CN114621500A - Composite flame retardant, flame-retardant high impact polystyrene material and preparation method - Google Patents
Composite flame retardant, flame-retardant high impact polystyrene material and preparation method Download PDFInfo
- Publication number
- CN114621500A CN114621500A CN202210329261.2A CN202210329261A CN114621500A CN 114621500 A CN114621500 A CN 114621500A CN 202210329261 A CN202210329261 A CN 202210329261A CN 114621500 A CN114621500 A CN 114621500A
- Authority
- CN
- China
- Prior art keywords
- flame retardant
- high impact
- impact polystyrene
- retardant
- paraquat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 127
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 124
- 229920005669 high impact polystyrene Polymers 0.000 title claims abstract description 45
- 239000004797 high-impact polystyrene Substances 0.000 title claims abstract description 45
- 239000002131 composite material Substances 0.000 title claims abstract description 38
- 239000000463 material Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 94
- FIKAKWIAUPDISJ-UHFFFAOYSA-L paraquat dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 FIKAKWIAUPDISJ-UHFFFAOYSA-L 0.000 claims abstract description 50
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 48
- NZUPFZNVGSWLQC-UHFFFAOYSA-N 1,3,5-tris(2,3-dibromopropyl)-1,3,5-triazinane-2,4,6-trione Chemical compound BrCC(Br)CN1C(=O)N(CC(Br)CBr)C(=O)N(CC(Br)CBr)C1=O NZUPFZNVGSWLQC-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000004695 Polyether sulfone Substances 0.000 claims abstract description 30
- 229920006393 polyether sulfone Polymers 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000002245 particle Substances 0.000 claims abstract description 14
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 7
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims description 24
- 238000010438 heat treatment Methods 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 17
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical group CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 15
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 10
- 235000012239 silicon dioxide Nutrition 0.000 claims description 10
- 239000007822 coupling agent Substances 0.000 claims description 9
- 239000011247 coating layer Substances 0.000 claims description 7
- 239000011148 porous material Substances 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 238000000151 deposition Methods 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- 230000000694 effects Effects 0.000 abstract description 15
- 238000000576 coating method Methods 0.000 abstract description 5
- 239000011159 matrix material Substances 0.000 abstract description 5
- 230000004048 modification Effects 0.000 abstract description 5
- 238000012986 modification Methods 0.000 abstract description 5
- 239000004793 Polystyrene Substances 0.000 abstract description 4
- 239000011248 coating agent Substances 0.000 abstract description 4
- 238000011068 loading method Methods 0.000 abstract description 4
- 229920002223 polystyrene Polymers 0.000 abstract description 4
- 238000001125 extrusion Methods 0.000 abstract 1
- 238000005469 granulation Methods 0.000 abstract 1
- 230000003179 granulation Effects 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 20
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 20
- 229910052794 bromium Inorganic materials 0.000 description 20
- 229920000642 polymer Polymers 0.000 description 16
- 150000001723 carbon free-radicals Chemical group 0.000 description 13
- -1 dimethylphenyl Chemical group 0.000 description 13
- 238000002485 combustion reaction Methods 0.000 description 10
- 150000003254 radicals Chemical class 0.000 description 10
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 9
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 8
- 238000005336 cracking Methods 0.000 description 8
- 238000012545 processing Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- 238000007599 discharging Methods 0.000 description 3
- 238000007323 disproportionation reaction Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229910021426 porous silicon Inorganic materials 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 230000001808 coupling effect Effects 0.000 description 1
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910001853 inorganic hydroxide Inorganic materials 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 230000000297 inotrophic effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/12—Adsorbed ingredients, e.g. ingredients on carriers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/26—Silicon- containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210329261.2A CN114621500B (en) | 2022-03-31 | 2022-03-31 | Composite flame retardant, flame-retardant high-impact polystyrene material and preparation method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210329261.2A CN114621500B (en) | 2022-03-31 | 2022-03-31 | Composite flame retardant, flame-retardant high-impact polystyrene material and preparation method |
Publications (2)
Publication Number | Publication Date |
---|---|
CN114621500A true CN114621500A (en) | 2022-06-14 |
CN114621500B CN114621500B (en) | 2023-11-28 |
Family
ID=81903527
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202210329261.2A Active CN114621500B (en) | 2022-03-31 | 2022-03-31 | Composite flame retardant, flame-retardant high-impact polystyrene material and preparation method |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN114621500B (en) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004331964A (en) * | 2003-04-16 | 2004-11-25 | Kaneka Corp | Styrenic resin foamed product and production process therefor |
JP2005068281A (en) * | 2003-08-22 | 2005-03-17 | Asahi Kasei Chemicals Corp | Flame retardant for aromatic polycarbonate resin |
CN1733709A (en) * | 2004-08-14 | 2006-02-15 | 德古萨股份公司 | Method for preparing solid(2,3- dibrompropyl) isocyanurate |
CN1847308A (en) * | 2005-04-04 | 2006-10-18 | 信越化学工业株式会社 | Flame retardant and an epoxy resin composition comprising the same for encapsulating semiconductor devices |
CN102766471A (en) * | 2012-03-29 | 2012-11-07 | 广东省宜华木业股份有限公司 | Preparation method of mesoporous silica nanometer composite flame retardant |
CN113372676A (en) * | 2021-05-25 | 2021-09-10 | 会通新材料股份有限公司 | Flame-retardant high impact polystyrene composition and preparation method thereof |
-
2022
- 2022-03-31 CN CN202210329261.2A patent/CN114621500B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004331964A (en) * | 2003-04-16 | 2004-11-25 | Kaneka Corp | Styrenic resin foamed product and production process therefor |
JP2005068281A (en) * | 2003-08-22 | 2005-03-17 | Asahi Kasei Chemicals Corp | Flame retardant for aromatic polycarbonate resin |
CN1733709A (en) * | 2004-08-14 | 2006-02-15 | 德古萨股份公司 | Method for preparing solid(2,3- dibrompropyl) isocyanurate |
CN1847308A (en) * | 2005-04-04 | 2006-10-18 | 信越化学工业株式会社 | Flame retardant and an epoxy resin composition comprising the same for encapsulating semiconductor devices |
CN102766471A (en) * | 2012-03-29 | 2012-11-07 | 广东省宜华木业股份有限公司 | Preparation method of mesoporous silica nanometer composite flame retardant |
CN113372676A (en) * | 2021-05-25 | 2021-09-10 | 会通新材料股份有限公司 | Flame-retardant high impact polystyrene composition and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN114621500B (en) | 2023-11-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20231024 Address after: No. 81 Xingye Street, Manzhuang Town, Daiyue District, Tai'an City, Shandong Province, 271000 Applicant after: Senior (Shandong) New Material Technology Co.,Ltd. Address before: 610000 Beihu Yinxiang community, Longtan street, Chenghua District, Chengdu, Sichuan Applicant before: Li Ling |
|
GR01 | Patent grant | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A composite flame retardant, flame retardant high impact polystyrene material and preparation method Granted publication date: 20231128 Pledgee: Weihai Commercial Bank Co.,Ltd. Tai'an Branch Pledgor: Senior (Shandong) New Material Technology Co.,Ltd. Registration number: Y2024980016901 |