CN114480922A - Ultra-light aluminum-lithium alloy and preparation method and application thereof - Google Patents

Ultra-light aluminum-lithium alloy and preparation method and application thereof Download PDF

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CN114480922A
CN114480922A CN202210086950.5A CN202210086950A CN114480922A CN 114480922 A CN114480922 A CN 114480922A CN 202210086950 A CN202210086950 A CN 202210086950A CN 114480922 A CN114480922 A CN 114480922A
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lithium alloy
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lithium
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CN114480922B (en
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廖荣跃
肖阳
刘志鹏
马凯杰
解海涛
刘金学
刘振杰
祁登科
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Zhengzhou Qingyan Alloy Technology Co ltd
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/047Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent

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Abstract

The invention belongs to the technical field of aluminum lithium alloys, and particularly relates to an ultra-light aluminum lithium alloy and a preparation method and application thereof. The invention solves the problems of oxidation burning loss and layered segregation caused by high Li and Mg contents by composite microalloying and adopting the processes of vacuum casting, deformation processing, heat treatment and the like, and obtains the ultralight aluminum-lithium alloy with good strong plasticity matching. The ultra-light aluminum-lithium alloy comprises the following components in percentage by mass: lithium: 3.0-8.0%, magnesium: 3.0-9.0%, beryllium: 0.01-0.03%, antimony: 0.01-0.30%, manganese: 0.10 to 0.80%, titanium: 0.02-0.20%, scandium: 0.10 to 0.30%, zirconium: 0.05-0.30%, the restIs aluminum. The ultra-light aluminum-lithium alloy obtained by the invention has excellent comprehensive performance and can realize the density of 2.18g/cm3Tensile strength of 340MPa, yield strength of 308MPa, and elongation after fracture of 10.4%. The ultra-light aluminum-lithium alloy has good strong plasticity, can be used as an advanced lightweight structural material to replace the conventional aluminum alloy member on an aircraft.

Description

Ultra-light aluminum-lithium alloy and preparation method and application thereof
Technical Field
The invention belongs to the technical field of aluminum lithium alloy processing, and particularly relates to an ultra-light aluminum lithium alloy and a preparation method and application thereof.
Background
The ultra-light aluminum-lithium alloy is used as a light metal structure material, the density is reduced by 3% when 1% of lithium is added into the alloy, if the ultra-light aluminum-lithium alloy is adopted to replace the conventional aluminum alloy, the structural mass can be reduced by 15% -30%, the elastic modulus can be improved by 9%, and the rigidity can be improved by 15% -20%, so that the ultra-light aluminum-lithium alloy has great significance for realizing light weight of aerospace equipment and has wide application prospects.
The main research and development idea of the ultra-light aluminum-lithium alloy is to add high-content Li (0.53 g/cm) into the alloy3) And Mg (1.74 g/cm)3) However, Li and Mg are light, easy to oxidize and inflammable in the smelting process, and once the Li content exceeds 3%, the alloy produced by the traditional casting metallurgy method has serious segregation phenomenon.
Although the problems of oxidation and segregation can be effectively solved by adopting a vacuum electromagnetic simulation microgravity smelting technology by Gunn macro and the like (see the literature, Gunn macro, Dadaan, Haoweixin, Zhang balance, rock. microgravity electromagnetic simulation for preparing the high-lithium-content aluminum-lithium alloy [ J ]. special casting and non-ferrous alloy, 2003(02):11-13+ 3.), the prepared alloy only contains two elements of Al and Li, has poor plasticity, is limited by cost and ingot casting size, is only suitable for laboratory research and cannot be industrially produced.
And when the content of Li and Mg in the aluminum lithium alloy is higher, large-size insoluble brittle phases such as Al can be precipitated on grain boundaries6Cu(LiMg)3And beta phase (Mg)5Al8Or Mg2Al3) And the like, are harmful to the material properties, and particularly have the problem of poor plasticity. For example, chinese patent publication No. CN 112853172 a discloses an ultra-low profileAccording to the density aluminum lithium alloy and the preparation method thereof, the Mg element with a high proportion (9-12.5%) is added into the alloy to improve the alloy performance, but the crystal boundary has more Mg-rich brittle phases, so that the plasticity is poor, and the elongation after fracture is only about 6%.
