CN114367428A - Spraying process of titanium porcelain water paint aluminum plate - Google Patents

Spraying process of titanium porcelain water paint aluminum plate Download PDF

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Publication number
CN114367428A
CN114367428A CN202210035127.1A CN202210035127A CN114367428A CN 114367428 A CN114367428 A CN 114367428A CN 202210035127 A CN202210035127 A CN 202210035127A CN 114367428 A CN114367428 A CN 114367428A
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CN
China
Prior art keywords
spraying
aluminum plate
parts
drying
water paint
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Pending
Application number
CN202210035127.1A
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Chinese (zh)
Inventor
蒋汉
蒋勇
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Hangzhou Jiayuan Environmental Protection Material Co ltd
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Hangzhou Jiayuan Environmental Protection Material Co ltd
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Publication date
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Priority to CN202210035127.1A priority Critical patent/CN114367428A/en
Publication of CN114367428A publication Critical patent/CN114367428A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B05D7/16Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using synthetic lacquers or varnishes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254After-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2202/00Metallic substrate
    • B05D2202/20Metallic substrate based on light metals
    • B05D2202/25Metallic substrate based on light metals based on Al
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • C08K3/042Graphene or derivatives, e.g. graphene oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • C08K7/26Silicon- containing compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a spraying process of a titanium porcelain water paint aluminum plate, belonging to the technical field of spraying, and the spraying process comprises the following steps: firstly, preprocessing, namely cleaning surface impurities of an aluminum plate to be sprayed, and polishing the surface of the aluminum plate by a polisher to improve the adsorption force of spraying; step two, preparing materials, wherein the spraying materials are titanium porcelain water paint and a curing agent in a weight ratio of 7: 3, stirring by an electric stirrer for more than 60min, standing for more than 30min after stirring, filtering the spraying material by a 200-wood filter screen before spraying, and standing for later use after filtering; spraying, namely spraying the surface of the aluminum plate by using a spray gun, wherein the caliber of the spray gun is 1-15mm, and the pressure is 4-5 kg; and step four, drying, namely after the spraying is finished, air-drying for 1-2 hours under a ventilation condition, and then drying in drying equipment.

