CN113876604B - 高结膏温度的氨基酸洁面膏及其制备方法 - Google Patents
高结膏温度的氨基酸洁面膏及其制备方法 Download PDFInfo
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Abstract
本发明属于化妆品领域,具体涉及一种高结膏温度的氨基酸洁面膏及其制备方法。包括下述组分:A相:EDTA二钠,甘油,椰油酰甘氨酸钾,羟苯甲酯,月桂酰两性基乙酸钠,甘油硬脂酸酯SE,月桂醇磺基琥珀酸酯二钠,去离子水补足余量;B相:丙烯酸(酯)类共聚物,柠檬酸;C相:苯氧乙醇,乙基己基甘油;D相:多种植物提取物;以上原料的重量百分比之和为100%。本发明外观细腻有珠光,温和无刺激,泡沫细腻易冲洗,洗后无残留,避免残留物对皮肤造成伤害,敏感肌亦可长期使用。制备过程中产品结膏温度在55℃左右,耐热稳定性好,外观细腻有珠光。
Description
技术领域
本发明属于化妆品领域,具体涉及一种高结膏温度的氨基酸洁面膏及其制备方法。
背景技术
随着经济的发展,人们的生活节奏加快,加上长期饱受雾霾等环境污染,敏感肌肤或者易于过敏的人群占比逐年升高,消费者越加强烈的选择温和的产品。洁面作为一款清洁产品是护肤过程中的第一步,过度清洁会导致皮肤的屏障功能受损,清洁不彻底,皮肤残留的污垢以及表活残留会影响后续产品的使用。
近几年氨基酸洁面成为洁面市场中的一大主流,其产品成分安全温和、呈弱酸性、去污能力适中、刺激性低受到广大消费者的欢迎。然而氨基酸洁面膏普遍存在产品稳定性较差,制备过程中结膏温度较低等技术难题。主要体现为:产品粘度以及膏体软硬度会随着温度变化较大,甚至会有出水、析出多元醇;受外部环境的影响,结晶型氨基酸洁面极易产生颗粒感使产品外观变粗,甚至析出结晶影响产品使用;产品制备过程中结膏温度一般在40℃左右,普遍较低。而低结膏温度导致产品在外界温度较高时存在较大的稳定性问题,甚至产生分层现象。
发明内容
本发明的目的在于克服现有技术中的缺点,提供一种高结膏温度的氨基酸洁面膏及其制备方法。
为实现上述目的,本发明采用的技术方案为:
一种高结膏温度的氨基酸洁面膏,包括下述组分:
A相:EDTA二钠:0.05-0.1%,甘油:30.0-40.0%,椰油酰甘氨酸钾:20.0-30.0%,羟苯甲酯:0.05-0.1%,月桂酰两性基乙酸钠:5.0-10.0%,甘油硬脂酸酯SE:0.8-1.5%,月桂醇磺基琥珀酸酯二钠:1.0-5.0%,去离子水补足余量;
B相:丙烯酸(酯)类共聚物:1.0-3.0%,柠檬酸2.0-2.3%;
C相:苯氧乙醇:0.3-0.6%,乙基己基甘油:0.1-0.5%;
D相:多种植物提取物:0.1-1.0%;
以上原料的重量百分比之和为100%。
优选的,A相:去离子水14.9%,EDTA二钠:0.1%,甘油:40.0%,椰油酰甘氨酸钾:30.0%,羟苯甲酯:0.1%,月桂酰两性基乙酸钠:5.0%,甘油硬脂酸酯SE:1.5%,月桂醇磺基琥珀酸酯二钠:1.0%;
B相:丙烯酸(酯)类共聚物:3.0%,柠檬酸:2.3%;
C相:苯氧乙醇:0.6%,乙基己基甘油:0.5%;
D相:多种植物提取物:1.0%;
以上各原料的重量百分比之和为100%。
本发明还包括一种所述的高结膏温度的氨基酸洁面膏的方法,包括下述步骤:
(1)将组分量去离子水、EDTA二钠、甘油、羟苯甲酯加入乳化锅中,搅拌转速30rpm,搅拌均匀后加入组分量椰油酰甘氨酸钾、月桂酰两性基乙酸钠、甘油硬脂酸酯SE、月桂醇磺基琥珀酸酯二钠,搅拌均匀后将乳化锅升温至85-90℃,保温搅拌20min,抽真空消泡;
(2)用5份去离子水溶解柠檬酸,待乳化锅中料全部溶解完全至透明后,调整搅拌速度至20rpm,保持温度不变在搅拌状态下加入溶解好的柠檬酸,搅拌均匀;
(3)用5份去离子水将丙烯酸(酯)类共聚物分散均匀,待乳化锅中料体透明均一后,将转速调整至15rpm,在搅拌状态下继续加入分散好的丙烯酸(酯)类共聚物,保温搅拌5min后抽真空降温;
(4)当温度降至65℃时,加入组分量苯氧乙醇、乙基己基甘油,搅拌均匀;
(5)当温度降至45℃时,加入组分量植物提取物,继续搅拌10-15min,搅拌均匀;
(6)40℃出料送检,各项指标合格后进行灌装。
与现有技术相比,本发明的有益效果是:
本申请通过选择特定配比的椰油酰甘氨酸钾、甘油、水,三者相互配合,搭配助乳化剂甘油硬脂酸酯SE在较高温度60℃左右开始结膏形成一个的氨基酸体系,最终使得洁面膏稳定性好,软硬度适中。
以椰油酰甘氨酸钾作为氨基酸表面活性剂,以月桂酰两性基乙酸钠、月桂醇磺基琥珀酸酯二钠为辅助表面活性剂,多种表面活性剂互相搭配,使得到的氨基酸洁面膏泡沫更加细腻丰富,膏体更加稳定。
通过各原料组分的合理选择以及配比特别是控制多元醇的种类以及配比使得本发明的洁面膏的结膏温度提高至60℃左右,延长结膏过程的时间,不仅提高了洁面膏的耐热稳定性同时让膏体更加细腻均匀,银白色珠光明显。
所述甘油的用量为30.0-40.0%,甘油作保湿剂的同时还能增强体系的防腐效果,搭配少量的尼泊金酯、苯氧乙醇、乙基己基甘油作为防腐体系,抗菌谱宽且安全性高。
总之,本发明一种高结膏温度氨基酸洁面膏,产品由氨基酸表面活性剂结晶制备而成,外观细腻有珠光,pH值6.0-6.5为弱酸性,温和无刺激,泡沫细腻易冲洗,洗后无残留,避免残留物对皮肤造成伤害,敏感肌亦可长期使用。制备过程中产品结膏温度在55℃左右,耐热稳定性好,外观细腻有珠光。
具体实施方式
为了使本技术领域的技术人员更好地理解本发明的技术方案,下面结合实施例对本发明作进一步的详细说明。
实施例1:一种高结膏温度的氨基酸洁面膏,其配方重量百分配比如下:
A相:去离子水30.6%,EDTA二钠:0.05%,甘油:30.0%,椰油酰甘氨酸钾:20.0%,羟苯甲酯:0.05%,月桂酰两性基乙酸钠:10.0%,甘油硬脂酸酯SE:0.8%,月桂醇磺基琥珀酸酯二钠:5.0%;
B相:丙烯酸(酯)类共聚物:1.0%,柠檬酸2.0%;
C相:苯氧乙醇:0.3%,乙基己基甘油:0.1%;
D相:多种植物提取物:0.1%;
以上各原料的重量百分比之和为100%。
其制备方法按以下步骤:
(1)将去离子水、EDTA二钠、甘油、羟苯甲酯加入乳化锅中,搅拌转速30rpm,搅拌均匀后加入椰油酰甘氨酸钾、月桂酰两性基乙酸钠、甘油硬脂酸酯SE、月桂醇磺基琥珀酸酯二钠,搅拌均匀后将乳化锅升温至85-90℃,保温搅拌20min,抽真空消泡;
(2)用5份去离子水溶解柠檬酸,待乳化锅中料全部溶解完全至透明后,调整搅拌速度至20rpm,保持温度不变在搅拌状态下加入溶解好的柠檬酸,搅拌均匀;
(3)用5份去离子水将丙烯酸(酯)类共聚物分散均匀,待乳化锅中料体透明均一后,将转速调整至15rpm,在搅拌状态下继续加入分散好的丙烯酸(酯)类共聚物,保温搅拌5min后抽真空降温;
(4)当温度降至65℃时,加入苯氧乙醇、乙基己基甘油,搅拌均匀;
(5)当温度降至45℃时,加入植物提取物,继续搅拌10-15min,搅拌均匀;
(6)40℃出料送检,各项指标合格后进行灌装。
实施例2:一种高结膏温度的氨基酸洁面膏,其配方重量百分配比如下:
A相:去离子水14.9%,EDTA二钠:0.1%,甘油:40.0%,椰油酰甘氨酸钾:30.0%,羟苯甲酯:0.1%,月桂酰两性基乙酸钠:5.0%,甘油硬脂酸酯SE:1.5%,月桂醇磺基琥珀酸酯二钠:1.0%;
B相:丙烯酸(酯)类共聚物:3.0%,柠檬酸:2.3%;
C相:苯氧乙醇:0.6%,乙基己基甘油:0.5%;
D相:多种植物提取物:1.0%;
以上各原料的重量百分比之和为100%。
其制备方法按以下步骤:
(1)将去离子水、EDTA二钠、甘油、羟苯甲酯加入乳化锅中,搅拌转速30rpm,搅拌均匀后加入椰油酰甘氨酸钾、月桂酰两性基乙酸钠、甘油硬脂酸酯SE、月桂醇磺基琥珀酸酯二钠,搅拌均匀后将乳化锅升温至85-90℃,保温搅拌20min,抽真空消泡;
(2)用5份去离子水溶解柠檬酸,待乳化锅中料全部溶解完全至透明后,调整搅拌速度至20rpm,保持温度不变在搅拌状态下加入溶解好的柠檬酸,搅拌均匀;
(3)用5份去离子水将丙烯酸(酯)类共聚物分散均匀,待乳化锅中料体透明均一后,将转速调整至15rpm,在搅拌状态下继续加入分散好的丙烯酸(酯)类共聚物,保温搅拌5min后抽真空降温;
(4)当温度降至65℃时,加入苯氧乙醇、乙基己基甘油,搅拌均匀;
(5)当温度降至45℃时,加入植物提取物,继续搅拌10-15min,搅拌均匀;
(6)40℃出料送检,各项指标合格后进行灌装。
实施例3:一种高结膏温度的氨基酸洁面膏,其配方重量百分配比如下:
A相:去离子水22.76%,EDTA二钠:0.07%,甘油:35.0%,椰油酰甘氨酸钾:25.0%,羟苯甲酯:0.07%,月桂酰两性基乙酸钠:8%,甘油硬脂酸酯SE:1.2%,月桂醇磺基琥珀酸酯二钠:3.0%;
B相:丙烯酸(酯)类共聚物:1.5%,柠檬酸2.15%;
C相:苯氧乙醇:0.45%,乙基己基甘油:0.3%;
D相:多种植物提取物:0.5%;
以上原料的重量百分比之和为100%。
其制备方法按以下步骤:
(1)将去离子水、EDTA二钠、甘油、羟苯甲酯加入乳化锅中,搅拌转速30rpm,搅拌均匀后加入椰油酰甘氨酸钾、月桂酰两性基乙酸钠、甘油硬脂酸酯SE、月桂醇磺基琥珀酸酯二钠,搅拌均匀后将乳化锅升温至85-90℃,保温搅拌20min,抽真空消泡;
(2)用5份去离子水溶解柠檬酸,待乳化锅中料全部溶解完全至透明后,调整搅拌速度至20rpm,保持温度不变在搅拌状态下加入溶解好的柠檬酸,搅拌均匀;
(3)用5份去离子水将丙烯酸(酯)类共聚物分散均匀,待乳化锅中料体透明均一后,将转速调整至15rpm,在搅拌状态下继续加入分散好的丙烯酸(酯)类共聚物,保温搅拌5min后抽真空降温;
(4)当温度降至65℃时,加入苯氧乙醇、乙基己基甘油,搅拌均匀;
(5)当温度降至45℃时,加入植物提取物,继续搅拌10-15min,搅拌均匀;
(6)40℃出料送检,各项指标合格后进行灌装。
表1示出不同实施例以及对比例的结果。
表1
为了证明本发明得到的洁面膏的性能,对上述实施例和对比例中的洁面膏产品进行性能测试:
取样品在室温和非阳光直射下目测样品外观是否细腻、是膏体状态还是流动的液体态。
pH的测量:pH测试采用的是稀释法。样品的稀释:准确称取5.0g样品于小烧杯中,加入去离子水至50.0g,搅拌至分散均匀,然后用校正后的pH计测量。
粘度:25℃,24h后,NDJ-79型8号转子测量。
稳定性测试:
(1)耐热测试:将样品置于48℃的生化培养箱中,30天后取出立即观察是否有分层现象或明显性状差异。样品恢复室温后,观察膏体中是否有泛粗、析出颗粒或明显性状差异。
(2)耐寒测试:将样品置于-15℃的冰箱中30天后取出,等样品恢复室温后观察膏体是否变硬、难挤出以及是否有颗粒析出或明显性状差异。
泡沫高度测试:
称取实验样品5.0g,加蒸馏水900mL溶解,再加入1500mg/kg硬水100mL,将溶液置于(40±0.5)℃恒温水浴锅中陈化,从把水溶液陈化开始总时间30min内,采用罗氏泡沫仪进行发泡力测试并记录读数。
从上表中可以看出,采用本发明中的主表活椰油酰甘氨酸钾(95%含量)、甘油、去离子水三者的比例不同对结膏点、最终产品的外观软硬度以及稳定性均有不同的影响。其中当水:椰油酰甘氨酸钾:甘油比例接近1:1:1.4时制得的产品,比市售同类氨基酸洁面产品S1-S2具有更加丰富的泡沫、更好的外观和更好的稳定性。说明采用本发明的技术方案制备得到的洁面膏性能更优异。以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。
Claims (1)
1.一种高结膏温度的氨基酸洁面膏,其特征在于,配方重量百分配比如下:
A相:去离子水14.9%,EDTA二钠:0.1%,甘油:40.0%,椰油酰甘氨酸钾:30.0%,羟苯甲酯:0.1%,月桂酰两性基乙酸钠:5.0%,甘油硬脂酸酯 SE:1.5%,月桂醇磺基琥珀酸酯二钠:1.0%;
B相:丙烯酸(酯)类共聚物:3.0%,柠檬酸:2.3%;
C相:苯氧乙醇:0.6%,乙基己基甘油: 0.5%;
D相:多种植物提取物:1.0%;
制备方法按以下步骤:
(1)将去离子水、EDTA二钠、甘油、羟苯甲酯加入乳化锅中,搅拌转速30rpm,搅拌均匀后加入椰油酰甘氨酸钾、月桂酰两性基乙酸钠、甘油硬脂酸酯 SE、月桂醇磺基琥珀酸酯二钠,搅拌均匀后将乳化锅升温至85-90℃,保温搅拌20min,抽真空消泡;
(2)用5份去离子水溶解柠檬酸,待乳化锅中料全部溶解完全至透明后,调整搅拌速度至20rpm,保持温度不变在搅拌状态下加入溶解好的柠檬酸,搅拌均匀;
(3)用5份去离子水将丙烯酸(酯)类共聚物分散均匀,待乳化锅中料体透明均一后,将转速调整至15rpm,在搅拌状态下继续加入分散好的丙烯酸(酯)类共聚物,保温搅拌5min后抽真空降温;
(4)当温度降至65℃时,加入苯氧乙醇、乙基己基甘油,搅拌均匀;
(5)当温度降至45℃时,加入植物提取物,继续搅拌10-15min,搅拌均匀;
(6)40℃出料送检,各项指标合格后进行灌装。
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