CN114561646A - Efficient rust remover for medical instruments and preparation method thereof - Google Patents

Efficient rust remover for medical instruments and preparation method thereof Download PDF

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Publication number
CN114561646A
CN114561646A CN202210177540.1A CN202210177540A CN114561646A CN 114561646 A CN114561646 A CN 114561646A CN 202210177540 A CN202210177540 A CN 202210177540A CN 114561646 A CN114561646 A CN 114561646A
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CN
China
Prior art keywords
acid
sodium
mixture
rust remover
rust
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Pending
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CN202210177540.1A
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Chinese (zh)
Inventor
不公告发明人
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Shanghai Shenying Biotechnology Co ltd
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Shanghai Shenying Biotechnology Co ltd
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Priority to CN202210177540.1A priority Critical patent/CN114561646A/en
Publication of CN114561646A publication Critical patent/CN114561646A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • C23G1/061Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors nitrogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • C23G1/063Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors heterocyclic compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • C23G1/066Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors phosphorus-containing compounds

Abstract

The invention discloses a high-efficiency rust remover for medical instruments and a preparation method thereof. The efficient rust remover for the medical instruments is a water-based solution compounded by a surfactant, an acid, a cleaning assistant, a chelating agent and the like through reasonable formula design. The high-efficiency rust remover for the medical apparatus has the advantages of high rust removing and descaling speed, no damage to stainless steel apparatuses, simple production and environmental friendliness.

