CN114424751A - Odor-absorbing antibacterial mixed cat litter capable of preventing foot cracks and preparation method thereof - Google Patents

Odor-absorbing antibacterial mixed cat litter capable of preventing foot cracks and preparation method thereof Download PDF

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Publication number
CN114424751A
CN114424751A CN202210072865.3A CN202210072865A CN114424751A CN 114424751 A CN114424751 A CN 114424751A CN 202210072865 A CN202210072865 A CN 202210072865A CN 114424751 A CN114424751 A CN 114424751A
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parts
cat litter
odor
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antibacterial
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郑益群
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Guangdong Litejing Disinfection Products Co ltd
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Guangdong Litejing Disinfection Products Co ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/015Floor coverings, e.g. bedding-down sheets ; Stable floors
    • A01K1/0152Litter
    • A01K1/0154Litter comprising inorganic material
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/015Floor coverings, e.g. bedding-down sheets ; Stable floors
    • A01K1/0152Litter
    • A01K1/0155Litter comprising organic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/25Coated, impregnated or composite adsorbents

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Zoology (AREA)
  • Animal Husbandry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Housing For Livestock And Birds (AREA)

Abstract

The invention belongs to the technical field of pet products, and discloses a mixed cat litter with odor absorption, antibiosis and foot crack prevention functions and a preparation method thereof. The mixed cat litter is prepared from the following raw materials in parts by weight: absorbing the odor raw materials: 40-80 parts of coconut shell activated carbon, 20-40 parts of plant extract, 10-30 parts of deodorizing medium, 5-15 parts of sepiolite and 5-15 parts of diatomite; antibacterial raw materials: 1-5 parts of a silver ion antibacterial agent; agglomerating the raw materials: 20-40 parts of natural peas, 20-40 parts of corn starch, 10-30 parts of natural guar gum and 10-30 parts of bentonite. According to the mixed cat litter, the silver ion raw material is added to inhibit the breeding of flora and reduce the generation of peculiar smell, the natural caking raw material is combined to play a role in preventing foot cracks, and meanwhile, the mixed cat litter has the advantages of being longer in antibacterial aging, more economical in dosage, better in deodorization caking, water-soluble and nearly dust-free. Has good market application prospect.

