CN113913994A - Elastic wool fabric of functional polyester composite filament and preparation method thereof - Google Patents

Elastic wool fabric of functional polyester composite filament and preparation method thereof Download PDF

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Publication number
CN113913994A
CN113913994A CN202111318568.4A CN202111318568A CN113913994A CN 113913994 A CN113913994 A CN 113913994A CN 202111318568 A CN202111318568 A CN 202111318568A CN 113913994 A CN113913994 A CN 113913994A
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China
Prior art keywords
wool
composite
filament
pet
pbt
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Application number
CN202111318568.4A
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Chinese (zh)
Inventor
刘伟
肖红
姜爱娟
代国亮
杨辰辉
陈敏
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Jiangsu Jianlu Worsted Co ltd
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Jiangsu Jianlu Worsted Co ltd
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Priority to CN202111318568.4A priority Critical patent/CN113913994A/en
Publication of CN113913994A publication Critical patent/CN113913994A/en
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    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/233Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads protein-based, e.g. wool or silk
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/292Conjugate, i.e. bi- or multicomponent, fibres or filaments
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/533Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/56Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads elastic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00Protein-based fibres, e.g. animal fibres
    • D10B2211/01Natural animal fibres, e.g. keratin fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Woven Fabrics (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

The invention discloses an elastic wool fabric of functional polyester composite filament and a preparation method thereof, wherein PET/PBT elastic polyester filament compounded by PET polyester and PBT polyester or filament compounded by functional PET filament and elastic PBT filament through texturing on a composite texturing machine and composite yarn formed by wool or wool blended spun yarn in the modes of doubling, Sirofil, core-spun and the like are taken as weft yarn, and the PET/PBT composite filament is dope-colored or white self-crimping filament; the wool fabric has 5-40% of stretching elasticity in the weft direction. The invention can provide the wool fabric with lasting elasticity and controllable elasticity and respectively having the functions of antibiosis, permeation prevention, static resistance, quick drying and the like, solves the problem that the existing wool fabric cannot give consideration to both the functions and the elasticity, and realizes a plurality of functional wool elastic fabrics with excellent composite performance and high cost performance.

