CN114479930B - 一种润滑油基础油生产方法和生产系统 - Google Patents
一种润滑油基础油生产方法和生产系统 Download PDFInfo
- Publication number
- CN114479930B CN114479930B CN202011166203.XA CN202011166203A CN114479930B CN 114479930 B CN114479930 B CN 114479930B CN 202011166203 A CN202011166203 A CN 202011166203A CN 114479930 B CN114479930 B CN 114479930B
- Authority
- CN
- China
- Prior art keywords
- reaction zone
- hydrogenation reaction
- hydrogenation
- base oil
- base stock
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002199 base oil Substances 0.000 title claims abstract description 93
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 58
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 55
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 121
- 238000006243 chemical reaction Methods 0.000 claims abstract description 40
- 239000000463 material Substances 0.000 claims abstract description 34
- 239000003054 catalyst Substances 0.000 claims description 55
- 238000000926 separation method Methods 0.000 claims description 54
- 239000002808 molecular sieve Substances 0.000 claims description 40
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 40
- 239000007788 liquid Substances 0.000 claims description 34
- 239000007791 liquid phase Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 29
- 229910052751 metal Inorganic materials 0.000 claims description 23
- 239000002184 metal Substances 0.000 claims description 23
- 238000004821 distillation Methods 0.000 claims description 21
- 239000007789 gas Substances 0.000 claims description 21
- 239000001257 hydrogen Substances 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 18
- 230000001050 lubricating effect Effects 0.000 claims description 17
- 238000005194 fractionation Methods 0.000 claims description 15
- 239000012071 phase Substances 0.000 claims description 14
- 239000011148 porous material Substances 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 14
- 239000003921 oil Substances 0.000 claims description 13
- 239000000314 lubricant Substances 0.000 claims description 12
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 7
- 239000012188 paraffin wax Substances 0.000 claims description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- 239000001993 wax Substances 0.000 claims description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052810 boron oxide Inorganic materials 0.000 claims description 4
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 4
- 239000004200 microcrystalline wax Substances 0.000 claims description 4
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 4
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 229910000510 noble metal Inorganic materials 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 239000012808 vapor phase Substances 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- -1 bright stock Substances 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- 239000000047 product Substances 0.000 abstract description 16
- 238000006317 isomerization reaction Methods 0.000 abstract description 15
- 238000006722 reduction reaction Methods 0.000 abstract description 8
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 239000012263 liquid product Substances 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 6
- 230000000881 depressing effect Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241001646834 Mesona Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/304—Pour point, cloud point, cold flow properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4006—Temperature
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4012—Pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/10—Lubricating oil
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Abstract
Description
原料油 | DAO | 石蜡 | 微晶蜡 | 费托蜡 |
<![CDATA[密度,kg/m<sup>3</sup>]]> | 925 | 820 | 845 | 802 |
馏程范围,℃ | 410~620 | 370~480 | 440~600 | 320~650 |
<![CDATA[粘度(100℃),mm<sup>2</sup>/s ]]> | 25.40 | 3.443 | 7.20 | 8.96 |
凝点,℃ | 45 | 56.4(熔点) | 75. 5(滴熔点) | 98(滴熔点) |
硫,μg/g | 30.5 | 14.0 | 33.8 | 1.0 |
氮,μg/g | 2.5 | 4.0 | 6.8 | 1.0 |
含油量,wt% | 24.8 | 0.36 | 1.50 | 5.52 |
催化剂 | 异构脱蜡催化剂 | 加氢改质催化剂 |
活性金属 | Pt | Pt |
物理性质 | ||
外形尺寸(φ×L)/mm | (1.4-1.6)×(3~8) | (1.5-1.7)×(3~8) |
<![CDATA[孔容,mL.g<sup>-1</sup>]]> | 0.28-0.38 | ≥0.28 |
<![CDATA[比表面积,m<sup>2</sup>.g<sup>-1</sup>]]> | 180-280 | ≥170 |
<![CDATA[堆积密度,g.cm<sup>-3</sup>]]> | 0.64-0.74 | 0.90~1.0 |
<![CDATA[压碎强度,N.cm<sup>-1</sup>]]> | 80-150 | >180 |
形状 | 四叶草 | 圆柱条 |
Claims (27)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011166203.XA CN114479930B (zh) | 2020-10-27 | 2020-10-27 | 一种润滑油基础油生产方法和生产系统 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011166203.XA CN114479930B (zh) | 2020-10-27 | 2020-10-27 | 一种润滑油基础油生产方法和生产系统 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN114479930A CN114479930A (zh) | 2022-05-13 |
CN114479930B true CN114479930B (zh) | 2023-05-05 |
Family
ID=81471362
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202011166203.XA Active CN114479930B (zh) | 2020-10-27 | 2020-10-27 | 一种润滑油基础油生产方法和生产系统 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN114479930B (zh) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103773466A (zh) * | 2012-10-24 | 2014-05-07 | 中国石油化工股份有限公司 | 加氢裂化-异构脱蜡组合生产润滑油基础油方法 |
CN111690434A (zh) * | 2019-03-15 | 2020-09-22 | 国家能源投资集团有限责任公司 | 由费托蜡制备润滑油基础油的方法及润滑油基础油 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7132042B2 (en) * | 2002-10-08 | 2006-11-07 | Exxonmobil Research And Engineering Company | Production of fuels and lube oils from fischer-tropsch wax |
-
2020
- 2020-10-27 CN CN202011166203.XA patent/CN114479930B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103773466A (zh) * | 2012-10-24 | 2014-05-07 | 中国石油化工股份有限公司 | 加氢裂化-异构脱蜡组合生产润滑油基础油方法 |
CN111690434A (zh) * | 2019-03-15 | 2020-09-22 | 国家能源投资集团有限责任公司 | 由费托蜡制备润滑油基础油的方法及润滑油基础油 |
Also Published As
Publication number | Publication date |
---|---|
CN114479930A (zh) | 2022-05-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4542902B2 (ja) | フィッシャー−トロプシュ・ワックスからの燃料および潤滑油の製造 | |
JP4384815B2 (ja) | フィッシャー−トロプシュワックスの水素異性化油をPt/H−モルデナイトにより脱ロウして製造されるイソパラフィン基油 | |
CN100384965C (zh) | 制备费-托产品的方法 | |
CA2897970A1 (en) | Production of lubricant base oils from dilute ethylene feeds | |
JP2003505576A (ja) | 潤滑基油を製造する方法 | |
ZA200600299B (en) | Fuels and lubricants using layered bed catalysts in hydrotreating waxy feeds, including Fischer-Tropsch wax, plus solvent dewaxing | |
EA036182B1 (ru) | Способ и установка для гидропереработки с использованием двух колонн фракционирования продуктов | |
EP1720961A1 (en) | Process to continuously prepare two or more base oil grades and middle distillates | |
EP2970793A1 (en) | Production of base oils from petrolatum | |
EP1789516B1 (en) | Production of extra-heavy lube oils from fischer-tropsch wax | |
CN114479930B (zh) | 一种润滑油基础油生产方法和生产系统 | |
CN114479931B (zh) | 一种费托蜡生产润滑油基础油的方法和系统 | |
JP5730103B2 (ja) | 灯油基材の製造方法及び灯油基材 | |
CN112745940B (zh) | 一种低浊点润滑油基础油的生产方法 | |
AU778654B2 (en) | Quenching dewaxing reactor with heavy dewaxate recycle | |
US11041129B2 (en) | Processes for producing a fuel range hydrocarbon and a lubricant base oil | |
AU604798B2 (en) | Process for the manufacture of kerosene and/or gas oils | |
EP3040404A1 (en) | Process for preparing naphtha and middle distillate fractions | |
ZA200509230B (en) | Process for upgrading fischer-tropsch products using dewaxing and hydrofinishing |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20231127 Address after: 100728 No. 22 North Main Street, Chaoyang District, Beijing, Chaoyangmen Patentee after: CHINA PETROLEUM & CHEMICAL Corp. Patentee after: Sinopec (Dalian) Petrochemical Research Institute Co.,Ltd. Address before: 100728 No. 22 North Main Street, Chaoyang District, Beijing, Chaoyangmen Patentee before: CHINA PETROLEUM & CHEMICAL Corp. Patentee before: DALIAN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC Corp. |
|
TR01 | Transfer of patent right |