CN113860947A - Liquid boron-molybdenum fertilizer and preparation method thereof - Google Patents
Liquid boron-molybdenum fertilizer and preparation method thereof Download PDFInfo
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- CN113860947A CN113860947A CN202111155212.3A CN202111155212A CN113860947A CN 113860947 A CN113860947 A CN 113860947A CN 202111155212 A CN202111155212 A CN 202111155212A CN 113860947 A CN113860947 A CN 113860947A
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- fertilizer
- boron
- molybdenum
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 63
- 239000007788 liquid Substances 0.000 title claims abstract description 37
- LGLOITKZTDVGOE-UHFFFAOYSA-N boranylidynemolybdenum Chemical compound [Mo]#B LGLOITKZTDVGOE-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 46
- 229910052796 boron Inorganic materials 0.000 claims abstract description 46
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 28
- 239000011733 molybdenum Substances 0.000 claims abstract description 28
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 13
- 239000006184 cosolvent Substances 0.000 claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000005648 plant growth regulator Substances 0.000 claims abstract description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 6
- 230000000694 effects Effects 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- JLIDBLDQVAYHNE-YKALOCIXSA-N (+)-Abscisic acid Chemical compound OC(=O)/C=C(/C)\C=C\[C@@]1(O)C(C)=CC(=O)CC1(C)C JLIDBLDQVAYHNE-YKALOCIXSA-N 0.000 claims description 4
- OORIKNJWZHTXDC-UHFFFAOYSA-N CCCC(CC)C(CC)(C(=O)OCC)N Chemical compound CCCC(CC)C(CC)(C(=O)OCC)N OORIKNJWZHTXDC-UHFFFAOYSA-N 0.000 claims description 4
- ZNJFBWYDHIGLCU-HWKXXFMVSA-N jasmonic acid Chemical compound CC\C=C/C[C@@H]1[C@@H](CC(O)=O)CCC1=O ZNJFBWYDHIGLCU-HWKXXFMVSA-N 0.000 claims description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229930192334 Auxin Natural products 0.000 claims description 3
- 239000002363 auxin Substances 0.000 claims description 3
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 claims description 3
- RMOGWMIKYWRTKW-UONOGXRCSA-N (S,S)-paclobutrazol Chemical compound C([C@@H]([C@@H](O)C(C)(C)C)N1N=CN=C1)C1=CC=C(Cl)C=C1 RMOGWMIKYWRTKW-UONOGXRCSA-N 0.000 claims description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- IXVMHGVQKLDRKH-VRESXRICSA-N Brassinolide Natural products O=C1OC[C@@H]2[C@@H]3[C@@](C)([C@H]([C@@H]([C@@H](O)[C@H](O)[C@H](C(C)C)C)C)CC3)CC[C@@H]2[C@]2(C)[C@@H]1C[C@H](O)[C@H](O)C2 IXVMHGVQKLDRKH-VRESXRICSA-N 0.000 claims description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 2
- 239000005979 Forchlorfenuron Substances 0.000 claims description 2
- 229930191978 Gibberellin Natural products 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 239000005985 Paclobutrazol Substances 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 2
- 229940010552 ammonium molybdate Drugs 0.000 claims description 2
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 2
- 239000011609 ammonium molybdate Substances 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- IXVMHGVQKLDRKH-KNBKMWSGSA-N brassinolide Chemical compound C1OC(=O)[C@H]2C[C@H](O)[C@H](O)C[C@]2(C)[C@H]2CC[C@]3(C)[C@@H]([C@H](C)[C@@H](O)[C@H](O)[C@@H](C)C(C)C)CC[C@H]3[C@@H]21 IXVMHGVQKLDRKH-KNBKMWSGSA-N 0.000 claims description 2
- 230000009920 chelation Effects 0.000 claims description 2
- -1 compound sodium nitrophenolate Chemical class 0.000 claims description 2
- 239000004062 cytokinin Substances 0.000 claims description 2
- UQHKFADEQIVWID-UHFFFAOYSA-N cytokinin Natural products C1=NC=2C(NCC=C(CO)C)=NC=NC=2N1C1CC(O)C(CO)O1 UQHKFADEQIVWID-UHFFFAOYSA-N 0.000 claims description 2
- FCRACOPGPMPSHN-UHFFFAOYSA-N desoxyabscisic acid Natural products OC(=O)C=C(C)C=CC1C(C)=CC(=O)CC1(C)C FCRACOPGPMPSHN-UHFFFAOYSA-N 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- GPXLRLUVLMHHIK-UHFFFAOYSA-N forchlorfenuron Chemical compound C1=NC(Cl)=CC(NC(=O)NC=2C=CC=CC=2)=C1 GPXLRLUVLMHHIK-UHFFFAOYSA-N 0.000 claims description 2
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 claims description 2
- 239000003448 gibberellin Substances 0.000 claims description 2
- ZNJFBWYDHIGLCU-UHFFFAOYSA-N jasmonic acid Natural products CCC=CCC1C(CC(O)=O)CCC1=O ZNJFBWYDHIGLCU-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 claims description 2
- ZUHZZVMEUAUWHY-UHFFFAOYSA-N n,n-dimethylpropan-1-amine Chemical compound CCCN(C)C ZUHZZVMEUAUWHY-UHFFFAOYSA-N 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 229920000768 polyamine Polymers 0.000 claims description 2
- 229960004889 salicylic acid Drugs 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- NWZBFJYXRGSRGD-UHFFFAOYSA-M sodium;octadecyl sulfate Chemical group [Na+].CCCCCCCCCCCCCCCCCCOS([O-])(=O)=O NWZBFJYXRGSRGD-UHFFFAOYSA-M 0.000 claims description 2
