CN114207031A - 一种生物降解树脂及其制备的薄膜 - Google Patents

一种生物降解树脂及其制备的薄膜 Download PDF

Info

Publication number
CN114207031A
CN114207031A CN202180004770.1A CN202180004770A CN114207031A CN 114207031 A CN114207031 A CN 114207031A CN 202180004770 A CN202180004770 A CN 202180004770A CN 114207031 A CN114207031 A CN 114207031A
Authority
CN
China
Prior art keywords
biodegradable resin
acid
anhydride
resin film
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202180004770.1A
Other languages
English (en)
Other versions
CN114207031B (zh
Inventor
桂宗彦
王儒旭
王珂
荒井崇
真锅功
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Advanced Materials Research Laboratories China Co Ltd
Original Assignee
Toray Advanced Materials Research Laboratories China Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Advanced Materials Research Laboratories China Co Ltd filed Critical Toray Advanced Materials Research Laboratories China Co Ltd
Publication of CN114207031A publication Critical patent/CN114207031A/zh
Application granted granted Critical
Publication of CN114207031B publication Critical patent/CN114207031B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/25Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/255Polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/40Applications of laminates for particular packaging purposes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/46Applications of disintegrable, dissolvable or edible materials
    • B65D65/466Bio- or photodegradable packaging materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/092Polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/15Heterocyclic compounds having oxygen in the ring
    • C08K5/151Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1545Six-membered rings
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29Laminated material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/04Polyesters derived from hydroxy carboxylic acids, e.g. lactones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/04Polyesters derived from hydroxy carboxylic acids, e.g. lactones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00Presence of polyester
    • C09J2467/006Presence of polyester in the substrate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Adhesive Tapes (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Wrappers (AREA)

Abstract

提供一种生物降解树脂,具有1.0dL/g以上的特性粘数,且经70℃、85%RH、6hr处理后,特性粘数损失率为10%以上。还提供一种生物降解树脂,含有70重量%以上的聚乳酸,且根据ASTM D5338‑15规定的条件,进行28℃家庭堆肥降解性评价时,在12个月内相对生物降解率达到90%以上。所述的生物降解树脂,兼备生物降解速度快和储存稳定的特点,且力学性能、光学性能、阻隔性能良好,可以适用于包括包装、快递运输等多方面,在使用寿命完成后,会快速生物降解为二氧化碳、水等小分子,不污染环境。还提供使用所述生物降解树脂的生物降解树脂薄膜及其制品,以及含有生物降解树脂薄膜的多层薄膜及其制品。

Description

PCT国内申请,说明书已公开。

Claims (40)

  1. PCT国内申请,权利要求书已公开。
CN202180004770.1A 2020-03-19 2021-03-19 一种生物降解树脂及其制备的薄膜 Active CN114207031B (zh)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
CN2020102000497 2020-03-19
CN202010199536 2020-03-19
CN202010200049 2020-03-19
CN2020101995366 2020-03-19
CN202011293825 2020-11-18
CN2020112970292 2020-11-18
CN202011297029 2020-11-18
CN2020112938259 2020-11-18
PCT/CN2021/081672 WO2021185339A1 (zh) 2020-03-19 2021-03-19 一种生物降解树脂及其制备的薄膜

Publications (2)

Publication Number Publication Date
CN114207031A true CN114207031A (zh) 2022-03-18
CN114207031B CN114207031B (zh) 2024-03-29

Family

ID=77769174

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202180004770.1A Active CN114207031B (zh) 2020-03-19 2021-03-19 一种生物降解树脂及其制备的薄膜

Country Status (6)

Country Link
US (1) US20230193021A1 (zh)
JP (1) JP2023524347A (zh)
CN (1) CN114207031B (zh)
CA (1) CA3172825A1 (zh)
MX (1) MX2022009337A (zh)
WO (1) WO2021185339A1 (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3231888A1 (en) * 2021-09-15 2023-03-23 Carol G. Leggett Biodegradable insect trap
CN115058065B (zh) * 2022-06-30 2023-07-11 万华化学集团股份有限公司 具有光氧降解剂缓释效果的改性填料及制备方法和降解速率可控的pbat地膜
WO2024049930A1 (en) 2022-08-31 2024-03-07 Toray Plastics (America), Inc. Biaxially oriented biodegradable composite film

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1771281A (zh) * 2003-05-27 2006-05-10 旭化成生活制品株式会社 可生物降解的树脂膜或片及其制造方法
CN1898294A (zh) * 2003-12-18 2007-01-17 伊斯曼化学公司 具有改善的热性能的高透明性薄膜
US20070254118A1 (en) * 2006-04-27 2007-11-01 Slawomir Opusko Multilayer film comprising polylactic acid
CN101362853A (zh) * 2008-09-12 2009-02-11 浙江海正生物材料股份有限公司 一种低成本全生物降解聚乳酸片材及其制备方法
CN101372550A (zh) * 2008-09-27 2009-02-25 浙江海正生物材料股份有限公司 一种耐水解聚乳酸复合材料
CN102731976A (zh) * 2011-04-12 2012-10-17 东丽纤维研究所(中国)有限公司 一种聚酯组合物及其制成的薄膜
US20130004760A1 (en) * 2011-07-01 2013-01-03 Salvatore Pellingra Biodegradable moisture barrier film
CN109897352A (zh) * 2017-12-09 2019-06-18 宿迁博古科技有限公司 一种可生物降解的环境友好型建筑支模材料及其制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7098292B2 (en) * 2003-05-08 2006-08-29 The Procter & Gamble Company Molded or extruded articles comprising polyhydroxyalkanoate copolymer and an environmentally degradable thermoplastic polymer
EP3424990B1 (en) * 2012-06-05 2021-05-05 CJ CheilJedang Corporation Biodegradable polymer blends
CN105602215B (zh) * 2016-01-26 2018-11-16 深圳市绿自然生物降解科技有限公司 一种生物降解耐热片材及其制备方法
CN110591309B (zh) * 2019-08-31 2022-07-01 佛山碧嘉高新材料科技有限公司 一种可生物降解的发泡塑料复合材料及其制备方法与应用
CN110540741A (zh) * 2019-09-23 2019-12-06 济南圣泉集团股份有限公司 一种可降解复合材料及其制备方法和应用

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1771281A (zh) * 2003-05-27 2006-05-10 旭化成生活制品株式会社 可生物降解的树脂膜或片及其制造方法
CN1898294A (zh) * 2003-12-18 2007-01-17 伊斯曼化学公司 具有改善的热性能的高透明性薄膜
US20070254118A1 (en) * 2006-04-27 2007-11-01 Slawomir Opusko Multilayer film comprising polylactic acid
CN101362853A (zh) * 2008-09-12 2009-02-11 浙江海正生物材料股份有限公司 一种低成本全生物降解聚乳酸片材及其制备方法
CN101372550A (zh) * 2008-09-27 2009-02-25 浙江海正生物材料股份有限公司 一种耐水解聚乳酸复合材料
CN102731976A (zh) * 2011-04-12 2012-10-17 东丽纤维研究所(中国)有限公司 一种聚酯组合物及其制成的薄膜
US20130004760A1 (en) * 2011-07-01 2013-01-03 Salvatore Pellingra Biodegradable moisture barrier film
CN109897352A (zh) * 2017-12-09 2019-06-18 宿迁博古科技有限公司 一种可生物降解的环境友好型建筑支模材料及其制备方法

Also Published As

Publication number Publication date
US20230193021A1 (en) 2023-06-22
WO2021185339A1 (zh) 2021-09-23
CN114207031B (zh) 2024-03-29
CA3172825A1 (en) 2021-09-23
MX2022009337A (es) 2022-08-18
JP2023524347A (ja) 2023-06-12

Similar Documents

Publication Publication Date Title
CN114207031B (zh) 一种生物降解树脂及其制备的薄膜
EP1188781B1 (en) Impact modifier and polyester composition containing the modifier
EP3122817B1 (en) Highly filled polymer systems
EP3004225A1 (en) Recyclate blends
EP1947145A2 (en) Mixtures of biodegradable polyesters and products manufactured from them
JP6008860B2 (ja) ジアンヒドロヘキシトールのアルキルエステルによる脂肪族ポリエステルの可塑化
KR101651319B1 (ko) 높은 변형성을 갖는 생분해성 중합체 조성물
CN102993654A (zh) 一种生物降解阻隔性薄膜及其制备方法和应用
US20160311203A1 (en) Polymer mixture for barrier film
CN110446754B (zh) 能够生物降解的薄膜
JP2006299133A (ja) 共重合体を含む乳酸系樹脂組成物、およびその成形体
KR101288445B1 (ko) 내열성이 우수한 생분해성 수지 조성물 및 이를 포함하는 생분해성 성형용기
JP2005280361A (ja) 成形体の製造方法
JP5213294B2 (ja) ポリグリコール酸系樹脂組成物
JP2007284595A (ja) 脂肪族ポリエステルフィルム
JP4693254B2 (ja) グリコール酸系樹脂組成物
JP3953773B2 (ja) 生分解性複合シート及びそれを用いた成形体
CN113493599A (zh) 一种取向薄膜及含有该取向薄膜的多层薄膜
CN116178916A (zh) 生物降解薄膜及包装材料、胶带
US20220033645A1 (en) Method for preparing a (co)polyester
JP2006274256A (ja) 低分岐度高分子量脂肪族ポリエステル樹脂組成物、成形品及びフィルム
CN116178915A (zh) 生物降解薄膜及包装材料、胶带
CN116178917A (zh) 生物降解薄膜及包装材料、胶带
CN116176088A (zh) 生物降解薄膜及包装材料、胶带
JP2006111744A (ja) 樹脂組成物

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant