CN108102213A - A kind of flame-proof polypropelene composition and its preparation method and application - Google Patents
A kind of flame-proof polypropelene composition and its preparation method and application Download PDFInfo
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- C08K5/13—Phenols; Phenolates
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- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
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- C08K5/3492—Triazines
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- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
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Abstract
The invention discloses a kind of flame-proof polypropelene composition and its preparation method and application, including component：60 parts 80 parts of acrylic resin；Environmentally friendly 10 parts 25 parts of bromide fire retardant；2 parts 10 parts of fire retarding synergist；2 parts 10 parts of thermal stabilization modifying agent；Wherein, the fire retarding synergist is antimony system fire retarding synergist and the compound of inorganic particle, the total weight based on fire retarding synergist, and the weight percentage of antimony system fire retarding synergist is 45 55%.The present invention in flame-proof polypropelene composition by adding thermal stabilization modifying agent and fire retarding synergist, the two synergistic effect, not only thermal stability significantly improves the flame-proof polypropelene composition being prepared, and good mobility is also retained, it can be widely applied to a variety of products and product for needing flame-proof heat-resistant such as accumulator, power supply, socket, lamp decoration, electric cooker, electromagnetic oven.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of flame-proof polypropelene composition and preparation method thereof
And application.
Background technology
It is well known that polypropylene belongs to combustible material because its oxygen index (OI) only only has 17%-18%, led in many small household appliances
Flame retardant property is the premise of its application in the use in domain.But for some products being heated for a long time, complicated, such as：
The electric appliance casings such as electric cooker, toilet lid, micro-wave oven, wiring board, electromagnetic oven or parts, except requiring material that there is flame retardant property
While, also require material that there is high fluidity and high-fire resistance.
It is polyacrylic it is flame-retardant modified mainly by acrylic resin add in fire retardant it is made to occur in combustion
Specific physical-chemical reaction achievees the purpose that fire-retardant.Mainly there are bromine system flame retardant series and Halogen suitable for polyacrylic fire retardant
Flame retardant series.Bromine system flame retardant series are mainly comprising eight bromo ether, eight bromine S ethers, decabromodiphenylethane, brominated triazine, polyacrylic acid five
Bromine Bian ester, brominated epoxy, brominated Polystyrene etc..Wherein eight brominated flame retardants are primarily referred to as eight bromo ether and eight bromine S ethers, because of it
High efficiency flame retardance is widely used in polypropylene fire retardant product, can generally meet UL94 standard samples for 127mm ×
The V-0 classification standards of 12.7mm × 1.6mm.Therefore, it is necessary to such a material, batten 127mm × 12.7mm × 0.6mm
Reach the flame retardant effect of V-0 grades with reference to the test method detection of UL94, to meet the market demand.But since eight bromine classes are fire-retardant
Agent itself decomposition temperature is relatively low, and in process, the bromine atoms on molecular structure easily emit hydrogen bromide with neighbouring hydrogen atom
Elimination reaction, and the fracture of other carbon bromine keys is further catalyzed, cause the thermal stability of eight brominated flame retardants to reduce so that addition
The polypropylene material of eight brominated flame retardants is easy in process to cross thermal degradation discoloration, and it is certain resistance in needs seriously to limit it
The application in hot field.
In order to improve the thermal stability of eight bromine class anti-flaming polypropylene materials, patent CN100398503C is disclosed by eight
Ionic emulsifying agent, nonionic emulsifier or amphoteric surfactant and Sionit, different are added in the preparation process of bromo-ether
Cyanurate ethylene oxidic ester, 1,4- butanediols double (beta-amino butenoic acid) esters improve the heat decomposition temperature of eight bromo ether.Hefei work
Industry college journal the 6th the 837-840 pages of the phase of volume 32 is reported a kind of coated using amino resin prepolymer and handles eight bromo ether
Method improves the heat decomposition temperature of eight bromo ether, after cladding the temperature of initial decomposition of eight bromo ether by 160 DEG C be increased to 240 DEG C with
On.Patent CN102250382A discloses a kind of zinc stearate/barium stearate by adding special ratios or zinc stearate/hard
Resin acid calcium compound thermal stabilization aid, the coupling agent of the composite antioxidant and certain species of specific dosage and special ratios carry
The method of high eight bromo ether thermal stability.
There is different degrees of effect in terms of thermal stability of the above method for improving eight bromo ether fire retardant, but technique is answered
Miscellaneous and cost is higher.
The content of the invention
In order to solve the problems, such as that above-mentioned flame-proof polypropelene composition thermal stability is poor, it is an object of the invention to provide one kind
Flame-proof polypropelene composition, not only thermal stability significantly improves flame-proof polypropelene composition, but also also retains good flowing
Property.
The present invention is achieved by the following technical solutions：
A kind of flame-proof polypropelene composition, is counted in parts by weight, including following components：
60 parts -80 parts of acrylic resin；
Environmentally friendly 10 parts -25 parts of bromide fire retardant；
2 parts -10 parts of fire retarding synergist；
2 parts -10 parts of thermal stabilization modifying agent；
0.1 part -2 parts of composite antioxidant；
Wherein, the fire retarding synergist is antimony system fire retarding synergist and the compound of inorganic particle, based on the total of fire retarding synergist
Weight,
The weight percentage of antimony system fire retarding synergist is 45-55%.Since antimony system fire retarding synergist can accelerate environmentally friendly bromine system fire-retardant
The decomposition of agent, reduces its heat decomposition temperature, and antimony system fire retarding synergist and other inorganic particles compounding are formed fire-retardant association by the present invention
Effect system since antimony oxide content will be to reducing, therefore reduces the damage of heat resistance, while can also ensure that reaching fire-retardant wants
The synergistic efficiency asked.
The acrylic resin is homopolypropylene.
Antimony system fire retarding synergist is one or more of antimony oxide, sodium antimonate, phosphoric acid antimony or phosphorous acid antimony
Mixture.
The inorganic particle is montmorillonite, wollastonite, calcium carbonate, silica, glass microballoon, carbon nanotubes or graphene
In
One or more of mixtures.
The environmental protection bromide fire retardant is eight bromo ether, eight bromine S ethers, polyacrylic acid pentabromo- Bian ester, decabromodiphenylethane or bromine
For the mixture of one or more of triazine.
The thermal stabilization modifying agent is in calcium zinc type thermal stabilizing agent, barium zinc type thermal stabilizing agent or organic tin heat stabilizer
One or more of mixtures, preferably organic tin heat stabilizer are 1 by weight with barium zinc type thermal stabilizing agent:1 compound.
The composite antioxidant is resistance phenols primary antioxidant and phosphorous acid esters auxiliary anti-oxidant by weight 1:5-5:1 answers
With object.
According to actual performance needs, the above-mentioned flame-proof polypropelene composition of the present invention is counted, further includes 0.1- in parts by weight
1 part of lubricant, the lubricant are the mixing of one or more of stearmide series lubricant agent, ester lubricant or White Mineral Oil
Object..
The present invention also provides the preparation methods of above-mentioned flame-proof polypropelene composition, include the following steps：
(a) each component raw material is sufficiently mixed 5-30 minutes by proportioning in high-speed mixer；
(b) said mixture is transported in double screw extruder, the control of each section of extruder temperature of extruder 160-220 DEG C it
Between, feeding rotating speed is 100-600 revs/min, and the screw slenderness ratio of double screw extruder is 25-40, screw speed 200-600
Rev/min, under the shearing of screw rod, batch mixing and conveying, material is able to fully melting, plasticizing, blending, using extruding pelletization,
It is dried to obtain flame-proof polypropelene composition.
The present invention also provides above-mentioned flame-proof polypropelene composition in power supply, socket, bathroom, accumulator, lamp decoration, electric meal
Application in pot or electromagnetic oven.
Compared with prior art, the present invention has the advantages that：
（1）The present invention in flame-proof polypropelene composition by adding fire retarding synergist, and using thermal stabilization modifying agent and compound
Antioxidant is combined, and not only thermal stability significantly improves the flame-proof polypropelene composition being prepared, but also also retains good
Mobility can be widely applied to a variety of systems for needing flame-proof heat-resistant such as accumulator, power supply, socket, lamp decoration, electric cooker, electromagnetic oven
Part and product.
（2）High fluidity, the flame-retardant polypropylene of high thermal stability can be prepared using the method for simple blend in the present invention
Ene compositions avoid eight brominated flame retardants for first preparing high thermal stability that the prior art is mentioned, it is recycled to prepare resistance
The complicated technique and method of polypropylene material is fired, preparation flow is simplified, has the characteristics that preparation efficiency is high, easy to operate.