Description

Elastic wool fabric of functional polyester composite filament and preparation method thereof
Technical Field
The invention relates to the technical field of novel textile materials, in particular to an elastic wool fabric of functional polyester composite filaments and a preparation method thereof.
Background
The elasticity achieved by wool fabrics is usually achieved by covering the elastic fibers with wool (or wool blend) yarns, such as spandex (e.g., Lycra), polyolefins (e.g., XLA fibers from DOW corporation), to form core yarns. The disadvantages of this type of elastic fiber application are: the bare yarn can not be applied, and the bare yarn is required to be coated by other fibers as a core yarn, so that the utility value is realized; the processing can be carried out only by special core-spun yarn equipment, the processing flow is long, and the elasticity is difficult to control uniformly; meanwhile, the elastic fabric has the defects of easy relaxation and poor chemical stability when repeatedly used for many times. After being colored by stock solution, the common polyester composite elastic filaments needing high-temperature and high-pressure dyeing can realize relatively lasting elasticity by means of ingenious organizational structure design, for example, patent ZL2007 patent polyester composite filament parallel linear latitudinal elastic wool fabric and preparation method thereof, patent ZL2007 patent polyester composite filament inter-latitudinal elastic wool fabric and preparation method thereof, and a method for realizing wool fabric elasticity by adopting PET/PTT polyester composite filaments is provided. However, it is clear that because PET/PTT requires high temperature and high pressure dyeing, and cannot piece-dye wool fibers, dope dyed filaments are required to achieve the elasticity of wool fabrics. The problems that the color light of wool fibers is difficult to coordinate, the fabric is easy to have flash and different colors, and the like exist.
Various excellent properties are the trend of future development of wool fabrics. On the basis of meeting the requirement of rich colors, the fabric has comfortable elasticity and also has functionality such as antibiosis, antistatic or anti-penetration. On the basis of elastic realization, certain functions such as antibiosis, penetration prevention, static resistance, moisture absorption and quick drying are added to the wool fabric through after-finishing. The function obtained by the afterfinish is difficult to persist on the one hand and can have an effect on other properties on the other hand.
Therefore, we propose an elastic wool fabric of functional polyester composite filaments and a method for preparing the same to solve the above problems.
Disclosure of Invention
The invention aims to provide an elastic wool fabric of functional polyester composite filaments and a preparation method thereof, which realize controllable elasticity of the wool fabric and have various functions and meet the increasing personalized clothing requirements of consumers.
In order to achieve the purpose, the invention provides the following technical scheme: a preparation method of an elastic wool fabric of functional polyester composite filaments comprises the following steps:
s1: selecting PET and PBT polyester composite filaments: respectively putting PET slices with the viscosity of 0.4-0.8dl/g and PBT slices with the viscosity of 0.8-1.4dl/g into corresponding different melting box bodies, mixing functional master batches into the corresponding melting box bodies, conveying the mixture to a spinneret plate through respective spinning channels, extruding the mixture in parallel to obtain composite white yarns and wool or wool blended spun yarns, wherein the composite ratio is 30/70-70/30;
s2: selecting functional master batches or functional PET filaments with special-shaped sections and elastic PBT filaments which are added in the spinning process, and forming the functional PET/PBT elasticated composite elastic filaments on an elasticated composite machine through elasticated composite; the fineness ratio of the PET filaments to the PBT filaments is 2: 8-8: 2;
s3: spinning: single or multiple roots of the composite white filaments in S1 or S2; or blending the wool or the wool with the spun yarn, spinning by Sirofil, doubling, core-spun and the like; obtaining single filament yarn or filament composite short fiber yarn containing wool, twisting to obtain yarn, wherein the twist coefficient is controlled at 135-150;
s4: weaving: weaving with yarns obtained from S3 as warp yarns or weft yarns; or common wool or wool blended yarns are used as warp yarns, the composite white yarns obtained in S1 or S2 are used as one of weft yarns, and the composite white yarns and the warp yarns are woven in at intervals;
s5: dyeing and finishing; presetting at 160-180 ℃, and controlling the fabric width to be not less than 152 cm; then continuous boiling is carried out for not less than 20min at the temperature of not less than 40 ℃ and the speed of not less than 200 r/min; (ii) a Decating pressure is not less than 0.6g, and cooling time is not less than 90 s.
Preferably, the functional master batch comprises an antibacterial master batch, an antistatic master batch, a penetration-proof master batch and a quick-drying master batch. In practice, according to different functions, functional master batches with different contents are added into different components. For the antibacterial function, no more than 3% of antibacterial master batch can be added into the two components respectively; for the antistatic function, the antistatic master batch can be added or not added in the modified polyester; for the anti-penetration function, no more than 5 percent of anti-penetration master batch can be added into the PBT component; for the moisture absorption and quick drying function, no more than 5 percent of quick drying master batch can be added into the PBT component.
Preferably, the fineness of the PET and PBT polyester composite filament is within the range of 33dtex-330dtex, and the strength is not lower than 2.2 cN/dtex.
Preferably, the ratio of the composite white silk and wool or wool blended spun yarn in S3 is 80/20-10/90.
Preferably, the weaving ratio in S4 is 1: 5-5: 1, the proportion range of the woven upper machine width to the finished product width is 1.1-1.5.
Preferably, the ratio of the pre-set web to the finished web in S5 ranges from 1.02 to 1.2.
Preferably, in S5, a two-step one-bath method can be adopted, wherein polyester is dyed by using disperse dyes, and wool is dyed by using acid dyes.
Preferably, the decating process in S5 needs to be performed at a setting temperature of 160 ℃.
