CN114434923A - 一种环保阻燃型橡塑复合棚被 - Google Patents

一种环保阻燃型橡塑复合棚被 Download PDF

Info

Publication number
CN114434923A
CN114434923A CN202210234226.2A CN202210234226A CN114434923A CN 114434923 A CN114434923 A CN 114434923A CN 202210234226 A CN202210234226 A CN 202210234226A CN 114434923 A CN114434923 A CN 114434923A
Authority
CN
China
Prior art keywords
parts
layer
polytetrafluoroethylene
aging
plastic composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210234226.2A
Other languages
English (en)
Inventor
高景岐
高景升
高伟民
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhou Energy Conservation Technology Group Co ltd
Original Assignee
Shenzhou Energy Conservation Technology Group Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhou Energy Conservation Technology Group Co ltd filed Critical Shenzhou Energy Conservation Technology Group Co ltd
Priority to CN202210234226.2A priority Critical patent/CN114434923A/zh
Publication of CN114434923A publication Critical patent/CN114434923A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/14—Greenhouses
    • A01G9/1438—Covering materials therefor; Materials for protective coverings used for soil and plants, e.g. films, canopies, tunnels or cloches
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/10—Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/14—Layered products comprising a layer of natural or synthetic rubber comprising synthetic rubber copolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0023—Use of organic additives containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066—Use of inorganic compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0095—Mixtures of at least two compounding ingredients belonging to different one-dot groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/552—Fatigue strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/712—Weather resistant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2410/00—Agriculture-related articles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2309/02—Copolymers with acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2427/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C08J2491/06—Waxes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Environmental Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明涉及棚被技术领域，提出了一种环保阻燃型橡塑复合棚被，所述复合棚被包括由上至下依次设置的聚四氟乙烯抗老化层、中间保温层和防火硅纤维贴面层；聚四氟乙烯抗老化层包括以下重量份的组分：聚四氟乙烯60‑100份，氟碳表面活性剂4‑7份，三异硬脂酰基钛酸异丙酯1‑1.5份，多孔碳酸钙13‑18份；中间保温层包括以下重量份的组分：丁腈橡胶15‑20份，聚氯乙烯树脂3‑5份，乙烯‑醋酸乙烯酯共聚物3‑5份，滑石粉20‑30份，氯化石蜡油13‑15份，环氧豆油1‑2份，防护蜡2‑4份，炭黑3‑5份，活性剂0.2‑0.3份，硬脂酸0.1‑0.3份，阻燃剂10‑20份，防老剂0.1‑0.3份，促进剂1‑3份，硫化剂0.1‑0.3份。通过上述技术方案，解决了相关技术中的保温棚被抗老化性和阻燃性差的问题。

