与其中，如锦纶、涤纶等占据着相当重要的地位。
其中，PVC复合面料是最为常见的箱包制造面料之一。PVC是一种乙烯基的聚合物质，作为世界上产量最大的聚合物之一，其在实际的加工过程中，经常添加一定量的各种加工助剂，然后打粉混合，挤出造粒，最后通过多种加工工艺，制造出具有独特性价比的不同PVC制品。加工助剂主要有热稳定剂、增塑剂、润滑剂、色母料、辅助加工剂、抗冲击剂及其它添加剂等等。其中，热稳定剂主要用于吸收PVC受热加工时分解出来的游离氯，增塑剂用于使PVC制品具有一定的柔韧性，润滑剂用于使得PVC制品在造粒时更易于挤出，色母料用于使PVC制品具有各种颜色。由于制成的PVC制品具有不易燃性、高强度、耐气侯变化性以及优良的几何稳定性，且对氧化剂、还原剂和强酸都有很强的抵抗力，目前已被广泛应用于箱包制造行业。
但是，聚氯乙烯在高温塑化时，其中的增塑剂DOP(邻苯二甲酸二辛脂)有一定残留，对人体有一定伤害，欧盟出台的RECAH标准对此有限定。并且箱包面料往往由涂层剂在面料表面涂层制成，而涂层剂则多采用溶剂型聚氨酯等材料，这类材料虽然耐候性强，不易黄变褪色，成膜性好等优点，但其含有易挥发性溶剂，不环保。而且现有的箱包用面料易被割破，防火性比较差，同时，由于现有的箱包用面料的吸湿性高，因此不易防水，容易造成箱包内部腐蚀，从而很大的影响了箱包的质量。
发明内容
针对现有技术的不足，本发明的目的在于提供一种环保型防腐蚀箱包布面料及其制造方法。
为实现上述目的，本发明提供如下技术方案：
一种环保型防腐蚀箱包布面料的制造方法，包括以下步骤：
(1)涤纶纱线表面处理：将涤纶纱线依次用无水乙醇、去离子水进行洗涤并烘干，随后浸入KMnO4和盐酸混合液中浸泡，随后再进行紫外辐照处理，得到预处理涤纶纱线；
(2)纱线表面接枝：将步骤(1)中得到的预处理涤纶纱线加入到N,N-二甲基甲酰胺中，随后再加入丙烯酰胺、引发剂α-溴代异丁酸乙酯，进行搅拌反应，反应完成后洗涤、干燥得到表面接枝改性涤纶纱线；
(3)面料织造：将步骤(2)中制得的表面接枝改性涤纶纱线织造为面料；
(4)面料后整理：将步骤(3)中所得面料放入复合整理剂中，浸渍后烘干，得到后整理面料；
(5)面料表面涂覆涂层：将步骤(4)中所得后整理面料表面涂覆改性水性聚氨酯，涂布量为260-400g/m2，在100-130℃下烘干2-4h，即得所述环保型防腐蚀箱包布面料。
优选的，步骤(1)中盐酸的质量分数为5-10％，KMnO4和盐酸的质量体积比为1g：30-50mL。
优选的，步骤(1)中所述浸泡温度为70-90℃，浸泡时间为20-40min；步骤(1)中所述紫外辐照处理条件为：紫外辐照剂量为800-1200mJ/cm2。
优选的，步骤(2)中所述搅拌反应温度为100-120℃，反应时间为6-10h。
优选的，步骤(2)中预处理涤纶纱线、N,N-二甲基甲酰胺、丙烯酰胺、引发剂α-溴代异丁酸乙酯的质量比为10：50-80：3-5：0.2-0.5。
优选的，步骤(4)中浸渍温度为60-80℃，浸渍时间为4-7h，烘干温度为90-120℃，烘干时间为3-6h。
优选的，步骤(4)中所述复合整理剂的制备方法如下：
将40-50份全氟己基乙基丙烯酸甲酯、10-15份十二烷基三甲基硫酸铵、5-10份甲基三甲氧基硅烷、10-20份甲基丙烯酸异癸酯、5-8份对叔丁基苯甲酸混合均匀，在30-40℃下搅拌10-20min，随后再缓慢加入6-10份硬脂酸聚氧乙烯酯、10-15份硬脂酸锌、5-8份钼酸铵、2-5份月桂二酸，8-10min内投料完毕，最后加入200-250份去离子水，继续搅拌混合20-30min，即得所述复合整理剂。
优选的，所述步骤(5)中改性水性聚氨酯的制备方法如下：