Therefore, it is urgently needed to develop a new ultra-light aluminum-lithium alloy and a preparation process suitable for industrial production to solve the problem of layering segregation of alloy components and improve the plasticity of the alloy.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide the ultralight aluminum lithium alloy, which solves the problems of oxidation burning loss and layered segregation caused by high Li and Mg contents by composite microalloying and adopting the processes of vacuum casting, deformation processing, heat treatment and the like, and obtains the ultralight aluminum lithium alloy with good strong plasticity matching.
The invention also provides a preparation method of the ultralight aluminum lithium alloy.
Based on the purpose, the invention adopts the following technical scheme:
an ultra-light aluminum-lithium alloy comprises the following components in percentage by mass: lithium: 3.0-8.0%, magnesium: 3.0-9.0%, beryllium: 0.01-0.03%, antimony: 0.01-0.30%, manganese: 0.10 to 0.80%, titanium: 0.02-0.20%, scandium: 0.10 to 0.30%, zirconium: 0.05-0.30% and the balance of aluminum.
The preparation method of the ultra-light aluminum-lithium alloy comprises the following steps:
(1) proportioning according to the mass percentage of each component in the alloy; smelting the prepared raw materials in an argon atmosphere at the temperature of 720-860 ℃ to obtain molten metal;
(2) refining the molten metal obtained in the step (1) for 10-20 min at 700-770 ℃ under an argon atmosphere, standing for 10-20 min at 710-770 ℃ to obtain a casting liquid, and casting and forming the casting liquid to obtain a cast ingot; carrying out homogenization annealing treatment on the obtained cast ingot in an argon atmosphere to obtain a homogenized cast ingot;
(3) removing a surface oxide layer from the ingot subjected to homogenization treatment in the step (2), preheating to 400-470 ℃, forging and cogging, and obtaining a forging with the diameter of 200-380 mm by adopting a small deformation multi-pass forging process;
(4) removing the surface oxide layer of the forged piece obtained in the step (3), then loading the forged piece into an extruder, and extruding at the temperature of 400-470 ℃ to obtain an extruded plate blank;
(5) and (4) carrying out hot rolling on the plate blank obtained in the step (4) at the temperature of 400-480 ℃, and obtaining a finished plate by the single-pass reduction of 5-10%.
Specifically, the smelting process in the step (1) comprises the following steps: the method comprises the steps of loading the prepared raw materials into a vacuum induction melting furnace, vacuumizing until the vacuum degree in the furnace is 0.1-10 Pa, introducing argon until the pressure in the furnace reaches 200-350 Pa, heating to 720-860 ℃, preserving the temperature to obtain molten metal, and performing electromagnetic stirring in the melting process.
Specifically, mechanical stirring is carried out in the refining process in the step (2), and the homogenization annealing treatment conditions in the step (2) are as follows: preserving heat for 12-60 h at 400-490 ℃, and then cooling to room temperature in air.
Specifically, the casting molding process in the step (2) is to cast the casting liquid into a water-cooled mold for cooling and solidification, wherein the cooling rate is 200-300 ℃/s.
Specifically, in the step (3), 5-8 times of multi-pass forging process are carried out, and the tempering is carried out after forging at the temperature of 400-470 ℃ each time.
Specifically, in the step (4), the extrusion ratio of the extrusion forming process is 5-20, and the extrusion speed is not more than 1.5 mm/s.
Further, the preparation method further comprises the step of carrying out post-treatment on the plate blank obtained in the step (5), wherein the post-treatment comprises the following steps: and (5) carrying out solution treatment on the plate blank obtained in the step (5).
Specifically, the solution treatment process comprises the following steps: preserving the heat for 60-180 min at the temperature of 400-480 ℃, and then quenching with water.
Preferably, the temperature of the cooling water for water quenching is 40-55 ℃.
The invention further provides an application of the ultralight aluminum-lithium alloy in preparing an aircraft case shell.
Compared with the prior art, the invention has the beneficial effects that:
1. the invention designs an ultra-light aluminum-lithium alloy with high Li and Mg contents by optimizing alloy components, simultaneously adds a proper amount of trace elements and alterants such as Al-5Ti-1B, Be, Sb and the like, and introduces Al which is coherent with a matrix3Sc、Al3(Scx,Zr1-x)、Al3Zr and other heterogeneous nucleation points, and a water-cooled copper mold is utilized to improve the solidification speed and refine the as-cast structure; the coarse and large phases are crushed through multi-pass forging, multiple intermediate tempering is utilized to promote the crushed phases to be fully dissolved back, then the deformation is continuously increased by adopting extrusion and rolling, the grain structure is refined, and the strong plasticity of the alloy is improved.