Description

Efficient rust remover for medical instruments and preparation method thereof
Technical Field
The invention belongs to an efficient rust remover for medical instruments, and relates to a preparation method of the rust remover.
Background
In hospitals all over the world, various medical instruments are frequently used every day, particularly various surgical instruments including common surgical instruments, precise minimally invasive surgical instruments and the like are contacted with pollutants such as bloodstains and the like in the process of operation, and if the pollutants are not treated in time, the pollutants can easily accelerate the rusting and corrosion of the medical instruments, so that the instruments are out of order and cannot be normally used. The existing medical instruments are often high in price, in order to reduce the using cost of the instruments, the instruments need to be cleaned and maintained in time after being used, and rusty spots need to be removed in time when rusting is found, so that the situation that the rust expands to cause that the instruments cannot be repaired when being scrapped is avoided.
The prior hospitals usually use strong acid rust removers, which can effectively remove rust spots and rust stains, particularly large-area rust stains, but have serious corrosion to instruments, which is a contradiction. The existing medical apparatus is expensive, so the strong acid rust remover is not suitable for removing rust of the apparatus, but rather a milder rust remover should be selected. However, the mild rust remover has the disadvantages of long rust removing time, low efficiency and incomplete rust removal, and cannot meet the use requirements.
In order to overcome the problems of the prior rust remover for medical instruments, the invention develops an efficient rust remover and a preparation method thereof. The composite surface active agent is used, so that the surface energy of the instrument is effectively reduced, the using amount of an acid agent is reduced, the corrosivity of acid to the instrument is reduced, and the corrosion of the instrument is effectively protected by using the composite chelating agent and the corrosion inhibitor.
Disclosure of Invention
Aiming at the problems in the prior art, the invention aims to provide an efficient rust remover for medical instruments and a preparation method thereof.
The technical scheme for realizing the purpose of the invention is as follows: a preparation method of a high-efficiency rust remover for medical instruments comprises the following steps:
adding the surfactant into deionized water, stirring and mixing until the surfactant is completely dissolved;
adding an acid mixture into the solution of 1), and stirring until the acid mixture is completely dissolved;
adding a rust removal auxiliary agent into the solution in the step 2), and stirring until the rust removal auxiliary agent is completely dissolved;
adding a chelating agent into the solution 3), and stirring to a constant volume to obtain the high-efficiency rust remover.
In the step 1), the surfactant comprises but is not limited to one or a mixture of more of high-carbon alcohol polyoxyethylene ether, modified grease ethoxylate, alkylolamide, sodium dodecyl benzene sulfonate, alkyl phosphate and fatty alcohol polyoxyethylene ether phosphate;
in the step 1), the using amount of the surfactant is preferably 1-15%;
in step 2), the acid agent includes but is not limited to one or a mixture of several of nitric acid, phosphoric acid, hydrochloric acid and sulfamic acid;
in the step 2), the amount of the acid agent to be used is preferably 1 to 30%, more preferably 1 to 15%;
in the step 3), the rust removal auxiliary agent comprises one or more of sodium phosphate, sodium gluconate and sodium borate;
in the step 3), the using amount of the rust remover additive is 1-10%;
in the step 4), the corrosion inhibitor comprises one or a mixture of more of EDTA4Na, triethanolamine oleate soap, HEDP, sodium tripolyphosphate, sodium pyrophosphate and a single-hetero benzene ring polyamino caproic acid antirust agent;
in step 4), the amount of corrosion inhibitor used is preferably 1 to 5%.
Detailed Description
The technical scheme of the invention is further detailed and completely explained by combining the embodiment, the comparative example and the application example.
Example 1
1) Weighing isomeric 13-carbon alcohol polyoxyethylene ether, sodium dodecyl benzene sulfonate and APGIC08 isomeric alcohol glucoside, mixing the isomeric 13-carbon alcohol polyoxyethylene ether, the sodium dodecyl benzene sulfonate and the APGIC08 isomeric alcohol glucoside according to the mass ratio of 3:3:4, adding 15% of the isomeric 13-carbon alcohol polyoxyethylene ether, the sodium dodecyl benzene sulfonate and the APGIC08 isomeric alcohol glucoside into deionized water, stirring and mixing until the isomeric 13-carbon alcohol polyoxyethylene ether, the sodium dodecyl benzene sulfonate and the APGIC08 isomeric alcohol glucoside are completely dissolved;
2) adding 5% nitric acid and 10% phosphoric acid into the solution of 1), and stirring until the nitric acid and the phosphoric acid are completely dissolved;
3) adding 5% sodium pyrophosphate into the solution in the step 2), and stirring until the sodium pyrophosphate is completely dissolved;
4) adding 2% of chelating agent triethanolamine phosphate, HEDP 1% and EDTA4Na 2% into the solution 3), stirring and fixing the volume to obtain the high-efficiency rust remover.
Example 2
1) Weighing dodecyl alkanolamide, dodecyl phosphate and isomeric tridecanol polyoxyethylene ether 1307, mixing the dodecyl alkanolamide, the dodecyl phosphate and the isomeric tridecanol polyoxyethylene ether at a mass ratio of 2:5:3, adding 10% of the mixture into deionized water, stirring and mixing until the mixture is completely dissolved;
2) adding 5% of hydrochloric acid, 5% of phosphoric acid and 3% of sulfuric acid into the solution in the step 1), mixing the hydrochloric acid, the phosphoric acid and the sulfuric acid according to the mass ratio of 3:4:3, adding the above components in total, and stirring until the components are completely dissolved;
3) adding 5% sodium borate into the solution in the step 2), and stirring until the sodium borate is completely dissolved;
4) adding 3 percent of chelating agent mono-heterocyclic benzene ring polyamino caproic acid, 2 percent of sodium pyrophosphate and EDTA4Na3 percent into the solution of 3), stirring and fixing the volume to obtain the high-efficiency rust remover.
Example 3
1) Weighing fatty alcohol polyoxyethylene ether phosphate, dodecyl phosphate and LF305 fatty alcohol EO-PO block polyether, mixing the fatty alcohol polyoxyethylene ether phosphate, the dodecyl phosphate and the LF305 fatty alcohol EO-PO block polyether according to the mass ratio of 4:3:2, adding 15% of the total amount into deionized water, stirring and mixing until the mixture is completely dissolved;
2) adding 5% of phosphoric acid, 6% of sulfamic acid and 2% of nitric acid into the solution of 1), and stirring until the phosphoric acid, the sulfamic acid and the nitric acid are completely dissolved;
3) adding 5% sodium gluconate into the solution in the step 2), and stirring until the sodium gluconate is completely dissolved;
4) adding 2% of chelating agent triethanolamine phosphate, 3% of triethanolamine oleate soap and 4Na 2% of EDTA into the solution in the step 3), stirring and metering volume to obtain the high-efficiency rust remover.
Example 4
1) Weighing sodium dodecyl benzene sulfonate, fatty alcohol polyoxyethylene ether phosphate and dodecyl phosphate, mixing the sodium dodecyl benzene sulfonate, the fatty alcohol polyoxyethylene ether phosphate and the dodecyl phosphate according to the mass ratio of 5:3:2, adding 12% of the mixture into deionized water, stirring and mixing until the mixture is completely dissolved;
2) adding sulfamic acid, phosphoric acid and citric acid into the solution 1) and mixing according to the mass ratio of 4:4:2, adding 15% in total, and stirring until the mixture is completely dissolved;
3) adding 3% sodium borate and 2% sodium pyrophosphate into the solution of 2), and stirring until the sodium borate and the sodium pyrophosphate are completely dissolved;
4) adding 2% of chelating agent triethanolamine phosphate, 2% of triethanolamine oleate soap and 1% of single-hetero-benzene-ring polyamino caproic acid into the solution in the step 3), stirring and fixing the volume to obtain the high-efficiency rust remover.
Finally, it should be pointed out here that: the above is only a part of the preferred embodiments of the present invention and should not be construed as limiting the scope of the present invention, and the insubstantial modifications and adaptations of the present invention by those skilled in the art based on the above description are intended to be covered by the present invention.