Specific embodiment
Embodiment is given below so that the present invention to be specifically described, but not limited to this.
Now the raw material used in embodiment and comparative example are done as described below, but be not limited to these materials：
Acrylic resin：The homopolypropylene of CSPC model PP HP500N；
Environmentally friendly bromide fire retardant：The eight bromo ether of Lianyun Harbour seawater chemical industry, eight bromine S ethers of red rosy clouds chemical industry；Hundred power chemistry of Taizhou is limited
The decabromodiphenylethane of company, the brominated triazine of Israel's chemical industry；
Fire-retardant effect agent is assisted by antimony system：The antimony oxide of Changde Chen Zhou Ti Pin Co., Ltds, Shenzhen Jing Qiao Science and Technology Ltd.s
Phosphoric acid antimony and phosphorous acid antimony；
Inorganic particle：The montmorillonite of Jiangxi Wei Pu Science and Technology Ltd.s, the firm wollastonite up to fine mineral Co., Ltd in Dalian, east
The calcium carbonate of tabernaemontanus bulrush Mei Litai Chemical Co., Ltd.s, the silica of Guangzhou Zhuo Fan Chemical Co., Ltd.s, 3M（China）Co., Ltd
Glass microballoon, the carbon nanotubes of Te Li green woods Science and Technology Ltd. of Shenzhen, Suzhou Tan Feng graphenes Science and Technology Ltd.
Graphene；
Thermal stabilization modifying agent：The organic tin heat stabilizer of Hubei Benxing Chemical Co., Ltd., the trade of Ai Dike Shanghai have
The barium zinc type thermal stabilizing agent of limit company；
Lubricant：Stearmide series lubricant agent；
Composite antioxidant：The resistance phenols primary antioxidant 168 and phosphorous acid esters auxiliary anti-oxidant 1010 of gas Ba Jinghua be in mass ratio
1：2-1：4 compound.
Performance test methods：
Melt index：Using plastics melt flow rate tester, test temperature is 230 DEG C, and counterweight weight is 2.16kg.
Temperature of initial decomposition：Using thermal gravimetric analyzer, Range of measuring temp is 30-700 DEG C, heating rate for 10 DEG C/
Min, it is temperature of initial decomposition to take the temperature corresponding to 5wt% thermal weight losses.
Embodiment 1-8 and comparative example 1-5：
The parts by weight as shown in table 1 weigh component, and each component raw material is sufficiently mixed 5-30 points in high-speed mixer by proportioning
Clock；Said mixture is transported in double screw extruder, each section of extruder temperature of extruder is controlled between 160-220 DEG C,
Feeding rotating speed is 100-600 revs/min, and the screw slenderness ratio of double screw extruder is 25-40, screw speed turns for 200-600/
Minute, under the shearing of screw rod, batch mixing and conveying, material is able to fully melting, plasticizing, blending, dry using extruding pelletization
Obtain flame-proof polypropelene composition.Corresponding test bars are made by standard, and measure its performance, concrete numerical value is listed in table 1.
1 anti-flaming polypropylene composite of table forms and performance
The present invention is special by being added in flame-proof polypropelene composition it can be seen from the test result of each embodiment and comparative example
Surely the fire retarding synergist compounded, and pass through the combination of thermal stabilization modifying agent and composite antioxidant, the polypropylene flame redardant being prepared
Not only thermal stability significantly improves composition, but also also retains good mobility.
Claims (10)
1. a kind of flame-proof polypropelene composition, which is characterized in that count in parts by weight, including following components：
60 parts -80 parts of acrylic resin；
Environmentally friendly 10 parts -25 parts of bromide fire retardant；
2 parts -10 parts of fire retarding synergist；
2 parts -10 parts of thermal stabilization modifying agent；
0.1 part -2 parts of composite antioxidant；
Wherein, the fire retarding synergist is antimony system fire retarding synergist and the compound of inorganic particle, based on the total of fire retarding synergist
Weight, the weight percentage of antimony system fire retarding synergist is 45-55%.
2. flame-proof polypropelene composition according to claim 1, which is characterized in that the acrylic resin is homopolymerization poly- third
Alkene.