- LEZAYTDLNNEFJT-UHFFFAOYSA-N tetracosasodium octaborate tetrahydrate Chemical compound O.O.O.O.[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] LEZAYTDLNNEFJT-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000003756 stirring Methods 0.000 abstract description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 230000002950 deficient Effects 0.000 description 5
- 230000012010 growth Effects 0.000 description 5
- 230000009471 action Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000004720 fertilization Effects 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 241000589151 Azotobacter Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 108090000913 Nitrate Reductases Proteins 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 230000006819 RNA synthesis Effects 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000023852 carbohydrate metabolic process Effects 0.000 description 1
- 235000021256 carbohydrate metabolism Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000024245 cell differentiation Effects 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 210000004602 germ cell Anatomy 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 208000006278 hypochromic anemia Diseases 0.000 description 1
- 210000001161 mammalian embryo Anatomy 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000001338 necrotic effect Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 230000001850 reproductive effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 210000002262 tip cell Anatomy 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/50—Surfactants; Emulsifiers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
The invention relates to the technical field of fertilizers and discloses a liquid boron-molybdenum fertilizer and a preparation method thereof, wherein the liquid boron-molybdenum fertilizer comprises 44-55 parts of boron fertilizer, 10-15 parts of molybdenum fertilizer, 35-40 parts of organic compound, 0.1-1 part of plant growth regulator, 0.1-2 parts of surfactant, 0.1-2 parts of cosolvent and 0.1-2 parts of antifreezing agent, and the preparation method comprises the steps of stirring the auxiliary agents such as cosolvent, surfactant and antifreezing agent together to prepare a clear liquid type fertilizer; the liquid boron-molybdenum fertilizer and the preparation method thereof have the advantages that the boron content of the liquid boron-molybdenum fertilizer is high, the water solubility is excellent, and the use is simple and convenient.
Description
Technical Field
The invention relates to the technical field of fertilizers, in particular to a liquid boron-molybdenum fertilizer and a preparation method thereof.
Background
Boron has various effects on crops, and the boron respectively comprises the following components: (1) boron can promote the growth of crop roots, and when boron is deficient, the cell differentiation and elongation of root tip meristems are influenced, and root tip cells are lignified; (2) boron plays an important role in crop photosynthesis-carbohydrate distribution and operation, and although the action mechanism is still unclear, boron is deficient, carbohydrate metabolism in crops is disordered, and a large amount of carbohydrates are accumulated in leaves; in addition, when the boron is deficient, the conduction tissues of the tender parts of the petioles and the stems are damaged, and the growing points die; (3) boron plays a particularly important role in the formation of the reproductive organs of crops and in flowering and fruiting processes, and is essential during pollen differentiation and pollen germ cell division, during fertilization and during development of embryo and endosperm after fertilization, and if boron is deficient, a large number of flowers and fruits are dropped or flowers are not fruited; (4) boron has great influence on the growth of the root nodules of the leguminous crops, and the root nodules are poor in development and even lose nitrogen fixation capacity in the absence of boron; (5) boron can be combined with polysaccharide components of plant cells to improve the stability of cell walls; boron is related to synthesis or utilization of auxin in plants, and particularly can promote rapid growth of meristems, and when boron is lacked, root tips and stem tips are firstly damaged, and growing points are necrotic; boron also affects ribonucleic acid synthesis, pollen tube germination.
The conventional boron fertilizer in agricultural production has the following problems: firstly, boron fertilizer has poor solubility, and is inconvenient to apply due to heating or stirring during dissolution and dilution; in addition, the boron fertilizer is easy to recrystallize or be fixed by soil, so that the boron fertilizer is difficult to absorb and utilize by crops, and the boron element in the soil is accumulated.