Claims (9)

1. A preparation method of a high-efficiency rust remover for medical instruments comprises the following steps:
1) adding the surfactant into deionized water, stirring and mixing until the surfactant is completely dissolved;
2) adding an acid mixture into the solution of 1), and stirring until the acid mixture is completely dissolved;
3) adding a rust removal auxiliary agent into the solution in the step 2), and stirring until the rust removal auxiliary agent is completely dissolved;
4) adding a chelating agent into the solution 3), and stirring to a constant volume to obtain the high-efficiency rust remover.
2. In the step 1), the surfactant includes, but is not limited to, one or a mixture of more of high alcohol polyoxyethylene ether, modified grease ethoxylate, alkylolamide, sodium dodecyl benzene sulfonate, alkyl phosphate and fatty alcohol polyoxyethylene ether phosphate.
3. In step 1), the amount of the surfactant used is preferably 1 to 15%.
4. In step 2), the acid agent includes but is not limited to one or a mixture of nitric acid, phosphoric acid, hydrochloric acid and sulfamic acid.
5. In step 2), the amount of the acid agent to be used is preferably 1 to 30%, more preferably 1 to 15%.
6. In the step 3), the rust removal auxiliary agent comprises one or more of sodium phosphate, sodium gluconate and sodium borate.
7. In the step 3), the usage amount of the rust remover additive is 1-10%.
8. In the step 4), the corrosion inhibitor comprises one or a mixture of more of EDTA4Na, triethanolamine oleate soap, HEDP, sodium tripolyphosphate, sodium pyrophosphate and a single hetero benzene ring polyamino caproic acid antirust agent.
9. In step 4), the amount of corrosion inhibitor used is preferably 1 to 5%.
CN202210177540.1A 2022-02-25 2022-02-25 Efficient rust remover for medical instruments and preparation method thereof Pending CN114561646A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210177540.1A CN114561646A (en) 2022-02-25 2022-02-25 Efficient rust remover for medical instruments and preparation method thereof

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Application Number Priority Date Filing Date Title
CN202210177540.1A CN114561646A (en) 2022-02-25 2022-02-25 Efficient rust remover for medical instruments and preparation method thereof

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Publication Number Publication Date
CN114561646A true CN114561646A (en) 2022-05-31

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115613029A (en) * 2022-09-08 2023-01-17 河北光束激光科技有限公司 Oil drill pipe marking method based on binary coding

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106757095A (en) * 2016-12-20 2017-05-31 粟飞 A kind of neutral rust remover
CN109112556A (en) * 2018-08-22 2019-01-01 佛山麟博科技新材料有限公司 Neutral rust remover and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106757095A (en) * 2016-12-20 2017-05-31 粟飞 A kind of neutral rust remover
CN109112556A (en) * 2018-08-22 2019-01-01 佛山麟博科技新材料有限公司 Neutral rust remover and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115613029A (en) * 2022-09-08 2023-01-17 河北光束激光科技有限公司 Oil drill pipe marking method based on binary coding

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