KR101938452B1 - sand for cats and cats sand manufacturing method - Google Patents

sand for cats and cats sand manufacturing method Download PDF

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KR101938452B1
KR101938452B1 KR1020160012598A KR20160012598A KR101938452B1 KR 101938452 B1 KR101938452 B1 KR 101938452B1 KR 1020160012598 A KR1020160012598 A KR 1020160012598A KR 20160012598 A KR20160012598 A KR 20160012598A KR 101938452 B1 KR101938452 B1 KR 101938452B1
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sand
weight
raw material
mixing
bentonite
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KR1020160012598A
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KR20170091842A (en
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이학섭
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이준용
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/01Removal of dung or urine, e.g. from stables
    • A01K1/0107Cat trays; Dog urinals; Toilets for pets
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/01Removal of dung or urine, e.g. from stables
    • A01K1/0107Cat trays; Dog urinals; Toilets for pets
    • A01K1/011Cat trays; Dog urinals; Toilets for pets with means for removing excrement
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/015Floor coverings, e.g. bedding-down sheets ; Stable floors
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/02Pigsties; Dog-kennels; Rabbit-hutches or the like
    • A01K1/035Devices for use in keeping domestic animals, e.g. fittings in housings or dog beds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K23/00Manure or urine pouches
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/047Zeolites
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay
    • C04B14/104Bentonite, e.g. montmorillonite

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Animal Husbandry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Zoology (AREA)
  • Ceramic Engineering (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • Housing For Livestock And Birds (AREA)

Abstract

The present invention relates to a process for producing cat litter which comprises the steps of mixing, mixing, rolling, drying, sorting and the like to form granular sand instead of powder, thereby minimizing dust generated when pet sand is used, It is intended to provide a new type of cat sand which is convenient for use in sand products and easy to handle, while preventing various diseases.
The present invention relates to a cementitious composition comprising 20% by weight of sodium bentonite in the form of a 200 mash powder, 60% by weight of sodium based bentonite in 1 to 2 mm granules, 5% by weight of calcium based zeolite, 7% by weight of sawdust, %, And 3 wt% of baking soda as an additive are mixed and kneaded, rolled and dried to form granules having a size of 2 to 5 mm.

Description

Technical Field [0001] The present invention relates to cat litter,

The present invention relates to a method for producing cat litter, and more particularly, to a method for producing cat litter by absorbing and coagulating secretions such as large and urine generated in a cat raised in a pet, (NH 3 , ammonia), which is a cause of stench caused by large and urine, and adsorbs odor. At the same time, the function of antibacterial, anion and far infrared rays due to the characteristics of minerals used as main raw materials And to a manufacturing method for producing the same.

In general, human beings are living, and food, clothing and shelter are basic essential elements. They are urbanized due to the development of industry and civilization, and live in an artificial environment away from nature. In the urbanized artificial environment, human instinct is environmentally friendly And the desire to return to nature in the nature is desperate, and the social contradiction due to economic development such as nuclear family, depression due to loneliness and loneliness due to aging, is getting more and more intense.

In the past, dogs and cats were raised for sale, and we were set up in a certain place outside the area without breeding in the indoor space. However, modern society changed the perception of pets including dogs and cats, Especially, the pet animals such as dogs and cats are expanding the means of acquiring familiarity between nature and animals in urban areas, knowing nature through sympathy, and improving the quality of life, and animal lovers and maniacs The demand for pets is gradually increasing.

Currently, pets are being raised in ordinary households. In particular, cats tend to be family members and the role of life companions beyond the concept of animals.

In order to raise cats, home, food, and other tools are required as well as people. Foods and Animals In our case, various types of feeds and we are widely used according to the characteristics of animals.

Since the cats are regarded as a family member and they are treated as companions living together, various items have been developed and used in various ways, and the concept of animals is not simply a means of securing a bed, but a means of sleeping, To accommodate the clean environment, various facilities such as toilet space, feed space, and dragonfly space are constructed.

In particular, in the case of cats, sand (so-called cat sand) is indispensably necessary because it differs from other pets in that the urine absorbs the toilet in the sand. .

For this purpose, cat sands and toilet articles have been developed and used in various ways. Cat sands are classified into absorbable sand and coagulated sand depending on the usage method.

The absorption type sand is a product having a function of absorbing urine of a cat, especially urine. It is made of silica (SiO 2 .2H 2 O) used as a desiccant, or absorbed by using paper grains such as sand or corn, Sand is a typical example, and coagulated sand is sand that is made by disrupting sodium bentonite collected from a mine.

The sodium-based bentonite is available in some countries around the world, has limited reserves, and only calcium-based bentonite is available in Korea.

As described above, the absorption type sand using silica or paper and grain is excellent in water absorbability, so that the urine absorbing ability of the cat is excellent, but the coagulation power is hardly accumulated, so that it does not aggregate in a solid form and the deodorizing function against the ammonia odor remarkably drops In particular, silica sand contains ingredients harmful to humans and the environment, and thus has a problem of providing cause of diseases such as eye diseases and skin diseases.

In addition, in the case of using sand or paper using sand, it is inconvenient to supply shortage of grain and post-treatment process, and it provides a cause of environmental destruction such as deforestation for obtaining paper, and when reusing a poor paper material The harmful components contained in the paper regeneration process create an environment that is bad for cats as well as the human body.

The coagulated sand using sodium bentonite is excellent in the coagulation power and is most widely used. However, since it is crushed into a small particle state by taking minerals, the dust is very likely to be generated by the dust, Because it is formed sharply, the cat has a closed end which is injured by stimulation when skin contact is used in the process of using for the toilet.

Especially, 99% of the products that are distributed in Korea with coagulant sand are imported from China or USA, and thus they are not contributing to domestic industry development.

As mentioned above, cats are members of the family and act as companions, but because they are low in intelligence and live faithfully to the animal's instincts, they become infected with animal-specific bacteria and odors, Odor is generated and the secretion can not be treated by itself, so that when it is raised indoors, various odors are generated, and clean sanitary control can not be achieved.

The conventional pet sand is used for simply dividing the floor and concealing the excrement. If there is no function, and if it is used for a long time, fine particles are generated due to drying, and it is a main cause In addition, there is a great demand for deodorization of odor in the state that the damage caused by dust is large, and there is almost no deodorizing function against the feces odor, and thus the foul odor generated in the feces is defenseless.

Conventional cat sands as described above are desired to be extracted by 10-2010-7012940 (animal litter sands, hereinafter referred to as "prior patent"), and the prior patent discloses animal litter sands comprising a plurality of granular materials, Each of the granular materials includes a group of particles made of an inorganic porous material, a silica gel, and a particle group and an inorganic binder integrally fixing the silica gel. The inorganic binder is cement, a cement, a non- . Wherein the noncementifying agent is at least one selected from the group consisting of zeolite, attapulgite, sepiolite, diatomaceous earth, and diatomaceous shale, and the inorganic porous material is a water-hardenable solidifying agent comprising calcium sulfate and magnesium oxide as main components. Respectively. The cement is a low alkali cement, and the plurality of particulate materials have a content of the inorganic binder of 5 mass% to 30 mass% and a content of the silica gel of 3 mass% to 20 mass%. However, the silicagel (SiO2. 2H2O) used in the above-mentioned prior art is excellent in water absorbency and is used as a moisture-proof and absorbing agent. Although the water absorbing power of pets is excellent, the solidifying power is lowered, And cement used as an inorganic binder contains carcinogens such as asbestos that are harmful to the human body and the environment, and thus has a problem of causing diseases such as eye diseases and skin diseases. The present invention relates to a method for manufacturing pet sands using natural materials and a method for producing the same, hereinafter referred to as " pet odor "), patent No. 837528 Referred to as the earlier patent). These prior art patents disclose a deodorant composition comprising 50 to 90% by weight of powdered zeolite, 1 to 5% by weight of food additives and 5 to 35% by weight of bentonite by mixing and kneading, compression, cutting and rolling, The powdered zeolite is mixed with 3 to 5% by weight of pulp, which is a vegetable fibrous agent, as an auxiliary raw material to serve as a filler to bind the zeolite having no viscosity, and the natural spice is mixed at a mixing ratio of 1% Is added. The prior application patents consist of 45% by weight of zeolite and 40% by weight of bentonite, which are the main raw materials in the powder state in constituting the sand used as a bottom material in the process of raising small animals such as cats, hamsters, hedgehogs and rabbits. And 3% by weight of tourmaline. The mixture is kneaded at a ratio of 12% by weight of purified water. The mixed kneaded raw material is rolled to form granules of 0.5 to 1 mm or less, granules of 1 to 3 mm or less, granules of 3 to 7 mm or less . The prior-art patent discloses a process for producing granular sand used as a flooring material for pet comprising zeolite, bentonite, tourmaline, plain wood powder and purified water of natural materials in an amount of 45 wt% of zeolite and 40 wt% of bentonite, 3% by weight of tourmaline, mixing and kneading in a mixer at a ratio of 12% by weight of purified water; Operating cylinder of the mixer; The raw material being discharged and conveyed by the first conveying conveyor; Feeding the transferred raw material to the spinning unit of the rolling unit; The rotation of the rolling part of the rolling part is rolled and formed into a spherical shape; The raw material formed by the rolling of the rolling part is discharged and transferred to the drying part by the second conveying conveyor; Drying the raw material by the hot air heater of the drying unit; Supplying the dried raw material to the sorting portion; Sorting by the first, second, and third sorting members of the sorting unit; Collecting the selected raw materials by respective first, second and third sorting materials; Feeding the selectively collected raw materials to a quantitative feeder; And quantitatively packed by a quantitative feeder.