Molybdenum is a trace element, is a constituent element of crop nitrate reductase, participates in the reduction process of nitric acid in crops, promotes the metabolism of crop nitrogen, and is beneficial to the formation of protein. Molybdenum is a component element of azotase and has good influence on the nitrogen fixation effect of azotobacter and rhizobia. The application of a proper amount of molybdenum fertilizer can improve the nitrogen fixation amount by 5-7 times. Meanwhile, molybdenum can reduce the toxicity of excessive manganese, copper, zinc and other elements to crops, such as leaf chlorosis and the like. When molybdenum is deficient, the plant is short and small, the leaf color is faded yellow, and the plant gradually withers and dies.
At present, fertilizers containing boron and molybdenum elements at the same time have been developed in the agricultural field, but the contents of boron and molybdenum in the fertilizers are relatively low, and the requirements of crops on growth cannot be fully met. In addition, the device has the defects of inconvenient use, instability and the like.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides a liquid boron-molybdenum fertilizer and a preparation method thereof, which can solve the problems that fertilizers containing boron and molybdenum elements at the same time are developed in the field of agriculture at present, but the contents of boron and molybdenum in the fertilizers are relatively low and the growth requirements of crops cannot be fully met; the invention effectively solves the problems in the prior art by arranging the liquid boron-molybdenum fertilizer and the preparation method thereof.
In order to achieve the purposes of the liquid boron-molybdenum fertilizer and the preparation method thereof, the invention provides the following technical scheme: a liquid boron-molybdenum fertilizer comprises 44-55 parts of boron fertilizer, 10-15 parts of molybdenum fertilizer, 35-40 parts of organic compound, 0.1-1 part of plant growth regulator, 0.1-2 parts of surfactant, 0.1-2 parts of cosolvent and 0.1-2 parts of antifreezing agent.
Preferably, the boric fertilizer is one or more of sodium octaborate tetrahydrate, sodium polyborate, borax, boric acid or liquid boron.
Preferably, the molybdenum fertilizer is one or more of molybdic acid or ammonium molybdate.
Preferably, the organic compound is one of monoethanolamine, diethanolamine, triethanolamine, ethylenediamine, diethylenetriamine, dimethylpropylamine, ethylene glycol, glycerol, and ethylenediaminetetraacetic acid, or a mixture of two or more thereof blended in an arbitrary ratio.
Preferably, the plant growth regulator is one or more of diethyl aminoethyl hexanoate (DA-6), forchlorfenuron, compound sodium nitrophenolate, auxin, gibberellin, ethylene, cytokinin, abscisic acid, brassinolide, salicylic acid, jasmonic acid, paclobutrazol and polyamine.
Preferably, the surfactant is sodium octadecyl sulfate C18H37SO4Na, sodium stearate C17H35One or more of COONa.
Further, the preparation method of the liquid boron-molybdenum fertilizer comprises the following steps:
firstly, auxiliary agents such as a cosolvent, a surfactant, an antifreezing agent and the like are stirred together to prepare a clear liquid type fertilizer;
and secondly, chelating boron and molybdenum together in a specific ratio in the presence of an organic compound by a high-activity organic carbon chelating technology to prepare a finished product.
Preferably, boron and molybdenum are chelated together in a specific ratio, and the chelation reaction temperature is 55 ℃ to 65 ℃.
Compared with the prior art, the invention provides a liquid boron-molybdenum fertilizer and a preparation method thereof, and the liquid boron-molybdenum fertilizer has the following beneficial effects:
the liquid boron-molybdenum fertilizer has high boron content, excellent water solubility and simple and convenient use, is a preparation combined with boron and molybdenum, has good influence on the nitrogen fixation effect of nitrogen-fixing bacteria and rhizobia, and has more obvious combined use effect.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
a liquid boron-molybdenum fertilizer comprises 44 parts of boron fertilizer, 10 parts of molybdenum fertilizer, 35 parts of organic compound, 0.1 part of plant growth regulator, 0.1 part of surfactant, 0.1 part of cosolvent and 0.1 part of antifreeze.
In conclusion, the preparation method comprises the following steps:
firstly, auxiliary agents such as a cosolvent, a surfactant, an antifreezing agent and the like are stirred together to prepare a clear liquid type fertilizer;
secondly, chelating boron and molybdenum together according to a specific ratio by a high-activity organic carbon chelating technology under the condition of the existence of an organic compound and at the reaction temperature of 55 ℃ to prepare a finished product.
Example two:
a liquid boron-molybdenum fertilizer comprises 50 parts of boron fertilizer, 12 parts of molybdenum fertilizer, 38 parts of organic compound, 0.5 part of plant growth regulator, 0.5 part of surfactant, 1 part of cosolvent and 1 part of antifreeze.