(a)将3-吡咯羧酸、吡咯加入到去离子水中，加入二氧化钛和氧化锌粉末，在氮气氛围下加入氯化铁，搅拌混合均匀，在40-50℃下搅拌4-8h，发生原位聚合反应，过滤，洗涤，干燥后得到聚吡咯/二氧化钛/氧化锌螯合物；
(b)将步骤(a)中所得聚吡咯/二氧化钛/氧化锌螯合物、丙烯酸聚硅氧烷酯加入水性聚氨酯中，混合后得到所述改性水性聚氨酯。
优选的，所述步骤(a)中3-吡咯羧酸、吡咯、二氧化钛、氧化锌和氯化铁的质量比为10：6-7：1-3：1-2：15-17；步骤(b)中聚吡咯/二氧化钛/氧化锌螯合物、丙烯酸聚硅氧烷酯、水性聚氨酯的质量比为3-5：5-10：100。
本发明还保护一种利用上述方法制备得到的环保型防腐蚀箱包布面料在箱包上的应用。
与现有技术相比，本发明具有如下的有益效果：
(1)本发明提供的环保型防腐蚀箱包布面料的制造方法，通过对涤纶表面进行酸处理和紫外辐照，紫外光对材料的穿透力差，故接枝聚合可严格地限定在材料的表面或亚表面进行，不会损坏材料的本体性能，使得纱线表现具有更高的亲水性和更多的羧酸基团，从而提高丙烯酸在纱线表面的接枝速度和接枝率；接着通过在涤纶纱线表面接枝丙烯酰胺，改善了涤纶纱线的亲水性能和浸润性，使其在后续浸渍整理剂和涂覆涂层时，大大提高了与整理剂与水性涂料的附着性能，使得面料耐水洗性能更好且柔软度好。
(2)本发明提供的环保型防腐蚀箱包布面料的制造方法，通过将二氧化钛、氧化锌与羧基的聚吡咯通过螯合作用形成络合物，加入水性聚氨酯涂料，大大改善了二氧化钛和氧化锌的团聚问题，并且聚吡咯的加入提高了聚氨酯涂层的抗静电性；加入的丙烯酸聚硅氧烷酯，由于含硅共聚物表面能低，疏水性强，使得面料表面自由能减小，接触角增大，增强了面料的疏水性；同时，在紫外线照射下，二氧化钛和氧化锌会产生电子-空穴对，这些光产生的空穴将空气中贴附在涂料上的水分子分裂成OH-和H+离子，溶解的氧物质被还原为超氧阴离子(·O-2)，其与H+反应生成(HO2·)，然后它与多数电荷载流子(e-)和氢离子碰撞以产生过氧化氢分子，产生的过氧化氢分子可以穿透细胞质膜并杀死细菌细，达到生物防腐的效果，提高面料的耐腐蚀性。
(3)本发明提供的环保型防腐蚀箱包布面料，通过使用涤纶纱线为原材料，避免了聚氯乙烯中增塑剂DOP的残留，同时使用的涂层涂料为水性聚氨酯，在保证了耐候性强、不易黄变褪色和成膜性好等优点时也对环境友好。
具体实施方式
下面将结合实施例对本发明的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例中所用涤纶纱线购自潍坊欣汇纺织有限公司；所述丙烯酸聚硅氧烷酯根据文献《聚酯薄膜表面接枝含硅氧烷共聚物及微生物黏附性研究》(张洪文，陆枫潇等，高分子学报2015年6月第6期)中方法所制得；所用水性聚氨酯牌号为AH-1720A，购自安徽安大化泰新材料有限公司。
实施例1
一种环保型防腐蚀箱包布面料的制造方法，包括以下步骤：
(1)涤纶纱线表面处理：将10份涤纶纱线依次用无水乙醇、去离子水进行洗涤并烘干，随后浸入100份KMnO4和质量分数为5-10％盐酸混合液中浸泡，KMnO4和盐酸的质量体积比为1g：40mL，浸泡温度为70℃，浸泡时间为40min，随后再进行紫外辐照处理，紫外辐照剂量为800mJ/cm2，得到预处理涤纶纱线；
(2)纱线表面接枝：将10份步骤(1)中得到的预处理涤纶纱线加入到50份N,N-二甲基甲酰胺中，随后再加入3份丙烯酰胺、0.2份α-溴代异丁酸乙酯，在100℃下搅拌反应10h，反应完成后洗涤、干燥得到表面接枝改性涤纶纱线；
(3)面料织造：将步骤(2)中制得的表面接枝改性涤纶纱线织造为面料；
(4)面料后整理：将步骤(3)中所得面料放入复合整理剂中，在浸渍60℃下浸渍7h，随后在90℃下烘干6h，得到后整理面料；
(5)面料表面涂覆涂层：将步骤(4)中所得后整理面料表面涂覆改性水性聚氨酯，涂布量为300g/m2，在100℃下烘干4h，即得所述环保型防腐蚀箱包布面料。