The invention also discloses piece-dyed elastic wool fabric of the functional polyester composite filament, which comprises white grey cloth formed by weaving composite yarn formed by doubling and twisting the functional PET and PBT polyester composite filament and wool or wool blended spun yarn as warp yarn or weft yarn.
Compared with the prior art, the invention has the beneficial effects that:
the invention can provide the wool fabric which has lasting elasticity and controllable elasticity, can be piece-dyed, and has the functions of antibiosis, anti-penetration, antistatic, quick drying and the like respectively, solves the problem that the existing wool fabric has difficulty in taking the functions and elasticity into consideration, and realizes a plurality of functional wool elastic fabrics with excellent composite performance and high cost performance.
Detailed Description
The technical solutions in the present invention will be described clearly and completely with reference to the following embodiments of the present invention, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the invention provides a technical scheme that: a preparation method of an elastic wool fabric of functional polyester composite filaments comprises the following steps:
(1) preparing a composite polyester filament: obtaining composite white yarns with the fineness of 65D by adopting polyethylene terephthalate (PET) and polytrimethylene terephthalate (PTT) according to the composite proportion of 60/40 through a composite spinning technology; or respectively adding PET-based master batch and PTT-based master batch in the spinning process to obtain the composite yarn with the same fineness range and the same dope coloring;
(2) weft yarn forming mode: doubling the composite white silk or the composite silk colored by the stock solution in the step (1) and 80Nm/2 wool/polyester 50/50 blended spun yarn with the twist of 790Z/m on a doubling machine, and twisting to obtain doubled yarn with the twist of 980S twist/m; the yarn doubling tension of the wool yarn is controlled to be 5.96g, the yarn doubling tension of the filament yarn is controlled to be 2.32g, and the composite white yarn or the composite yarn is in a state of being straightened and not extending so as to prevent the small plait yarn from appearing. The ratio of the fineness of the composite white yarn or the composite yarn to the fineness of the wool or wool blended yarn is 1.8, and the ratio of the composite white yarn or the composite yarn/wool or wool blended yarn formed after doubling is 60/40.
(3) Weaving mode: weaving by using common wool yarns or wool blended yarns with single yarn twist of 790Z twist/m and strand twist of 980S twist/m and 80Nm/2 as warp yarns and using the doubled yarns obtained in the step 2) as weft yarns. In the weaving process, the weft yarns are woven by matching large and small bobbins by adopting at least two weft accumulators. The warp and weft density of the grey cloth is 480 multiplied by 340 pieces/10 cm.
(4) A finishing procedure: after singeing, a continuous boiling procedure is adopted, and the fabric passes through a high-temperature continuous boiling groove with the temperature of 80-110 ℃ at the speed of 25m/min on continuous boiling equipment, or the fabric width is effectively shrunk under the high-temperature and wet state with the temperature of 80 ℃ on single-double boiling equipment. Enabling the width of the fabric to shrink to 162cm, continuing effective width shrinkage in the subsequent wet finishing process, and tentering for 1-2cm during setting; if the door is not continuously cooked, the door width is reduced to about 155cm mainly by setting. Finally, the width of the finished product reaches 150cm after the decating process. The warp and weft density of the finished product is 512 multiplied by 376 pieces/10 cm. The weft stretching elasticity of the five two fly-warp surface satins is within 20 percent.
(5) And (3) functional detection: firstly, the charge surface density of the antistatic function is not more than 7.0uC/m2 after 10 times of washing, and the standard is implemented (GB/T12703.2-2009); the bacteriostasis rate of the antibacterial function to staphylococcus aureus and escherichia coli is more than or equal to 70 percent, the bacteriostasis rate to candida albicans is more than or equal to 60 percent, and the execution standard is GB/T20944.3-2008; thirdly, the water absorption rate of the moisture absorption and sweat releasing functions is more than or equal to 100 percent, and the execution standard (GB/T216555.1-2008) is adopted; air permeability is more than or equal to 115mm/s, and the execution standard [ GB/T5453-1997 ] and the like.
Example two:
the invention provides a technical scheme that: a preparation method of an elastic wool fabric of functional polyester composite filaments comprises the following steps:
selecting PET and PBT polyester composite filaments: the PET chips are cut into pieces, the viscosity is 0.8dl/g, the fineness of the PET and PBT polyester composite filament is in the range of 330dtex, and the strength is 2.2 cN/dtex. And (2) slicing PBT (polybutylene terephthalate) with the viscosity of 1.4dl/g, respectively putting the PBT slices into corresponding different melting boxes, and mixing functional master batches into the corresponding melting boxes, wherein the functional master batches comprise antibacterial master batches, antistatic master batches, penetration-proof master batches and quick-drying master batches. Extruding the mixture to a spinneret plate through respective spinning channels in parallel to obtain composite white yarn and wool or wool blended spun yarn, wherein the composite ratio is 70/30;
selecting functional master batches or functional PET filaments with special-shaped sections and elastic PBT filaments which are added in the spinning process, and forming the functional PET/PBT elasticated composite elastic filaments on an elasticated composite machine through elasticated composite; the fineness ratio of the PET filaments to the PBT filaments is 8:2;
spinning: the composite white silk is single or multiple; or blending the wool or the wool with the spun yarn, spinning by Sirofil, doubling, core-spun and the like; obtaining single filament yarn or filament composite short fiber yarn containing wool, twisting to obtain yarn, and controlling the twist coefficient at 150;
weaving: weaving by using the yarns as warp yarns or weft yarns; or common wool or wool blended yarns are used as warp yarns, the composite white yarns obtained in S1 or S2 are used as one of weft yarns, and the composite white yarns and the warp yarns are woven in at intervals;
dyeing and finishing; presetting at 180 ℃, and controlling the fabric width at 152 cm; continuously boiling at 40 deg.C and 200r/min for 20 min; (ii) a Decating pressure 0.6g, and cooling time 90 s.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (7)