Description

Odor-absorbing antibacterial mixed cat litter capable of preventing foot cracks and preparation method thereof
Technical Field
The invention belongs to the technical field of pet products, and particularly relates to a mixed cat litter with odor absorption, antibiosis and foot crack prevention functions and a preparation method thereof.
Background
The native environment of cats is a desert environment, and the behavior habit carved in the gene makes them bury their own excrement and urine with a substance similar to sand, so cat litter can be understood as sand and ore. Can be used with a cat litter box in a household environment; the cat litter has a certain water absorption and agglomeration effect, can reduce the peculiar smell of excrement, and can also be used for landfill in public environments, household ant removal and the like. The cat litter is a consumable necessary for pet life, but the existing cat litter on the market has uneven quality and easily derives a series of problems: in the aspect of cat litter, the water absorption and agglomeration effects are not ideal, the odor absorption effect is poor, the odor returns rapidly, the bottom is not easy to clean, the cat feet can be damaged due to different and too coarse particles, and the cat litter has the defects of difficult water dissolution, no environmental protection and the like; in the aspect of pets, stones, problems of urinary tract systems, over-standard aflatoxin and formaldehyde and the like are easily caused; therefore, most cat litters that have now on the market are either deodorant bactericidal action relatively poor, or easy pulverization, inconvenient clean, or too coarse can harm the cat foot, and difficult water is not environmental protection.
Patent CN109042356A discloses a cat litter and a preparation method thereof, belonging to the technical field of preparation of objects for burying domestic pet excrement and urine, wherein the cat litter comprises the following components: (1) taking pine sawdust and crushing to obtain pine sawdust powder; (2) adding water into the honey residue according to a certain proportion, stirring and heating, filtering out liquid, airing and grinding under natural conditions to obtain honey residue powder; (3) uniformly stirring deodorant sodium benzoate, spice and antibacterial agent, and adding pine sawdust powder and honey residue powder to obtain a mixture; (4) adding soda lime and anhydrous calcium chloride into the mixture, and stirring to obtain the cat litter finished product for burying the feces and urine of the domestic pets. The cat litter product can be quickly pasted after absorbing water, has the effects of odor removal and antibiosis, but has poor agglomeration effect, and is easy to disperse and troublesome to clean. And the adoption of soda lime and anhydrous calcium chloride can damage the feet of the cat.
Patent CN110050707A discloses a multifunctional cat litter and a preparation method thereof, and the components of the cat litter comprise: (1) taking wet aluminum hydroxide gel as a main base material, adding water-absorbing resin, diatomite, alumina, activated carbon, hydroxymethyl cellulose and tea tree essential oil, and stirring to obtain a mixture; (2) the mixed material is used for extruding a required strip by a strip extruding device; (3) putting the prepared wet particles into drying equipment for drying treatment; (4) and (4) feeding the dried product into a screening device for screening to obtain a cat litter finished product. Compared with cat litters on the market, the cat litter product has more efficient water absorption and odor removal functions, but has the defects of poor agglomeration and antibacterial effects, more dust and the like, and can not really solve the pain of pet owners.
Disclosure of Invention
Aiming at the defects and shortcomings of the prior art, the mixed cat litter has the primary purpose of absorbing odor and resisting bacteria and can prevent foot cracks. According to the mixed cat litter, the silver ion raw material is added to inhibit the breeding of flora and reduce the generation of peculiar smell, the natural caking raw material is combined to play a role in preventing foot cracks, and meanwhile, the mixed cat litter has the advantages of being longer in antibacterial aging, more economical in dosage, better in deodorization caking, water-soluble and nearly dust-free.
The invention also aims to provide a preparation method of the mixed cat litter with odor absorption, antibiosis and foot crack prevention.
The purpose of the invention is realized by the following technical scheme:
the mixed cat litter with odor absorption, antibiosis and foot crack prevention functions comprises the following raw materials in parts by weight:
absorbing the odor raw materials: 40-80 parts of coconut shell activated carbon, 20-40 parts of plant extract, 10-30 parts of deodorizing medium, 5-15 parts of sepiolite and 5-15 parts of diatomite;
antibacterial raw materials: 1-5 parts of a silver ion antibacterial agent;
agglomeration raw materials: 20-40 parts of natural peas, 20-40 parts of corn starch, 10-30 parts of natural guar gum and 10-30 parts of bentonite.
Further, the plant extract is at least one of tea polyphenol, a Chinese rose extract, a chlorophytum comosum extract, a centella asiatica extract and a honeysuckle flower extract.
Further, the deodorization medium is a compound biological enzyme.
Further preferably, the odor absorption raw material comprises coconut shell activated carbon: plant extracts: deodorizing medium: sepiolite: the weight ratio of the diatomite is 6: 3: 2: 1: 1.
further preferably, the agglomerated feedstock comprises a mixture of natural peas: corn starch: natural guar gum: the weight ratio of the bentonite is 3: 3: 2: 2.
the preparation method of the mixed cat litter with odor absorption, antibiosis and capability of preventing the crack of the foot comprises the following preparation steps:
(1) adding an antibacterial material, namely a silver ion antibacterial agent, into water, uniformly mixing and dispersing, adding odor absorbing raw materials, namely coconut shell activated carbon, a plant extract, a deodorizing medium, sepiolite and diatomite, and agglomerating raw materials, namely natural peas, corn starch, natural guar gum and bentonite, uniformly stirring and mixing to obtain a mixed material;
(2) and (2) extruding the mixed material obtained in the step (1) through a screw extrusion device for granulation, then putting the mixed material into drying equipment for drying, and finally screening the dried mixed material through screening equipment to obtain the finished product of the mixed cat litter which has the functions of absorbing smell, resisting bacteria and preventing foot cracks.
Further, the weight ratio of the silver ion antibacterial agent to water in the step (1) is 1-5: 1000.
Further, the step (1) of uniformly stirring and mixing refers to stirring for 30min at 15-35 ℃.
Further, the extrusion granulation in the step (2) refers to preparing cylindrical particles with the diameter of 1-1.5 mm.
Further, in the drying process in the step (2), the humidity is controlled to be less than or equal to 70%, and the temperature is controlled to be 180-240 ℃.
Further, the screening in the step (2) means that the size of the screened particles is less than or equal to 15 mm.
Compared with the prior art, the invention has the beneficial effects that:
(1) the mixed cat litter adopts silver ions as a main antibacterial component, is combined with a pure natural caking raw material, can decompose odor organic molecules causing peculiar smell in cat litter caking substances, is combined with cell membranes of flora, directly destroys the cell structure of the flora, and radically removes the odor in a physical antibacterial mode; after the bacteria die and are cracked, the silver ions are in a free state again and can be contacted with other thalli again, so that the cat litter box has a relatively durable antibacterial effect, the cat litter box is not easy to breed the bacteria, and the using amount is less and more durable; the silver ion antibacterial function is combined with the pure natural caking raw material, so that the cat foot crack prevention effect is achieved to a certain extent; the cat can not cause harm to the body even if being eaten by mistake, and the cat health care food has the advantages of safety and no toxicity.
(2) The mixed cat litter adopts coconut shell activated carbon, plant extracts, deodorizing medium, sepiolite and diatomite as main odor absorbing components, can obtain higher odor absorbing capacity, and the plant extracts contain quercetin, flavone, aromatic oil and other components, so that peculiar smell can be further eliminated.
(3) The mixed cat litter disclosed by the invention adopts natural peas, corn starch, natural guar gum and bentonite as main caking components, can obtain higher caking capacity, is less in using amount and long in duration, does not have liquid water seepage, can wrap excrement in the cat litter after water absorption expansion to form caking blocks, only needs to clean the caking blocks, and has no adverse effect on careless eating of clean cat litter by cat. The natural components have small stimulation and damage to the feet of the cat, and have certain effect of preventing the foot cracks by combining with silver ion antibiosis.
(4) The mixed cat litter product of the formula disclosed by the invention focuses more on water absorption, odor removal, antibiosis and convenience in cleaning, and more meets the actual requirements of customers, the product can keep the surface of particles dry after water absorption, can coat excrement, is efficient in odor removal and convenience in cleaning, and has strong antibacterial performance; when the cat litter box is actually used, unlike the situation that most of cat litter in the whole cat litter box needs to be completely cleaned after similar products are used, the cat litter box only coats excrement, other particles are kept dry, the cat litter is saved during cleaning, and the cleaning difficulty and the cleaning cost can be greatly reduced; the specific weight of the whole product is lighter, and the product with the same weight can have more weight, so that the consumption cost is reduced; the whole production process is simple, the raw material cost is low, the product performance is excellent, and the product has a higher market value.
Detailed Description
The present invention will be described in further detail with reference to examples, but the embodiments of the present invention are not limited thereto.
Example 1
The preparation method of the mixed cat litter with odor absorption, antibiosis and capability of preventing foot cracks in the embodiment comprises the following steps:
(1) adding an antibacterial raw material silver ion antibacterial agent into 1000 parts of water by weight, uniformly mixing and dispersing, adding 60 parts of odor absorption raw materials of coconut shell activated carbon, 30 parts of plant extract, 20 parts of deodorization medium, 10 parts of sepiolite and 10 parts of diatomite, mixing 30 parts of agglomeration raw materials of natural pea, 30 parts of corn starch, 20 parts of natural guar gum and 20 parts of bentonite, and stirring the proportioned raw materials for 30min at 15-35 ℃ to obtain a mixed material;
(2) preparing the mixed material obtained in the step (1) into cylindrical particles with the diameter of 1-1.5 mm through a screw extrusion device, then putting the cylindrical particles into drying equipment, controlling the humidity to be less than or equal to 70%, and controlling the temperature to be 180-240 ℃ to obtain dried particles, finally putting the dried particles into screening equipment, screening the particles to be less than or equal to 15mm, and carrying out screening powder treatment to obtain the odor-absorbing antibacterial mixed cat litter finished product capable of preventing foot cracks.
In the present example, the antibacterial ability of the cat litter was verified by adjusting the addition amount of the silver ion antibacterial agent (test method: quantitative sterilization test of suspension in 2002 edition-2.1.1.7.4, Ministry of health of the people's republic of China), the addition amount of the silver ion antibacterial agent was adjusted to 4 parts, 3 parts, 2 parts and 1 part, and the mixed cat litter without the addition of the silver ion antibacterial agent was used as a comparison, and the test results are shown in table 1 below.
TABLE 1
Adding amount of silver ion antibacterial agent 4 portions of 3 portions of 2 portions of 1 part of 0 portion of
Antibacterial rate of Escherichia coli 99.9% 99.8% 99.4% 98.9% 87.1%
Antibacterial rate of staphylococcus aureus 99.9% 99.7% 99.3% 98.7% 86.8%
The results in table 1 show that the antibacterial ability of the mixed cat litter can be significantly improved by adding a certain amount of silver ion antibacterial agent into the mixed cat litter.
Example 2
The preparation method of the mixed cat litter with odor absorption, antibiosis and capability of preventing foot cracks in the embodiment comprises the following steps:
(1) adding 4 parts of an antibacterial material, namely a silver ion antibacterial agent, into 1000 parts of water by weight, uniformly mixing and dispersing, adding 60 parts of odor absorbing raw materials, namely coconut shell activated carbon, 30 parts of plant extract, 20 parts of deodorizing medium, 10 parts of sepiolite and 10 parts of diatomite, and mixing agglomeration raw materials, namely natural pea, corn starch, natural guar gum and bentonite, and stirring the proportioned raw materials for 30min at 15-35 ℃ to obtain a mixed material;
(2) preparing the mixed material obtained in the step (1) into cylindrical particles with the diameter of 1-1.5 mm through a screw extrusion device, then putting the cylindrical particles into drying equipment, controlling the humidity to be less than or equal to 70%, and controlling the temperature to be 180-240 ℃ to obtain dried particles, finally putting the dried particles into screening equipment, screening the particles to be less than or equal to 15mm, and carrying out screening powder treatment to obtain the odor-absorbing antibacterial mixed cat litter finished product capable of preventing foot cracks.
In the embodiment, the water absorption and agglomeration performance of the agglomerated material is verified by adjusting the addition amount of the agglomerated material (the test method adopts 100g of experimental cat litter and 600g of experimental water, and the action time is 10 min). Wherein the weight ratio of the natural peas, the corn starch, the natural guar gum and the bentonite is 3: 3: 2: 2. the total amount of added clumping material was 100%, 75%, 50% and 25% of that of example 1, and the results of the tests are shown in table 2 below, using as a comparison the mixed litter obtained without the addition of clumping material.
TABLE 2
Addition amount of agglomeration raw material 100% 75% 50% 25% 0
Water-absorbing and agglomerating effect 6g/g 4.8g/g 3.3g/g 1.7g/g 0.3g/g
Water absorption and conglomeration state Is completely absorbed Most of the absorption Partially absorb A small part is absorbed Has no obvious absorption
As can be seen from the results in Table 2, the mixed cat litter obtained by adding a certain amount of agglomeration raw materials has good water absorption agglomeration effect. Practical application shows that the product only coats excrement, other particles are kept dry, and the cat litter is saved by cleaning without cleaning the whole product. The cat litter obtained without adding the caking raw material does not have the caking coating effect.
1. Aflatoxin B1 and formaldehyde standard test experiments were performed on the mixed cat litter (the added amounts of the agglomeration raw materials were 100% and 25%, respectively, as test samples) obtained in the present invention, and the results are shown in table 3.
TABLE 3
Serial number Detecting items Unit of The result of the detection Requirement of limit Conclusion Detection method
1 Aflatoxin B1 μg/kg Not detected (<2.0) ≤10 Conform to NY/T2071-2011
2 Formaldehyde (I) mg/kg Not detected (<0.1) ≤1.5 Conform to T/CIQA11-2020
The results in table 3 show that aflatoxin B1 and formaldehyde were not detected in any of the mixed litters of the invention.
2. The mixed cat litter obtained by the invention (the addition amount of the silver ion antibacterial agent is 4 parts, the addition amount of the agglomeration raw material is 100% (test sample 1), the addition amount of the silver ion antibacterial agent is 2 parts, the addition amount of the agglomeration raw material is 100% (test sample 2), the addition amount of the silver ion antibacterial agent is 4 parts, and the addition amount of the agglomeration raw material is 75% (test sample 3)) is tested in the practical application of pet raising families, pet stores and pet hospitals. The experiment selects 3 pet families in Guangzhou city, pet stores and pet hospitals respectively, and 9 application experiments are performed in total to test the satisfaction degree of the user in practical application of the mixed cat litter. Wherein the satisfaction degree score of the odor absorption effect is 1-5, the satisfaction degree score of the agglomeration effect is 1-5, 1 is very unsatisfactory, 2 is less unsatisfactory, 3 is medium evaluation, 4 is more satisfactory, and 5 is very satisfactory. Specific results are shown in table 4.
Table 4 results of satisfaction
Figure BDA0003482910930000061
Figure BDA0003482910930000071
As can be seen from the results in Table 4, the mixed cat litter has high using satisfaction degree in pet raising families, pet stores and pet hospitals.
3. The mixed cat litter (the addition amount of the silver ion antibacterial agent is 4 parts, and the addition amount of the agglomeration raw material is 100%) obtained by the present invention was tested for the effect of preventing foot cracks. The cat in a good health state is used for a practical application test, and the cat uses commercial cat litter made of common inorganic water-absorbing materials before the test, so that the foot part of the cat exhibits certain cracks, and the plantar skin of the foot is rough. The change of the skin and the cracks of the feet were observed for 3 days, 7 days, 14 days and 28 days. And cat litter obtained without adding silver ion antibacterial agent (comparative example 1) and without adding agglomerating raw material (comparative example 2) was used as a comparison, and the test results are shown in table 5 below.
TABLE 5
Figure BDA0003482910930000081
The results in table 5 show that the invention has good effect of preventing foot cracks and achieves good synergistic effect by combining the agglomeration raw material of natural components with silver ion antibacterial.
The above embodiments are preferred embodiments of the present invention, but the present invention is not limited to the above embodiments, and any other changes, modifications, substitutions, combinations, and simplifications which do not depart from the spirit and principle of the present invention should be construed as equivalents thereof, and all such changes, modifications, substitutions, combinations, and simplifications are intended to be included in the scope of the present invention.

Claims (10)

1. The mixed cat litter with odor absorption, antibiosis and foot crack prevention functions is characterized by comprising the following raw materials in parts by weight:
absorbing the odor raw materials: 40-80 parts of coconut shell activated carbon, 20-40 parts of plant extract, 10-30 parts of deodorizing medium, 5-15 parts of sepiolite and 5-15 parts of diatomite;
antibacterial raw materials: 1-5 parts of a silver ion antibacterial agent;
agglomerating the raw materials: 20-40 parts of natural peas, 20-40 parts of corn starch, 10-30 parts of natural guar gum and 10-30 parts of bentonite.
2. The mixed cat litter with odor absorbing, antibacterial and foot crack preventing functions as claimed in claim 1, wherein the plant extract is at least one of tea polyphenol, Chinese rose extract, chlorophytum comosum extract, centella asiatica extract and honeysuckle flower extract.
3. The odor-adsorbing, antibacterial, and foot crack-preventing mixed litter of claim 1 wherein the deodorizing medium is a complex biological enzyme.
4. The odor-absorbing antibacterial mixed cat litter capable of preventing foot cracks as claimed in claim 2 or 3, wherein the odor-absorbing raw materials comprise coconut shell activated carbon: plant extracts: deodorizing medium: sepiolite: the weight ratio of the diatomite is 6: 3: 2: 1: 1.
5. the odor-absorbing, antibacterial and foot crack preventing mixed cat litter according to claim 4, wherein the natural pea: corn starch: natural guar gum: the weight ratio of the bentonite is 3: 3: 2: 2.
6. the preparation method of the odor-absorbing antibacterial mixed cat litter capable of preventing foot cracks as claimed in any one of claims 1 to 5, which is characterized by comprising the following preparation steps:
(1) adding an antibacterial raw material, namely a silver ion antibacterial agent, into water, uniformly mixing and dispersing, adding odor absorbing raw materials, namely coconut shell activated carbon, a plant extract, a deodorizing medium, sepiolite and diatomite, and agglomerating raw materials, namely natural peas, corn starch, natural guar gum and bentonite, uniformly stirring and mixing to obtain a mixed material;
(2) and (2) extruding the mixed material obtained in the step (1) through a screw extrusion device for granulation, then putting the mixed material into drying equipment for drying, and finally screening the dried mixed material through screening equipment to obtain the finished product of the mixed cat litter which has the functions of absorbing smell, resisting bacteria and preventing foot cracks.
7. The preparation method of the mixed cat litter with odor absorption, bacteria resistance and foot crack prevention functions as claimed in claim 6, wherein the weight ratio of the silver ion antibacterial agent to water in the step (1) is 1-5: 1000.
8. The preparation method of the mixed cat litter with odor absorption, bacteria resistance and foot crack prevention functions as claimed in claim 7, wherein the step (1) of uniformly stirring and mixing is to stir at 15-35 ℃ for 30 min.
9. The method for preparing odor-absorbing antibacterial mixed cat litter capable of preventing foot cracks according to claim 6, wherein the extrusion granulation in the step (2) is to prepare cylindrical particles with the diameter of 1-1.5 mm.
10. The preparation method of the mixed cat litter with odor absorption, bacteria resistance and foot crack prevention functions as claimed in claim 9, wherein in the drying process in the step (2), the humidity is controlled to be less than or equal to 70%, and the temperature is controlled to be 180-240 ℃; the screening means that the size of the screened particles is less than or equal to 15 mm.
CN202210072865.3A 2022-01-21 2022-01-21 Odor-absorbing antibacterial mixed cat litter capable of preventing foot cracks and preparation method thereof Pending CN114424751A (en)

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CN115918555A (en) * 2022-11-21 2023-04-07 深圳市蓝宝炭业有限公司 Cat litter mate deodorizing pill-shaped particle and preparation method thereof
CN115968793A (en) * 2022-12-27 2023-04-18 山东格林小镇宠物用品有限公司 Pet cat litter easy to absorb water and deodorize and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115918555A (en) * 2022-11-21 2023-04-07 深圳市蓝宝炭业有限公司 Cat litter mate deodorizing pill-shaped particle and preparation method thereof
CN115918555B (en) * 2022-11-21 2023-09-12 深圳市蓝宝炭业有限公司 Cat litter mate deodorizing pill-shaped particles and preparation method thereof
CN115968793A (en) * 2022-12-27 2023-04-18 山东格林小镇宠物用品有限公司 Pet cat litter easy to absorb water and deodorize and preparation method thereof

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