其中，步骤(4)中所述复合整理剂的制备方法如下：
将40份全氟己基乙基丙烯酸甲酯、10份十二烷基三甲基硫酸铵、5份甲基三甲氧基硅烷、10份甲基丙烯酸异癸酯、5份对叔丁基苯甲酸混合均匀，在30℃下搅拌20min，随后再缓慢加入6份硬脂酸聚氧乙烯酯、10份硬脂酸锌、5份钼酸铵、2份月桂二酸，8min内投料完毕，最后加入200份去离子水，继续搅拌混合30min，即得所述复合整理剂。
步骤(5)中改性水性聚氨酯的制备方法如下：
(a)将10份3-吡咯羧酸、6份吡咯加入到200份去离子水中，加入1份二氧化钛和1份氧化锌粉末，在氮气氛围下加入15份氯化铁，搅拌混合均匀，在40℃下搅拌8h，发生原位聚合反应，过滤，洗涤，干燥后得到聚吡咯/二氧化钛/氧化锌螯合物；
(b)将3份步骤(a)中所得聚吡咯/二氧化钛/氧化锌螯合物、5份丙烯酸聚硅氧烷酯加入100份水性聚氨酯中，混合后得到所述改性水性聚氨酯。
实施例2
一种环保型防腐蚀箱包布面料的制造方法，包括以下步骤：
(1)涤纶纱线表面处理：将10份涤纶纱线依次用无水乙醇、去离子水进行洗涤并烘干，随后浸入100份KMnO4和质量分数为8％盐酸混合液中浸泡，KMnO4和盐酸的质量体积比为1g：40mL，浸泡温度为80℃，浸泡时间为30min，随后再进行紫外辐照处理，紫外辐照剂量为1000mJ/cm2，得到预处理涤纶纱线；
(2)纱线表面接枝：将10份步骤(1)中得到的预处理涤纶纱线加入到60份N,N-二甲基甲酰胺中，随后再加入4份丙烯酰胺、0.3份α-溴代异丁酸乙酯，在110℃下搅拌反应8h，反应完成后洗涤、干燥得到表面接枝改性涤纶纱线；
(3)面料织造：将步骤(2)中制得的表面接枝改性涤纶纱线织造为面料；
(4)面料后整理：将步骤(3)中所得面料放入复合整理剂中，在浸渍70℃下浸渍6h，随后在100℃下烘干4h，得到后整理面料；
(5)面料表面涂覆涂层：将步骤(4)中所得后整理面料表面涂覆改性水性聚氨酯，涂布量为300g/m2，在110℃下烘干3h，即得所述环保型防腐蚀箱包布面料。
其中，步骤(4)中所述复合整理剂的制备方法如下：
将45份全氟己基乙基丙烯酸甲酯、13份十二烷基三甲基硫酸铵、7份甲基三甲氧基硅烷、15份甲基丙烯酸异癸酯、6份对叔丁基苯甲酸混合均匀，在35℃下搅拌15min，随后再缓慢加入8份硬脂酸聚氧乙烯酯、12份硬脂酸锌、7份钼酸铵、3份月桂二酸，10min内投料完毕，最后加入230份去离子水，继续搅拌混合25min，即得所述复合整理剂。
步骤(5)中改性水性聚氨酯的制备方法如下：
(a)将10份3-吡咯羧酸、7份吡咯加入到200份去离子水中，加入2份二氧化钛和1份氧化锌粉末，在氮气氛围下加入16份氯化铁，搅拌混合均匀，在45℃下搅拌6h，发生原位聚合反应，过滤，洗涤，干燥后得到聚吡咯/二氧化钛/氧化锌螯合物；
(b)将4份步骤(a)中所得聚吡咯/二氧化钛/氧化锌螯合物、8份丙烯酸聚硅氧烷酯加入100份水性聚氨酯中，混合后得到所述改性水性聚氨酯。
实施例3
一种环保型防腐蚀箱包布面料的制造方法，包括以下步骤：
(1)涤纶纱线表面处理：将10份涤纶纱线依次用无水乙醇、去离子水进行洗涤并烘干，随后浸入100份KMnO4和质量分数为10％盐酸混合液中浸泡，KMnO4和盐酸的质量体积比为1g：50mL，浸泡温度为90℃，浸泡时间为20min，随后再进行紫外辐照处理，紫外辐照剂量为1200mJ/cm2，得到预处理涤纶纱线；
(2)纱线表面接枝：将10份步骤(1)中得到的预处理涤纶纱线加入到80份N,N-二甲基甲酰胺中，随后再加入5份丙烯酰胺、0.5份α-溴代异丁酸乙酯，在120℃下搅拌反应6h，反应完成后洗涤、干燥得到表面接枝改性涤纶纱线；
(3)面料织造：将步骤(2)中制得的表面接枝改性涤纶纱线织造为面料；
(4)面料后整理：将步骤(3)中所得面料放入复合整理剂中，在浸渍80℃下浸渍7h，随后在120℃下烘干3h，得到后整理面料；
(5)面料表面涂覆涂层：将步骤(4)中所得后整理面料表面涂覆改性水性聚氨酯，涂布量为300g/m2，在130℃下烘干2h，即得所述环保型防腐蚀箱包布面料。
其中，步骤(4)中所述复合整理剂的制备方法如下：
将50份全氟己基乙基丙烯酸甲酯、15份十二烷基三甲基硫酸铵、10份甲基三甲氧基硅烷、20份甲基丙烯酸异癸酯、8份对叔丁基苯甲酸混合均匀，在40℃下搅拌10min，随后再缓慢加入10份硬脂酸聚氧乙烯酯、15份硬脂酸锌、8份钼酸铵、5份月桂二酸，10min内投料完毕，最后加入250份去离子水，继续搅拌混合20min，即得所述复合整理剂。
步骤(5)中改性水性聚氨酯的制备方法如下：
(a)将10份3-吡咯羧酸、7份吡咯加入到200份去离子水中，加入3份二氧化钛和2份氧化锌粉末，在氮气氛围下加入17份氯化铁，搅拌混合均匀，在50℃下搅拌4h，发生原位聚合反应，过滤，洗涤，干燥后得到聚吡咯/二氧化钛/氧化锌螯合物；
(b)将5份步骤(a)中所得聚吡咯/二氧化钛/氧化锌螯合物、10份丙烯酸聚硅氧烷酯加入100份水性聚氨酯中，混合后得到所述改性水性聚氨酯。
对比例1
一种环保型防腐蚀箱包布面料的制造方法，包括以下步骤：
(1)面料织造：将涤纶纱线织造为面料；
(2)面料后整理：将步骤(1)中所得面料放入复合整理剂中，在浸渍60℃下浸渍7h，随后在90℃下烘干6h，得到后整理面料；
(3)面料表面涂覆涂层：将步骤(2)中所得后整理面料表面涂覆改性水性聚氨酯，涂布量为260g/m2，在100℃下烘干4h，即得所述环保型防腐蚀箱包布面料。
其中，步骤(2)中所述复合整理剂的制备方法如下：
将40份全氟己基乙基丙烯酸甲酯、10份十二烷基三甲基硫酸铵、5份甲基三甲氧基硅烷、10份甲基丙烯酸异癸酯、5份对叔丁基苯甲酸混合均匀，在30℃下搅拌20min，随后再缓慢加入6份硬脂酸聚氧乙烯酯、10份硬脂酸锌、5份钼酸铵、2份月桂二酸，8min内投料完毕，最后加入200份去离子水，继续搅拌混合30min，即得所述复合整理剂。
步骤(3)中改性水性聚氨酯的制备方法如下：
(a)将10份3-吡咯羧酸、6份吡咯加入到200份去离子水中，加入1份二氧化钛和1份氧化锌粉末，在氮气氛围下加入15份氯化铁，搅拌混合均匀，在40℃下搅拌8h，发生原位聚合反应，过滤，洗涤，干燥后得到聚吡咯/二氧化钛/氧化锌螯合物；
(b)将3份步骤(a)中所得聚吡咯/二氧化钛/氧化锌螯合物、5份丙烯酸聚硅氧烷酯加入100份水性聚氨酯中，混合后得到所述改性水性聚氨酯。
对比例2
一种环保型防腐蚀箱包布面料的制造方法，包括以下步骤：
(1)面料织造：将涤纶纱线织造为面料；
(2)面料表面涂覆涂层：将步骤(1)中所得后整理面料表面涂覆改性水性聚氨酯，涂布量为260g/m2，在100℃下烘干4h，即得所述环保型防腐蚀箱包布面料。
步骤(2)中改性水性聚氨酯的制备方法如下：
(a)将10份3-吡咯羧酸、6份吡咯加入到200份去离子水中，加入1份二氧化钛和1份氧化锌粉末，在氮气氛围下加入15份氯化铁，搅拌混合均匀，在40℃下搅拌8h，发生原位聚合反应，过滤，洗涤，干燥后得到聚吡咯/二氧化钛/氧化锌螯合物；
(b)将3份步骤(a)中所得聚吡咯/二氧化钛/氧化锌螯合物、5份丙烯酸聚硅氧烷酯加入100份水性聚氨酯中，混合后得到所述改性水性聚氨酯。
对比例3
一种环保型防腐蚀箱包布面料的制造方法，包括以下步骤：
(1)面料织造：将涤纶纱线织造为面料；
(2)面料后整理：将步骤(1)中所得面料放入复合整理剂中，在浸渍60℃下浸渍7h，随后在90℃下烘干6h，得到后整理面料；
(3)面料表面涂覆涂层：将步骤(2)中所得后整理面料表面涂覆水性聚氨酯，涂布量为260g/m2，在100℃下烘干4h，即得所述环保型防腐蚀箱包布面料。
其中，步骤(2)中所述复合整理剂的制备方法如下：
将40份全氟己基乙基丙烯酸甲酯、10份十二烷基三甲基硫酸铵、5份甲基三甲氧基硅烷、10份甲基丙烯酸异癸酯、5份对叔丁基苯甲酸混合均匀，在30℃下搅拌20min，随后再缓慢加入6份硬脂酸聚氧乙烯酯、10份硬脂酸锌、5份钼酸铵、2份月桂二酸，8min内投料完毕，最后加入200份去离子水，继续搅拌混合30min，即得所述复合整理剂。
将实施例1-3和对比例1-3制备得到的环保型防腐蚀箱包布面料进行性能测试，采用接触角测试仪，分别测试样品与去离子水的接触角，以判定疏水性；对面料的抗菌性能(参考GB/T 20944.3-2008《纺织品抗菌性能的评价第3部分：振荡法》，测试面料对大肠杆菌的抑菌率)；溶剂残留-DMFu采用GC-MS分析，测试结果如下表1：
表1各面料性能测试结果
疏水角/° 抗菌率/％ 溶剂残留-DMFu(mg/kg)
实施例1 157 98.6 未检出
实施例2 166 99.3 未检出
实施例3 164 98.8 未检出
对比例1 144 93.5 未检出
对比例2 139 88.2 未检出
对比例3 125 无抗菌性 未检出
按照JIS L-0217-103方法，对实施例1-3和对比例1-3制备得到的环保型防腐蚀箱包布面料反复洗涤30次和50次，然后评价疏水性和抗菌性，测试结果如下表2：
表2各面料在洗涤30次和50次后的性能测试结果
Figure BDA0003527687990000141
从表1中可以看出，本发明提供的环保型防腐蚀箱包布面料具有良好的疏水性能和抗菌率，且无溶剂残留，其环保性良好；并且经过50次反复洗涤后该织物仍具有较优异的疏水抗菌性能，说明本发明的面料在经过表面改性后，与整理剂和水性聚氨酯涂料的附着性能较强，提高了面料的耐水洗性能。对比例1中由于未对涤纶纱线表面进行表面改性，其综合性能有所下降；对比例2中未对涤纶纱线表面进行表面改性且未浸入复合整理剂，性能下降较为明显；对比例3未对涤纶纱线表面进行表面改性且未对水性聚氨酯改性，其疏水性能和耐洗涤性能下降明显，且无抗菌性。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。

Claims (8)

1.一种环保型防腐蚀箱包布面料的制造方法，其特征在于，包括以下步骤：
（1）涤纶纱线表面处理：将涤纶纱线依次用无水乙醇、去离子水进行洗涤并烘干，随后浸入KMnO4和盐酸混合液中浸泡，随后再进行紫外辐照处理，得到预处理涤纶纱线；
（2）纱线表面接枝：将步骤（1）中得到的预处理涤纶纱线加入到N,N-二甲基甲酰胺中，随后再加入丙烯酰胺、引发剂α-溴代异丁酸乙酯，进行搅拌反应，反应完成后洗涤、干燥得到表面接枝改性涤纶纱线；
（3）面料织造：将步骤（2）中制得的表面接枝改性涤纶纱线织造为面料；
（4）面料后整理：将步骤（3）中所得面料放入复合整理剂中，浸渍后烘干，得到后整理面料；
（5）面料表面涂覆涂层：将步骤（4）中所得后整理面料表面涂覆改性水性聚氨酯，涂布量为260-400g/m2，在100-130℃下烘干2-4h，即得所述环保型防腐蚀箱包布面料；
其中，步骤（4）中所述复合整理剂的制备方法如下：
将40-50份全氟己基乙基丙烯酸甲酯、10-15份十二烷基三甲基硫酸铵、5-10份甲基三甲氧基硅烷、10-20份甲基丙烯酸异癸酯、5-8份对叔丁基苯甲酸混合均匀，在30-40℃下搅拌10-20min，随后再缓慢加入6-10份硬脂酸聚氧乙烯酯、10-15份硬脂酸锌、5-8份钼酸铵、2-5份月桂二酸，8-10min内投料完毕，最后加入200-250份去离子水，继续搅拌混合20-30min，即得所述复合整理剂；
所述步骤（5）中改性水性聚氨酯的制备方法如下：