In conclusion, the preparation method comprises the following steps:
firstly, auxiliary agents such as a cosolvent, a surfactant, an antifreezing agent and the like are stirred together to prepare a clear liquid type fertilizer;
secondly, chelating boron and molybdenum together according to a specific ratio by a high-activity organic carbon chelating technology under the condition of organic compound existence and the reaction temperature of 60 ℃ to prepare a finished product.
Example three:
a liquid boron-molybdenum fertilizer comprises 55 parts of boron fertilizer, 15 parts of molybdenum fertilizer, 40 parts of organic compound, 1 part of plant growth regulator, 2 parts of surfactant, 2 parts of cosolvent and 2 parts of antifreezing agent.
In conclusion, the preparation method comprises the following steps:
firstly, auxiliary agents such as a cosolvent, a surfactant, an antifreezing agent and the like are stirred together to prepare a clear liquid type fertilizer;
secondly, chelating boron and molybdenum together according to a specific ratio by a high-activity organic carbon chelating technology in the presence of an organic compound at a reaction temperature of 60 ℃ to prepare a finished product
The liquid boron-molybdenum fertilizer and the preparation method thereof have high boron content, excellent water solubility and simple and convenient use, the liquid boron-molybdenum fertilizer is a preparation combining boron and molybdenum, and boron and molybdenum have good influence on the nitrogen fixation effect of nitrogen-fixing bacteria and rhizobia, and the combined use effect of the boron and the molybdenum is more obvious.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (8)
1. A liquid boron-molybdenum fertilizer is characterized in that: the fertilizer comprises 44-55 parts of boron fertilizer, 10-15 parts of molybdenum fertilizer, 35-40 parts of organic compound, 0.1-1 part of plant growth regulator, 0.1-2 parts of surfactant, 0.1-2 parts of cosolvent and 0.1-2 parts of antifreezing agent.
2. The liquid boron-molybdenum fertilizer of claim 1, wherein: the boric fertilizer is one or more of sodium octaborate tetrahydrate, sodium polyborate, borax, boric acid or liquid boron.
3. The liquid boron-molybdenum fertilizer of claim 1, wherein: the molybdenum fertilizer is one or more of molybdic acid or ammonium molybdate.
4. The liquid boron-molybdenum fertilizer of claim 1, wherein: the organic compound is one or a mixture of more than two of monoethanolamine, diethanolamine, triethanolamine, ethylenediamine, diethylenetriamine, dimethylpropylamine, ethylene glycol, glycerol and ethylenediamine tetraacetic acid which are mixed according to any proportion.
5. The liquid boron-molybdenum fertilizer of claim 1, wherein: the plant growth regulator is one or more of diethyl aminoethyl hexanoate (DA-6), forchlorfenuron, compound sodium nitrophenolate, auxin, gibberellin, ethylene, cytokinin, abscisic acid, brassinolide, salicylic acid, jasmonic acid, paclobutrazol and polyamine.
6. The liquid boron-molybdenum fertilizer of claim 1, wherein: the surfactant is sodium octadecyl sulfate C18H37SO4Na, sodium stearate C17H35One or more of COONa.
7. A preparation method of liquid boron-molybdenum fertilizer is characterized by comprising the following steps: the liquid boron-molybdenum fertilizer based on claims 1-6, wherein the preparation method comprises the following steps:
firstly, auxiliary agents such as a cosolvent, a surfactant, an antifreezing agent and the like are stirred together to prepare a clear liquid type fertilizer;
and secondly, chelating boron and molybdenum together in a specific ratio in the presence of an organic compound by a high-activity organic carbon chelating technology to prepare a finished product.
8. The method for preparing a liquid boron-molybdenum fertilizer according to the second step of claim 7, wherein the method comprises the following steps: boron and molybdenum are chelated together according to a specific proportion, and the chelation reaction temperature is 55-65 ℃.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993258A (en) * | 2009-08-27 | 2011-03-30 | 张小川 | Quick-acting organic liquid-molybdenum-boron fertilizer and preparation method thereof |
| CN102603400A (en) * | 2012-03-06 | 2012-07-25 | 北京雷力农用化学有限公司 | Liquid boron-molybdenum fertilizer and preparation method thereof |
| CN111470902A (en) * | 2020-04-17 | 2020-07-31 | 华南农业大学 | High-activity organic calcium boron liquid compound fertilizer and preparation method and application thereof |
-
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993258A (en) * | 2009-08-27 | 2011-03-30 | 张小川 | Quick-acting organic liquid-molybdenum-boron fertilizer and preparation method thereof |
| CN102603400A (en) * | 2012-03-06 | 2012-07-25 | 北京雷力农用化学有限公司 | Liquid boron-molybdenum fertilizer and preparation method thereof |
| CN111470902A (en) * | 2020-04-17 | 2020-07-31 | 华南农业大学 | High-activity organic calcium boron liquid compound fertilizer and preparation method and application thereof |
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