Description

Spraying process of titanium porcelain water paint aluminum plate
Technical Field
The invention relates to the technical field of spraying, in particular to a spraying process of a titanium porcelain water paint aluminum plate.
Background
The paint is a continuous film which is coated on the surface of a protected or decorated object and can form firm adhesion with the object to be coated, and is a viscous liquid which is prepared by taking resin, oil or emulsion as a main material, adding or not adding pigments and fillers, adding corresponding auxiliary agents and using organic solvent or water. The paint is a material which can be coated on the surface of an object by different construction processes to form a continuous solid film with firm adhesion and certain strength. The film thus formed is generally called a coating film, also called a paint film or a coating. The early coating mostly uses vegetable oil as a main raw material, so the coating is called as 'paint', the traditional coating product using natural substances as raw materials or the coating product using synthetic chemical products as raw materials in modern development belong to organic chemical high polymer materials, and the formed coating film belongs to a high polymer compound type. According to the modern popular classification of chemical products, the coating belongs to fine chemical products.
The common coating is generally used for spraying the aluminum plate, and only can protect the aluminum plate to a certain extent, so that the wear resistance and corrosion resistance of the aluminum plate cannot be improved, and the hardness of the aluminum plate cannot be improved.
Disclosure of Invention
The technical problem to be solved by the invention is to provide a spraying process of a titanium porcelain water paint aluminum plate, which can improve the wear resistance and corrosion resistance of the aluminum plate.
In order to solve the technical problems, the technical scheme of the invention is as follows:
a spraying process of a titanium porcelain water paint aluminum plate comprises the following steps:
firstly, preprocessing, namely cleaning surface impurities of an aluminum plate to be sprayed, and polishing the surface of the aluminum plate by a polisher to improve the adsorption force of spraying;
step two, preparing materials, wherein the spraying materials are titanium porcelain water paint and a curing agent in a weight ratio of 7: 3, stirring by an electric stirrer for more than 60min, standing for more than 30min after stirring, filtering the spraying material by a 200-wood filter screen before spraying, and standing for later use after filtering;
spraying, namely spraying the surface of the aluminum plate by using a spray gun, wherein the caliber of the spray gun is 1-15mm, and the pressure is 4-5 kg;
and step four, drying, namely after the spraying is finished, air-drying for 1-2 hours under a ventilation condition, and then drying in drying equipment.
Preferably, the stirring time of the spray material is 60min, wherein the rotation speed of the electric stirrer is 1000 rpm at the initial 10min, and 400 rpm at the later 50 min.
Preferably, in the third step, the thickness of the sprayed material on the aluminum plate is 40UM-70UM, and after drying, the thickness of the sprayed material on the aluminum plate is 25UM-40 UM.
Preferably, in the fourth step, when the sprayed aluminum plate enters a drying device for drying, the temperature of the drying device is gradually increased from 80 ℃ to 150 ℃, the temperature increasing speed is 3.5 ℃ per minute, and the drying time is 20 minutes.
Preferably, the titanium porcelain water paint is prepared from the following raw materials in parts by weight: 10-12 parts of nano titanium dioxide, 12-17 parts of nano silicon dioxide, 5-10 parts of nano aluminum oxide, 2-5 parts of rare earth, 2-5 parts of graphene, 3-5 parts of a dispersing agent, 15-20 parts of an adhesive and 90-95 parts of deionized water.
Preferably, the binder is a silica sol or a resin.
By adopting the technical scheme, because the titanium porcelain water paint is sprayed on the aluminum plate, the wear resistance and the corrosion resistance of the aluminum plate can be improved, and the hardness of the sprayed aluminum plate is improved, so that the aluminum plate can obtain better performance, and meanwhile, the titanium porcelain water paint has non-toxic environmental protection property.
Detailed Description
The following further describes the embodiments of the present invention. It should be noted that the description of the embodiments is provided to help understanding of the present invention, but the present invention is not limited thereto. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
The spraying process comprises the following steps:
firstly, preprocessing, namely cleaning surface impurities of an aluminum plate to be sprayed, and polishing the surface of the aluminum plate by a polisher to improve the adsorption force of spraying;
step two, preparing materials, wherein the spraying materials are titanium porcelain water paint and a curing agent in a weight ratio of 7: 3, stirring by an electric stirrer for more than 60min, standing for more than 30min after stirring, filtering the spraying material by a 200-wood filter screen before spraying, and standing for later use after filtering;
spraying, namely spraying the surface of the aluminum plate by using a spray gun, wherein the caliber of the spray gun is 1-15mm, and the pressure is 4-5 kg;
drying, namely drying the sprayed coating for 1-2h under a ventilation condition, and then drying the sprayed coating in drying equipment;
the titanium porcelain water paint has the characteristics of environmental protection, has no emission of formaldehyde, toluene and heavy metals in the production, application and recovery processes, can resist the high temperature of 500-1200 ℃, has corrosion resistance, has super strong tolerance to salt fog and seawater due to a unique Si-O bond structure, has wide applicability, can be sprayed on copper, aluminum, pot paste, wood, plastic, glass fiber reinforced plastic, concrete, GRC and calcium silicate board glass, can directly express the texture of a base material, has the performance of normal temperature curing, has high hardness, has the hardness of 4-9H after being sprayed, is multiple times of that of the traditional paint, has excellent hydrophobic characteristic, is not easy to be stained with dust, can be cleaned after being washed by rainwater, is a semi-permanent material, has tolerance to environmental change and ultraviolet rays within a long time, is not easy to change color and pulverize, and has good antistatic performance, the adsorption of dust on the surface of the coating can be reduced, the self-cleaning performance is better, and the potential safety hazard caused by static electricity can be effectively reduced in the electronic industry and the petrochemical industry;
the stirring time of the spraying material is 60min, wherein the rotation speed of the electric stirrer in the initial 10min is 1000 revolutions per minute, and the rotation speed in the later 50min is 400 revolutions per minute;
in the third step, the thickness of the sprayed material on the aluminum plate is 40UM-70UM, and after drying, the thickness of the sprayed material on the aluminum plate is 25UM-40 UM;
in the fourth step, when the sprayed aluminum plate enters a drying device for drying, the temperature of the drying device is gradually increased from 80 ℃ to 150 ℃, the temperature increasing speed is 3.5 ℃ per minute, and the drying time is 20 minutes;
the titanium porcelain water paint is prepared from the following raw materials in parts by weight: 11 parts of nano titanium dioxide, 15 parts of nano silicon dioxide, 7 parts of nano aluminum oxide, 4 parts of rare earth, 3 parts of graphene, 4 parts of dispersing agent, 17 parts of adhesive and 93 parts of deionized water;
in the preparation process of the titanium porcelain water paint, 11 parts of nano titanium dioxide, 15 parts of nano silicon dioxide, 7 parts of nano aluminum oxide, 4 parts of rare earth, 3 parts of graphene and 93 parts of deionized water are mixed, first stirring is carried out after mixing, 17 parts of adhesive is added in the first stirring process, 4 parts of dispersant is added after the first stirring is finished, second stirring is carried out, and emulsion is formed after the stirring is finished, namely the titanium porcelain water paint;
wherein the adhesive is silica sol or resin;
in other embodiments of this embodiment, the titanium porcelain enamel is prepared from the following raw materials in parts by weight: 10 parts of nano titanium dioxide, 12 parts of nano silicon dioxide, 5 parts of nano aluminum oxide, 2 parts of rare earth, 2 parts of graphene, 3 parts of a dispersing agent, 15 parts of an adhesive and 90 parts of deionized water;
in the preparation process of the titanium porcelain water paint, 10 parts of nano titanium dioxide, 12 parts of nano silicon dioxide, 5 parts of nano aluminum oxide, 2 parts of rare earth, 2 parts of graphene and 90 parts of deionized water are mixed, first stirring is carried out after mixing, 15 parts of adhesive is added in the first stirring process, 3 parts of dispersant is added after the first stirring is finished, second stirring is carried out, and emulsion is formed after the stirring is finished, namely the titanium porcelain water paint;
wherein the adhesive is silica sol or resin;
in other embodiments of this example, the titanium porcelain enamel is prepared from the following raw materials in parts by weight: 12 parts of nano titanium dioxide, 17 parts of nano silicon dioxide, 10 parts of nano aluminum oxide, 5 parts of rare earth, 5 parts of graphene, 5 parts of dispersing agent, 20 parts of adhesive and 95 parts of deionized water;
in the preparation process of the titanium porcelain water paint, mixing 12 parts of nano titanium dioxide, 17 parts of nano silicon dioxide, 10 parts of nano aluminum oxide, 5 parts of rare earth, 5 parts of graphene and 95 parts of deionized water, stirring for the first time after mixing, adding 20 parts of adhesive in the first stirring process, adding 5 parts of dispersant after the first stirring is finished, stirring for the second time, and forming emulsion liquid which is the titanium porcelain water paint after the stirring is finished;
because the titanium porcelain water paint is sprayed on the aluminum plate, the wear resistance and the corrosion resistance of the aluminum plate can be improved, and the hardness of the sprayed aluminum plate is improved, so that the aluminum plate can obtain better performance, and meanwhile, the titanium porcelain water paint has non-toxic environmental protection property.
The embodiments of the present invention have been described in detail, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, and the scope of protection is still within the scope of the invention.