（a）将3-吡咯羧酸、吡咯加入到去离子水中，加入二氧化钛和氧化锌粉末，在氮气氛围下加入氯化铁，搅拌混合均匀，在40-50℃下搅拌4-8h，发生原位聚合反应，过滤，洗涤，干燥后得到聚吡咯/二氧化钛/氧化锌螯合物；
（b）将步骤（a）中所得聚吡咯/二氧化钛/氧化锌螯合物、丙烯酸聚硅氧烷酯加入水性聚氨酯中，混合后得到所述改性水性聚氨酯。
2.根据权利要求1所述环保型防腐蚀箱包布面料的制造方法，其特征在于，步骤（1）中盐酸的质量分数为5-10%，KMnO4和盐酸的质量体积比为1g：30-50mL。
3.根据权利要求1所述环保型防腐蚀箱包布面料的制造方法，其特征在于，步骤（1）中所述浸泡的温度为70-90℃，浸泡的时间为20-40min；步骤（1）中所述紫外辐照处理的条件为：紫外辐照剂量为800-1200mJ/cm2。
4.根据权利要求1所述环保型防腐蚀箱包布面料的制造方法，其特征在于，步骤（2）中所述搅拌反应的温度为100-120℃，反应的时间为6-10h。
5.根据权利要求1所述环保型防腐蚀箱包布面料的制造方法，其特征在于，步骤（2）中预处理涤纶纱线、N,N-二甲基甲酰胺、丙烯酰胺、引发剂α-溴代异丁酸乙酯的质量比为10：50-80：3-5：0.2-0.5。
6.根据权利要求1所述环保型防腐蚀箱包布面料的制造方法，其特征在于，步骤（4）中浸渍温度为60-80℃，浸渍时间为4-7h，烘干温度为90-120℃，烘干时间为3-6h。
7.根据权利要求1所述环保型防腐蚀箱包布面料的制造方法，其特征在于，所述步骤（a）中3-吡咯羧酸、吡咯、二氧化钛、氧化锌和氯化铁的质量比为10：6-7：1-3：1-2：15-17；步骤（b）中聚吡咯/二氧化钛/氧化锌螯合物、丙烯酸聚硅氧烷酯、水性聚氨酯的质量比为3-5：5-10：100。
8.一种利用权利要求1-7任一项所述方法制备得到的环保型防腐蚀箱包布面料在箱包上的应用。
CN202210197553.5A 2022-03-02 2022-03-02 一种环保型防腐蚀箱包布面料及其制造方法 Active CN114635278B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210197553.5A CN114635278B (zh) 2022-03-02 2022-03-02 一种环保型防腐蚀箱包布面料及其制造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210197553.5A CN114635278B (zh) 2022-03-02 2022-03-02 一种环保型防腐蚀箱包布面料及其制造方法

Publications (2)

Publication Number Publication Date
CN114635278A CN114635278A (zh) 2022-06-17
CN114635278B true CN114635278B (zh) 2022-09-16

Family

ID=81946890

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210197553.5A Active CN114635278B (zh) 2022-03-02 2022-03-02 一种环保型防腐蚀箱包布面料及其制造方法

Country Status (1)

Country Link
CN (1) CN114635278B (zh)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000032844A1 (en) * 1998-12-02 2000-06-08 The Board Of Governors For Higher Education, State Of Rhode Island And Providence Plantations Water-borne polymeric complex and anti-corrosive composition