2. Mn element can form a large amount of Al dispersed in the matrix6Mn pins the subgrain boundary, inhibits the occurrence of recovery and dynamic recrystallization, retains the subgrain structure with high dislocation density, and plays a role in dispersion strengthening; meanwhile, the solid solubility of Sc is reduced due to the solid solution of Mn element into alpha (Al), so that more Al is precipitated from the alloy3Sc、Al3(Scx,Zr1-x)、Al3The fine-grained strengthening phases such as Zr inhibit the recrystallization of the alloy in the deformation and heat treatment processes, improve the recrystallization temperature of the alloy and further improve the strong plasticity of the alloy.
3. The invention adopts vacuum melting and casting technology to effectively reduce oxidation burning loss, solves the problem of layered segregation by electromagnetic stirring and mechanical stirring, prepares alloy ingot blanks with high purity and improves the natural defect of poor alloy plasticity.
4. The invention adopts a forging cogging mode to break the grain structure and the coarse phase of the original cast ingot, promotes the dissolution of the broken phase by tempering for many times, and then solves the problems of poor alloy plasticity and large deformation resistance by high-temperature slow extrusion, further refines the grains and effectively improves the alloy plasticity.
5. According to the invention, the solid solution state is selected as the final finished product state, the ultralight aluminum-lithium alloy material with good strong plasticity matching is obtained, the product with excellent comprehensive performance is finally obtained, and the density can be realized at 2.18-2.40g/cm3Tensile strength of 340-308-440MPa and elongation after fracture of 7.2-10.4 percent. The ultra-light aluminum-lithium alloy has good strength and plasticity, can be used as an advanced lightweight structural material to replace the conventional aluminum alloy component on an aircraft, and achieves the weight reduction effect of 25%.
Drawings
FIG. 1 is a metallographic image of an ingot obtained in step (2) of example 1 of the present invention.
Detailed Description
In order to make the technical purpose, technical scheme and beneficial effects of the invention clearer, the technical scheme of the invention is further described with reference to specific examples, which are intended to explain the invention and are not to be construed as limiting the invention, and the specific techniques or conditions are not indicated in the examples, which are performed according to the techniques or conditions described in the literature in the field or according to the product specification, and the raw materials used in the following examples are all common commercial products.
The prepared raw materials comprise high-purity aluminum ingots (not less than 99.996 percent), pure lithium ingots (not less than 99.9 percent), pure magnesium ingots (not less than 99.95 percent) and pure Sb (not less than 99.7 percent), and the intermediate alloy adopts AlMn10, AlTi10, AlBe3, AlSc2 and AlZr 10.
Example 1
An ultra-light aluminum-lithium alloy comprises the following components in percentage by mass: li: 5%, Mg: 4.5%, Mn: 0.6%, Ti: 0.1%, Sb: 0.05%, Be: 0.01%, Sc: 0.2 percent and the balance of Al.
The preparation method of the ultralight aluminum-lithium alloy comprises the following specific steps:
(1) proportioning according to the mass percentage of each component in the alloy; placing the prepared raw materials into a vacuum induction melting furnace, preheating to 100 ℃, vacuumizing until the vacuum degree reaches 10Pa, introducing high-purity argon until the pressure in the furnace reaches 300Pa, heating to 730 ℃, and carrying out electromagnetic stirring melting under the argon atmosphere to obtain molten metal;
(2) refining the molten metal obtained in the step (1) for 15min in an argon atmosphere at 730 ℃, and keeping mechanical stirring during refining; standing at 730 ℃ for 10min, casting the molten metal into a cylindrical water-cooled copper mould with the diameter of 350mm, cooling and solidifying at the cooling rate of 300 ℃/s, and cooling to room temperature to obtain a cast ingot;
(3) putting the ingot obtained in the step (2) into a vacuum heat treatment furnace, vacuumizing, introducing argon, and carrying out homogenization annealing to obtain a homogenized ingot; wherein the homogenizing annealing conditions are as follows: firstly, preserving heat for 40h at 400 ℃, and then cooling to room temperature in air;
(4) turning the cast ingot subjected to homogenization treatment in the step (3) to remove a surface oxide layer, preheating to 420 ℃, forging and cogging, and forging with small deformation by adopting a three-pier three-drawing process to obtain a forging piece with the diameter of 350 mm;
(5) after removing the surface oxide layer of the forged piece obtained in the step (4), preheating to 420 ℃, and then loading the forged piece into an extruder for extrusion to obtain an extruded plate blank, wherein the extrusion ratio is 10, and the extrusion speed is 1.5mm/s, so that a plate blank with the thickness of 60mm is obtained;
(6) carrying out hot rolling on the plate blank obtained in the step (5) at the temperature of 420 ℃, wherein the single-pass reduction is 10%, and finally obtaining a plate with the thickness of 5 mm;
(7) carrying out solution treatment on the plate obtained in the step (6), wherein the solution treatment process comprises the following steps: keeping the temperature at 430 ℃ for 60min, and then quenching with water at 45 ℃ to obtain the product.
The gold phase diagram of the ingot obtained in step (2) of example 1 is shown in fig. 1, and it can be seen from fig. 1 that the plate crystal grains are equiaxed, fine and uniform, and there are no large eutectic phases of metals near the grain boundaries.
Example 2
An ultra-light aluminum-lithium alloy comprises the following components in percentage by mass: li: 4.5%, Mg: 4%, Mn: 0.6%, Ti: 0.1%, Sb: 0.05%, Be: 0.01%, Sc: 0.2%, Zr: 0.1 percent and the balance of Al.
The preparation method of the ultralight aluminum-lithium alloy comprises the following specific steps:
(1) proportioning according to the mass percentage of each component in the alloy; placing the prepared raw materials into a vacuum induction melting furnace, preheating to 100 ℃, vacuumizing until the vacuum degree reaches 10Pa, introducing high-purity argon until the pressure in the furnace reaches 300Pa, heating to 750 ℃, and carrying out electromagnetic stirring melting under the argon atmosphere to obtain molten metal;
(2) refining the molten metal obtained in the step (1) for 15min in an argon atmosphere at 750 ℃, and keeping mechanical stirring during refining; standing at 750 ℃ for 10min, casting the molten metal into a cylindrical water-cooled copper mould with the diameter of 350mm, cooling and solidifying at the cooling rate of 300 ℃/s, and cooling to room temperature to obtain a cast ingot;
(3) putting the ingot obtained in the step (2) into a vacuum heat treatment furnace, vacuumizing, introducing argon, and carrying out homogenization annealing to obtain a homogenized ingot; wherein the homogenizing annealing conditions are as follows: firstly, preserving heat at 420 ℃ for 24 hours, and then cooling to room temperature in the air;
(4) turning the cast ingot subjected to homogenization treatment in the step (3) to remove a surface oxide layer, preheating to 430 ℃ for forging cogging, and forging with small deformation by adopting a three-pier three-drawing process to obtain a forging piece with the diameter of 350 mm;
(5) after removing the surface oxide layer of the forged piece obtained in the step (4), preheating to 430 ℃, and then loading the forged piece into an extruder for extrusion to obtain an extruded plate blank, wherein the extrusion ratio is 10, and the extrusion speed is 1.5mm/s, so that a plate blank with the thickness of 60mm is obtained;
(6) carrying out hot rolling on the plate blank obtained in the step (5) at the temperature of 430 ℃, wherein the single-pass reduction is 10%, and finally obtaining a plate with the thickness of 5 mm;
(7) carrying out solution treatment on the plate obtained in the step (6), wherein the solution treatment process comprises the following steps: keeping the temperature at 440 deg.C for 60min, and water quenching at 45 deg.C.
Example 3
An ultra-light aluminum-lithium alloy comprises the following components in percentage by mass: li: 3.2%, Mg: 4%, Mn: 0.6%, Ti: 0.1%, Sb: 0.05%, Be: 0.01%, Sc: 0.2%, Zr: 0.1 percent and the balance of Al.
The preparation method of the ultralight aluminum-lithium alloy comprises the following specific steps:
(1) proportioning according to the mass percentage of each component in the alloy; placing the prepared raw materials into a vacuum induction melting furnace, preheating to 100 ℃, vacuumizing until the vacuum degree reaches 10Pa, introducing high-purity argon until the pressure in the furnace reaches 300Pa, heating to 740 ℃, and carrying out electromagnetic stirring melting under the argon atmosphere to obtain molten metal;
(2) refining the molten metal obtained in the step (1) for 15min in an argon atmosphere at 770 ℃, and keeping mechanical stirring during refining; standing at 770 ℃ for 10min, casting the molten metal into a cylindrical water-cooled copper mould with the diameter of 350mm, cooling and solidifying at the cooling rate of 300 ℃/s, and cooling to room temperature to obtain a cast ingot;
(3) putting the ingot obtained in the step (2) into a vacuum heat treatment furnace, vacuumizing, introducing argon, and carrying out homogenization annealing to obtain a homogenized ingot; wherein the homogenizing annealing conditions are as follows: preserving heat for 24 hours at 430 ℃, and then cooling to room temperature in air;
(4) turning the homogenized ingot obtained in the step (3) to remove a surface oxide layer, preheating to 450 ℃ for forging cogging, and forging with small deformation by adopting a three-pier three-drawing process to obtain a forging piece with the diameter of 350 mm;
(5) after removing the surface oxide layer of the forged piece obtained in the step (4), preheating to 450 ℃, and then loading the forged piece into an extruder for extrusion to obtain an extruded plate blank, wherein the extrusion ratio is 10, and the extrusion speed is 1.5mm/s, so that a plate blank with the thickness of 60mm is obtained;
(6) carrying out hot rolling on the plate blank obtained in the step (5) at the temperature of 450 ℃, wherein the single-pass reduction is 10%, and finally obtaining a plate with the thickness of 5 mm;
(7) carrying out solution treatment on the plate obtained in the step (6), wherein the solution treatment process comprises the following steps: keeping the temperature at 460 deg.C for 60min, and water quenching at 45 deg.C.
Example 4
An ultra-light aluminum-lithium alloy comprises the following components in percentage by mass: li: 2.1%, Mg: 8%, Mn: 0.6%, Ti: 0.1%, Sb: 0.05%, Be: 0.01%, Sc: 0.2%, Zr: 0.1 percent and the balance of Al.
The preparation method of the ultralight aluminum-lithium alloy comprises the following specific steps:
(1) proportioning according to the mass percentage of each component in the alloy; placing the prepared raw materials into a vacuum induction melting furnace, preheating to 100 ℃, vacuumizing until the vacuum degree reaches 10Pa, introducing high-purity argon until the pressure in the furnace reaches 300Pa, heating to 750 ℃, and carrying out electromagnetic stirring melting under the argon atmosphere to obtain molten metal;
(2) refining the molten metal obtained in the step (1) for 15min in an argon atmosphere at 770 ℃, and keeping mechanical stirring during refining; standing at 770 ℃ for 10min, casting the molten metal into a cylindrical water-cooled copper mould with the diameter of 350mm, cooling and solidifying at the cooling rate of 300 ℃/s, and cooling to room temperature to obtain a cast ingot;
(3) putting the ingot obtained in the step (2) into a vacuum heat treatment furnace, vacuumizing, introducing argon, and carrying out homogenization annealing to obtain a homogenized ingot; wherein the homogenizing annealing conditions are as follows: firstly, keeping the temperature at 440 ℃ for 20h, and then cooling the mixture to room temperature in the air;
(4) turning the homogenized ingot obtained in the step (3) to remove a surface oxide layer, preheating to 460 ℃ for forging cogging, and forging with small deformation by adopting a three-pier three-drawing process to obtain a forging with the diameter of 350 mm;
(5) after removing the surface oxide layer of the forged piece obtained in the step (4), preheating to 460 ℃, and then loading the forged piece into an extruder for extrusion to obtain an extruded plate blank, wherein the extrusion ratio is 10, and the extrusion speed is 1.5mm/s, so that a plate blank with the thickness of 60mm is obtained;
(6) carrying out hot rolling on the plate blank obtained in the step (5) at the temperature of 460 ℃, wherein the single-pass reduction is 10%, and finally obtaining a plate with the thickness of 5 mm;
(7) carrying out solution treatment on the plate obtained in the step (6), wherein the solution treatment process comprises the following steps: keeping the temperature at 480 deg.C for 60min, and water quenching at 45 deg.C.
Comparative example 1
The 1420 aluminum lithium alloy is taken as a comparison group, and compared with the ultralight aluminum lithium alloy, specifically, the 1420 aluminum lithium alloy consists of the following components in percentage by mass: li: 2.1%, Mg: 5.3%, Zr: 0.1 percent and the balance of Al. 1420 aluminum lithium alloy was prepared in the same manner as in example 4.
Next, mechanical properties of the samples (the ultra-light aluminum lithium alloy obtained in examples 1 to 4 and the 1420 aluminum lithium alloy of comparative example 1) were measured by using a SUN10 electronic universal tester, and 3 sets of parallel samples were taken and averaged for each state. The results of the performance tests are shown in table 1.
TABLE 1 Performance test results for the low density ultra-light aluminum lithium alloys described in examples 1-4 and comparative example 1
Sample numbering Tensile strength (MPa) Yield strength (MPa) Elongation (%) Density (g/cm)3)
Example 1 340 308 10.4 2.18
Example 2 385 362 8.1 2.25
Example 3 462 440 7.5 2.35
Example 4 428 400 7.2 2.40
Comparative example 1 460 290 10.1 2.47
As can be seen from Table 1, the minimum density of the ultra-light aluminum-lithium alloy prepared by the invention is only 2.18g/cm under the condition of the same mechanical property3Compared with conventional aluminum alloys such as 5083, 7050 and the like (the density is 2.66-2.83 g/cm)3In between) can reduce weight by more than 25%.
Application example 1
The housing of the machine case is a common structural form applied in the aerospace field, is usually machined from a whole metal, and requires good electromagnetic shielding property and shock absorption property, in the prior art, the material of the housing of the machine case is mostly 2A12 aluminum alloy, but in order to pursue lightweight design, a light metal material with high elastic modulus is urgently needed to replace the light metal material.
The invention prepares an ultra-light aluminum-lithium alloy, and the ultra-light aluminum-lithium alloy of embodiment 1 of the invention is applied to the case shell, so that the structural strength of the case can reach more than 300MPa, and the plasticity can reach 10%. Because of the high elastic modulus, can carry out the thin-walled design, in addition the density is low, and the machine case casing subtracts heavy proportion and reaches up to 25%, can realize completely that the replacement of the machine case casing with 2A12 aluminum alloy. The ultra-light aluminum-lithium alloy has wide application prospect in the field of machine case shells.
While specific embodiments of the present invention have been described above, it should be understood that the present invention is not limited to the specific embodiments described above. Various changes or modifications may be made by those skilled in the art within the scope of the claims without departing from the spirit of the invention.

Claims (8)

1. The ultra-light aluminum-lithium alloy is characterized by comprising the following components in percentage by mass: lithium: 3.0-8.0%, magnesium: 3.0-9.0%, beryllium: 0.01-0.03%, antimony: 0.01-0.30%, manganese: 0.10 to 0.80%, titanium: 0.02-0.20%, scandium: 0.10 to 0.30%, zirconium: 0.05-0.30% and the balance of aluminum.
2. The method for preparing the ultra-light aluminum lithium alloy of claim 1, which comprises the following steps:
(1) proportioning according to the mass percentage of each component in the alloy; smelting the prepared raw materials in an argon atmosphere at the temperature of 720-860 ℃ to obtain molten metal;
(2) refining the molten metal obtained in the step (1) for 10-20 min at 700-770 ℃ under an argon atmosphere, standing for 10-20 min at 710-770 ℃ to obtain a casting liquid, and casting and forming the casting liquid to obtain a cast ingot; carrying out homogenization annealing treatment on the obtained cast ingot in an argon atmosphere to obtain a homogenized cast ingot;
(3) removing a surface oxide layer from the ingot subjected to homogenization treatment in the step (2), preheating to 400-470 ℃, forging and cogging, and obtaining a forging with the diameter of 200-380 mm by adopting a small deformation multi-pass forging process;
(4) removing the surface oxide layer of the forged piece obtained in the step (3), then loading the forged piece into an extruder, and extruding at the temperature of 400-470 ℃ to obtain an extruded plate blank;
(5) and (4) carrying out hot rolling on the plate blank obtained in the step (4) at the temperature of 400-480 ℃, and obtaining a finished plate by the single-pass reduction of 5-10%.
3. The production method according to claim 2, wherein the melting process in the step (1) is: the method comprises the steps of loading the prepared raw materials into a vacuum induction melting furnace, vacuumizing until the vacuum degree in the furnace is 0.1-10 Pa, introducing argon until the pressure in the furnace reaches 200-350 Pa, heating to 720-860 ℃, and preserving heat to obtain molten metal.
4. The manufacturing method according to claim 2, wherein the homogenizing annealing conditions in the step (2) are: preserving heat for 12-60 h at 400-490 ℃, and then cooling to room temperature in air.
5. The production method according to claim 2, wherein in the step (4), the extrusion ratio of the extrusion molding process is 5 to 20, and the extrusion speed is not more than 1.5 mm/s.
6. The manufacturing method according to claim 2, further comprising subjecting the slab obtained in step (5) to solution treatment; the solid solution treatment process comprises the following steps: preserving the heat for 60-180 min at the temperature of 400-480 ℃, and then quenching with water.
7. The preparation method according to claim 6, wherein the cooling water temperature of the water quenching is 40-55 ℃.
8. Use of the ultra-light aluminum lithium alloy of claim 1 for the manufacture of an aircraft cabin housing.
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