Claims (6)

1. The spraying process of the titanium porcelain water paint aluminum plate is characterized by comprising the following steps:
firstly, preprocessing, namely cleaning surface impurities of an aluminum plate to be sprayed, and polishing the surface of the aluminum plate by a polisher to improve the adsorption force of spraying;
step two, preparing materials, wherein the spraying materials are titanium porcelain water paint and a curing agent in a weight ratio of 7: 3, stirring by an electric stirrer for more than 60min, standing for more than 30min after stirring, filtering the spraying material by a 200-wood filter screen before spraying, and standing for later use after filtering;
spraying, namely spraying the surface of the aluminum plate by using a spray gun, wherein the caliber of the spray gun is 1-15mm, and the pressure is 4-5 kg;
and step four, drying, namely after the spraying is finished, air-drying for 1-2 hours under a ventilation condition, and then drying in drying equipment.
2. The spraying process of the titanium porcelain water paint aluminum plate as claimed in claim 1, which is characterized in that: the stirring time of the spraying material is 60min, wherein the rotation speed of the electric stirrer in the initial 10min is 1000 rpm, and the rotation speed in the later 50min is 400 rpm.
3. The spraying process of the titanium porcelain water paint aluminum plate as claimed in claim 1, which is characterized in that: in the third step, the thickness of the sprayed material on the aluminum plate is 40UM-70UM, and after drying, the thickness of the sprayed material on the aluminum plate is 25UM-40 UM.
4. The spraying process of the titanium porcelain water paint aluminum plate as claimed in claim 1, which is characterized in that: in the fourth step, when the sprayed aluminum plate enters the drying equipment for drying, the temperature of the drying equipment is gradually increased from 80 ℃ to 150 ℃, the temperature increasing speed is 3.5 ℃ per minute, and the drying time is 20 minutes.
5. The spraying process of the titanium porcelain water paint aluminum plate as claimed in claim 1, which is characterized in that: the titanium porcelain water paint is prepared from the following raw materials in parts by weight: 10-12 parts of nano titanium dioxide, 12-17 parts of nano silicon dioxide, 5-10 parts of nano aluminum oxide, 2-5 parts of rare earth, 2-5 parts of graphene, 3-5 parts of a dispersing agent, 15-20 parts of an adhesive and 90-95 parts of deionized water.
6. The spraying process of the titanium porcelain water paint aluminum plate as claimed in claim 5, wherein the spraying process comprises the following steps: the adhesive is silica sol or resin.
CN202210035127.1A 2022-01-13 2022-01-13 Spraying process of titanium porcelain water paint aluminum plate Pending CN114367428A (en)

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Application Number Priority Date Filing Date Title
CN202210035127.1A CN114367428A (en) 2022-01-13 2022-01-13 Spraying process of titanium porcelain water paint aluminum plate

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115109444A (en) * 2022-06-14 2022-09-27 中昊北方涂料工业研究设计院有限公司 Multi-color-changing irreversible temperature indicating coating and preparation method thereof
CN116145135A (en) * 2022-12-05 2023-05-23 广州三孚新材料科技股份有限公司 Aluminum alloy-inorganic titanium porcelain-graphene composite material and preparation method thereof

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CN209227886U (en) * 2018-10-12 2019-08-09 常州中赫新材料科技有限公司 A kind of aluminum veneer convenient for splicing for suspended ceiling
US20200317946A1 (en) * 2019-04-04 2020-10-08 King Fahd University Of Petroleum And Minerals Method of making uhmwpe hybrid nanocomposite coating reinforced with nanoclay and carbon nanotubes
CN112831252A (en) * 2021-01-29 2021-05-25 烟台万华新材料技术有限公司 Water-based high-temperature-resistant anticorrosive composition

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115109444A (en) * 2022-06-14 2022-09-27 中昊北方涂料工业研究设计院有限公司 Multi-color-changing irreversible temperature indicating coating and preparation method thereof
CN116145135A (en) * 2022-12-05 2023-05-23 广州三孚新材料科技股份有限公司 Aluminum alloy-inorganic titanium porcelain-graphene composite material and preparation method thereof

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Application publication date: 20220419