CN102154832A (zh) * 2010-12-31 2011-08-17 泉州红瑞兴纺织有限公司 一种具有电磁屏蔽功能的织物涂层整理剂及其制备方法
CN104047091A (zh) * 2014-06-27 2014-09-17 江苏金宏针纺织有限公司 阻燃防腐涤纶针织面料
CN111636202A (zh) * 2020-06-29 2020-09-08 长沙柔织新材料科技有限公司 一种高吸水性芳香涤纶织物的制备方法
CN111851084A (zh) * 2020-06-19 2020-10-30 成都新柯力化工科技有限公司 一种防水透湿服装面料的整理方法
CN112063282A (zh) * 2020-08-05 2020-12-11 新昌县品宏科技有限公司 一种阻燃型导电聚吡咯-聚氨酯水性复合涂料及其制法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2441004A1 (en) * 2001-03-15 2002-09-26 Cabot Corporation Corrosion-resistant coating composition
US20140170418A1 (en) * 2011-05-23 2014-06-19 Axalta Coating Systems Ip Co., Llc Anti-corrosion coating composition and use thereof
US9683109B2 (en) * 2013-12-30 2017-06-20 Council Of Scientific & Industrial Research Self healing anti corrosive coatings and a process for the preparation thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000032844A1 (en) * 1998-12-02 2000-06-08 The Board Of Governors For Higher Education, State Of Rhode Island And Providence Plantations Water-borne polymeric complex and anti-corrosive composition
CN102154832A (zh) * 2010-12-31 2011-08-17 泉州红瑞兴纺织有限公司 一种具有电磁屏蔽功能的织物涂层整理剂及其制备方法
CN104047091A (zh) * 2014-06-27 2014-09-17 江苏金宏针纺织有限公司 阻燃防腐涤纶针织面料
CN111851084A (zh) * 2020-06-19 2020-10-30 成都新柯力化工科技有限公司 一种防水透湿服装面料的整理方法
CN111636202A (zh) * 2020-06-29 2020-09-08 长沙柔织新材料科技有限公司 一种高吸水性芳香涤纶织物的制备方法
CN112063282A (zh) * 2020-08-05 2020-12-11 新昌县品宏科技有限公司 一种阻燃型导电聚吡咯-聚氨酯水性复合涂料及其制法

Also Published As

Publication number Publication date
CN114635278A (zh) 2022-06-17