3. flame-proof polypropelene composition according to claim 1, which is characterized in that antimony system fire retarding synergist is three oxygen
Change the mixture of one or more of two antimony, sodium antimonate, phosphoric acid antimony or phosphorous acid antimony.
4. flame-proof polypropelene composition according to claim 1, which is characterized in that the inorganic particle is montmorillonite, silicon
The mixture of one or more of lime stone, calcium carbonate, silica, glass microballoon, carbon nanotubes or graphene.
5. flame-proof polypropelene composition according to claim 1, which is characterized in that the environmental protection bromide fire retardant is eight bromines
The mixture of one or more of ether, eight bromine S ethers, polyacrylic acid pentabromo- Bian ester, decabromodiphenylethane or brominated triazine.
6. flame-proof polypropelene composition according to claim 1, which is characterized in that the thermal stabilization modifying agent is calcium zinc class
The mixture of one or more of heat stabilizer, barium zinc type thermal stabilizing agent or organic tin heat stabilizer, preferably organic tin
Heat stabilizer and barium zinc type thermal stabilizing agent are 1 by weight:1 compound.
7. flame-proof polypropelene composition according to claim 1, which is characterized in that the composite antioxidant is resistance phenols master
Antioxidant and phosphorous acid esters auxiliary anti-oxidant are by weight 1:5-5:1 compound.
8. according to claim 1-7 any one of them flame-proof polypropelene compositions, which is characterized in that count in parts by weight, also
Including 0.1-1 parts of lubricants, the lubricant is one kind or several in stearmide series lubricant agent, ester lubricant or White Mineral Oil
The mixture of kind.
9. according to the preparation method of claim 1-8 any one of them flame-proof polypropelene compositions, which is characterized in that including such as
Lower step：
(a) each component raw material is sufficiently mixed 5-30 minutes by proportioning in high-speed mixer；
(b) said mixture is transported in double screw extruder, the control of each section of extruder temperature of extruder 160-220 DEG C it
Between, feeding rotating speed is 100-600 revs/min, and the screw slenderness ratio of double screw extruder is 25-40, screw speed 200-600
Rev/min, under the shearing of screw rod, batch mixing and conveying, material is able to fully melting, plasticizing, blending, using extruding pelletization,
It is dried to obtain flame-proof polypropelene composition.
10. according to claim 1-8 any one of them flame-proof polypropelene composition in power supply, socket, bathroom, accumulator, lamp
Application in decorations, electric cooker or electromagnetic oven.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109486041A (en) * | 2018-11-01 | 2019-03-19 | 广东基地光电有限公司 | A kind of fire-retardant PP diffuser plate and preparation method thereof |
| WO2020010989A1 (en) * | 2018-07-09 | 2020-01-16 | 金发科技股份有限公司 | Flame-retardant polypropylene material, preparation method, and application thereof |
| CN111205553A (en) * | 2020-01-09 | 2020-05-29 | 山东清河化工科技有限公司 | Preparation method of ultrahigh molecular weight polypropylene material with high thermal-oxidative stability |
| CN111484668A (en) * | 2019-12-19 | 2020-08-04 | 会通新材料股份有限公司 | Flame-retardant polypropylene composite material and preparation method thereof |
| CN112358687A (en) * | 2020-11-10 | 2021-02-12 | 江苏金发科技新材料有限公司 | Flame-retardant polypropylene composition and preparation method thereof |
| CN112480534A (en) * | 2020-11-26 | 2021-03-12 | 上海明克包装制品有限公司 | Heat-resistant flame-retardant paper-plastic composite bag and preparation method thereof |
| CN114085448A (en) * | 2021-12-23 | 2022-02-25 | 南通科顺建筑新材料有限公司 | High-temperature-resistant waterproof coiled material sizing material composition, high-temperature-resistant waterproof coiled material sizing material, and preparation method and application thereof |
| CN114835556A (en) * | 2022-05-11 | 2022-08-02 | 常州巨德新材料有限公司 | Bromine-containing norbornene derivative, preparation method thereof and flame-retardant polydicyclopentadiene material |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08113682A (en) * | 1994-10-14 | 1996-05-07 | Sumitomo Bakelite Co Ltd | Flame-retardant polypropylene sheet |
| JP2003160705A (en) * | 2001-11-28 | 2003-06-06 | Suzuhiro Kagaku:Kk | Flame-retardant polypropylene composition |
| CN1536012A (en) * | 2003-04-07 | 2004-10-13 | 上海日之升新技术发展有限公司 | Magnesium solt whisker rein forced fire-resisting polypropylene composition |
| CN1696188A (en) * | 2005-03-07 | 2005-11-16 | 广东顾地塑胶股份有限公司 | Fire retardant composite material of polypropylene and application |
| CN101469095A (en) * | 2007-12-28 | 2009-07-01 | 上海普利特复合材料股份有限公司 | Environment protective and flame-retardant polypropelene composition |
| CN102250382A (en) * | 2011-05-17 | 2011-11-23 | 山东兄弟科技股份有限公司 | Preparation method of high thermostable eight bromo ether |
-
2017
- 2017-11-10 CN CN201711106143.0A patent/CN108102213B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08113682A (en) * | 1994-10-14 | 1996-05-07 | Sumitomo Bakelite Co Ltd | Flame-retardant polypropylene sheet |
| JP2003160705A (en) * | 2001-11-28 | 2003-06-06 | Suzuhiro Kagaku:Kk | Flame-retardant polypropylene composition |
| CN1536012A (en) * | 2003-04-07 | 2004-10-13 | 上海日之升新技术发展有限公司 | Magnesium solt whisker rein forced fire-resisting polypropylene composition |
| CN1696188A (en) * | 2005-03-07 | 2005-11-16 | 广东顾地塑胶股份有限公司 | Fire retardant composite material of polypropylene and application |
| CN101469095A (en) * | 2007-12-28 | 2009-07-01 | 上海普利特复合材料股份有限公司 | Environment protective and flame-retardant polypropelene composition |
| CN102250382A (en) * | 2011-05-17 | 2011-11-23 | 山东兄弟科技股份有限公司 | Preparation method of high thermostable eight bromo ether |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020010989A1 (en) * | 2018-07-09 | 2020-01-16 | 金发科技股份有限公司 | Flame-retardant polypropylene material, preparation method, and application thereof |
| CN109486041A (en) * | 2018-11-01 | 2019-03-19 | 广东基地光电有限公司 | A kind of fire-retardant PP diffuser plate and preparation method thereof |
| CN111484668A (en) * | 2019-12-19 | 2020-08-04 | 会通新材料股份有限公司 | Flame-retardant polypropylene composite material and preparation method thereof |
| CN111205553A (en) * | 2020-01-09 | 2020-05-29 | 山东清河化工科技有限公司 | Preparation method of ultrahigh molecular weight polypropylene material with high thermal-oxidative stability |
| CN112358687A (en) * | 2020-11-10 | 2021-02-12 | 江苏金发科技新材料有限公司 | Flame-retardant polypropylene composition and preparation method thereof |
| CN112480534A (en) * | 2020-11-26 | 2021-03-12 | 上海明克包装制品有限公司 | Heat-resistant flame-retardant paper-plastic composite bag and preparation method thereof |
| CN114085448A (en) * | 2021-12-23 | 2022-02-25 | 南通科顺建筑新材料有限公司 | High-temperature-resistant waterproof coiled material sizing material composition, high-temperature-resistant waterproof coiled material sizing material, and preparation method and application thereof |
| CN114085448B (en) * | 2021-12-23 | 2022-11-18 | 南通科顺建筑新材料有限公司 | High-temperature-resistant waterproof coiled material sizing material composition, high-temperature-resistant waterproof coiled material sizing material, and preparation method and application thereof |
| CN114835556A (en) * | 2022-05-11 | 2022-08-02 | 常州巨德新材料有限公司 | Bromine-containing norbornene derivative, preparation method thereof and flame-retardant polydicyclopentadiene material |
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Effective date of registration: 20211228 Address after: 221000 Jiangsu, Xuzhou, Pizhou high tech Industrial Development Zone, the southern side of Chun Hing Road, the west side of Jian Qiu road. Patentee after: Jiangsu golden hair Environmental Protection Technology Co.,Ltd. Address before: 510663 Guangzhou science and Technology Development Zone, Guangdong, China, 33 Patentee before: KINGFA SCI. & TECH. Co.,Ltd. Patentee before: Tianjin Jinfa New Material Co., Ltd |