1. A preparation method of an elastic wool fabric of functional polyester composite filaments is characterized by comprising the following steps:
s1: selecting PET and PBT polyester composite filaments: respectively putting PET slices with the viscosity of 0.4-0.8dl/g and PBT slices with the viscosity of 0.8-1.4dl/g into corresponding different melting box bodies, mixing functional master batches into the corresponding melting box bodies, conveying the mixture to a spinneret plate through respective spinning channels, extruding the mixture in parallel to obtain composite white yarns and wool or wool blended spun yarns, wherein the composite ratio is 30/70-70/30;
s2, selecting functional master batches or functional PET filaments with special-shaped cross sections and elastic PBT filaments in the spinning process, and forming the functional PET/PBT elastic composite filaments by elastic composite on an elastic composite machine; the fineness ratio of the PET filaments to the PBT filaments is 2: 8-8: 2;
s3: spinning: single or multiple roots of the composite white filaments in S1 or S2; or blending the wool or the wool with the spun yarn, spinning by Sirofil, doubling, core-spun and the like; obtaining single filament yarn or filament composite short fiber yarn containing wool, twisting to obtain yarn, wherein the twist coefficient is controlled at 135-150;
s4: weaving: weaving with yarns obtained from S3 as warp yarns or weft yarns; or common wool or wool blended yarns are used as warp yarns, the composite white yarns obtained in S1 or S2 are used as one of weft yarns, and the composite white yarns and the warp yarns are woven in at intervals;
s5: dyeing and finishing; presetting at 160-180 ℃, and controlling the fabric width to be not less than 152 cm; then continuous boiling is carried out for not less than 20min at the temperature of not less than 40 ℃ and the speed of not less than 200 r/min; (ii) a Decating pressure is not less than 0.6g, and cooling time is not less than 90 s.
2. The method of claim 1, wherein: the functional master batch comprises an antibacterial master batch, an antistatic master batch, an anti-penetration master batch and a quick-drying master batch.
3. The method of claim 1, wherein: the fineness of the PET and PBT polyester composite filament is within the range of 33dtex-330dtex, and the strength is not lower than 2.2 cN/dtex.
4. The method of claim 1, wherein: the proportion of the composite white silk and wool or wool blended spun yarn in the S3 is 80/20-10/90.
5. The method of claim 1, wherein: the weaving proportion of the S4 is 1: 5-5: 1, the proportion range of the woven upper machine width to the finished product width is 1.1-1.5.
6. The method of claim 1, wherein: before the decating process in S5, shaping is needed, wherein the shaping temperature is not lower than 160 ℃.
7. An elastic wool fabric of functional polyester composite filament, which is characterized in that: the preparation method of any one of claims 1 to 6, which comprises the step of twisting the functional PET and PBT polyester composite filament and wool or wool blended spun yarn by means of Sirofil spinning, core covering, doubling and the like to form the composite yarn as warp or weft, and the step of weaving to form the grey cloth.
CN202111318568.4A 2021-11-09 2021-11-09 Elastic wool fabric of functional polyester composite filament and preparation method thereof Pending CN113913994A (en)

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Application publication date: 20220111