Similar Documents

Publication Publication Date Title
Ferrero et al. Antimicrobial finish of textiles by chitosan UV-curing
CN112111970B (zh) 一种环保表面改性棉纤维的制备方法
Ibrahim et al. Poly (acrylic acid)/poly (ethylene glycol) adduct for attaining multifunctional cellulosic fabrics
JP5864594B2 (ja) 抗菌性を有する剤が固定化された物品及びその製造方法
CN111455665B (zh) 一种耐水洗三防易去污透气防钻绒面料及其制备方法
CN112376277A (zh) 一种涤纶面料的染色工艺
CN114635278B (zh) 一种环保型防腐蚀箱包布面料及其制造方法
Niu et al. Investigation on multifunctional modification of cotton fabrics for salt-free dyeing, resisting crease and inhibiting bacteria
CN111945446A (zh) 一种环保型棉用亲水性固色剂及其制备方法
CN113373691B (zh) 一种阳离子改性剂tctac的制备方法及应用
TWI383084B (zh) 交聯丙烯酸酯系纖維之染色方法，及含以該染色方法染色之交聯丙烯酸酯系纖維之纖維製品
Jang et al. Continuous photografting of HEMA onto polypropylene fabrics with benzophenone photoinitiator
KR100455509B1 (ko) 셀룰로오스계섬유함유직편물의수지가공방법
CN111809395A (zh) 一种抗静电大衣整理工艺
Fahmy et al. Synthesis of poly (N-vinyl-2-pyrrolidone)/pyrodextrins adducts and their utilization in functionalization of cotton fabric
Sharma et al. Surface modification of cellulosic fabric
CN109518496B (zh) 一种亚麻织物的染色方法
Li et al. Biocidal activity of n-halamine methylenebisacrylamide grafted cotton
CN110820321A (zh) 一种涤纶纤维整理剂及制备方法和纤维整理方法
CN110273294B (zh) 一种防暴雨耐热水帆布面料及其制备方法
EP3470573A1 (de) Verfahren zur herstellung eines textilen artikels mit hydrophobierter textiler oberfläche durch plasmabehandlung und nasschemische behandlung
CN115283227A (zh) 一种抗菌抗静电防紫外聚氨酯合成革的制备方法
CN112144301A (zh) 一种棉针织面料印染工艺
CN110820339A (zh) 一种用于纺织品的高浓度含氟拒水拒油剂及其制备方法
CN113550144B (zh) 一种抗菌疏水牛仔织物的制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant