CN114231340A - 一种挤压润滑拉伸油及其制备方法 - Google Patents

一种挤压润滑拉伸油及其制备方法 Download PDF

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CN114231340A
CN114231340A CN202111519595.8A CN202111519595A CN114231340A CN 114231340 A CN114231340 A CN 114231340A CN 202111519595 A CN202111519595 A CN 202111519595A CN 114231340 A CN114231340 A CN 114231340A
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sulfurized
extrusion
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吴守敏
范成立
丁佳
张新红
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Francool Lubricating Technology Taicang Co ltd
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Abstract

本发明公开了一种挤压润滑拉伸油,包括以下重量百分比的组分:硫化脂肪酸甲酯含量1‑5%、硫化烯烃1‑5%、硫化猪油1‑3%、氯化脂肪5‑15%、磷酸酯胺盐0.3‑0.5%、聚异丁烯20‑30%、聚已丙烯增粘剂20‑30%、棕油5‑15%、余量为矿物型基础油。本发明还公开了一种挤压润滑拉伸油的制备方法。本发明相较于现有技术,可以保证拉伸液的冷却、润滑、渗透及清洗性能,利用添加剂的复配表面成膜技术,在工件表面迅速吸附成膜,减少设备与工件之间的直接摩擦,最大限度的提高极压润滑性能,延长设备的使用寿命,适用于不锈钢的中至重负荷加工工艺。

Description

一种挤压润滑拉伸油及其制备方法
技术领域
本发明属于钢材加工油领域,尤其涉及一种挤压润滑拉伸油及其制备方法。
背景技术
金属加工是机械工程中的一个重要分支,为了使工件得到所期望的几何形状、尺寸、精度和表面质量以及满足工件的硬度要求需要对材料进行切削加工、压力成型、热处理、清洗和防锈等一系列加工过程。金属加工挤压润滑就是金属加工过程中,所使用的润滑材料、冷却材料等,主要包括金属塑性加工润滑剂(包括金属锻造加工润滑剂、金属材料拉拔润滑剂等。随着科学技术的发展,润滑技术和润滑材料不断更新。采用先进的润滑技术和润滑材料,可使设备在苛刻条件下持久稳定的工作,同时能提高机械效率与产品合格率,减少维修与停工损耗,节约能源、减少材料损耗与提高综合经济效益。
在金属加工时,与普通碳钢相比,不锈钢在同样硬度条件下,它的延展率要大得多,也就是人们所说的“发粘”,同时不锈钢的密度比碳钢要大,拉伸需要的功耗大,产生的热量大,形成的温度高,容易损坏设备。
由于不锈钢的拉伸加工性较差,对加工液的冷却、润滑、渗透及清洗性能有更高的要求,常用的加工液有以下几类:乳化液、硫化油和机油、锭子油等矿物油。目前的这些常规切削液都是单一的满足不锈钢的某一道加工工艺,如常见的冷却介质——乳化液,具有较好的冷却、清洗、润滑性能,常用于不锈钢粗车:加工过程中能在金属表面形成高熔点硫化物的硫化油,硫化油在高温下不易破坏,具有良好的润滑作用,并有一定的冷却效果,一般用于钻孔,铰孔及攻丝;润滑性能较好的机油、锭子油等矿物油,但冷却和渗透性较差,适用于外圆精车。
针对不锈钢的拉伸性差、加工中易断刀粘刀等状况,现有加工液的挤压性、润滑性和油膜粘附性不能满足要求。
发明内容
本发明的目的在于:提供一种挤压润滑拉伸油及其制备方法,具有超强的挤压性、润滑性和油膜粘附性,适用于大型不锈钢板材、棒材、管材的极高难度拉伸成型加工工艺。
为了实现上述目的,一方面,本发明提供了一种挤压润滑拉伸油,包括以下重量百分比的组分:
Figure BDA0003408140660000021
作为上述技术方案的进一步描述:
包括以下重量百分比的组分:硫化脂肪酸甲酯含量1.5-2.5%、硫化烯烃1.5-2.5%、硫化猪油2-3%、氯化脂肪8-15%、磷酸酯胺盐0.3-0.5%、聚异丁烯20-30%、聚已丙烯增粘剂20-30%、棕油5-15%、余量为矿物型基础油。
作为上述技术方案的进一步描述:
包括以下重量百分比的组分:硫化脂肪酸甲酯1-3%、硫化烯烃2-3%、硫化猪油1-2%、氯化脂肪5-10%、磷酸酯胺盐0.3-0.5%、聚异丁烯25%、聚已丙烯增粘剂20%、棕油5-15%、余量为矿物型基础油。
作为上述技术方案的进一步描述:
矿物型基础油为加氢矿物油。
作为上述技术方案的进一步描述:
硫化烯烃为硫化烯烃GS440。
作为上述技术方案的进一步描述:
硫化脂肪酸甲酯为硫化脂肪酸甲酯RC6073。
作为上述技术方案的进一步描述:
磷酸酯胺盐为KING化学公司的AW6110磷酸酯胺盐。
作为上述技术方案的进一步描述:
棕油为10#棕油,棕油在组分中的添加比例为10%。
另一方面,本发明还提供了一种挤压润滑拉伸油的制备方法,包括以下步骤:
S1、根据上述的配比,准备挤压润滑拉伸油的制备材料;
S2、将聚异丁烯、聚已丙烯增粘剂按照比例同时加入到矿物油中,升温至100℃,反应4小时;
S3、继续升温至150℃,依次按比例加入剩余组分,继续反应2小时,降温检测。
综上所述,由于采用了上述技术方案,本发明的有益效果是:
1、本发明中,挤压润滑拉伸油的组分中含有氯化脂肪和硫化脂肪等挤压添加剂,具有超强的挤压性、润滑性和油膜粘附性,可以保证拉伸油的冷却、挤压润滑、渗透及清洗性能,利用添加剂的复配表面成膜技术,在工件表面迅速吸附成膜,减少刀具与工件之间的直接摩擦,最大限度的提高极压润滑性能,延长刀具的使用寿命,适用于不锈钢的冲压、压延、拉伸、攻牙等高难度的加工工艺。
2、本发明中,为了保证挤压润滑拉伸油的挤压润滑性能,其组分中下列产品的添加比例为:硫化脂肪酸甲酯含量1.5-2.5%、硫化烯烃1.5-2.5%、硫化猪油2-3%、氯化脂肪8-15%、磷酸酯胺盐0.3-0.5%。
3、本发明中,为了保证挤压润滑拉伸油的油品流动性能、减少机械设备磨损程度,其组分中下列产品的添加比例为:聚异丁烯20-30%、聚已丙烯增粘剂20-30%。
4、本发明中,为了保证挤压润滑拉伸油的节能降本、减排环保,其组分中下列产品的添加比例为:硫化脂肪酸甲酯1-3%、硫化烯烃2-3%、硫化猪油1-2%、氯化脂肪5-10%、磷酸酯胺盐0.3-0.5%、聚异丁烯25%、聚已丙烯增粘剂20%。
5、本发明中,为了实现挤压润滑拉伸油的典型值性能最优及降本,10#棕油的添加比例为10%。
具体实施方式
下面将更详细地描述本公开的示例性实施例。虽然显示了本公开的示例性实施例,然而应当理解,可以以各种形式实现本公开而不应被这里阐述的实施例所限制。相反,提供这些实施例是为了能够更透彻地理解本公开,并且能够将本公开的范围完整的传达给本领域的技术人员。
实施例一:
取包括以下重量百分比组分的挤压润滑拉伸油的制备材料:
硫化脂肪酸甲酯:1.5%、硫化烯烃GS4401.5%、硫化猪油2%、氯化石蜡8%、10#棕油:10%、磷酸酯胺盐0.3%、聚异丁烯20%、聚乙丙烯增粘剂25%、矿物型基础油28.7%。
先将聚异丁烯、聚已丙烯增粘剂按照比例同时加入到矿物油中,升温至100℃,反应4小时;然后继续升温至150℃,依次按比例加入剩余组分,继续反应2小时,降温检测。
实施例二:
取包括以下重量百分比组分的挤压润滑拉伸油的制备材料:
硫化脂肪酸甲酯:1.5%、硫化烯烃GS4401.5%、硫化猪油2%、氯化石蜡9%、10#棕油:10%、磷酸酯胺盐0.3%、聚异丁烯20%、聚乙丙烯增粘剂25%、矿物型基础油28.7%。
制备方法同实施例一。
实施例三:
取包括以下重量百分比组分的挤压润滑拉伸油的制备材料:
硫化脂肪酸甲酯:1.5%、硫化烯烃GS4401.5%、硫化猪油2%、氯化石蜡9%、10#棕油:10%、磷酸酯胺盐0.5%、聚异丁烯20%、聚乙丙烯增粘剂25%、矿物型基础油28.7%。
制备方法同实施例一。
实施例四:
取包括以下重量百分比组分的挤压润滑拉伸油的制备材料:
硫化脂肪酸甲酯:1.5%、硫化烯烃GS4402%、硫化猪油2%、氯化石蜡10%、10#棕油:10%、磷酸酯胺盐0.3%、聚异丁烯20%、聚乙丙烯增粘剂25%、矿物型基础油28.7%。
制备方法同实施例一。
实施例五:
取包括以下重量百分比组分的挤压润滑拉伸油的制备材料:
硫化脂肪酸甲酯:2.0%、硫化烯烃GS4401.5%、硫化猪油2%、氯化石蜡10%、10#棕油:10%、磷酸酯胺盐0.3%、聚异丁烯20%、聚乙丙烯增粘剂25%、矿物型基础油28.7%。
制备方法同实施例一。
实施例六:
取包括以下重量百分比组分的挤压润滑拉伸油的制备材料:
硫化脂肪酸甲酯:2%、硫化烯烃GS4402%、硫化猪油2%、氯化石蜡10%、10#棕油:10%、磷酸酯胺盐0.3%、聚异丁烯20%、聚乙丙烯增粘剂25%、矿物型基础油28.7%;
制备方法同实施例一。
现有技术
硫化烯烃GS4402%,脂肪酸酯5%,硬脂酸异辛酯3%,磷酸酯胺盐0.3%,自主合成酯8%,季戊四醇油酸酯3%,基础油78.7%;
本实施例1-6与对比例的实验数据对比如下表所示:
Figure BDA0003408140660000061
Figure BDA0003408140660000071
注:Pb值反应挤压性能,其数值越大说明挤压性能越好,磨斑直径为常磨润滑性,其数值越小说明润滑性能越好。
根据上述对比,可以看出,实施例1-6相较于对比例(现有技术)在PB值和磨斑直径上皆获得了提高,从而使得本实施例1-6在拉伸中提供了优秀的挤压润滑性能,减少了设备的磨损。
同时,实施例1-6相较于对比例(现有技术)在成本上获得了降低。
挤压润滑拉伸油的组分中含有氯化脂肪和硫化脂肪等挤压添加剂,具有超强的挤压性、润滑性和油膜粘附性,可以保证拉伸油的冷却、挤压润滑、渗透及清洗性能,利用添加剂的复配表面成膜技术,在工件表面迅速吸附成膜,减少刀具与工件之间的直接摩擦,最大限度的提高极压润滑性能,延长刀具的使用寿命,适用于不锈钢的冲压、压延、拉伸、攻牙等高难度的加工工艺。
因而,本实施例提供的一种不锈钢挤压润滑拉伸油及其制备方法相较于现有技术具有以下优点:
1)满足不锈钢金属的冲压、压延、拉伸、攻牙等工艺;
2)在不锈钢加工过程中,优异的润滑性能保证工作的质量效率;
3)通过自主吸附成膜技术,提高润滑性能,减少设备的磨损,降低成本。
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。

Claims (9)

1.一种挤压润滑拉伸油,其特征在于,包括以下重量百分比的组分:
Figure FDA0003408140650000011
2.根据权利要求1所述的一种挤压润滑拉伸油,其特征在于,包括以下重量百分比的组分:硫化脂肪酸甲酯含量1.5-2.5%、硫化烯烃1.5-2.5%、硫化猪油2-3%、氯化脂肪8-15%、磷酸酯胺盐0.3-0.5%、聚异丁烯20-30%、聚已丙烯增粘剂20-30%、棕油5-15%、余量为矿物型基础油。
3.根据权利要求1所述的一种挤压润滑拉伸油,其特征在于,包括以下重量百分比的组分:硫化脂肪酸甲酯1-3%、硫化烯烃2-3%、硫化猪油1-2%、氯化脂肪5-10%、磷酸酯胺盐0.3-0.5%、聚异丁烯25%、聚已丙烯增粘剂20%、棕油5-15%、余量为矿物型基础油。
4.根据权利要求1-3任一所述的一种挤压润滑拉伸油,其特征在于,所述矿物型基础油为加氢矿物油。
5.根据权利要求1-3任一所述的一种挤压润滑拉伸油,其特征在于,所述硫化烯烃为硫化烯烃GS440。
6.根据权利要求1-3任一所述的一种挤压润滑拉伸油,其特征在于,所述硫化脂肪酸甲酯为硫化脂肪酸甲酯RC6073。
7.根据权利要求1-3任一所述的一种挤压润滑拉伸油,其特征在于,所述磷酸酯胺盐为KING化学公司的AW6110磷酸酯胺盐。
8.根据权利要求1-3任一所述的一种挤压润滑拉伸油,其特征在于,所述棕油为10#棕油,所述棕油在组分中的添加比例为10%。
9.一种挤压润滑拉伸油的制备方法,其特征在于,包括以下步骤:
S1、根据权利要求1-8任一所述的配比,准备挤压润滑拉伸油的制备材料;
S2、将聚异丁烯、聚已丙烯增粘剂按照比例同时加入到矿物油中,升温至100℃,反应4小时;
S3、继续升温至150℃,依次按比例加入剩余组分,继续反应2小时,降温检测。
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