 In general, pet sand, especially sand used as cat sand, is used to break up natural sodiumbentonite into small particles, and has a function of coagulating urine by using sodium-based characteristics. However, since sodium bentonite in a natural state is composed of natural minerals as described above and is environmentally friendly, it is composed of small particles in a crushed state, so that a large amount of dust is generated during use, Since sodium bentonite is not produced domestically but can be produced only in the US and China, more than 99% of the products in circulation depend on imports. Therefore, the price is high and the supply is not smooth. have.

Disclosure of Invention Technical Problem [10] The present invention provides a method of treating a feline by absorbing secretions such as large and small feces generated in the process of growing cats, solidifying the feces in a solid form to provide convenient convenience after secretion treatment, And at the same time to maintain the health by the far infrared rays and anions emitted from the minerals, and to provide a pleasant and clean sanitary environment, as well as to manufacture cat litter in Korea and localize the products, , And to provide a new type of cat sand that can provide high quality products at an affordable price, thereby increasing customer satisfaction.

The present invention relates to a process for producing cat litter which comprises the steps of mixing, mixing, rolling, drying, sorting and the like to form granular sand instead of powder, thereby minimizing dust generated when pet sand is used, It is intended to provide a new type of cat sand which is convenient for use in sand products and easy to handle, while preventing various diseases.

The present invention relates to a method for producing a sintered product, which comprises mixing a raw material composed of 20% by weight of sodium bentonite in a 200 mash powder state, 60% by weight of sodium based bentonite of 1 to 2 mm in granular weight and 5% by weight of calcium based zeolite, 7 wt% of sawdust and 5 wt% of mineral water are added as an additive in the mixing of the primary raw materials in the cat litter having granules of 2 to 5 mm in size by mixing, kneading, rolling and drying 3 wt% By weight of sodium bicarbonate, 20% by weight of sodium bentonite, 60% by weight of sodium based bentonite of 1 to 2 mm granule, 5% by weight of calcium based zeolite and 3% by weight of baking soda as additives, Respectively.

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The sawdust is used by crushing pine and oak to a size of 0.1 to 2 mm and the mineral water is characterized by using natural minerals containing many kinds of mineral components or using zeolite and bentonite. And cattle sand consisting of zeolite bentonite and zeolite, sawdust and mineral water, and baking soda as an additive, is prepared by mixing 200 mesh 20 wt% of sodium-based bentonite in a mash powder state, 60 wt% of sodium-based bentonite of 1 to 2 mm granularity, and 5 wt% of calcium-based zeolite into a mixer to form a primary raw material; Mixing 7 wt% of sawdust and 5 wt% of mineral water in the primary raw material to form a secondary raw material; Mixing 3% by weight of baking soda as an additive to form a tertiary raw material; Kneading and mixing the third raw material to form granulated sand in the form of granules; Selecting sand having a particle size of 5 mm or less by using a separator equipped with a mesh net of 5 mm size in granular sand; A step of putting the selected sand into a rolling machine for surface treatment and a primary drying using an electric panel; The surface treatment and drying of the primary dried sand at a temperature of 60 캜 for 24 hours in a dryer using an electric panel.

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As described above, the cat litter according to the present invention can be used to remove odors caused by the large and the urine while providing convenience in handling the cat, urine, As domestic pet sand is localized, high-quality products can be provided at a low price, thereby reducing the burden of consumption, which is economical. Further, it can reduce the waste of foreign currency due to import, It can achieve a very ripple industrial and economic effect that can secure competitiveness.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a process diagram showing a method for manufacturing cat litter according to the present invention;
2 is a photograph showing cat sands according to the present invention,
FIG. 3A is a photograph showing a step of constituting a first raw material in the process of manufacturing cat sands according to the present invention,
FIG. 3B is a photograph showing a step of putting cat sand according to the present invention into a rolling machine during its manufacturing process,
FIG. 3c is a photograph showing the step of drying the cat sands according to the present invention during the manufacturing process,
4 is a photograph showing the use state of cat sands according to the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention will be described in more detail with reference to the accompanying drawings.

The cat litter according to the present invention comprises 20% by weight of sodium bentonite in the form of a 200 mash powder, 60% by weight of sodium bentonite in 1 to 2 mm granular form, A step (S20) of mixing a primary raw material with 7% by weight of sawdust to form a secondary raw material, and a step (S20) of mixing the primary raw material with a secondary raw material by mixing 5% by weight of calcium type zeolite into a mixer to constitute a primary raw material A step (S30) of forming a tertiary raw material by mixing 5% by weight of mineral water and 3% by weight of baking soda as an additive in the secondary raw material, and a step (S30) of mixing the tertiary raw material by granulating the granular granulated sand (S40) of sanding the granulated sand and selecting a sand having a particle size of 5 mm or less by using a sorter equipped with a mesh network having a size of 5 mm (S50), sanding the selected sand into a rolling machine, (S60), and drying the surface And drying the preliminarily dried sand at a temperature of 60 캜 for 24 hours in a dryer using an electric panel (S70).

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In this process, the mineral water (5% by weight) used in the step (S30) for constituting the tertiary raw material is precipitated for about 36 hours by adding minerals having high mineral content to the water so that the mineral component contained in the mineral is contained in the water And the surface treatment is a rolling treatment to smooth the surface without being roughened.

At this time, the number of minerals is based on the biotool developed by the present applicant and registered in Patent No. 1329637, and a detailed description thereof will be omitted.

FIG. 2 is a photograph showing cat sands according to the present invention, which comprises 20% by weight of sodium bentonite in the form of a 200-mesh mash, 60% by weight of sodium based bentonite in 1 to 2 mm granular form and 5% by weight of calcium based zeolite The mixture was mixed to prepare a primary raw material. The primary raw material was mixed with 7 wt% of sawdust to form a secondary raw material. To the secondary raw material, 5 wt% of mineral water and 3 wt% of baking soda as an additive Mixed in a kneader (a conventional powder mixing kneader, not shown in the figure) in a state where the third raw material is constituted, and is formed in the form of granules having a particle size of about 5 mm.

In this case, the mineral water mixed in the sand is added in order to make the particles in powder form to be aggregated in the mixing and mixing process. In the drying process, pure water H 2 O is evaporated by about 90% The remaining minerals remain adsorbed on the raw material, and the granulated sand is selected to have a size of 5 mm or less by using a sorter equipped with a mesh net of 5 mm size.

The components of the mineral water are shown in Table 1 below.

Figure 112016010920812-pat00001

In another embodiment of cat sand according to the present invention, 5 wt% of sodium bentonite in powder form, 28 wt% of sodium based bentonite in 1 to 2 mm granule, 40 wt% of calcium based zeolite, 20 wt% of sawdust, , 5% by weight of mineral water and 2% by weight of baking soda as an additive are mixed and kneaded, rolled and dried to form granules having a size of 2 to 5 mm, thereby being environmentally friendly and providing a forest bath effect It is.

FIG. 3A is a photograph showing a step of constructing a primary raw material in the production process of cat sands according to the present invention, wherein 20 wt% of sodium bentonite in a 200 mesh mash powder state and 20 wt% of sodium bentonite 60 (S20) of mixing a primary raw material with 7% by weight of sawdust to form a secondary raw material; and (2) mixing the primary raw material with the main raw material in an amount of 5% by weight and calcium-based zeolite in an amount of 5% And 5% by weight of mineral water and 3% by weight of baking soda as an additive are mixed in the second raw material to constitute the third raw material (S30) are mixed and mixed to form sand.

FIG. 3B is a photograph showing a step of putting cat sand according to the present invention into a rolling machine for surface treatment by rolling the raw material mixed and mixed in a cylindrical rolling device to form a sandy material.

FIG. 3C is a photograph showing a step of drying the cat litter according to the present invention during the manufacturing process, wherein the raw material is dried using the electric panel.

FIG. 4 is a photograph showing the use state of cat sands according to the present invention. When a certain amount of sand is put into a prepared cat toilet container in the breeding of cats, when the cat uses the sand contained in the toilet container, As you can see, due to the characteristics of the cat, after digging the sand, after peeing, urinating, and then covering the excrement with the sand again, in the ideal situation, the user would use a separate tool (sand shovel) , The cat is excreted, the urine is solidified by the sand to form a lump, and the user removes the lump of the cat's excrement solidified by the sand.

In this process, the sand according to the present invention is in a state of being manufactured through mixing, mixing, rolling and drying processes of natural raw materials, so that the surface is smooth and rounded, so that the skin is excellent in touch, The ammonia component which is a cause of the malodor generated in the excrement due to the characteristic is adsorbed and decomposed, so that the malodorous deodorization is performed.

20% by weight of sodium bentonite in the form of a 200 mash powder used as the main raw material in the present invention, 60% by weight of sodium bentonite in 1 to 2 mm granular form and the chemical components of the calcium-based zeolite are shown in Tables 2, 3 and 4 .

Figure 112016010920812-pat00002

[Sodium-based bentonite in a 200 mesh (mash) powder state]

Figure 112016010920812-pat00003

[Sodium-based bentonite of 1 to 2 mm granularity]


Product Name

Silicic acid

Alumina

iron

magnesium

calcium

salt

potassium

Zeolite

65.01%

19.5%

2.84%

1.27%

2.30%

0.49%

2.22%

[Calcium-based zeolite]

Table 5 below shows the deodorizing power of the raw material constituting the pet sand according to the present invention.

Figure 112016010920812-pat00004

* Source: Korea Living Environment Research Institute

The cat litter according to the present invention is used by putting a certain amount of pet litter in a generally used cat litter box (not shown in the drawing). When a cat catches urine in a container, pet litter absorbs urine, So that they form a lump.

As described above, when the urine is absorbed and solidified by the cat sand to form a lump, the user can easily and conveniently handle the solidified urine in a solidified state.

Claims (3)

20 wt% sodium bentonite in a 200 mash powder state, 60 wt% sodium 1-2 wt% bentonite, 5 wt% calcium zeolite, 7 wt% sawdust, 5 wt% mineral water, baking And 3% by weight of soda are mixed and kneaded, rolled and dried to produce granules of 2 to 5 mm in size. delete Sodium bentonite and zeolite, sawdust and mineral water, and baking soda as an additive were prepared. 20% by weight of sodium bentonite in the form of 200 mash powder and 1% by weight of sodium bentonite 60 And 5% by weight of calcium-based zeolite into a mixer to form a primary raw material;
Mixing 7 wt% of sawdust and 5 wt% of mineral water in the primary raw material to form a secondary raw material;
Mixing 3% by weight of baking soda as an additive to form a tertiary raw material;
Kneading and mixing the third raw material to form granulated sand in the form of granules;
Selecting sand having a particle size of 5 mm or less by using a separator equipped with a mesh net of 5 mm size in granular sand;
A step of putting the selected sand into a rolling machine for surface treatment and a primary drying using an electric panel;
And drying the dried primary sand at a temperature of 60 캜 for 24 hours in a dryer using an electric panel.
KR1020160012598A 2016-02-01 2016-02-01 sand for cats and cats sand manufacturing method KR101938452B1 (en)

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KR20230141002A (en) 2022-03-30 2023-10-10 푸른들영농조합법인 Composition for Cat Litter(sand) Made of Soy Bean Hull Comprising Hydrolysate with Organic Acid of Waste Shell and Manufacturing Method Thereof

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