Description

一种环保阻燃型橡塑复合棚被
技术领域
本发明涉及棚被技术领域，具体的，涉及一种环保阻燃型橡塑复合棚被。
背景技术
理想的保温棚被应同时具有保温性、防水防潮性、透光性、收放自如、使用寿命长等特点。随着温室种植业的快速发展，保温棚被也在逐渐被农户所接受。保温棚被作为大棚的“棉衣”，覆盖在大棚表面，提高大棚温度的同时提高了大棚的抗风、抗雨雪能力。
保温棚被多以稻草毡和多层无纺布棉毡为主，存在以下问题：保温棚被在使用一段时间后保温性能下降，是由于在室外环境中，下雨、下雪、夜晚结露结霜等天气导致水缓慢渗入棚被中使棉被变潮湿，从而导致棚被的保温性能大大降低，其次，保温棚被的易燃，且燃烧时会产生有毒气体，不环保。
为了解决上述问题，申请号为201310632648.6的发明专利申请公开了一种泡沫保温被，包括被体，被体由外到内依次为外防水层、外保温层、内保温层、内防火层，具有良好的保温、防水和防火效果，但是，由于其外防水层采用防水橡胶布，该防水橡胶布的耐候性差和阻燃性均较差，导致该保温被在室外环境中炎热或寒冷天气中长时间使用时，防水橡胶布会老化龟裂分解等，从而影响保温被的使用寿命，同时，防水橡胶布的阻燃性能差，虽然该保温被内层有防火层，但外层并不防火，也会影响保温被的使用。
发明内容
本发明提出一种环保阻燃型橡塑复合棚被，解决了现有技术中的保温棚被抗老化性和阻燃性差的问题。
本发明的技术方案如下：
一种环保阻燃型橡塑复合棚被，包括由上至下依次设置的聚四氟乙烯抗老化层、中间保温层和防火硅纤维贴面层，
所述聚四氟乙烯抗老化层包括以下重量份的组分：聚四氟乙烯60-100份，阴离子氟碳表面活性剂4-7份，三异硬脂酰基钛酸异丙酯1-1.5份，多孔碳酸钙13-18份。
作为进一步的技术方案，所述中间保温层包括以下重量份的组分：丁腈橡胶15-20份，聚氯乙烯树脂3-5份，发泡剂4-7份，乙烯-醋酸乙烯酯共聚物3-5份，滑石粉20-30份，氯化石蜡油13-15份，环氧豆油1-2份，防护蜡2-4份，炭黑3-5份，活性剂0.2-0.3份，硬脂酸0.1-0.3份，阻燃剂10-20份，防老剂0.1-0.3份，促进剂1-3份，硫化剂0.1-0.3份。
作为进一步的技术方案，所述防火硅纤维贴面层为涂覆氟硅橡胶的玻璃纤维布层，所述氟硅橡胶与所述玻璃纤维布的质量比为(10-15)：(85-90)。
作为进一步的技术方案，所述聚四氟乙烯抗老化层的厚度为0.2mm，所述中间层的厚度为1-5cm，所述防火硅纤维贴面层的厚度为0.2mm。
作为进一步的技术方案，所述多孔碳酸钙的粒径为200-300nm。
作为进一步的技术方案，所述多孔碳酸钙的制备方法包括以下步骤：将氯化钙溶解在泊洛沙姆水溶液中，加入碳酸钠，溶解后在60-70℃下反应8-10h，将所得产物离心洗涤干燥后的得到多孔碳酸钙。
作为进一步的技术方案，所述氯化钙与所述碳酸钠的摩尔比为1：1。
作为进一步的技术方案，所述聚四氟乙烯抗老化层的制备方法包括以下步骤：将聚四氟乙烯与阴离子氟碳表面活性剂、多孔碳酸钙混合后熔融挤出，得到聚四氟乙烯抗老化层。
作为进一步的技术方案，所述聚四氟乙烯抗老化层与所述中间保温层、所述防火硅纤维贴面层通过热压复合得到环保型橡塑复合棚被。
本发明的工作原理及有益效果为：
1、本发明中，在中间保温层上设置聚四氟乙烯抗老化层，聚四氟乙烯抗老化层以聚四氟乙烯为基体，与阴离子氟碳表面活性剂、三异硬脂酰基钛酸异丙酯、多孔碳酸钙混合后熔融挤出，其中，聚四氟乙烯与碳酸钙相互配伍，显著提高了聚四氟乙烯抗老化层的耐候性，聚四氟乙烯与阴离子氟碳表面活性剂协同作用，显著提高了聚四氟乙烯抗老化层的阻燃性，从而该以聚四氟乙烯抗老化层为上层的橡塑复合棚被具有良好的抗老化性和阻燃性，有效解决了现有技术中的保温棚被抗老化性和阻燃性差的问题。
2、本发明中，上层聚四氟乙烯抗老化层具有良好的阻燃性，下层防火硅纤维贴面层也具有良好的防火性，从而使得该橡塑复合棚被在实际使用时内外都具有良好的阻燃性，实用性更强。
3、本发明中，在聚四氟乙烯抗老化层中加入多孔碳酸钙，还显著提高了聚四氟乙烯抗老化层的透气性，而中间保温层和防火硅纤维贴面层也具有良好的透气性，从而使得该橡塑复合棚被具有良好的透气性，使用性能更好。
4、本发明中，以聚四氟乙烯为基体，与阴离子氟碳表面活性剂、三异硬脂酰基钛酸异丙酯、多孔碳酸钙混合后熔融挤出形成的抗老化层还具有良好的防水性，在与中间保温层热压复合后，在中间保温层上面形成一层0.2mm厚的防水透气膜，良好的防水性使得该橡塑复合棚被在雨天等天气使用时能有效防水水滴渗入，从而有效避免了橡塑复合棚被在使用过程中由于水滴渗入而保温性能变差的问题。
5、本发明中，多孔碳酸钙的粒径为200-300nm，单独加入聚四氟乙烯基体中容易出现多孔碳酸钙聚集而在聚四氟乙烯基体中分散不均匀，加入阴离子氟碳表面活性剂与三异硬脂酰基钛酸异丙酯，二者协同配伍，使得多孔碳酸钙在聚四氟乙烯基体中分散均匀，从而进一步提高了聚四氟乙烯抗老化层的透气性。
具体实施方式
下面将结合本发明实施例，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都涉及本发明保护的范围。
下述实施例中，多孔碳酸钙的制备方法为：将11.1g氯化钙溶解在200mL泊洛沙姆水溶液中，加入10.6g碳酸钠，溶解后在65℃下反应9h，将所得产物离心洗涤干燥后的得到粒径为200-300nm的多孔碳酸钙；泊洛沙姆水溶液的质量浓度为5％，泊洛沙姆的型号为F127；发泡剂为发泡剂DAB，活性剂为氧化锌，促进剂为N-环己基-2-苯并噻唑次磺酰胺，硫化剂为硫磺，防老剂为防老剂D；
实施例1
一种环保阻燃型橡塑复合棚被，包括由上至下依次设置的聚四氟乙烯抗老化层、中间保温层和防火硅纤维贴面层，聚四氟乙烯抗老化层的厚度为0.2mm，中间层的厚度为1-5cm，防火硅纤维贴面层的厚度为0.2mm；
聚四氟乙烯抗老化层包括以下重量份的组分：聚四氟乙烯60份，磺酸基阴离子氟碳表面活性剂4份，三异硬脂酰基钛酸异丙酯1份，多孔碳酸钙13份；
中间保温层包括以下重量份的组分：丁腈橡胶15份，聚氯乙烯树脂3份，发泡剂4份，乙烯-醋酸乙烯酯共聚物3份，滑石粉20份，氯化石蜡油13份，环氧豆油1份，防护蜡2份，炭黑3份，活性剂0.2份，硬脂酸0.1份，阻燃剂10份，防老剂0.1份，促进剂1份，硫化剂0.1份；
防火硅纤维贴面层为涂覆氟硅橡胶的玻璃纤维布层，氟硅橡胶与玻璃纤维布的质量比为10：(85-90)；
上述环保阻燃型橡塑复合棚被的制备方法，包括以下步骤：
(1)将聚四氟乙烯与磺酸基阴离子氟碳表面活性剂、多孔碳酸钙混合后熔融挤出，得到聚四氟乙烯抗老化层；
(2)将丁腈橡胶、聚氯乙烯树脂、发泡剂、阻燃剂、滑石粉、炭黑、氯化石蜡油、环氧豆油、乙烯-醋酸乙烯酯共聚物、防老剂、防护蜡、活性剂、硬脂酸投入密炼机共混，待共混温度达到165℃排料至开练机降温复练，温度降至80℃，开片继续自然冷却后存放24小时后，开炼机继续混练，加入硫化剂和促进剂，混练均匀后出条；出条后的胶条通过挤出机挤出成型，送入烘箱进行硫化发泡；得到中间保温层；
(3)在玻璃纤维布表面涂覆氟硅橡胶，得到防火硅纤维贴面层；
(4)将聚四氟乙烯抗老化层与中间保温层、防火硅纤维贴面层热压复合，得到环保阻燃型橡塑复合棚被。
实施例2
一种环保阻燃型橡塑复合棚被，包括由上至下依次设置的聚四氟乙烯抗老化层、中间保温层和防火硅纤维贴面层，聚四氟乙烯抗老化层的厚度为0.2mm，中间层的厚度为1-5cm，防火硅纤维贴面层的厚度为0.2mm；
聚四氟乙烯抗老化层包括以下重量份的组分：聚四氟乙烯80份，磷酸酯基阴离子氟碳表面活性剂5份，三异硬脂酰基钛酸异丙酯1.2份，多孔碳酸钙15份；
中间保温层包括以下重量份的组分：丁腈橡胶18份，聚氯乙烯树脂4份，发泡剂5份，乙烯-醋酸乙烯酯共聚物4份，滑石粉25份，氯化石蜡油14份，环氧豆油1.5份，防护蜡3份，炭黑4份，活性剂0.25份，硬脂酸0.2份，阻燃剂15份，防老剂0.2份，促进剂2份，硫化剂0.2份；
防火硅纤维贴面层为涂覆氟硅橡胶的玻璃纤维布层，氟硅橡胶与玻璃纤维布的质量比为(10-15)：(85-90)；
上述环保阻燃型橡塑复合棚被的制备方法，同实施例1。
实施例3
一种环保阻燃型橡塑复合棚被，包括由上至下依次设置的聚四氟乙烯抗老化层、中间保温层和防火硅纤维贴面层，聚四氟乙烯抗老化层的厚度为0.2mm，中间层的厚度为1-5cm，防火硅纤维贴面层的厚度为0.2mm；
聚四氟乙烯抗老化层包括以下重量份的组分：聚四氟乙烯100份，羧酸基阴离子氟碳表面活性剂7份，三异硬脂酰基钛酸异丙酯1.5份，多孔碳酸钙18份；
中间保温层包括以下重量份的组分：丁腈橡胶20份，聚氯乙烯树脂5份，发泡剂7份，乙烯-醋酸乙烯酯共聚物5份，滑石粉30份，氯化石蜡油15份，环氧豆油2份，防护蜡4份，炭黑5份，活性剂0.3份，硬脂酸0.3份，阻燃剂20份，防老剂0.3份，促进剂3份，硫化剂0.3份；
防火硅纤维贴面层为涂覆氟硅橡胶的玻璃纤维布层，氟硅橡胶与玻璃纤维布的质量比为(10-15)：(85-90)；
上述环保阻燃型橡塑复合棚被的制备方法，同实施例1。
对比例1
一种聚四氟乙烯抗老化层，与实施例1的区别仅在于未加入多孔碳酸钙。
对比例2
一种聚四氟乙烯抗老化层，与实施例1的区别仅在于未加入磺酸基阴离子氟碳表面活性剂。
对比例3
一种聚四氟乙烯抗老化层，与实施例1的区别仅在于未加入三异硬脂酰基钛酸异丙酯。
对比例4
一种聚四氟乙烯抗老化层，与实施例1的区别仅在于未加入磺酸基阴离子氟碳表面活性剂和三异硬脂酰基钛酸异丙酯。
对实施例1及对比例1-4得到的聚四氟乙烯抗老化层进行阻燃性测试，测试方法按照GB/T2406-1993《塑料燃烧性能试验方法氧指数法》的规定进行，测试结果见下表：
表1实施例1及对比例1-4中得到的聚四氟乙烯抗老化层的阻燃性测试结果
测试项目 实施例1 对比例1 对比例2 对比例3 对比例4
氧指数 28.6 28.1 26.9 28.4 26.7
从上表中数据可以看出，实施例1得到的聚四氟乙烯抗老化层的氧指数为28.6，具有良好的阻燃效果，通过实施例1和对比例1、2对比可以看出，氟硅表面活性剂的加入，显著提高了聚四氟乙烯抗老化层的氧指数，多孔碳酸钙的加入，进一步提高了聚四氟乙烯抗老化层的氧指数。
对实施例1及对比例1-4得到的聚四氟乙烯抗老化层进行抗老化性测试，测试方法按照GB/T 7141-2008《塑料热老化试验方法》的规定进行，在热老化试验箱内分别放置测试样品，在50℃下测试有样品的失效周期，测试结果见下表：
表2实施例1及对比例1-4中得到的聚四氟乙烯抗老化层的抗老化性测试结果
Figure BDA0003541533690000051
从上表中数据可以看出，实施例1得到的聚四氟乙烯抗老化层具有良好的抗老化性，通过实施例1与对比例1-4对比可以看出，多孔碳酸钙的加入，显著提高了聚四氟乙烯抗老化层的抗老化性，阴离子氟碳表面活性剂和三异硬脂酰基钛酸异丙酯协同，进一步提高了聚四氟乙烯抗老化层的抗老化性。
对实施例1-3中得到的聚四氟乙烯抗老化层进行防水性测试，测试方法按照GB/T1037-1988《塑料薄膜和片材透水蒸气性试验方法(杯式法)》试验条件：T＝(38±0.6)℃，RH＝(90±2)％，测试结果见下表：
表3实施例1-3中得到的聚四氟乙烯抗老化层的防水性测试结果：
测试项目 实施例1 实施例2 实施例3
水蒸气透过量g/(m<sup>2</sup>·24h) 3.1 3.2 2.9
从上表中数据可以看出，实施例1-3制得的聚四氟乙烯抗老化层在透水蒸汽试验测试时，水蒸气透过量小，说明本发明的聚四氟乙烯抗老化层具有良好的防水性，从而使以该聚四氟乙烯抗老化层为上层的橡塑复合棚被在雨天等天气使用时能有效防水水滴渗入，从而有效避免了橡塑复合棚被在使用过程中由于水滴渗入而保温性能变差的问题。
对实施例1及对比例1-4中得到的聚四氟乙烯抗老化层进行透气性测试，测试时采用透气性测试仪，测试气体为氮气，测试时间为24小时，测试压力为0.2Mpa，测试结果见下表：
表4实施例1及对比例1-4的聚四氟乙烯抗老化层的透气性测试结果
测试项目 实施例1 对比例1 对比例2 对比例3 对比例4
透气量mL/m<sup>2</sup> 2371 1469 2158 1803 1675
从上表中数据可以看出，实施例1的聚四氟乙烯抗老化层具有良好的透气性，通过实施例1与对比例1-4对比可以看出，多孔碳酸钙的加入，显著提高了聚四氟乙烯抗老化层的透气性，阴离子氟碳表面活性剂和三异硬脂酰基钛酸异丙酯协同，进一步提高了聚四氟乙烯抗老化层的透气性。
以上仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (8)

1.一种环保阻燃型橡塑复合棚被，其特征在于，所述复合棚被包括由上至下依次设置的聚四氟乙烯抗老化层、中间保温层和防火硅纤维贴面层，
所述聚四氟乙烯抗老化层包括以下重量份的组分：聚四氟乙烯60-100份，阴离子氟碳表面活性剂4-7份，三异硬脂酰基钛酸异丙酯1-1.5份，多孔碳酸钙13-18份。
2.根据权利要求1所述的一种环保阻燃型橡塑复合棚被，其特征在于，所述中间保温层包括以下重量份的组分：丁腈橡胶15-20份，聚氯乙烯树脂3-5份，发泡剂4-7份，乙烯-醋酸乙烯酯共聚物3-5份，滑石粉20-30份，氯化石蜡油13-15份，环氧豆油1-2份，防护蜡2-4份，炭黑3-5份，活性剂0.2-0.3份，硬脂酸0.1-0.3份，阻燃剂10-20份，防老剂0.1-0.3份，促进剂1-3份，硫化剂0.1-0.3份。
3.根据权利要求1所述的一种环保阻燃型橡塑复合棚被，其特征在于，所述防火硅纤维贴面层为涂覆氟硅橡胶的玻璃纤维布层，所述氟硅橡胶与所述玻璃纤维布的质量比为(10-15)：(85-90)。
4.根据权利要求1所述的一种环保阻燃型橡塑复合棚被，其特征在于，所述聚四氟乙烯抗老化层的厚度为0.2mm，所述中间层的厚度为1-5cm，所述防火硅纤维贴面层的厚度为0.2mm。
5.根据权利要求1所述的一种环保阻燃型橡塑复合棚被，其特征在于，所述多孔碳酸钙的粒径为200-300nm。
6.根据权利要求1所述的一种环保阻燃型橡塑复合棚被，其特征在于，所述多孔碳酸钙的制备方法包括以下步骤：将氯化钙溶解在泊洛沙姆水溶液中，加入碳酸钠，溶解后在60-70℃下反应8-10h，将所得产物离心洗涤干燥后的得到多孔碳酸钙。
7.根据权利要求6所述的一种环保阻燃型橡塑复合棚被，其特征在于，所述氯化钙与所述碳酸钠的摩尔比为1：1。
8.根据权利要求1所述的一种环保阻燃型橡塑复合棚被，其特征在于，所述聚四氟乙烯抗老化层的制备方法包括以下步骤：将聚四氟乙烯与阴离子氟碳表面活性剂、多孔碳酸钙混合后熔融挤出，得到聚四氟乙烯抗老化层。
CN202210234226.2A 2022-03-10 2022-03-10 一种环保阻燃型橡塑复合棚被 Pending CN114434923A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210234226.2A CN114434923A (zh) 2022-03-10 2022-03-10 一种环保阻燃型橡塑复合棚被

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210234226.2A CN114434923A (zh) 2022-03-10 2022-03-10 一种环保阻燃型橡塑复合棚被

Publications (1)

Publication Number Publication Date
CN114434923A true CN114434923A (zh) 2022-05-06

Family

ID=81358941

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210234226.2A Pending CN114434923A (zh) 2022-03-10 2022-03-10 一种环保阻燃型橡塑复合棚被

Country Status (1)

Country Link
CN (1) CN114434923A (zh)

Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2390401Y (zh) * 1999-07-21 2000-08-09 王凤奎 复合保温被
US20070243373A1 (en) * 2006-04-12 2007-10-18 Asahi Glass Company, Limited Film for membrane structure
CN104592694A (zh) * 2015-01-04 2015-05-06 和县科嘉阀门铸造有限公司 一种阀门密封用纳米碳酸钙改性聚四氟乙烯复合材料
US20160121575A1 (en) * 2013-07-26 2016-05-05 Asahi Glass Company, Limited Laminate sheet and process for producing same
CN105850588A (zh) * 2016-03-31 2016-08-17 太仓市璜泾华南农机作业专业合作社 一种农用复合薄膜
CN106084415A (zh) * 2016-07-28 2016-11-09 安徽吉思特智能装备有限公司 一种用于室外的防水防腐蚀楼宇光缆用护套材料及其制备方法
CN205694653U (zh) * 2016-06-03 2016-11-23 江苏碧云天农林科技有限公司 一种紫背天葵越冬保温大棚
CN206835764U (zh) * 2017-03-28 2018-01-05 张明强 大棚保温被及大棚
CN108395619A (zh) * 2018-03-27 2018-08-14 江苏启能新能源材料有限公司 一种耐候耐酸聚丙烯复合材料及其制备方法
CN109126285A (zh) * 2017-06-28 2019-01-04 湖北亿玛汽车电子有限公司 一种无机纤维特高温复合过滤材料
CN209111689U (zh) * 2018-09-06 2019-07-16 诺弗斯绝热材料有限公司 一种空调用橡塑复合保温材料
CN210247727U (zh) * 2019-04-12 2020-04-07 北京华美沃龙农业科技有限公司 一种复合式橡塑四季棚室保温隔热被
CN111117017A (zh) * 2020-01-06 2020-05-08 神州节能科技集团有限公司 一种无短链氯化石蜡橡塑制品及其制备方法
CN111518323A (zh) * 2020-06-28 2020-08-11 神州节能科技集团有限公司 一种无dop橡塑制品及其制备方法
WO2020248514A1 (zh) * 2019-06-10 2020-12-17 宁波先锋新材料股份有限公司 一种农用膜及其制备方法

Patent Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2390401Y (zh) * 1999-07-21 2000-08-09 王凤奎 复合保温被
US20070243373A1 (en) * 2006-04-12 2007-10-18 Asahi Glass Company, Limited Film for membrane structure
US20160121575A1 (en) * 2013-07-26 2016-05-05 Asahi Glass Company, Limited Laminate sheet and process for producing same
CN104592694A (zh) * 2015-01-04 2015-05-06 和县科嘉阀门铸造有限公司 一种阀门密封用纳米碳酸钙改性聚四氟乙烯复合材料
CN105850588A (zh) * 2016-03-31 2016-08-17 太仓市璜泾华南农机作业专业合作社 一种农用复合薄膜
CN205694653U (zh) * 2016-06-03 2016-11-23 江苏碧云天农林科技有限公司 一种紫背天葵越冬保温大棚
CN106084415A (zh) * 2016-07-28 2016-11-09 安徽吉思特智能装备有限公司 一种用于室外的防水防腐蚀楼宇光缆用护套材料及其制备方法
CN206835764U (zh) * 2017-03-28 2018-01-05 张明强 大棚保温被及大棚
CN109126285A (zh) * 2017-06-28 2019-01-04 湖北亿玛汽车电子有限公司 一种无机纤维特高温复合过滤材料
CN108395619A (zh) * 2018-03-27 2018-08-14 江苏启能新能源材料有限公司 一种耐候耐酸聚丙烯复合材料及其制备方法
CN209111689U (zh) * 2018-09-06 2019-07-16 诺弗斯绝热材料有限公司 一种空调用橡塑复合保温材料
CN210247727U (zh) * 2019-04-12 2020-04-07 北京华美沃龙农业科技有限公司 一种复合式橡塑四季棚室保温隔热被
WO2020248514A1 (zh) * 2019-06-10 2020-12-17 宁波先锋新材料股份有限公司 一种农用膜及其制备方法
CN111117017A (zh) * 2020-01-06 2020-05-08 神州节能科技集团有限公司 一种无短链氯化石蜡橡塑制品及其制备方法
CN111518323A (zh) * 2020-06-28 2020-08-11 神州节能科技集团有限公司 一种无dop橡塑制品及其制备方法

Similar Documents

Publication Publication Date Title
CN108715653B (zh) 一种阻燃、耐候的绝热材料及其制备方法
CN102587521B (zh) 一种防火保温材料及制备方法
CN111320821A (zh) 一种低密度三元乙丙橡胶挤出海绵材料及其制备方法
CN107446304B (zh) 酚醛树脂预浸料及其制造酚醛复合材料的方法
CN112592661A (zh) 一种耐老化性改性沥青防水卷材及制备方法
CN114891451B (zh) 一种复合热塑高分子tpo防水卷材
CN103980620B (zh) 一种耐高温、难燃的输送带覆盖层胶料及其制备方法
CN112143053A (zh) 一种橡塑发泡保温板及其制备工艺
CN114434923A (zh) 一种环保阻燃型橡塑复合棚被
CN110951137A (zh) 一种阻燃抗静电辐照交联聚乙烯彩色泡棉及其制备方法
CN110564058A (zh) 一种绿色膨胀型阻燃聚丙烯及其制备方法
CN108621497A (zh) 一种a级阻燃铝箔气泡隔热材料及其制备方法
CN110511512A (zh) 一种新型抗老化的阻燃电缆料
CN111647223A (zh) 一种高速铁路用电线电缆护套材料及其制备方法
CN113771326B (zh) 一种阻燃夹层玻璃用eva胶片的生产工艺方法
CN114957865A (zh) 一种抗紫外线橡塑发泡保温材料及制备方法
CN110843302A (zh) 一种双向阻燃防水涂层
CN111941977B (zh) 一种防水透气膜及其生产工艺
CN114907633A (zh) 一种耐根穿刺pe/poe复合防水卷材、制备方法及其应用
CN111518323A (zh) 一种无dop橡塑制品及其制备方法
CN111409333A (zh) 一种防毒阻燃氯醚橡胶防护胶布及制备方法
CN109294013A (zh) 一种耐臭氧耐紫外光的保温材料及其制备方法
CN105097998B (zh) 一种太阳能电池封装前膜的制备方法及应用
CN111909504B (zh) 一种隐形车衣用聚氨酯阻燃薄膜及其制备方法和用途
CN112574540B (zh) 聚合物发泡材料及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination